11.

1.0

Warm up (C

D
A
Y
8 Exercise 12.C

(Target NEET) (

13.T

equilibrium constant (K.) 5. In which of the following, dissociation of NH,OH will he

1, At constant temperature, the minimum?
2NO,(a) is
for the decomposition reaction N,O,(g) (a) NaOH (b) H,0
(4x°p) where, p=pressure, (c) NH,CI (d) NaCI
expressed by Kp
(1-x²) alkaline
following 6. An aqueous solution of sodium carbonate is
x= extent of decomposition, which one of the because sodium carbonate is a salt of
statements is true?
p
(a) weak acid and weak base
(a) K, increases with increase of
(b) strong acid and weak base 14. T
(b) K, remains constant with change in p and x (c) weak acid and strong base
(c) Kp increases with increase of x (d) strong acid and strong base
(d) None of the above gaseous
7. Partial pressure of A, B,Cand D on the basis of
2. For the reaction, PCl_(g) +Cl,(g)PCI;(g), the
system; A+2BC+ 3D; are A=0.20, B=010
15. F
position of equilibrium can be shifted to the right by C=0.30 and D = 0.50 atm. The numerical value of
(a) doubling the volume equilibrium constant is
(b) increasing the temperature (a) 3.75 (b) 18.75
(c) addition of Cl, at constant volume (c) 17.85 (d) 15.87
(o) addition of equimolar quantities of PCl, and PCis 8. 4.5 moles each of hydrogen and iodine heated in a
3. 4 moles of Aare mixed with 4 moles of B. At equilibrium sealed 10 L vessel. At equilibrium, 3 moles of HIl were
for the reaction, ABC+D,
+ 2 moles of C andD found. The equilibrium Constant for
are formed. The equilibrium constant for the reaction will H,(g) +I,(g 2HI(g) is
be (a) 1 (b) 5
(a) 1 (b) 1/2 (c) 4 (d) 1/4 (c) 10 (d) 0.5
16. Ir
4. For the synthesis of ammonia by the reaction 9. One mole of a compound AB reacts with one mole of a
N, + 3H,’ 2NH in the Haber process, the compound CD according to the equation
attainment of equililbrium is correctly predicted by the AB + CDAD + CB. When equilibrium had been
CUrve concentration established it was found that 3/4 mol each of reactants
concentration
AB and CD had been converted to AD and C8-There is
molar H molar H, 17. T
no change in volume. The equilibrium constant for the
(a) N2 (b) N2 reaction is

NH3 NH3 (a (b)

