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https://koderma.nic.in/education/
https://youtube.com/@degstrainingcentre2255

PROJECT RAIL 2.0

MODEL QUESTION PAPER - 2023
SET - 1
Class-12th
Subject- Chemsitry

01- Which one of the following is non- crystalline or amorphous in nature \

(A) Diamond (B) Graphite (C) Common salt (D) Glass

02- Which of the following is paramagnetic in nature?{

(A) Tio2 (B) Nacl (C) N2 (D) Cuo

03- Which of the following ions has the largest ionic radius
(A) (B) (C) (D)

04- Freckle and Scotty defect both are found in :-

(A) Agbr (B) Agcl (C) Zns (D) Nacl
05- Colligative properties of the solutions depend on :
(A) Size of the particles (B) Nature of the solvent (C) Number of the particles (D) nature of the
particles
06- Molarity of an aqueous solution Containing 2g of Naoh in 200 ml of Solution is :-
(A) 0.5 (B) 10 (C) 5 (D) 0.25

07- 200 ml water is added to 500 ml of 0.2 M solution what is the molarity of the diluted
solution?

(A) 0.5010 M (B) 0.2897 M (C) 0.7093 M (D) 0.1428 M

08- The SI unit of molar Conductivity is :-

 (A) 5 cm2mo1-1 (B) 52cm-1 (C) 5-1cm2mo1-2 (D)

09- For a galvanic cell, which one of the following Statements is not correct :
(A) Anode is negatively charged (B) Cathode is positively charged

(C) Reduction takes place at anode (D) Reduction takes place at cathode

10- The unit of cell constant is :-

(A) cm (B) cm (C) cm (D)

11- How many coulombs of charge is is required for reduction of 1 mole of to

(A) 96500 C (B) 193000 C (C) 289500C (D) 144750 C
12- Unit of rate constant for second order reaction K is :-
(A) (B) L (C) (D) mol
13- The rate of reaction does not depends upon :-
(A) Concentration of reactant (B) Molecularity of reaction (C) Activation energy of
reaction (D) Temperature

14- Emulsion is a colloidal solution of

(A) Two liquids (B) Two Solids (C) two gas (D) one solid and one
liquid

15- Which of the following are is concentrated by the forth flotation process :-
(A) Haematite (B) magnetite (C) Copper pyrite (D) Bauxite

16- Which one of the following is an oxide is?

(A) Malachite (B) copper glance (C) Haematite (D) Zinc Blende

17- Of the following an amphoteric hydroxide is

(A) ca(oH)2 (B) NaoH (C) Be(oH)2 (D) LioH

18- The hybridization of Xe in ͵ Xe is

(A) (B) (C) (D)

19- Which of the following ions is colored in aqueous solution

 (A) (B) (C) (D)

20- Oxidation number of ni in

(A) 0 (B) 1 (C) 2 (D) 4

21- The oxidation number of Pt in [Pt ( ]

(A) +1 (B) +2 (C) +3 (D) +4

22- Here A Is
(A) (B) (C) (D)
23- One important method for preparation of ether is :
(A) Wartz reaction (B) Williamson Synthesis (C) Friedel Craft՚s reaction(D) Etard
reaction

24- Reaction of HCHo with Followed by hydrolysis gives.

(A) (B) (C) (D)

25- Lucas thes is used to distinguish between

(A) Primary, Secondary and fertiary alcohols (B) Alt aidehydes and ketones (C)
Benzene and taluene (D) Aromatic and aliphatic acids

26- Product, the product is

(A) (B) (C) (D) None of these

27- Acid Chloride is reduced to aldehyde by

(A) Wurtz reaction (B) Rosenmund reduction (C) Fitting Reduction (D) None of
these

28- Tolllens reagent is

(A) Mixture of and NaOH (B) Ammoniacal silver nitrate solution (C) A
solution of Copper Sulphate, sodium Citrate and Sodium Carbonate (D) None of these

29- [ ] A+ “A” is
 (A) Ethane (B) Methane (C) Prop ane (D) NonAe of these

30- Benzene + acetyl Chloride → A , A is

(A) Benzophenone (B) Acetophenone (C) Acetone (D) None of these

31- Acctaldehyde +4 {H} → A, “A is

(A) Methane (B) Propane (C) Ethane (D) none of these

Product is (A) (B) (C)

(D) None of these

32- Maltose is made of

(A) α-D -Glucose (B) α and β-D Glucose (C) Glucose and Fructose (D)
Glucose and Galactose

33- Buna -5 Is Obtained from

(A) Butadine and Styrene (B) Adipic acid and hexamine (C) Urea and Formaldehyde (D)
Chloroprene

Class-12th

Subject- Chemsitry

Section A

The total number of question in section “A” is 07. Answer any 05 of them. Each Question from
this section is of 01 Marks.

