pay — J SEAT NUMBER (an [2] CHEMISTRY (55) Time : 3 Hrs. (7 Pages) Max, Marks : 70 General Instructions : The question paper is divided into four sections. (Il) SectionA: Q. No. I contains Ten multiple choice type of questions carrying One mark each. Q. No. 2 contains Eight very short answer type of questions carrying One mark each. 0. No. 3 10 Q. No. 14 are Twelve short answer type of questions carrying Two marks each. (Attempt any Eight) Q. No. 1510 Q. No. 26 are Twelve short answer type of questions carrying Three marks each.(Attempt any Eight) Q. No. 27 to Q. No. 31 are Five long answer type of questions carrying Four marks each.(Attempt any (2) Section B: (3) SectionC: (4) SectionD: Three) Use of log table is allowed. Use of calculator is not allowed. (o} ) ry) Figures to the right indicate full marks. For each multiple choice type of question, it is mandatory to write the correct answer along with its alphabet €.g. (A).....-.00L (B) serve (CD cvvaversoee LQ) sore sees Ole No mark (s) shall be given, if alphabet of the correct answer is written. Only the first attempt will be considered for evaluation. ONLY the correct answer or the Page 1 P.T.O.-A sECTION the following multiple iy Q. 1. Select and write the correct answer for els ject and wri choice type of questions : o-ordination number of atoms in body centred cubic (i) The et structure (bec) is . (a) 4 (b) 6 (c) 8 (d) 12 jon of solute (ji) Incalculating osmotic pressure, the concentration is expressed in (@)_ molarity (b) molality (d) percentage mass (c) mole fraction (ii) The enthalpy change for the chemical reaction 10,57 HO is called enthalpy of —_— (a) vapourisation (b) fusion (c) combustion (d) sublimation Which of the following transition element shows maximum @) oxidation state? (a) Sc Fe (c) Mn @v (v) The correct formula for the complex compound, sodium hexacyanoferrate (III) is : (@)_Na[Fe(CN),) (b) Na, [Fe(CN),] (c) Na, [Fe(CN),] (d) Na, [Fe(CN),] (vi) Isopropylbenzene on air oxidation followed by decomposition by dilute acid gives : ° C,H,OH (b) C,H,COOCH, ¢) C.H.COOH (d) C,H,CHO Ao Page 2(vii) ‘The name of metal nanoparticle which acts aS highly effective bacterial disinfectant in water purification process is (b) silver (a) copper (a) carbon black (©) gold (viii) Acid anhydride on reaction with primary amine g) compound having a functional group ___ (a) amide (b) nitrile (c) secondary amine (d)_ imine ‘ives (ix) The standard potential of the cell in the following reaction is Cd 2 2+ (s) + CuaM — Choy + Cu, Oe (E04 =70.403V, Bey =0.334V) (b) 0.737V (a) -0.737V (d) 0,069 V (c) -—0,069 V The value of (H,O*] in mol lit of 0.001 M acetic acid solution (Ka = 1.8 x 10°) is &) (b) 1.34« 107 (@) 134*107 (c) 134x107 (@) 1341074 Answer the following questions : [8] (i) Write the product formed when alkyl halide reacts with silver nitrite. (i) Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine. (iii) Write the name of biodegradable polyamide copolymer. (iv) Identify the molecularity of following elementary reaction : — +0 NO gy #3) Nace) * P.T.O. Page 3i s ? (v) Whats the action of selenium on magnesium metal? (vi) Write the name of isomerism in the following complexes : [Cu(NH,),] {PtCI,) and [PUNH,),] [CuCl] (vil) Write the name of the alloy used in Fischer Tropsch process in the synthesis of gasoline. 