16
Concentration
time concentration
time 16
molar
(C) (d) 9
NH3 molar -NH3 19

(c) H
(d) -N2 10. Ammonia gas dissolves in water to form NH,OH. In this 18.
N H reaction water acts as
(a) a conjugate base (b) a
time time
(c) an acid
non-polar solvent
(d) a base
 95
Equilibrium
and O,
of CO,, CO
pressure
11. The solubility in water of a sparingly soluble salt AB, is 19. At 3000K, the equilibrium thereaction
respectively. K, for
10x 10-5 mol L', its solubility product (Ksp) is are 0.6, 0.4 and 0.2 atm
2 CO, 2 CO+ O, is (d) 0.198
(a) 4 x 10-15
(b) 4 x 10-10 (c) 0.189
(a) 0.089 (b) 0.098 salt
(c) 1x 10-15 (d) 1x 10 -10
a sparingly soluble 'S
20. The molar solubility (mol L- of. productis Kao:
12. Change in volume of the system does not alter the | solubility
MX, is 'S. The corresponding
number of moles in which of the following equilibrium? relation
IS given in terms of K.. by the (128 Ks
(a) N,(g) +O,(g) 2NO(g) (a) S = (256 K. Y'5 (b) S - /256)5
(b) PCIs(g)PCI, (g) + Cl,(g) (c) S =(Ksn 1128)4 (d) S =(Kso 10-4
(c) N,(g)+ 3H,(g)2NHa(g) weak acid is 1x
21. Dissociation constant of a
strong base is
(d) SO,CI, (g) SO,(g)+Cl,lg) Equilibrium constant of its reaction with
equilibrium constant for the reaction (a) 1x 1o-4 (b) 1x1010
13. The 9rlt
N,(g)+ O2(g)2NO(g) at temperature T is 4x 10-. (C) 1x 10-10 (d) 1 x 104
ammonia has
The value of Ke for the reaction and H, to form
22. The reaction between Ng numerical
temperature 500°C. The
NOI9)N(9)+0,0) atathe same temperature K =6x 10-2 at the
value of K, for this reaction is
10-6
(a) 1.5 x 10-5 (b) 1.5 x
(a) 25 (b) 50 (d) 15 x 106
(c) 1.5x105
shift the equilibrium
(c) 75 (d) 100
23. Of the following which change will
14. The aqueous solution of FeCI, is acidic due to
towards the product?
(a) acidic impurities (b) ionisation
l,(g) 2l(g): AH, °(298) =+150 kJ
(c) hydrolysis (d) dissociation (a) Increase in temperature
15. For the reaction, (b) Increase in total pressure
(c) Increase in concentration ofI
Hzlg) +C0,(g) CO(g)+ HOlg): (d) Decrease in concentration of l,
if initial concentration of [H,]= [CO,] and x mol/L of COCI,(g): the Ke
hydrogen is consumed at equilibrium, the correct 24. For the reaction, co(g)+Cl,(g)
expression of K, is is equal to
(b) (2+ x)² 1 (b) AT
(a) (a)
(1-x?
(1+ x² (c) VAT
(c) (d) (d)
1-x° (1- x?
16. In which one of the following gaseous equilibria, K, is 25. What is the effect of increasing pressure on the
dissociation of PCIl,, according to the equation?
less than K,?
(b) 2S0, + O,2S0, PCI,(g) PCl,(g)+ Cl,(g)-x cal
(a) NO,2NO, (a) DissSociation decrease
(c) 2HIH,+ (d) N, + O,2NO (b) DisSociation increase
(c) DisSOciation does not change
17. The solubility of Agl in Nal solution is less than that in
pure water because (d) None of the above

