14.

Warm up
D
A 22 Exercise
(Target NEET)
15.

16.
7. The activation energy of a reaction is 9 k
1, For the reaction, increase in the rate constant when its cal/mol. Theis
Ha(g)+ Br,(g)’ 2HBr(g) raised from 295 to 300 K is approXimately
(b) 50% (c) 100%
temperature
(d) 29%
the experimental data suggest (a) 10 %
rate =K[H,] (Br,'2 8. The rate constant of a reaction at temperature 200 K.
The molecularity and order of the reaction are 10 times less than the rate constant at 400 K. What is th
activation energy (E,) of the reaction?
respectively
1 (a) 1842.4 R (b) 921.2 A (c) 460.6 R (d) 230.3A
(b) 1,1
(a) 1; 9. The temperature coefficient of most of the reactions lies
3 3
(c) 32 (d) 2. 2 between
(a) 1and 3 (b) 2 and 3 17.
2. For the reaction, 2A + B ’ products; the active mass (c) 1and 4 (d) 2 and 4
of Bis kept constant, and that of A
is doubled. The rate of 10. Activation energy of a chemical reaction can he
reaction will be then
determined by
(a) decrease 4 times (b) decrease 2 times
(c) increase 4 times (d) increase 2 times
(a) evaluating rate constant at standard temperatures
(b) evaluating velocities of reaction at two different
3. The first order rate constant for dissociation of N,O, is temperatures
6.2 x 10s. The half-life period of this dissociation (c) evaluating rate constant at two different temperatures
(in second) will be (d) changing concentration of reactants
(a) 1117.7 (b) 111.7 11. The efficiency of an enzyme in catalysing a reaction is
(c) 223.4 (d) 160.9 due to its capacity
4. The rate constant for the reaction (a) to form a strong enzyme substrate complex
(b) to decrease the bond energy of all substrate molecules 18.
2N,O, 4NO, + O,
(c) to change the shape of the substrate molecule
is 3.0 x 10s. If the rate of reaction is 2.40 x 10 then
. (d) to lower theactivation energy of the reaction
the concentration of N,O, (in mol/L) is
(a) 1.4 (b) 1.2 12. If E, and E, are the activation energies of the forward and
(c) 0.04 (d) 0.8 reverse reactions and the reaction is known to be
exothermic then 19.
5. The rate constant of a zero order reaction is
0.2 mol dmh. If the concentration of the reactant after (a) E, < E,
30 min is 0.05 mol dm, Then, its initial (b) E, > E,
WOuld be
concentration (c) E, = E,
(d) No relation can be given between E, and E, .as
(a) 0.01 mol dm3 (b) 0.15 mol dmn-3 not sufficient
data are
20.
(c) 0.25 mol dm-3 (d) 4.00 mol dm3
13. The half-life period for zero
6. The ratio of the times of 99.9% of order reaction
the reaction to ’ product; is 100 min. How long will it take in 80'%
Complete and half of the reaction to complete is completion?
(a) 2 (b) 4 (a) 80 min (b) 160 min
(c) 8 (d) 10 (c) 100 min
(d) 200 min
 Chemical Kinetics 271
For thereaction, N, + 3H, 2NH,
21. For a zero order rate
The rate
of change of
concentration for hydrogen is reaction A ’P, tu is (k is
03x 10 Ms
constant)
Therate of change of concentration of ammonia is (a (b
In 2
(a) -02x 10-4 2k k
(b) 0.2x 10-4 1
(c) 01x 10-4 (C) In 2
(d) 0.3x 10-4 (d)
K[AJ (A,]k
15. For a
first order reaction, the 0.1 Mto
08 to 0.4 in 15 min. Theconcentration changes 22. The from
time taken for the concentration of reactant Xdecreases
O000 M in 40 min If the reaction follows first order
concentration to change from 0.1 Mto 0.025 Mis
(a) 30 min kinetics, the rate of reaction when concentration of iS
(b) 15 min 0.01 M will be
(c) 75 min (d) 60 min -1
(a) 1.73 x 10 Mmin-! (b)3 47x 10 M min
. For a reaction between A and B. the min!
initial rate of (c) 3.47x 105 Mmin-1 (d) 7.50x 10M
reaction is measured for various intial
and B. The data provided are concentrations of A 23. What is the order of a reaction which has following rate
expression?
[AJ [B] Initial reaction rate rate =k(A)32(B)-'?
(1) 0.20 M 0.30 M 5x 10-5 la)3 1
(2) 0.20 M 0.10 M 5x 10-5 2 (b) ;
(3 0.40 M 0.05 M (c) 0 (d) None of these
1x 10-4
The overall order of the reaction is 24. The half-life of the reaction;
(a) one (b) two
(c) two and half (d) three N,0,’ 2NOO, is 2.4 h. Starting with 10.8 g of
17. Given the
hypothetical reaction mechanism N,O5. how much oxygen will be obtained after period of
96 h?
ABc ’E and the date as
(a) 1.5 L (b) 3.36 L
Species formed Rate of its formation (c) 1.05L (d) 0.07L
0.002 mol/h per mole of A 25. Consider the reaction, N(g)+ 3H,(g) ’ 2NH,
0.030 mol/h per mole of B
D 0.011 mol/h per mole of C
0.420 mol/h per mole of D
the equality relationship between d[NH,] and
dt -d[H2lis
dt
(a) d[NH,] 1d [H,] (b)
+d [NH,] 2d [H]
The rate determining step is dt 3 dt dt 3 dt
(a) step | (b) step ll (c) + d[NH,] 3d [H,] d[NH,] d[H,)
(c) step Il| 2 dt
(d)
(d) step V dt dt
18. After how many seconds will the concentration of the 8
26. The rate law for a reaction between the
substances A
reactant in a first order reaction be halved if the rate and B is given by rate = k[AT[BY". On doubling the
Constant is 1.155x 10 s-l? concentration of A and halving the
the ratio of the new rate to the earlier concentration
of B
(a) 600 (b) 100 rate of the reaction
will be as
(c) 60 (d) 10 1