34 (viii) Henry’s law constant for CH,Br, vis 0.159 mol dm™ bar at 25°C. What is solubility of CH,Br, ) in water at same temperature and partial pressure of 0.164 bar? SECTION - B Attempt any EIGHT of the following questions : 116) Q 3. Q. 4, Q.5. Q. 6. Q.7. Q.8, Q9 Explain pseudo-first order reaction with suitable example. Write the consequences of Schottky defect with reasons, What is the action of following on ethyl bromide : @ Nain dry ether ii) Mg in dry ether Explain formation of peptide linkage in protein with an example. Derive an expression to calculate molar mass of non volatile solute by osmotic pressure measurement Explain monodentate and ambidentate ligands with example. Explain the trends in the following atomic properties of group 16 elements : (i) Atomic radii Gi) Tonisation enthalpy (iii) Electronegativity (iv) Electron gain enthalpy Page 4. 10. Wi . e "Me Preparation of phenol from aniline. Q. I. Write chemi, . @ acetone to prepare ethanamine from : @) nitroethane Q. 12. Identi Y A.andB from the following reaction CH, | 2CH, -C=9_Ba(Ou 37-00, gt, B+H,0 Q. 13. One mok i . * ofan ideal gas is expanded isothermally and reversibly from 10 L to 15 L at 300 K. Calculate the work done in the Process. -hitps://www.maharashtrastudy.com . 14. Hor Q Ww many moles of electrons are required for reduction of 2 2+ moles of Zn** to Zn? How many Faradays of electricity will be required? SECTION - C Attempt any EIGHT of the following questions : [24] Q. 15. Write chemical composition of haematite. Write the names and electronic configurations of first two elements of group 17. Q. 16. Write classification of polymers on the basis of structure. Q. 17. Define green chemistry. Write two disadvantages of nanotechnology. Q. 18. Write commercial method for preparation of glucose. Write structure of adipic acid. Page 5 PTO.oxyethane: Q. 19. Write chemical reactions of following reagents on meth y' (i) hot HI (i) PCI, Gi) dilute H,SO, ith Q. 20. Explain cationic, anionic and neutral sphere complexes Wl example. ivalent cation of 1, Calculate spin only magnetic moment of di transition metal with atomic number 25. Salts of Ti** are colourless. Give reason. Q. 22. What is lanthanoid contraction? Write preparation of acetic acid from @ dry ice (ii) acetyl chloride. Write the classification of aliphatic ketones with example. What is the action of sodium hypoiodite on acetone? Define half life of first order reaction. Obtain the expression for half life and rate constant of the first order reaction. . Calculate the standard enthalpy of formation of CH, Oy ) from the following data @ CH,OH, +5044) >C0,, )+2H,0, AH?=-726kJ mol! .. OL! -1 (i) wea 700, AH = ~393 kJ mol a oO 1 (iii) Hye) +2 3 Oar) > H,0,) 4; A. H°= ~286 kJ mol™ Q. 26. Calculate the pH of buffer solution composed of 0.01 M weak base BOH and 0.02M ofits salt BA. [K,=1.8%10™ for weak base } [s]2] Page 6Q. 28. Q. 29. Q. 30. Q.31. SECTION -D sitempt any THREE Of the fol ions : ot. lowing questions : Define the following terms: () — Isotonic Solution (1) Osmosis Gold crystallises of unit con isan into face-centred cubic cells. The edge length [ Molar mass of 8 « 10°* cm. Calculate the density of gold. $8 of gold = 197g mol! } Write the m athematical e. i i he first law of thermodynamics for “avon fees (i) isothermal Process, (ti) adiabatic process Derive the relationship between pH and pOH. Define reference electrode. Write functions of salt bridge. tae neat. labelled diagram of standard hydrogen electrode (SHE). Explain metal deficiency defect with example. Write chemical equation for preparation of sulphur dioxide from sulphur. Write uses of sulphur. Write chemical reactions for the following conversions : (i) Ethyl bromide to ethyl methyl ether. (ii) Ethy] bromide to ethene. (iii) Bromobenzene to toluene. (iv) Chlorobenzene to biphenyl. ooo