(a) Agl forms complex with Nal 26. The species among the following which can act as an
(b) of common ion effect acid and a base is
(c) solubility product of Agl is less (a) HSO (b) SO (c) H,0* (d) CI
(d) the temperature of the solution decrease
reaction 27. Amixture of 0.3 moles of H, and 0.3 mole of l, is allowed
18. The value of Ko for the following
to react in a 10 Levacuated flask at 500°C. The reaction is
2H,S(g) 2H,(g) + S>(g): is 12 x 10 at 106.5°C. Ha + l,2HI, the K is found to be 64. The amount of
The value of K, for this reaction is unreacted l, at equilibrium is
(a) =1.2x10-2 (b) <1.2 x10-2 (a) 0.03 mol (b) 0.06 mol
(c) > 1.2 x102 (d) None of these (c) 0.09 mol (d) 3.6 mol
 Encounter with NEET Chemistry in Just 40 Days
96
36. 01 mole of CH,NH, (Kh =5x 10 ) 4.EC
product of PbCI, at 20°C is 15x 104
28. The solubility 0.08 mole of HCI and diluted to 1 L. What
Calculate the solubility. Mil be the
(b) 3.34x 10-2 H concentration in the solution?
10-4
(a) 3.75 x (d) None of these (a) 8x10 M (b) 8x 10'M
(c) 3.34 x 102 (c) 1.6x 10-1'M (d) 8x10o-°M
solid NH,HS is placed in a flask already
al
29. An amount of 37. For the reaction, 2NOCI(g) 2NO(g) +C,(g) k
at a certain temperature and
containing ammonia gas Ammonium 427°C is 3x 106 Lmol-1, The value of K, is nearly
pressure. hydrogen sulphide
0.50 atm to yield NH, and HS gases in the
(a
decomposes flask. (a) 7.5 x 10-5
eguilibriurm
When the decomposition reaction reaches at (b) 2.5 x10-5
0.84 atm The
the total pressure in the Tlask rises to (c) 2.5x 104
equilibrium constant for NHHS decomposition at this 45.C
(d) 1.72 x10-4
temperature is
(b) 0.22 38. A weak acid, HA has K¡ of 1.00 x 10-5 If 0.100 mole of C
(a) 0.11
(c) 0.33 (d) 0.44 this acid is dissolved in one litre of water, the percente (
30. A reaction is, A+BC+ D; initially we start with of acid dissociated at equilibrium is closest to (
(a) 9.90% (b) 1.00%
equal concentrations of A and B. At equilibrium, we find (d) 0.100%
(c) 99.9%
the moles of Cis two times of A. What is the equilibrium 46.
constant of the reaction? 39. By adding 20 mL of 0.1 N HCI to 20 mL 0.001 N KOH the
(a) 2 (b) 4 pH of the obtained solution will be
1 1 (b) 1.3
(d) (a) 2
() ; (c) 0 () 7
31. 0.1 mole of CH,NH,(Kp =5x 104) is mixed with 40. For the reaction,
0.08 moles of HCI and diluted to one litre. What will be CH,(g) +20,(g) C0,(g) +2H,0(/);
the H' concentration in the solution? A,H=-170.8 kJ mol-1 47.
(a) 8x10 M (b) 8 x10-1'M
(b) 1.6x 10-1" M Which of the following statements is not true?
(d) 8x10-5 M
(a) At equilibrium, the concerntration of CO,(g) and H,0 )
32. Given pH of a solution A is 3 and it is mixed with another are not equal
solution B having pH 2. If both mixed then resultant pH of (b) The equilibrium constant for the reaction is gven by
the solution willbe [CO,]
Kp
(a) 3.2 (b) 1.9 (c) 3.4 (d) 3.5 [CH,] [O,] 48. V
33. A buffer solution with pH 9 is to be prepared by mixing (c) Addition of CH,(g)or O,(g) at equilibrium will cause a
NH,CI and NH,OH. Calculate the number of moles of shift to the right
NH,CI that should be added to one litre of 1.0 MNHOH. (d) The reaction is exothermic
(K, =1.8 x105] 41. The solubility product of As,O, is 10.8 x 10. It is 50%
(a) 3.4 (b) 2.6 dissociated in saturated solution. The solubility of salt is
(c) 1.5 (d) 1.99 49
(a) 10-2 (b) 2 x10-2
34. In hydrolysis of a salt of weak acid and strong base (c) 5x1o-3 (d) 5.4 x 10-9
A + H,OHA + OH 42. The hydrogen ion concentration of a 10* M HCI aqueous
the hydrolysis constant (K,) is equal to solution at 298 K (K, =1014) is
(a) (b) K. (a) 1.0 x10-6 M
K, Kp (b) 1.0525 x 10- M
(C (d) Ky
K, K,
(c) 9.525 x 10- M
(d) 1.0 x 10-8 M
35. A weak acid HX has the dissociation constant 1x 10- M. 43. 40 mL of 0.1 M
it forms a salt NaX on reaction with alkali. The degree of
ammonia
0.1 MHCI. What is the pH solution
is mixed with 20 mL ot 50,
of the mixture?
hydrolysis of 0.1 Msolution of NaX is (pk, of ammonia solution = 4.74)
(a) 0.0001% (b) 0.01% (a) 4.74
(c) 0.1% (b) 2.26
(d) 0.15% (c) 9.26
(d) 5.00