1- Define Schottky defect. ?

2- What is mole fraction?
3- Define parts per million (ppm) ?
4- Explain the term cell Constant. ?
5- What are adsorbent ?
6- Define Calcinations ?
7- What is lanthanoid Contraction ?
34-
Section B
The total number of question in section “B” is 07. Answer any 05 of them. Each Question from
this section is of 03 Marks.

8- Define molarity and molality?

9- Define specific conductance/ Conductions ?
10- State faradays laws of electrolysis what is faraday constant ?
11- What do you mean by lyophillic and lyopohic colloidal solutions ?
12- What is the difference between calinations and roasting ?
13- What is leaching ? or which reactions are involved in leaching of alumina from
bauxite ? Give reactions only.
14- What is the oxidation number of central metal atom in each of the following ?
(A) {Pt ( (B) [ ] (C) Ni(C0 (D) [
Section C

The total number of question in section “C” is 05. Answer any 03 of them. Each Question from
this section is of 05 Marks.

15- Describe the following

(a) Kolbey Reaction (B) Reimer- Tiemann Reaction

16- Complete the following reactions

(a) ?
(b) OH → ?
(c) OH → ?
(d) + HI → ?

(e) +2[O] → ?

17- Define the following with example

(i) Polyester (ii) Polyamid e ( Nylon-6)
18- Draw the structure of the following with hybridization
(i) (HP (ii) 5 (iii) (iv) Xe (V)
19- Derive the expression for the rate constant (Integrated rate equation) of a First
order reaction and Calculate its half life period.

Model – PAPER SET- 2

 12TH CHEMISTRY

• MULTIPLE CHOICE QUESTIONS (M.C.Q'S) [1x35 = 35]

1. Due to Schottky defect. The density of crystal
(A) Increases (b) Decreases (c) remains same (d) None of these
2. Co- ordination number of a particle in body centered cubic packing is –
(a) 4 (b) 6 (c) 8 (d) 12
3. The Normality of 0.2 (M) aqueous solution of a dibasic acid is –
(a) 0.4 N (b)0.1 N (c)0.8 N (d) None of these
4. The mole fraction of a component in a binary solution is 0.25 then the mole fraction of
other
component is-
(a) 0.25 (b)0.75 (c)0.5 (d) None of these
5. the Rate constant unit of a zero- order reaction is-
(a) sec-1 (b) mol L-1 S-1 (c) mol-1 L-1 S-1 (d) None of these
6. The molecularity of reaction given below is H2(g)+I2(g) = 2HI
(a) 3 (b) 2 (c) 1 (d) Zero
7. The charge present on 1 mol of electron is equal to –
(a) 965 C (b) 96,500 C (c) 9.65x105 C (d) None
8. The unit of conductivity or specific conductance is –
(a) S.cm (b)S.cm-1 (c)mho.cm-1 (d) Both B &C
9. Tyndall effect is observed by –
(A) Lyophilic colloids (b) Lyophobic collids (c) Both (d) None
10. The device transforming chemical energy into electrical energy is known as –
(A) Electrolytic cell (b) Electrochemical cell (c) salt- Bridge (d) None
11. BAUXIDE is an ore of –
(A) Fe (b) Cu (c) Al (d) Pb
12. Cinnabar is an ore of –
(A) Hg (b) pb (c) Zn (d) None
13. Gangue+ Flux = ??
(A) Slag (b) Refractory materials (c) Dopant (d) None
14. The spin only formula is given by the expression –
(A) √ B.M (b) √ B.M (c) √ B.M (d) None
15. The no. of unpaired electrons is maximum in-
(A) Cu+ (b) Fe2+ (c) Sc3+ (d) Zn2+
16. d-d Transition is transitional metal compounds is responsible for-
(A) Catalytic activity (b) Colour of compounds (c) Both A & B (d) None
17. Which one of the following is paramagnetic in Nature ?
(A) Ti4+ (b) Fe2+ (c) Sc3+ (d) Zn2+
18. The oxidation number of Cr in Cr2o7 is-
(A) +5 (b) +6 (c) +7 (d) None
19. The oxidation no of c.m.i in [Cu(NH3)4)S is-
(A) +1 (b) +2 (c) Zero (d) None
+
20. The Co- ordination no of co.in [Co(en)2Cl2] is-
(A) +4 (b) +6 (c) +3 (d) None

