Exp 6

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Name ...................................................... Code .................................. Section .................


Group No. ................. Date ....................................... Time ……………………………

Report Data

Conc. of HCl Area of Zn Time: t rate


Section (mol/L) (cm2) (s) (mol H2/ s)
1 0.5 24
2 1.0 24
3 0.5 48

1. The reaction of hydrogen gas

………… + ……….. ……….. + …………

2. Determine the rate


Section 1. A 3 cm 4 cm of zinc plate with 24 cm2 surface area reacts with 0.5 M
HCl solution
6mL 1molH 2
rate 1 =
.........s 24,862mL

rate 1 = .................................mol H 2 / s

Section 2. A 3 cm 4 cm of zinc plate with 24 cm2 surface area reacts with 1.0 M
HCl solution
6 mL 1molH 2
rate2 = ×
.........s 24,862mL

rate2 = .................................mol H 2 / s

Fundamentals of Chemistry for Engineers


87

Section 3. Two of 3 cm 4 cm of zinc plate with 48 cm2 surface area reacts with
0.5 M HCl solution
6mL 1molH 2
rate 3 = ×
.........s 24,862mL

rate 3 = .................................mol H 2 / s

3. Calculate order of reaction with HCl (m)


rate1 = ………………………. mol H2/s

rate2 = ………………………. mol H2/s

rate2 k(1) m (24) n ...................


= m n
= .
rate1 k(0.5) (24) .....................

m
1
= ……………………………….
0.5

2m = ……………………………….

m = ……………………………….

4. Calculate order of reaction with zinc ( n)


rate 1 = ……………........…… mol H2/s

rate 3 = ………………………. mol H2/s

rate3 k(0.5) m (48) n .......... ..........


= m n
=
rate1 k(0.5) (24) .......... ..........

Chemical Kinetic
88

n
48
= ……………………………….
24

2n = ……………………………….

n = ………………………………...

6. Calculate k of rate 1, 2 and 3


rate
k =
Cm n
HCl C Zn

..........................
k1 = =…………………… for rate 1.
(.......) (........)(.......) (........)

..........................
k2 = =……………………for rate 2.
(.......) (........)(.......) (........)

..........................
k3 = =…………………… for rate 3.
(.......) (........)(.......) (........)

7. Calculate average of k
k1 +k 2 +k 3
kavg =
3
...............................+.................................+...........................
=
3

= ………………………..

Fundamentals of Chemistry for Engineers


89

8. Write an equation for the rate of reaction rate = k C m n


HCl C Zn by replacing k, m and n

from the experiment

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Suggestion

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Chemical Kinetic

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