TALLER DE CINÉTICA

PRESENTADO POR: TORRES GUZMAN YULYNDA CUI:20222783

Para A:

𝑉 = 𝐾[𝐴] 𝑋 [𝐵]𝑌
1.41𝑥10 𝑘[0.933] 𝑋 [0.933]𝑌
=
5.65𝑥10 𝑘[1.865] 𝑋 [0.933]𝑌
1.41𝑥10 [0.933] 𝑋
=
5.65𝑥10 [1.865] 𝑋
0.25 = 0.50𝑥
log[0.25] = 𝑥log⁡[0.50]
𝑥 = 2⁡⁡𝑜𝑟𝑑𝑒𝑛⁡[𝐴]
Para B
1.41𝑥10 𝑘[0.933] 𝑋 [0.933]𝑌
=
1.13𝑥10² 𝑘[0.933] 𝑋 [1.865]𝑌
1.41𝑥10 [0.933]𝑦
=
1.13𝑥10² [1.865]𝑦
0.12 = 0.50𝑦
log[0.12] = 𝑦log⁡[0.50]
𝑦 = 3⁡𝑜𝑟𝑑𝑒𝑛⁡[𝐵]

Orden total es x+y=5

2.

1 1
− = 𝑘𝑡
[𝐵] [𝐵]𝑜
1 1
= 𝑘𝑡 +
[𝐵] [𝐵]𝑜
1 [𝐵]𝑜𝑘𝑡 + 1
=
[𝐵] [𝐵]𝑜
[𝐵]𝑜 3𝑥10−1 𝑀
[𝐵 ] = =
[𝐵]𝑜𝑘𝑡 + 1 3𝑥10−1 𝑀 (0.622𝑀−1 )(100min) + 1

[𝐵] = 1.05𝑥10−1

1 1
( − ) = 𝑘𝑡
[𝐵] [𝐵]𝑜
1 1 1
( − ) =𝑡
[𝐵] [𝐵]𝑜 𝑘
1 1 1
𝑡=( −2
− )
2.5𝑥10 0.40 7.1𝑥10−3
𝑡 = 23.9𝑠

4.

𝐿𝑛[𝐵] = −𝑘𝑡 + ln⁡[𝐵]

0.21
[𝐵 ] = = 0.16
1.3
4𝑚𝑖𝑛𝑥60𝑠
𝐿𝑛[𝐵] = (−0.000222𝑠 −1 ) ( ) + ln⁡(0.16)
1𝑚𝑖𝑛
[𝐵] = 0.052𝑀
 𝑚𝑜𝑙
𝑚𝑜𝑙𝐵 = 0.152 𝑥1.3𝐿 = 0.198𝑚𝑜𝑙
𝐿
5.

1 1
− = 𝑘𝑡
(𝐵)𝑡 (𝐵)𝜊
1 1 1
𝑡= [ − ]𝑠
𝑘 (𝐵)𝑡 (𝐵)𝜊
1 1 1
𝑡= [ − ]𝑠
004 07 (𝐵)𝜊
1𝑚𝑖𝑛
𝑡 = 600𝑠 ( ) = 10 min
60𝑠
6.

0.693
𝑡 1⁄2 =
𝑘
0.693
𝑡 1⁄2 =
1.68 ⋅ 10−2 𝑆 −2
𝑡 1⁄2 = 41.2𝑠

7.

1
𝑡 1⁄2 =
𝑘[𝐵]𝜊
1
= 𝑠
(0.039)(0.027)
1𝑚𝑖𝑛
𝑡1⁄2 = 0.950𝑠 ( )
60𝑠
𝑡1⁄2 = 16 min
8.
 𝑘1 𝐸𝑎 1 1
ln = ( − )
𝑘2 𝑅 𝑇2 𝑇1
𝐸𝑎 1 1
ln 𝑘2 = ln 𝑘 1 − ( − )
𝑅 𝑇2 𝑇1
𝑘2 = 1.50𝑥109 𝑆 −1

9.

𝑘1 𝐸𝑜 1 1
𝑙𝑛 = ( − )
𝑘2 𝑅 𝑇2 𝑇1

𝑅𝑋𝑇1𝑋𝑇2 𝑘1
𝐸𝑜 = ( ) 𝐿𝑛( )
𝑇1 − 𝑇2 𝑘2

8.314𝑥10−3 𝑋499𝑋1003 0.57

𝐸𝑜 = ( ) 𝐿𝑛( )
499 − 1003 2,384.96

𝐸𝑜 = 38.8283𝐾𝑗/𝑚𝑜𝑙

10.

a) Energía de activación.
2.41𝑥10−10 𝐸𝑜 673 − 573
ln ( −6
)= ( )
1.16𝑥10 8.134 673𝑥573

𝐸𝑜 = 271𝑘𝐽𝑚𝑜𝑙
b) La constante de Arrhenius.

𝐸𝑜
ln[𝐴] = 𝑙𝑛𝐾 +
𝑅𝑇
−10 ]
2.71𝑥105
[ ] [
ln 𝐴 = 𝐿𝑛 2.41𝑥10 +
(8.314)(573)
[𝐴] = 1.6𝑥1015 𝑠 −1