9. If a certain reaction is first order with respect to A, (a) (b) (m + n) (c) (n - m) (d) 2n-m)
second order with respect to B and zero order with
respect to C then what is the order of reaction? 27. ta can be taken as the time taken for
the concentration
(a) First (b) Second of a reactant to drop to 3 of its
(c) Third (d) Zero initial value. If the rate
Constant for a first order reaction is k, the
t,s can be
0. A drop of solution (volume = 0.05 mL) contains written as
60.0x 10-'mol of H.If the rate of disappearance of H* is (a) 0.75/k (b) 0 69/k (c) 0.29/k
6.0x 105 mol / Lx s, how long will it take for H* to (d) 0.10/k
28. A first order reaction is 75%
disappear from the drop? complete after 32 min. When
was 50% of the reaction completed?
(a) 8.0 x10s -(b) 2.0 x 10-s
(a) 16 min (b) 8 min
(c) 6.0x 10 s (d) 2.0x 10 s
(C) 4 min (d) 32 min
 Encounter with NEET Chemistry in Just 40 Days
ANO, +O,. 36. For a reversible reaction. A 8 which one
reaction, 2NO of the
29. In the following staternents is wrong frorn
the given
Inibial pressure is 500 a and Tate constant k is
3.38x 10s After 10) min the final pressure of N,O, iS
profile diagram? energv
(a) 490 atm (b) 250 atm
c) 480 atm (d) 420 atm