stant (K
 97
Equilibrium
ansers
one of the
more thananswer and mark it
A4, Equilibrium constants K, and K, for the following Directions (Q. No. 51 and 52)
correct
equilibrium given may be Correct. Select the
according to the codes.
1
NO(g) + K2 NO(9) Codes
(b) 1and 2
are correct
correct
(a) 1,2 and 3 are correct 3 are
(c) 2 and 4 are correct (d) 1 and
and 2NO,(g) 2NO(g) +O,(g) are
are related as 51. The Lewis acids among thefollowing
1 1. BE 2. AICI,
(a) K2 K, (b) K, = K? 4. H,O
3. BeCl,
1
(c) K2 K,K1 52. Study the following table
Volume (in mL) of
salt of
45. CaC0,CaO + CO reaction in a line goes to Butfer Volume (in mL) of 1 M 0.1 M sodium
solution weak acid weak acid
completion because
4.0
(a) CaO does not react to CO, to give CaCO, 1 4.0
40.0
(b) backward reaction is very low 40
4.0
(c) CO, formed escapes out 40.0
(d) None of the above 10.0
4 0.1
46. The degree of dissociation of 1.0 Mweak acid, HA is have least pH?
Whichof the two sets of buffer solutions
0.5%. If 2 mL of 1.0 MHA solution is diluted to 32 mL, the Column ) with relation
degree of dissociation of the acid and H0* ion 53. Match the chemical reactions (in the correct
Concentration in the resulting solution will be between K, and K. (in Column ) and choose
codes.
respectively?
(a) 0.02 and 8.2 x 10-12 (b) 0.02 and 3.125 x 10-4 Column Il
Columnl
(c) 0.02'and 1.25x10-3 (d) 1.25 x10 and 0.02
A. 2S0,(g)+ O,(g)2S0,(g) 1. Kp = Ke
47, If 0.1 M of weak acid is taken and its degree of B. PCI,(g) PCI, (g) + Cl,(g) 2. K =K(ATS
dissociation is 1.34%, then ionisation constant will be
(a) 0.8x105 C. H,(g) +I,g) 2HI(g) 3. K, = K/RT
(b) 1.79 >x10-5 D. Nalg) + 3H,(g) 2NH,(g) 4. K, = Ke (AT)
(c) 0.182 x 10-5
(d) None of the above Codes
A BC D A D
48. When 10 mL of 0.1 M acetic acid pK, =5.0) is titrated
(a) 1 4 1 2 (b) 2 1 4
against 10 mL of 0.1 M ammonia solution (pk, =5.0), (c) 3 2 4 1 (d) 4 1 3
the equivalence point occurs at pH
(a) 5.0 (b) 6.0 54. Match the salt (in Column I) with its equation of pH
(in Column I) and choose the correct codes.
(c) 7.0 (d) 9.0
49. The rapid change of pH near the stoichiormetric point of Column l(salt) Column IM (pH)
an acid base titration is the basis of indicator detection.
1
A. Weak acid and strong 1.
pH of the solution is related to ratio of the concentration base
of the conjugate acid (Hin) and base (In) forms of the B. Strong acid and weak 2.
indicator given by the expression base
K, pK, -pk,)
C. Weak acid and weak base3.
(a)log n].= pKin -PH (b) log [Hin pKin - pH K, -pk, -logC]
(Hin] [In]
1
D. Strong acid and strong 4. pK, +pk, logC)
(c) log [Hin) = pH- pkin (d) log (In") = pH- pKin base
(In] [Hin]
Codes
50. What is the pH of 0.01 M glycine solution? For glycine A B C D A B C D
Ka =4.5x 10* and Ka, =1.7 x 10-1° at 298 K? (a) 1 2 3 4 (b) 4 2 1 3
(a) 3.0 (b) 10.0 (c) 4 3 2 1 (d) 2 3 1 4
(c) 6.1 (d) 7.1
 98 Encownter with NEET Chemistry in Just 40 Days
Directions (QNOs. 55 to 60) Each of these questions containe
63. Buffer solutions have constant acidty
and Reason. Each of these and
two statements Assertion questions because alkal
also has four allernative choices, Oniy one of which is the Correct
