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Article On Investigating Quality of Cement in Eth
Article On Investigating Quality of Cement in Eth
Introduction
Cement is a binder, a substance used for construction that sets, hardens, and adheres to other
materials to bind them together. Cement is seldom used on its own, but rather to bind sand and
gravel (aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or
with sand and gravel, produces concrete. Concrete is the most widely used material in existence
and is only behind water as the planet's most-consumed resource (Francesca, 2010).
Cements used in construction are usually inorganic, often lime or calcium silicate based, which
can be characterized as non-hydraulic or hydraulic respectively. The lime based non-hydraulic
cement does not set in wet conditions or under water, rather, it sets as it dries and reacts with
carbon dioxide in the air. On the other hand, the silicate based hydraulic cement (e.g. Portland
cement) set and become adhesive due to a chemical reaction between the dry ingredients and
water (Blezard, 2004).
John Smeaton made an important contribution to the development of cements when he was
planning the construction of the third Eddystone Lighthouse (1755–9) in the English Channel.
He used a hydraulic mortar that would set and develop some strength in twelve hours’ period
between successive high tides. Later in 1824, Joseph Aspdin patented a similar material, which
he called Portland cement, because the render made from it was in colour similar to the
prestigious Portland stone. The following years, investigations of L.J. Vicat led him to prepare an
artificial hydraulic lime by calcining an intimate mixture of limestone and clay. After two
decades, in 1845 Isaac Charles Johnson burnt a mixture of clay and chalk till the clinkering stage
to make better cement and established factories in 1851.
The German standard specification for Portland cement was drawn in 1877. Next to Germany,
the first British standard and ASTM specifications for cement was drawn up in 1904.
Ethiopia’s first cement factory, Dire Dawa Cement and Lime Factory, was established by the
Italian occupying forces in 1938. Currently, there are about nineteen cement plants with total
actual installed production capacity of 15MT per year and capacity utilization rate of over 60%.
According to CSA, 2016; MOI, 2017 reports, out of the 11.9MT cement produced and consumed
in the reported year in Ethiopia, 70% of the market is supplied by the top six brands which are
Dangote, Derba, Mugher, Habesha, Messebo and National Cements. The remaining market share
covered by medium and small scale brands like Abyssinia, Capital, Pioneer, Jema, East cement,
Holeta cement, Zengeshan, Jiangsu, Huang Shuan, Inchini and Red fox cements.
TYPES OF CEMENT
Globally, there are over fourteen different types of cements that are used for construction
purposes, and they differ by their composition and are manufactured for different uses. These are
ordinary portland cement (OPC), portland pozzolanic cement (PPC), portland limestone cement
(PLC), rapid hardening cement (RHC), quick-setting cement (QSC), low heat cement (LHC),
sulphate-resisting cement (SRC), low heat high sulphate resisting cement (LHHC), blast furnace
slag cement (BFSC), high-alumina cement (HAC), white cement (WC), coloured cement (CC),
air-entraining cement (AEC), and hydrophobic cement (HPC).
When we come to Ethiopia, the major types of cements manufactured & consumed are OPC and
PPC. Though insignificant, the demand of the other types of cement in the construction sector of
the country is mostly satisfied via import. Recently, local companies like Mugher and Messebo
started to produce RHC, PLC and LHHC based on customer order.
MANUFACTURING PROCESS
Cement is made by heating limestone (calcium carbonate) with small quantities of other
materials (such as clay) to 1450 °C in a kiln, in a process known as calcination, whereby a
molecule of carbon dioxide is liberated from the calcium carbonate to form calcium oxide, or
quicklime, which is then blended with the other materials that have been included in the mix.
The resulting hard substance, called 'clinker', is then ground with a small amount of gypsum into
a powder to make 'Ordinary Portland Cement', the most commonly used type of cement (often
referred to as OPC). Cement manufacturing process is briefly described here under in four steps.
Step 1 – Quarrying: Limestone and a 'cement rock' such as clay or shale are quarried and
brought to the cement works. These rocks contain lime (CaCO3), silica (SiO2), alumina
(Al2O3) and ferrous oxide (Fe2O3) - the raw materials of cement manufacture.
Step 2 - Raw material preparation: To form a consistent product, it is essential that the same
mixture of minerals is used every time. For this reason, the exact composition of the limestone
and clay is determined at this point, and other ingredients added if necessary. The rock is also
ground into fine particles to increase the efficiency of the reaction. The raw materials are
crushed and mixed either by dry or wet processes to obtain the raw mix.
