Gelest, Inc.

PHOSPHORUS

P
P C2H5O Si

Atomic number 15 Atomic weight 30.973762 CAS number 7723-14-0 Boiling point Melting point 280C (white) Specific gravity (20C) 1.82 (white) 2.25 - 2.69 (black) name
CH3

Crystal form Cubic Electrical resistivity (20C) 10 cm Enthalpy of melting 0.659kJ/mol Enthalpy of vaporization 56.5kJ/mol Ionization potential (spectral) 10.486eV (I) 19.725eV (II) (aqueous) MW

Oxidation states 0, 3, 5 Electronegativity, Pauling 2.1 Specific heat (25C) 0.18 cal/g K Thermal conductivity (25C) 0.236w/m K

bp/mm (mp)

D420

nD20

COMPOUNDS
P

CH2CH2SiCH2CH2 CH2 CH2 OC2H5 OC2H5

SIB1091.0 BIS(2-DIPHENYLPHOSPHINOETHYL)660.92 METHYLSILYLETHYLTRIETHOXYSILANE, mixed isomers C37H50O3P2Si2 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water HMIS: 2-2-1-X 1.0g/$174.00

1.07

1.5746

P(C6H5)2 Fe P(C6H5)2

OMFE022 1,1-BIS(DIPHENYLPHOSPHINO)554.56 (180-4)mp FERROCENE, dppf yellow-orange crystals C34H28FeP2 in combination w/PdCl2 cross-couples Grignards with aryl halides HYDROLYTIC SENSITIVITY: 8 reacts rapidly with moisture, water, protic solvents [12150-46-8] HMIS: 2-2-1-X 10g/$96.00 INNI023 1,3-BIS(DIPHENYLPHOSPHINO)PROPANE542.05 (210-220)mp NICKEL II CHLORIDE color: red C27H26Cl2P2Ni catalyst for the reaction of Grignards with enol ethers forming olefins1. 1. E. Wenkert et al, J. Am. Chem. Soc., 101, 2246, 1979 HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions [15629-92-2] HMIS: 3-1-0-X 5.0g/$74.00 SIB1852.8 BIS(TRIMETHYLSILYL)AMIDODIMETHYL221.43 55-60/0.4 PHOSPHINE C8H24NPSi2 intermediate for polydimethylphosphazenes1. 1. R. Neilson et al, Inorg. Chem., 21, 3568, 1982 [63744-11-6] HMIS: 3-2-1-X 10g/$140.00 OMPH011 t-BUTYLDICHLOROPHOSPHINE 159.00 146-8 (44-9)mp C4H9Cl2P HYDROLYTIC SENSITIVITY: 8 reacts rapidly with moisture, water, protic solvents 10g/$48.00 [25979-07-1] HMIS: 3-4-1-X OMPH012 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE BMIMPF6 C8H15N2F6P 284.18 (>340)-d. 1.396 viscosity, 20C: 280 cSt. soluble: methanol, THF, CH2Cl2 insoluble: water, hexane air and water stable immonium salt that is an ionic liquid1. ionic liquid reviewed2. 1. J. Fuller et al, Chem. Commun., 299, 1994 2. T. Walton, Chem. Rev., 99, 2071, 1999 HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions [174501-64-5] HMIS: 3-2-0-X 50g/$220.00 SID3385.0 DICYCLOHEXYLPHOSPHINOETHYLTRI- 388.60 ETHOXYSILANE C20H41O3PSi ligand for immobilization of precious metal catalytic complexes HYDROLYTIC SENSITIVITY: 7 Si-OR reacts slowly with water/moisture [55289-47-9] HMIS: 3-1-0-X 5.0g/$120.00
2005 Gelest, Inc.