answer. You have to select one of the codes (a), (b). (c), (d) qiven (a) these give unionised acid (CBSE-AIPWTwith 2012
or base on reaction
below
la) Assertion is true, Heason is rue, Heason is a correct
acid or alkali
(b) acids and alkalies in these solutions are ad ded
explanation for Assertion
(b) Assertion is true, Reason is true, Reason is not a correct
attack by other ions
(C) they have large excess of H" or OH ions
shielded from
explanation for Assertion
(c) Assertion is true, Reason is false. (d) they have fixed value of pH
(d) Assertion is false, Reason is true. 64. Equimolar solutions of the folowing
55, Assertion NaCl solution can be purified by passage of
substances e
prepared separately. Which one of these will reCord
hydrogen chloride through brine. highest pH value?
Reason This type of purification is based on (a) BaCl, (b) AICI, (c) LiCI [CBSE-AIPMT 20121
(d) BeCl,
Le-Chatelier principle. 65. pH of a saturated solution of Ba(OH), is
56. Assertion On mixing 500 mL of 10 MCa2t ion and 12. The valus e:
500mL of 10 MF ion, the
precipitate of CaF, will be solubility product Ko of Ba(OH,) is (CBSE-AIPMT 2017
(a) 3.3 x 10-7 (b) 5.0 x 10-7
obtained. Kso (CaF, = 10).
(c) 4.0 x 10-6 (d) 5.0 x 10-6
Reason If Ken iS greater than ionic product, a 66. On adding 0.1 Msolution each of [Ag"].
will develop. precipitate [Ba(Ca2-;Jin
a Na,SO, solution, species first
57. Assertion On cooling ina freezing mixture, colour of precipitated
[Ksp BaS0, =10-", Kso CaSO, = 10 and
is
mixture turns to pink from deep the
blue for a reaction. Ksp AgsO, =10]
Co(H,0 (aq) + 4CI (aq) CoCI? (ag) + 6H,0 () (a) Ag,SO4 [AFMC2012)
(b) BaSO,
Reason Reaction is endothermic, so on (c) CaSO,
reaction moves to backward direction. cooling, the (d) Allof these
58. 67. For the reaction,
Assertion Addition of an inert gas to the
mixture has no effect on the state equilibrium 2NO,(g) 2NO(g) +
Constant volume or at constant of equilibrium at (K, =1.8 x10 at 184°C O,(g)
and R= 0.00831 kJ/mol K)
pressure.
Reason The addition of inert gas at When Ko and K, are compared at 184°C, it is [AFMC 2012)
not alter the constant volume will found that
concentrations of the
products of a reaction mixture. reactants as well as
(a) whether K, is
greater than less than or equal to K.
depends upon the total gas pressure
59. Assertion The pk, of a (b) K, = Ke
weak acid become equal to the (c) K, is less than K
pH of the solution at the mid point of its
Reason The molar
titration. (d) K, is greater than K
and proton donor concentrations
become
of proton
acceptor 68. What is the
correct
titration of a weak acid. equal at the mid
point of isomolar solutions ofrelationship
sodium
between the pHs of
60. Assertion sulphide (pH), oxide (pH,), sodium
Addition of NH,OH to an
BaCl, in presence of NH,CI aqueous solution of telluride (pH,)? sodium selenide (pH), and sodium
(excess) precipitates (a) pH, > pH, pH, > [AIIMS 2012]
Ba(OH)2 (b) pH, < pH <pH, < pH,
Reason Ba(OH), is insoluble in water. (c) pH, < pH < pHg pH 2
31. Assertion pH of neutral solution is (d) pH, > pH, > pH, >pH,
Reason pH of
always 7. pH,
a solution does 69. Abuffer
of NH, is solution
not is 5
depend upon
temperature. 0.30 Mandprepared in which the 6