21. The shape of I3- is –

(A) Triangular planar (b) linear (c) T.b.p (d) None
22. HCHO + 4[H]→ A , HERE A IS-
(A) methane (b) ethane (c) peopane (d) None of these
23. CH3OH + Socl2 → product (P) identify the product here –
(A) CH3Cl (b) HCOOH (c) CH4 (d) None
24. CHCl3 + Ag (Dust) Product (P) Here ‘P’ is-
(A) C2H4 (b) C2H2 (c) CH4 (d) C2H6
25. CH3Cl + KI → CH3I +KCI, The reaction is-
(A) Borodine- Hunsicker’s reaction (b) Finkelstein’s reaction
(c) Swart’s reaction (d) None of these
26. CH3COOC2H5 → product (p), Here 'P' is

(a) CH3OH (b) C2H5OH (c) CH3-CH(OH)C2H5 (d) None

27. CH3-CH2OH → 'A' , Here 'A' is

(a) CH3CHO (b) CH3CH2COOH (c) HCHO (d) None

28. CH3-NH2 + HNO2 'P', Here is

(a) CH3 2 (b) CH3OH (c) CH3NO2 (d) None

29. C CONH2 + KOH+Br2 CH3NH2 + KBr + K2CO3 + H2O

this reaction is

(a) Reimer- Tiemann reaction (b) Carbly anine Test

(c) Mustard oil reaction (d) Hoffmaan՚s rearrangement

30. Nylon-66 is a polymer of

(a) Caprolactam (b) Adipic acid & Hexamethylene diammine (c) Ethylene Glycol + Terephathalic
acid (d) None

31. Dacron is a polymer of:

(a) Caprolactam (b) Ethylene Glycol & Terephtalic acid (c) Adipic acid & Hexamethylene
diammine (d) None

32. Maltose upon hydloysis gives-

(a) Glucose only (b) Glucose + Fructose (c) Ribose + Glucose (d) None

33. The Nitrogen bases present in D.N.A molecule are :

(a)A, T, C & G (b) A, U, C & G

(c) A, C & G (d) None

34. The Enzyme responsible for conversion of Sucrose into Glucose & Frutose is

(a) Maltase (b) Invertase (c) Urease (d) None

35. ANTIHISTAMINES are also known as

(a) Antacids (b) Anti-malarial drugs. (c) Antipyretics (d) Anti-allergic drugs.

SUGJECTIVE PAPER

GROUP A [VERY SHORT ANSWER TYPE] ANSWER any 5 Question

1. Calculate the overall order of a Reaction, whose Rate Expression.

Rate = K[A] [B]

2. An Example of food-preservative is-

3. The monomer of ORLON is-

4.The End product of Digestion of protein is-

5. Give an example of an EMULSION.

6. Give an example of Ambidentate ligand.

7. What is Formalin?

Group B ( Short Answer Type)

3x5=15 Answer any 5 (five) Questions

8. Write the Differences between

Thermoplastics and Thermosetting polymers.

9. Define each with 1 examples

(a) Antacids (b) Analgesics (c) Antiseptic

10- Discuss the differences between DNA & RNA

11. Complete Reactions:

(a) CH3Cl + AgN (alc.)

(b) C6H5 OH + P

(C) CH3CH2 OH + + NaOH

2. What happens when ?

(a) Aniline is treated with NaNo2 & Hcl at 0-5°c.

(b) Phenol is treated with Fecl3 solution.

(c) Sodium alkoxide is treated with an alkyl halide in Dry ether

13.State and explain Raoults low of relative lowering of vapour presure . Also Derive it.

14. write I.U.P.A.C names of the following complexes-

(a) [Zn(oH)4}] (b) [Ni(CN)4] (c) [Cr(N C ]

GROUP C [(LONG ANSWER TYPE]

5X3=15 ANSWER ANY 3 QUESTIONS.

15.Write sheeet woles on following

a .Carbyl amine test b. Williamson՚s Synthesis .or Rosenmunds reaction.

c . Cannizoros rection.

16. Bring about the following conversiont

(a). Methane into ethane.(b) .Acetone into Chloroform

(c). Ethane nitrile into ethanol

(d). Benene into Aniline.

(e). Benene into Acltopherone.

17. Identify A'' .B'' C'' D'' E' IN the following reaction in Sequence-

(a) CH3Cl → A B

(b) ) CH3COOH → C→ D

(c) C6H5 Cl → E

18. Draw the Structures (shapes) of the following

(a) I (b) c) S (d) N e) P

19. a) Show that for a 1st order reaction, the time required for 99% completion of a reaction is
twice the time required to complete 90% of the reaction .