The dry process:
The quarried clay and limestone are crushed separately until nothing bigger than a tennis ball
remains. Samples of both rocks are then sent off to the laboratory for mineral analysis. If
necessary, minerals are then added to either the clay or the limestone to ensure that the correct
amounts of aluminum, iron etc. are present. The clay and limestone are then fed together into a
mill where the rock is ground until more than 85% of the material is less than 90µm in diameter.
The wet process:
The clay is mixed to a paste in a wash-mill - a tank in which the clay is pulverized in the
presence of water. Crushed lime is then added and the whole mixture is further ground (broken
down). Any material which is too coarse is extracted and reground. The slurry is then tested to
ensure that it contains the correct balance of minerals, and any extra ingredients blended in as
necessary.
Step 3 – Clinkering: The raw materials are then dried, heated and fed into a rotating kiln. Here
the raw materials react at very high temperatures to form a granular mixture of compounds called
clinker. The compounds constituting clinker are; 3CaO • SiO2 (tri calcium silicate), 2CaO • SiO2
(di calcium silicate), 3CaO • Al2O3 (tri calcium aluminate) and 4CaO • Al2O3 • Fe2O3 (tetra
calcium alumino-ferrate).
kiln: The kiln shell is steel, 60m long and inclined at an angle of 1 in 30. The shell is supported
on 3 roller trunnions and weighs in at over 1100 T. The kiln is heated by injecting pulverized
coal dust into the discharge end where it spontaneously ignites due to the very high temperatures.
Coal is injected with air into the kiln at a rate of 9 - 12 T/hr.
Step 4 - Cement milling: The 'clinker' that has now been produced will behave just like cement,
but it is in particles up to 3 cm in diameter. So it is ground with gypsum (3-6%) to adjust setting
time producing the final cement powder to be packed and marketed.
The raw materials used for the manufacture of cement consist mainly of lime, silica, alumina and
iron oxide. These oxides interact with one another in the kiln at high temperature to form more
complex compounds. The relative proportions of these oxide compositions are responsible for
influencing the various properties of cement; in addition to rate of cooling and fineness of
grinding.
Table 1: Compounds constituting the finally produced cement powder.
Mineral Chemical formula Abbreviation Percentage (Wt)
C3A: is characteristically fast reacting with water & may lead to a rapid stiffening of the paste
with a large amount of the heat generation (Flash-Set)-(Quick-Set). In order to prevent this rapid
reaction gypsum is added to the clinker. Gypsum, C 3A & water react to form relatively insoluble
Calcium Sulfo-Aluminates.
C3A+CŚH2+10H→C4AŚH12 (calcium- aluminomonosulfohydrate)
C3A+3CŚH2+26H→C6AŚ3H32 (calcium-aluminotrisulfohydrate “ettringite”)
When there is enough gypsum “ettringite” forms with great expansion. If there is no enough
gypsum flash-set will occur. If there is more than enough gypsum, ettringite formation increases
which will cause cracking. Therefore, gypsum content shall be regulated optimally so that to
avoid formation of either ettringite or flash-setting.
Also Calcium-Sulfo Aluminates are less resistant to sulfate attack & does not contribute much
for strength. The cement to be used in making concretes that are going to be exposed to soils or
waters that contain sulfates should not contain more than 5% C3A.
C4AF: The hydration of ferrite phase is not well understood. Ferrite phase has lesser role in
development of strength. The hydration products are similar to C 3A. Alumina & iron oxide occur
interchangeably in the hydration products.
C4AŚH12 or C4FŚH12
C6AŚ3H32 or C6FŚ3H32
HEAT OF HYDRATION
Hydration process of cement is accompanied by heat generation (exothermic). As concrete is a
fair insulator, the generated heat in mass concrete may result in expansion & cracking. This
could be overcome by using suitable cement type. High heat of hydration could also be
advantages for cold weather concreting.
The heat of hydration of OPC is on the order of 85-100 cal/gr. About 50% of this heat is
liberated within 1-3 days & 75% within 7 days. By limiting C 3S & C3A content heat of hydration
can be reduced.
FINENESS OF CEMENT
As hydration takes place at the surface of the cement particles, it is the surface area of cement
particles which provide the material available for hydration. The rate of hydration is controlled
by fineness of cement. For a rapid rate of hydration, a higher fineness is necessary.
However, higher fineness requires higher grinding which means higher production cost. Finer
cements deteriorate faster upon exposure to atmosphere. They are also very sensitive to alkali-
aggregate reaction. In addition to these, finer cements require more gypsum and water for proper
hydration.