eguilibrium constant,concentration concentration

2. [AIIMS 2011] If the the of NH; is 0.20 M. 71
Assertion N, is a weaker base than NH,. Ko
[AIIMS 2010) what is the pH of this for NH,
Reason The lone pair of equals 1.8 x 10
solution? (log2.7 =0.43)
asp-orbital while in electrons on N atom in Na is in (a) 9.43
NH, it is in an
sp-orbital. (c) 8.73 (b) 11.72
(d) 9.08
(CBSE-AIPMT 2011)
 99
Equilibrium
0.20 Min
solution that is
70. The value of AH for the reaction. 76. What a
is [H*] in mol/L of CH,COOH?
X,(g)+ 4,(g) 2XY,(g) is less than zero. Formation of CH,COONa and 0.10 Mlin [CBSE-AIPMT2010]
XY, (g)will be favoured at [CBSE-AIPMT 2011] (K, for CH,coOH = 1.8x 10°)
(a) low pressure and low temperature (b) 1.1x10-5
(a) 3.5 x 10-4 10-6
(b) high temperature and loW pressure (c) 1.8 x105 (d) 9.0 x value of
(c) high pressure and low temperature of Ba(OH), is 12,the
77. If pH of a saturated solution [CBSE-AIPMT2010]
(d) high temperature and high pressure
its Ksp IS 10- M
71, For the reaction Nz(g) +O2(g) 2NO(g), the (a) 4.00 x10-6 M (b) 4.00x 10-7M
equilibrium constant is K. The equilibrium constant is K, (c) 5.00 x10-® M (d) 5.00 x orange
for the reaction 2NO(g) + O,(g) 2NO,(g). What is K of methyl
1 78. 100 mL of HCI + 35 m of NaOH, colour [AFMC 2010]
for the reaction NO,(g) Nz(g) +O2lg)? in this solution will be
(CBSE-AIPMT 2011) (a) red
(a) 1/4K,K2) (b) [1/KKze (b) yellow
(c) 1/(KK2) (d) 1/2K,K2) (c) can't be predicted
(a) methylorange is not a suitable indicator
72. Which of the following is least likely to behave as Lewis [AIIMS 2010]
base? [CBSE-AIPMT 2011] 79. The following equilibria are given
(a) NH, (b) BF, 1. N, + 3H, 2NH3; K,
(c) OH (d) H0 I.N + Oz 2NO; K2
73. Ammonium ion is [AFMC 2011] 1
Kg
(a) neither an acid nor base (b) both an acid and a base
(c) a conjugate acid The equilibrium constant for the reaction,
(d) a conjugate base
74. In a buffer solution containing equal concentration of B 2NH, +0, 2NO+ 3H,0
and HB, the K, for B is 10-10, The pH of buffer solution is in terms of K, K, and K, will be
[CBSE-AIPMT 2010]
(a) KiKzKg (b) KK2
(a) 10 (b) 7 K3
(c) 6 (d) 4
(c) KK () K,K?
75. In which of the following equilibrium K, and K, are not K2 K,
equal? [CBSE-AIPMT 2010]
80. If the concentration of Cro:?ions in a staurated solution of
(a) 2C(s) +Oz(g) 2C0,(g) silver chromate is 2 x 104 M, the solubility product of
(b) SO,(g) +NO,(g)s0,(g)+ NOG) silver chromate would be (AIIMS 2010]
(c) Hzg) + lz(g) 2HI(g) (a) 32 x 10-12 (b) 8x10-12
(d) 2NOg) Ng)+ Oz(g) (c) 16x 10-12 (d) 8x10-8

Answers
1 2. (c) 3. (a) 4. (a) 5. (c) 6. (c) 7. (b) 8. (a) 9. (d) 10. (c)
11. 12. (a) 13. (b) 14. (c) 15. (a) 16. (b) 17. (b) 18. (b) 19. (a) 20. (d)
21. 22. (a) 23. (a) 24. (a) 25. (a) 26. (a) 27. (b) 28. (b) 29. (a) 30.
31. 32. (b) 33. (d) 34. (a) 35. (b) 36. (b) 37. (d) 38. (b) 39. (b) 40.
41. 42. (b) 43. (C) 44. (d) 45. (C) 46. (c) 47. (b) 48. (c) 49. (d) 50.
51. 52. (d) 53. (a) 54. (c) 55. (C) 56. (d) 57. (a) 58. (a) 59. (a) 60.
61, (d) 62. (a) 63. (a) 64. (a) 65. (b) 66. (b) 67. (d) 68. (d) 69. (a) 70.
71. (b) 72. (a) 73. (c) 74. (d) 75. (a) 76. (d) 77. (d) 78. (a) 79. (d) 80.