chemical reaction
30. The rate law for the
4
2NO,CI 2NO, + CI, is
rate =K(NO C] The rate determining step is
la) 2NOC’2NO, - 2C1
Reaction coordinate
NO,CI C
(b) NO, Cl, (a) Activation energy of forward reaction is greater hor
(C) NO,CI+ Cl’NO, Cl, backward reaction
(d) 2NO,CI’2NO, Cl, (b) The forward reaction is endothermic
(c) The threshold energy is less than that of activation enerov
21 Which of the following statement is in accordance with
collision theory? (d) The energy of activation of forvward reaction is equal to
the sum of heat of reaction and the energy of activation of
) Rate is directly proportional to collision frequency backward reaction
() Rate depends upon orientation of atoms
() Termperature determines the rate 37. For the two gaseous reactions, following data are given
(a) Only Il (b) land | A ’ B, k, = 10 -20 000/T
(C) Il and I|l (d) All of these
C ’ D; k, = 10o'e-24 606/ T
32. For afirst order reaction, A’B, the
reaction rate at the temperature at which k, becomes equal to k, is
reactant concentration of 0.01 M is found to be
20× 10 mol LS The half-life period of the (a) 400K (b) 100OK
reaction is (C) 800K (d) 150OK
(a) 220 s (b) 30 s (c) 300s (d) 347s 38. The rate constant is doubled when temperature
33. For a reaction aA ’XP, when [A] = 2.2 mM, the increases from 27°Cto 37°C. Activation energy in kJ is
rate (a) 34 (b) 54
was found to be 24 m Ms On reducing
concentration
of Ato half, the rate changes to 0.6 m Ms The
(c) 100 (d) 53
order of
reaction with respect to A is Directions (Q. No. 39 and 40) In the following questions, more
(a) 1.5 (b) 20 (c) 2.5 (d) 3.0 than one of the answers given may be correct. Select the correct
answer and mark it according to the codes.
34. The rate of first order reaction is 15x 10 mol L-min Dire
Codes
at 05 M concentration of the reactant. The
half-life of the (a) 1,2 and 3 are correct
reaction is
(b) 1 and 2 are correct
(a) 0.383min (b) 23 1 min (c) 2 and 4 are correct
(c) 8.73 min (d) 7.53 min (d) 1and 3 are correct
35. The rate constant for the reaction
39. Consider thefollowing statements with respect of zero
N,O,(9) 2NO,(9)+0,(9) order reaction
2 1. The reate of the
IS 2.3x 10 s
reaction is independent of ternperature.
Which eguation given below describes 2. The rate of the
reaction is independent of reactant
the change of [N,O,] with time? Concentration
3. The rate constant of the
[N,Osh and (N,O,), corresponds to concentration of reaction is independent of
N,O. initially and at time t temperature
4. The rate constant of
(a) (N,0,), = (N,O, b+ kt the reaction is
reactant concentration independent
of
(b) (N,0, =log [N,O,) + kt 40. For the first order reaction
(c) iog (N,0,), =log[N,0,b + kt 1. the degree of
= kt 2 a plot of
dissociation is equal to (1 -e )
(N,O,) reciprocal concentration of the reactant versus
times gives a straight line
 273
Chemical Kinetics
3 the pre-exponential| factor in the Arrhenius equation has reaction is zero,
time, T !
45. Assertion If the activation energy of a constant.
the dimernsion of temperature will have no effect on the
rate
thetimetaken
for the completion of 75% reaction is thrice faster is the
4 1
of the reaction. Reason Lower the activation energy.
them reaction
2
HCI is
Match Column | with Column Il and choose the correct 46. Assertion The hydrolysis of methyl I acelate by dil
41.codesgiven below a pseudo first order reaction
Column l Column I|
Reason HCI acts as a catalyst for the hydrolysis
reaction 1
0.693 47. Assertion For the reactiorn,
A Rate of k
reaction N,(g) + 3H,(g) 2NH,(g)
B Average rate of 2 2 to 3
[AIIMS 2012|
dx Unit of K. =L? mol2
C Half-ite 3
dt
A[A) Reason Equilibrium constant,
D Temperature coefficient 4
At
K = (NH,
Codes [N] (H,'
A B C D A BCD
2 48. In a zero order reaction for every 10° rise of temperature,
(a) 4 3 1 (b) 2 3 4 1
(c) 3 4 1 2 (d) 1 2 3 4 the rate is doubled. If the temperature is increased from
10° C to 100C, the rate of the reaction will become
42. Match the reaction in Column | with their order in [CBSE-AIPMT 2012]
Column Il and choose the correct code given below. (b) 512 times
(a) 256 times
Column | Column | (c) 64 times (d) 128 times

A 2NO, ’2NO + O, Zero 49. In a reaction A + B ’ product. are is doubled when

H, + Br, hv, 2HBr

2 One
2NO +Cl,2 ’2NOCI 3 Two
D 2H,0,’2H,0 + 0, 4 Three
the concentration of B is doubled, and rate increases by
a factor of 8 when the concentrations of both the
reactants (A and B) are doubled. Rate law for the
[CBSE-AIPMT 2012]
reaction can be written as