Fineness of cement is determined by air permeability methods. For example, in the Blaine air
permeability method a known volume of air is passed through cement. The time is recorded and
the specific surface is calculated by a formula.
Fineness is expressed in terms of specific surface of the cement (cm2/gr). For OPC specific
surface is 2600-3000 cm2/gr.
SETTING OF CEMENT
Setting refers to a change from liquid state to solid state. Although, during setting cement paste
acquires some strength, setting is different from hardening.
The water content has a marked effect on the time of setting. In acceptance tests for cement, the
water content is regulated by bringing the paste to a standard condition of wetness. This is called
“normal consistency”. Normal consistency of O.P.C. Ranges from 20-30% by weight of cement.
Vicat apparatus is used to determine normal consistency. Normal consistency is that condition
for which the penetration of a standard weighed plunger into the paste is 10mm in 30sec. By trial
& error determine the w/c ratio.
In practice, the terms initial set & final set are used to describe arbitrary chosen time of setting.
Initial set indicates the beginning of a noticeable stiffening & final set may be regarded as the
start of hardening (or complete loss of plasticity). Standards specify initial setting time between
45-60mins and final setting time between 375-480mins.
Factors Affecting Setting Time are:
Temperature & Humidity
Amount of Water
Chemical Composition of Cement
Fineness of Cement (finer cement, faster setting)
Flash-Set: is the immediate stiffening of cement paste in a few minutes after mixing with water.
It is accompanied by large amount of heat generation upon reaction of C3A with water. Gypsum
is placed in cement to prevent flash-set. The rigidity cannot be overcome & plasticity may not be
regained without addition of water. Amount of gypsum must be such that it will be used up to
almost hardening. Because expansion caused by ettringite can be distributed to the paste before
hardening. More gypsum will cause undesirable expansion after hardening.
False-Set: is a rapid development of rigidity of cement paste without generation of much heat.
This rigidity can be overcome & plasticity can be regained by further mixing without addition of
water (Vibration). In this way cement paste restores its plasticity & sets in a normal manner
without any loss of strength.
Probable Causes of False-Set:
When gypsum is ground by too hot of a clinker, gypsum may be dehydrated into
hemihydrate (CaSO4.1/2H2O) or anhydrate (CaSO4). These materials when react with
water gypsum is formed, which results in stiffening of the paste.
Alkali oxides in cement may carbonate during storage. Upon mixing such a cement with
water, these alkali carbonates will react with Ca(OH 2) (CH or Calcium Hydroxide)
liberated by hydrolysis of C3S resulting in CaCO3. CaCO 3 precipitates in the mix &
results in false-set.
SOUNDNESS OF CEMENT
Soundness is defined as the volume stability of cement paste. The cement paste should not
undergo large changes in volume after it has set. Free CaO & MgO may result in unsound
cement. Upon hydration C & M will form CH & MH with volume increase thus cracking.
Since unsoundness is not apparent until several months or years, it is necessary to provide an
accelerated method for its determination.
Lechatelier Method: Only free CaO can be determined.
Autoclave Method: Both free CaO & MgO can be determined.
STRENGTH OF CEMENT
Strength tests are not carried out on neat cement pastes, because it is very difficult to form these
pastes due to cohesive property of cement.
Strength tests are carried out on cement mortar prepared by standard gradation (1-part cement+3-
parts sand+1/2-part water). The three types of cement strength tests are direct tensile, flexural
and compression strength tests.
PORTLAND POZZOLANA CEMENT (PPC)
This type of Portland Cement is manufactured by the inter grading of Ordinary Portland Cement
clinker mixing with 15 to 35 % of pozzolanic material and gypsum.
A pozzolanic material is a siliceous or aluminous material which do not possess any cementing
properties. When this material is in the presence of water in a fine powdered form, it readily
reacts with calcium hydroxide liberated during the hydration process at ordinary temperature.
The reaction of the pozzolanic material with calcium hydroxide forms a compound which
possess cementing property.
Pozzolanic materials used in the manufacturing of PPC are calcined clay or fly ash. Fly ash, as it
is known, is found to be a waste material produced in thermal power station which uses
powdered coal as a fuel. The fly ash is collected in electrostatic precipitator.
Use of Fly Ash: Hydration of Calcium silicate, produce huge quantity of calcium hydroxide
which is almost a useless material considering its strength or long durability. If such useless mass
is converted into a useful cementing product, it improves the quality of concrete. The use of fly
ash plays such a very dominating role.
Properties of PPC:
The PPC produces lower rate of heat on hydration.
It offers superior resistance to the attack by forceful waters.