(b). An antifreeeze solution is prepared from 222.6 g of ethylene glycol (OH and 200g of
water. Calculate the molality of the solution.IF the density of solution is 1.072 g /ml.1 then,What
shall be the molarity of the solution
 MODEL SET - 3
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d{kk&12th fo"k; & Chemistry
le; & 3 ?kaVk iw.kkZad & 70

SECTION – A
All the question are compulsory
(Each question carries 1 marks) 35 01 =35
1. Which of the following defects decrease the density?
a) Interstitial defect b) Dislocation defect
c) Impurity defect d) Schottky defect
2. The correct order of the packing efficiency in different types of unit cells is……………………….
a) fcc bcc Simple cubic b) fcc bcc Simple cubic
c) fcc bcc Simple cubic d) bcc fcc Simple cubic
3. Which of the following point defects are shown by AgBr(s) crysteils?
a) Schottky defect b) frenkel defect
c) Metal excess defect d) Metal deficiency defect.
i) a) and b)
ii) c) and d)
iii) a) and c)
iv) b) and d)
4. Which of the following unit is useful in relating concentration of solution with its vapour
pressure?
a) Mole fraction b) Parts per million
c) Mass percentage d) Molality
5. Low concentration of oxygen in the blood and tissues of people living at high altitude is due
t……………………….
a) Low temperature b) Low atmospheric pressure
c) High atmospheric pressure
d) Both low temperature and high atmospheric pressure
6. Value of Henry's Constant ………………………..
a) Increases with increase in temperature
 b) Decreases with increase in temperature
c) Remains Constant
d) First increases then decreases
7. m(NH4OH) is equal to……………………
a) m(NH4OH) + m(NH4Cl) – (HCl)
b) m(NH4OH) + m(NaOH) – (NaCl)
c) m(NH4Cl) + m(NaCl) – (NaOH)
d) m((NaOH) + (NaCl) – (NH4Cl)
8. While charging the lead storage battery………………………………
a) PbSo4 Anode is reduced to Pb.
b) PbSo4 Cathode is reduced to Pb.
c) PbSo4 Cathode is oxidised to Pb
d) PbSo4 Anode is oxidised to Pbo2
9. According to Arrhenius equation rate constant K is equal to . Which of the
following options represents the graph of lnk Vs

a) b) lnk

lnk

1/T 1/T

c) d)
lnk ink

1/T 1/T

10. The role of a Catalyst is to change…………………..

a) Gibbs energy of reaction b) Enthalpy of reaction
c) Activation Energy of reaction d) Equilibrium constant
11. Which of the following statements are applicable to a balanced chemical equation of an
elementary reaction?
a) Order is same as molecularirty
b) Order is less than the molecularirty
c) Order is Greater than the molecularity
d) Molecularirty can never by Zero.
12. At the equilibrium position in the process of adsorption…………………
a) b)
c) d)
13. Which of the following is an example of absorption?
a) Water on silica gel b) Water on calcium chloride
c) Hydrogen on finely divided nickel
d) Oxygen on metal surface.
14. Which of the following process is responsible for the formation of delta at a place where
rivers meet the sea?
a) Emulsification b) Colloid formation
c) Coagulation d) Peptisation
15. Electrolytic refining is used to purity which of the following metals?
a) Cu and Zn b) Ge and Si
c) Zr and Ti d) Zn and Hg
16. Common impurities present in Bauxite ore……………………………
a) Cuo b) Zno
c) Fe2O3 d) SiO2
17. Which of the following elements can be involved in p – dπ bonding?
a) Carbon b) Nitrogen
c) Phosphorus d) Boron
18. The oxidation state of central atom in the anion of compound NaH2PO2 will be……………..
a) +3 b) +5 c) +1 d) -3
19. In Solid state PCl5 is a………………….
a) covalent solid b) octahedral structure
c) Ionic solid with [PCl6] octahedral and [PCl4]- tetrahedral
+