C6H5 P

C6H5 Ni P Cl Cl C6H5

C6H5

(CH3)3Si N (CH3)3Si P

CH3 CH3

Cl tC4H9 P Cl

1.41

(H3 C N

CH2CH2CH2CH3 ) PF 6

PCH 2CH2Si(OC2H5)3

Gelest, Inc.
name
O C2H5O C2H5O PCH 2CH2Si(OC2H5)3
SID3412.0 DIETHYLPHOSPHATOETHYLTRIETHOXYSILANE, 95%
DIETHOXYPHOSPHORYLETHYLTRIETHOXYSILANE

MW

bp/mm (mp)

D420

nD20

328.41 141/2 flashpoint: 70C (158F)

1.03125 1.4216

C12H29O6PSi water-soluble silane; anti-pilling agent for textiles HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [757-44-8] TSCA HMIS: 3-2-1-X 25g/$48.00 OMPH027 DIETHYLPHOSPHITE C4H11O3P 138.11 50-1/2 flashpoint: 90C (194F) viscosity: 1.2 cSt. forms phosphonates by reaction with alkyl halogenides F&F 1, 251; 2, 132; 12, 187 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [762-04-9] TSCA HMIS: 2-2-1-X 25g/$14.00

100g/$156.00 1.072 1.4080

CH3 CH2O CH3 CH2O

O P H

100g/$45.00 1.059 1.4300

O CH3 CH2O

O CH3 PCH 2COSi CH3 CH3

CH3CH2O

SID3420.0 DIETHYL(TRIMETHYLSILOXYCARBONYL- 268.33 93/0.0005 METHYL)PHOSPHONATE, 95% flashpoint: 44C(112F) C9H21O5PSi forms , unsaturated acids from carbonyls1,2. 1. L. Lombardo et al, Synthesis, 131, 1978; F&F, 8, 171 2. J. Am. Chem Soc., 112, 701, 1990 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [66130-90-3] HMIS: 2-3-1-X 10g/$136.00 SID4245.0 DIMETHYL(TRIMETHYLSILYL)PHOSPHITE 182.23 73-7/56 C5H15O3PSi flashpoint: 38C(102F) HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [36198-87-5] HMIS: 3-2-1-X 10g/$45.00 OMPH025 DIPHENYLCHLOROPHOSPHINE C12H10ClP [1079-66-9] TSCA HMIS: 4-2-1-X 220.64 100-2/1 flashpoint: >110C (>230F) 25g/$29.00

H3 CO H3 CO

O P Si(CH3)3

0.954

1.4091

50g/$180.00 1.19 1.360

Cl

OMPH029 DIPHENYLPHOSPHINE 186.20 280 1.070 1.6250 C12H11P pKa: 0.03 HYDROLYTIC SENSITIVITY: 9 reacts extremely rapidly with moisture and oxygen may be pyrophoric- glove box or sealed system required [838-85-7] TSCA HMIS: 3-4-1-X 25g/$86.00 OMPH029.2 DIPHENYLPHOSPHINE, 20% in heptane 186.20 280 0.755 pKa: 0.03 C12H11P HYDROLYTIC SENSITIVITY: 8 reacts rapidly with moisture, water, protic solvents [838-85-7] TSCA HMIS: 3-4-1-X 25g/$20.00 100g/$65.00 SID4557.5 2-(DIPHENYLPHOSPHINO)ETHYL316.46 160/1 DIMETHYLETHOXYSILANE C18H25OPSi HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [359859-29-3] HMIS: 2-2-1-X 10g/$124.00 SID4558.0 2-(DIPHENYLPHOSPHINO)ETHYL376.50 182/1.3 1.05 TRIETHOXYSILANE flashpoint: 134C(273F) C20H29O3PSi immobilizing ligand for precious metals adhesion promoter for gold substrates in microelectronic applications1. 1. J. Helbert, US Pat. 4,497,890, 1985 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [18586-39-5] TSCA HMIS: 3-1-0-X 5.0g/$39.00 25g/$156.00

CH3 P CH2CH2SiOC2H5 CH3

E FAC TION SURDIFICA MO

CH2CH2Si(OC2H5)3

(215) 547-1015

FAX: (215) 547-2484

2005 Gelest, Inc.

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Gelest, Inc.
name MW bp/mm (mp) D420 nD20
SID4558.5 (DIPHENYLPHOSPHINO)TRIMETHYL258.38 120/0.2 1.009 1.6030 SILANE, 95% C15H19PSi HYDROLYTIC SENSITIVITY: 8 reacts rapidly with moisture, water, protic solvents [17154-34-6] HMIS: 3-3-1-X 5.0g/$106.00 OMPH056 DIPHENYLPHOSPHORYL AZIDE 275.20 157/0.17 C12H10O3N3P employed in preparation of macrocyclic lactams1. 1. L. Qian et al, Tet. Lett., 31, 6469, 1990 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [26386-88-9] HMIS: 3-2-1-X 25g/$48.00