The most important quality of the PPC is that it reduces the leaching of calcium
hydroxide when used in hydraulic structures.
PPC is found to be useful in marine as well as hydraulic constructions, including mass
concrete constructions.
The strength of PPC is expected to be similar to that of OPC but only when at the later
ages, provided the concrete is cured under moist condition for a sufficient period of time.
If PPC is manufactured by using the right quality and type of pozzolanic material, it can
be inferior to OPC in any way except for the rate of development of strength up to 7 days.
Advantages of Portland Pozzolanic Cement:
PPC is useful and can be replaced at all places, wherever, OPC is used. In fact, technically PPC
is found to be more advantages than OPC when made by using optimum percentage and right
quality of fly ash or pozzolanic material.
STANDARD SPECIFICATIONS
Composition, specifications and conformity criteria for common cements (EN 1992-1-
1:2011 uses EN 197-1)
This European Standard was approved by CEN on 6 August 2011
This document (EN 197-1:2011) has been prepared by Technical Committee CEN/TC 51
“Cement and building limes”, the secretariat of which is held by NBN.
This European Standard shall be given the status of a national standard, either by publication of
an identical text or by endorsement, at the latest by March 2012, and conflicting national
standards shall be withdrawn at the latest by June 2013.
The Ethiopian building code standard EBCS EN 1992-1-1:2014 published before the above
deadline endorses EN 197-1 as a reference standard regarding composition, specification and
conformity criteria for common cements manufactured in Ethiopia.
It is recognized that different cements have different properties and performance. Those
performance tests now available (i.e. setting time, strength, soundness and heat of hydration),
have been included in this standard. In addition, work is being carried out by CEN/TC 51 to
identify any additional tests which are needed to specify further performance characteristics of
cement. Until further performance tests are available it is necessary that the choice of cement,
especially the type and/or strength class in relation to the requirements for durability depending
on exposure class and type of construction in which it is incorporated, follows the appropriate
standards and/or regulations for concrete or mortar valid in the place of use.
This European Standard defines and gives the specifications of 27 distinct common cements, 7
sulfate resisting common cements as well as 3 distinct low early strength blast furnace cements
and 2 sulfate resisting low early strength blast furnace cements and their constituents. The
definition of each cement includes the proportions in which the constituents are to be combined
to produce these distinct products in a range of nine strength classes. The definition also includes
requirements which the constituents have to meet. It also includes mechanical, physical, and
chemical requirements. Furthermore, this standard states the conformity criteria and the related
rules. Necessary durability requirements are also given.
Standard strength
The standard strength of a cement is the compressive strength determined in accordance with EN
196-1 at 28 days and shall conform to the requirements in table 2 below.
Three classes of standard strength are included: class 32.5, class 42.5 and class 52.5
Early strength
The early strength of a cement is the compressive strength determined in accordance with EN
196-1 at either 2 days or 7 days and shall conform to the requirements in table 2.
Three classes of early strength are included for each class of standard strength, a class with
ordinary early strength, indicated by N, a class with high early strength, indicated by R and a
class with low early strength, indicated by L.
Table 2: Mechanical and Physical requirements given as a characteristic value
Specifications and conformity criteria for Concrete (EBCS EN 1992-1-1:2014, Section 3.1)
The compressive strength of concrete is denoted by concrete strength classes which relate to the
characteristic 5% cylinder strength fck or the cube strength fck,cube in accordance with EN 206-
1.
fck,cube = 1.25*fck
The mean compressive strength of concrete at 28 days, fcm, is specified as follows;
fcm = fck + 8Mpa.
The compressive strength of concrete at a time t, fck(t), is specified as follows;
fck(t) = fcm(t) – 8Mpa. For 3 < t < 28 days
fck(t) = fck. For t > or = 28 days
The compressive strength of concrete at an age t depends on the type of cement, temperature and
curing conditions. For a mean temperature of 20 degrees centigrade and curing in accordance
with EN 12390, the mean compressive strength of concrete at various ages fcm(t) is specified as
follows;
fcm(t) = βcc(t)*fcm
βcc(t) = exp(s(1-(28/t)1/2 ))
Where:
fcm(t) is the mean compressive strength of concrete at an age t day
fcm is the mean compressive strength of concrete at 28 days
βcc(t) is a coefficient which depends on the age t days of the concrete
t is the age of the concrete in days
s is a coefficient which depends on the type of cement:
= 0.2 for cement of strength class CEM 42.5R, 52.5N and 52.5R
= 0.25 for cement of strength class CEM 32.5R and 42.5N
= 0.38 for cement of strength class CEM 32.5N