d) Ionic solid with [PCl4]+ tetrahedral and [PCl6]- octahedral

20. Which of the following reactions are disproportionation reactions?
a) Cu+ Cu2+ + Cu
b) 3MnO4- + 4H+ 2MnO4- + MnO2 + 2H2O
 c) 2KMnO4 K2MnO4 + MnO2 + O2
d) 2MnOu- + 3Mn2+ 2H2O+ 5MnO2 4H+
i) a,b ii) a,b,c iii) b,c,d iv) a,d
21. Which of the following is Amphoteric oxide?
Mn2O7, CrO3, Cr2O3, CrO, V2O5, V2O4
a) V2O5, Cr2O3 b) Mn2O7, CrO3,
c) CrO, V2O5 d) V2O5, V2O4
22. Which of the following oxidation state is common for all lamthanoids?
a) +2 b) +3 c) +4 d) +5
23. The correct IUPAL name of [Pt(NH3)2Cl2] is
a) Diamminedichlorido platinum (II)
b) Diamminedichlorido platinum (IV)
c) Diamminedichlorido platinum (0)
d) Dichloridodiammine platinum (II)
24. Which of the following options are correct for [Fe(CN)6]3- complex?
a) d2Sp3 hybridisation b) SP3d2 hybridisation
c) Paramagnetic d) Diamagnetic
25. Identify the correct Statement for the behaviour of Ethane -1,2 diamine as a figamel.
a) It is a neutral legend b) It is a didentate legend
c) It is a chelating legend d) It is a unidentate legend

26. IUPAC name of the compound CH3 CH-O-CH3 is ……………………..

CH3

a) 1 – Methoxy -1-Methylethane
b) 2 – Methoxy -2-Methylethane
c) 2–
Methoxy
Propane
 d) Isopropylemthyl ether

27. The position of –Br in the compound in CH3CH=CHC(Br)-(CH3)2

a) Allyl b) Aryl
c) vinyl d) Secondary
28. Identify the compound y in the following reaction.
29. Cannizaro's reactions is not Given by ……………………

CHO

a) b) CHO
CH3

c) HCHO d) CH3CHO
30. Which is the most Suitable reagent for the following conversion?
O O

CH3 CH=CH CH2 C CH3 CH3 CH=CH H2 C OH

a) Tollen's reagent b) Benzoyl Peroxide
c) and NaoH Solution d) Sn and NaoH Solution
31. The Source of Nitrogen in Gabriel synthesis of Amines is……………….
a) Sodium Azide, NaN3 b) Sodium Nitrite NaNO2
c) Potassium cyanide, KCN d) Potassium Phthalimide
C6H4(Co)2N-K+
32. Which of the following B group vitamins can be stored in our body?
a) vitamin b) vitamin
c) vitamin d) vitamin

33. Which of the following polymer can be formed by using the following monomer.

34. Equanil is…………………..

 a) Artificial sweetener b) Tranquilizer
c) Antihistamine d) Anti fertility drug
35. Which of the following enhances leathering property of soap?
a) Sodium carbonate b) Sodium rosinate
c) Sodium stearate d) Tri sodium Phosphate

SECTION – A
Answer any 05 of the following questions 05 01=5
(Each question carries 01 marks)
1. What is Schottky defect?
2. what is metallurgy?
3. Write the IUPAC name of
CH2 = CH CH2 C CH
4. Write down an Example of Antacids?
5. Which catalyst is used in Haber's proess?
6. How many atoms are present in body centred cubic (bcc) unit cell?
7. What is Ziegler natta catalyst?

SECTION – B
Answer any 05 of the following questions: 05 03=15
(Each question carries 03 marks)
8. Write the difference between physisorption and chemisorptions.
9.Give two advantages of fuel cell.
10.Arrange the following Compounds in decreasing order of their boiling points Butanol,
Butanamine, Butane.
11. How will you distinguish aldehyde and Ketone. Give reaction.
12. Draw the Shape of the following compounds.
a) N b) Xe c) Xe
13. Write the final products in Each of the following reactions.
CH3

a) CH3 C O CH3 + HI

CH3
Cu /573K
 b) CH3 CH2 CH CH3 CH

OH
CHC /aq NaOH
c) C6H5 OH

14. Why aniline does not undergo Friedel-Craft reaction. Give reason.

SECTION –C
Answer any 03 of the following questions: 03 05=15
(Each question carries 05 marks)
15 Write down the difference between
Buna – N and Buna - S
16.Draw the structure of the following compounds:-
a) ClF3 b) BF3 c) XeF2
d) SO2Cl2 e) H2S2O7
17.Calculate the time of deposit 1.17g of Ni at Cathode when a current of 5 A was passed
through the solution of Ni(NO3)2.
(Molar mass of Ni = 58.5g Mol-1, 1F = 96500(C Mol-1)
18.Give the difference between order and Molecularity.
19.Write short notes on:- 2 2=5
a) Sandmeyer Reaction:-
b) Kolbe Electrolysis Reaction:-