Si(CH3)3

O P O

O N3

1.277

1.5520

Cl Cl P Cl N

Cl P

Cl N

Cl
+

P n Cl

Cl PCl6

INPH055 POLY(PHOSPHONITRILIC CHLORIDE), 95% >650 (60-80)mp Cl3(NPCl2)nNOCl3.PCl6 soluble: chloroform catalyst for the polymerization of polysiloxanes from silanol oligomers1,2,3,4. 1. S. Nitzsche et al, US Pat. 3,839,388, 1974 2. S. Nye et al, US Pat. 5,753,751, 1998 3. U. Dittrich et al, US Pat. 5,919,883, 1999 4. J. Burkhart, US Pat. 4,053,494, 1977; 4,203,913, 1980 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [31550-05-7] HMIS: 3-1-1-X 10g/$124.00 AKS733 SODIUM DI(ISOBUTYL)DITHIOPHOSPHINATE, 232.31 1.14 50% in water TOXICITY- oral rat, LD50: 3350mg/kg C8H18PS2Na decomposes >350 chelates/recovers silver, cadmium; flotation agent for metallic sulfides HYDROLYTIC SENSITIVITY: 0 forms stable aqueous solutions [13360-78-6] TSCA HMIS: 2-1-0-X 25g/$32.00 100g/$104.00 OMPH064 TETRABUTYLPHOSPHONIUM CHLORIDE 294.89 (80-3)mp C16H36ClP HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions [2304-30-5] HMIS: 1-3-0-X 25g/$40.00 100g/$130.00 OMPH057 TETRABUTYLPHOSPHONIUM HYDROXIDE, 276.45 40% in water pH: >12 C16H37OP forms catalysts used in silicone polymerization HYDROLYTIC SENSITIVITY: 0 forms stable aqueous solutions [14518-69-5] TSCA HMIS: 3-0-0-X 100g/$40.00

S S
S Na
+

((CH3)2CHCH 2)2P

CH3CH2CH2CH2

CH2CH2CH2CH3 + P CH2CH2CH2CH3 ClCH2CH2CH2CH3

SIS TALY CA

CH3 CH2CH2CH2 + OH P CH2CH2CH2CH3 CH3 CH2CH2CH2 CH3 CH2CH2CH2

0.989

1.4120

500g/$160.00

CH3(CH2)12CH2

CH2(CH2)4CH3 Cl+ P CH2(CH2)4CH3 CH2(CH2)4CH3

P(C 6H5) 2 CH2

OMPH066 TETRADECYL(TRIHEXYL)PHOSPHONIUM 519.31 (-40)mp 0.895 1.4818 CHLORIDE C33H68ClP viscosity: 2250 cSt. catalyst modifies montmorillonite clays useful in high temperature composites1. 1.W. Xie et al, Chem. Mater., 14, 4837, 2002 HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions [258864-54-9] TSCA HMIS: 1-3-0-X 25g/$16.00 100g/$52.00 SIT7281.0 TETRAKIS(DIPHENYLPHOSPHINOETHYL)- 1089.46 TETRAMETHYLCYCLOTETRASILOXANE C60H68O4P4Si4 HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions HMIS: 2-1-0-X 1.0g/$145.00

H 3C O Si

CH 2 O Si

CH 3 CH 2 O

(C 6H)52P CH2 CH 2
CH 3

CH2 P(C 6H5) 2

Si

O Si

H2C

CH 3

CH2 P(C6H5)2

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2005 Gelest, Inc.

Gelest, Inc.
name MW bp/mm (mp) D420 nD20
OMPD082 TETRAKIS(TRIPHENYLPHOSPHINE)1155.58 PALLADIUM (O) C72H60P4Pd catalyst for coupling reactions1. 1. S. Danishefsky et al, J. Am. Chem. Soc., 115, 6094, 1993 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [14221-01-3] HMIS: 3-2-1-X store <5 5.0g/$116.00
+

[(C6H5)3P]4Pd

HT ION LIG ERACT INT

PF 6 S
-+

PF 6

PF 6

OMPH076 (THIOPHENOXYPHENYL)DIPHENYLSULFON- 516.50 1.31 IUM HEXAFLUOROPHOSPHATE - BIS(DIPHENYLSULFONIUM)DIPHENYLTHIOETHER HEXAFLUOROPHOSPHATE BLEND 50% in propylene carbonate TOXICITY - oral rat, LD50: >5000mg/kg C24H19S2F6P UV initiator for cationic polymerizations, e.g. cycloaliphatic epoxides HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions [74227-35-3][68156-13-8] TSCA HMIS: 2-2-1-X 25g/$34.00 SNT7980 TIN II PYROPHOSPHATE 411.32 (>400)d O7P2Sn2 soluble: hydrochloric acid diagnostic aid in radioactive bone-scanning1. 1. D. Pavel et al, J. Nucl. Med., 18, 305, 1977 [15578-26-4] TSCA HMIS: 2-0-0-X 25g/$16.00 AKT889.1 TITANIUM TRIS(DIOCTYLPHOSPHATO)1191.33 ISOPROPOXIDE, 90% amber liquid flashpoint: 63C(145F) C51H109O13P3Ti dispersion agent for conductive fillers in capacitance discs1. 1. M. Labib, US Pat. 4,532,074, 1985 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [68585-79-5] HMIS: 2-2-1-X 25g/$24.00 OMPH074 TRIETHYLPHOSPHATE C6H15O4P 182.16 4.01

Sn2P2O 7

100g/$52.00 1.04

E FAC TION SURDIFICA MO

C8H17O O C8H17O P O Ti
3

OiC3H7

100g/$78.00

IC CTR IELEMIC D A CER

O C2H5O P OC2H5

OC2H5

215 1.072 1.4050 (-57)mp TOXICITY - oral mouse, LD50: 1600mg/kg flashpoint: 116C (241F) in combination w/TEOS precursor for CVD of phosphosilicate glass (PSG) HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [78-40-0] TSCA HMIS: 2-3-1-X 25g/$10.00 100g/$29.00

(C2H5)3P

AuCl

OMGO017 TRIETHYLPHOSPHINEGOLD I CHLORIDE 350.57 (85-7)mp C6H15ClPAu HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [15529-90-5] HMIS: 3-2-1-X 1.0g/$94.00 OMPH077 TRIETHYLPHOSPHITE C6H15O3P

5.0g/$376.00

CH2CH3 O CH3CH2 O P O CH2CH3

166.16 156 0.969 1.4130 TOXICITY- oral rat, LD50: 1840mg/kg flashpoint: 54C (130F) HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions [122-52-1] TSCA HMIS: 2-3-0-X 100g/$10.00 500g/$40.00

O CH3PO(CH 2)3Si(OH) 3 O Na
+

SIT8378.5 3-TRIHYDROXYSILYLPROPYLMETHYL238.18 1.25 PHOSPHONATE, SODIUM SALT, 42% in water flashpoint: 79C(174F) C4H12O6NaPSi contains 4-5% methanol, sodium methylphosphonate HYDROLYTIC SENSITIVITY: 0 forms stable aqueous solutions [84962-98-1] TSCA HMIS: 1-2-0-X 100g/$15.00 500g/$60.00 OMPH079 TRIMETHYLPHOSPHITE C3H9O3P vapor pressure, 20: 17mm 111 1.052 (-76)mp TOXICITY- oral rat, LD50: 1600mg/kg flashpoint: 27C (82F) with BOMe3 and SiOEt4 forms borophosphosilicate glasses by sol-gel1. 1. C. Canevali et al, Chem. Mater., 16, 315, 2004 HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions [121-45-9] TSCA HMIS: 3-3-0-X 100g/$12.00
2005 Gelest, Inc.

124.08

1.4080

CH3 O H3C O P O CH3

Gelest, Inc.
tC4H9

name

MW

bp/mm (mp)

D420

nD20

tC4H9 O tC4H9 O tC4H9 P O tC4H9 tC4H9

OMPH082 TRIS(2,4-DI-t-BUTYLPHENYL)PHOSPHITE 646.93 (182-6)mp 0.98 TOXICITY- oral rat, LD50: >6000mg/kg C42H63O3P stabilizer for polyesters, polyamides, polycarbonates at 0.2-0.8% HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions [31570-04-4] TSCA HMIS: 1-1-0-X 100g/$19.00 500g/$76.00 SIT8722.7 TRIS(TRIMETHYLSILYLMETHYL)PHOSPHINE 292.62 C12H33PSi3 70/1-sub (66-70)mp soluble: hexane HYDROLYTIC SENSITIVITY: 9 reacts extremely rapidly with moisture and oxygen [18077-42-4] HMIS: 3-4-1-X 1.0g/$156.00 SIT8723.0 TRIS(TRIMETHYLSILYL)PHOSPHATE 314.54 85-7/4 C9H27O4PSi3 (2-4)mp Hvap: 9.7 kcal/mole flashpoint: >110C(>230F) cocatalyst for epoxidation of allyl-TMS ethers w/ silylperoxides1. 1. T. Hiyama, M. Obayashi, Tet. Let., 24, 395, 1983 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [10497-05-9] TSCA HMIS: 2-1-0-X 25g/$32.00 0.959 1.4090

(CH3)3SiCH2

CH2Si(CH3)3

CH2Si(CH3)3

O (CH3)3SiO P OSi(CH 3)3 OSi(CH 3)3

100g/$104.00

SIT8723.4 TRIS(TRIMETHYLSILYL)PHOSPHINE, 10% 250.54 102-5/16 0.71 in hexane flashpoint: -18C(-1F) C9H27PSi3 HYDROLYTIC SENSITIVITY: 8 reacts rapidly with moisture, water, protic solvents [15573-38-3] HMIS: 4-4-2-X 10g/$84.00 50g/$336.00 SIT8723.6 TRIS(TRIMETHYLSILYL)PHOSPHITE, 95% 298.55 90-2/20 0.893 1.4090 C9H27O3PSi flashpoint: 66C(150F) reacts with aryl bromides yielding arylbis(trimethylsilyl)phosphonic acid esters1. used for mild preparation of bis(TMS)phosphonates (Arbuzov reaction)2. 1. Anorg. Allg. Chem., 259, 151, 1985 2. M. Sekine et al, J. Chem. Soc. Chem. Comm. 285, 1978 HYDROLYTIC SENSITIVITY: 7 reacts slowly with moisture/water [1795-31-9] HMIS: 3-2-1-X 2.5g/$20.00 INRH082 TRIS(TRIPHENYLPHOSPHINE)RHODIUM I CHLORIDE
WILKINSONS CATALYST

(CH3)3SiO

OSi(CH 3)3

OSi(CH 3)3

925.23

(>170)-d.

SIS TALY CA

[(C6H5)3P]3RhCl

C54H45P3ClRh soluble: chloroform, warm acetone, ethanol hydroboration, hydrosilylation catalyst catalyst for dehydrogenative coupling of silanes with olefins forms alkylchlorides by decarbonylation of acid halides forms alkanes by decarbonylation of aldehydes HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions [14694-95-2] TSCA HMIS: 3-1-0-X 1.0g/$40.00 5.0g/$200.00 SIV9077.0 VINYL(DIPHENYLPHOSPHINOETHYL)298.45 DIMETHYLSILANE C18H23PSi HYDROLYTIC SENSITIVITY: 4 no reaction with water under neutral conditions HMIS: 2-2-0-X 5.0g/$116.00

CH CH3 Si (C 6H5) 2PCH2CH2 CH3

H2C

DOUBLE METAL AND POLYMERIC ALKOXIDES

PSIP0-019 DIETHOXYSILOXANE - ETHYLPHOSPHATE copolymer [(C2H5O)2SiO][(C2H5O)OPO] hygroscopic [51960-53-3] HMIS: 2-3-1-X 25g/$40.00 19.1-19.6% Si 1.4-1.5% P 100g/$130.00

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2005 Gelest, Inc.