Codes
(a) Rate =k[A] [B'
A BC D A B CD (b) Rate = k[A [B
(a) 3 1 4 2 (b) 3 4 1 2
(c) 2 4 3 1 (d) 1 3 (c) Rate =k[A][B]
(d) Rate=k[A [B].
Directions (Q. Nos. 43 to 47) Each of these questions ’ 4NO, (g) +0z(g)
contains two statements: Assertion and Reason. Each of these 50. 2N,O, (g)
oJestions also has four alternative choices, only one of which is What is the ratio of the rate of decomposition of N,O , to
the correct answer. You have to select one of the codes (a), (b), rate of formation of NO,? [AFMC 2012|
(C) (d) given below
(a) 1:2 (b) 2:1
(a) Assertion is true, Reason is true: Reason is a correct (c) 1:4 (d) 4: 1
explanation for Assertion.
51. The rate of reaction between two reactants A and B
(b) Assertion is true, Reason is true; Reason is not a correct decreases by a factor of 4, if the Concentration of
explanation for Assertion.
reactant B is doubled. The order of this reaction with
(c) Assertion is true, Reason is false.
respect to reactant B is [AIIMS 2012]
(d) Assertion is false, Reason is true.
fractional (a) -1 (b) -2
43. Assertion The order of a reaction can have (c) 1 (d) 2
value.
written from 52. For a first order reaction A ’ B, the reaction rate at
Reason The order of a reaction cannot be reactant concentration of 0.01 M is found to be
balanced equation of a reaction.
20x 10mol L-s The half-life period of the reaction is
complex
4. Assertion Molecularity has no meaing for a (b) 30 s
[AIIMS 2012]
(a) 220s
reaction. (c) 300s (d) 347s
reaction is
Heason The overall molecularity of a complex
step.
equal to the molecularity of the slowest
 274 Encounter with NEET Chemistry in Just 40 Days
53. Which one of the following statements for the order of a
reaction is incorrect? AJ mol (B/mor! Initial rate of
[CBSE-AIPMT 2011|
(a) Order is nottinfluenced by stoichiometric
reactants coefficient of the
Ru-n
01
of D/mol Lmin
60 10 }
formatlion
03 02 7 20 102
(b) Order of reaction iS Sum of power to the
terms of reactants to express the rate of f concentration 03 04 2 88× 10
I Order of reaction is always whole numberreaction 0.4 01 2 40× 102
id) Order can be determined only experimentally
Based on the above data which one of the folowing is
54. Halt-|ife of a reaction is found to be correct?
to the cube of initial inversely proportional (b) Rate = k[A][B]
concentration. The order of reaction (a) Rate =k[A} [B]
[AFMC 2011| (c) Rate =k[AÝ (B () Rate = k[A| [B
(a) 5 (b) 2
(c) 4 (d) 3 58. For the reaction, N,0s(g) ’2NO,(g) + 1.
55. Aschematic plot of In Keo
Versus inverse of temperature The value of rate of
for a reaction is shown below
625x 10 mol L's
disappearance of N,Os is given ae
The rate of
6.0 and O, is given respectively as formation NO,
of
(a) 6.25 x10 mol L- s' and 6.25 x10
molL-s-1
(b) 1.25 x10-* mol L s and 3.125 x 10 mol L--!
In Kea (C) 6.25 x10 mol L-s and 3.125 x10 mol
L!-1 2.
(d) 1.25 x10* molL's and 6.25 x10 mol
L's!
2.0 59. The reaction.
1.5 x 10-3
2 x 10-3
1/T(K-1) N,O, in CCI, (solution)’ 2NO, (solution) +
The reaction must be is of first order in N,O,
2 0, (9)
[AIIMS 2011] wth rate
What is the value of rate of constant
(a) highly 62 x 10s!
(b) one withspontaneous
at ordinary
temperature reaction when (N,0.1
(c)
negligible
endothermic enthalpy change =1.25 mol L-1
(d) exothermic (a) 5.15 x10-5 mol L-'s-! 3.
(b) 6.35 x 10 mol Ls!
(c) 7.75x 10 mol L s-!
56. tya can be taken as (d) 3.85x 10 mol L s!
the time taken for the 60. At a certain
of a reactant to
drop to 3 of its initial
concentration is found to temperature,
the first order rate
4 value. If the rate be smaller than the constant, k,
constant for afirst order reaction is k, the constant, k,. If the energy of second order rate
Written as tya can be order reaction is greater than activation, E, of the first 4
(a) 0.75/k [AIIMS 2011] the second order energy of activation, E, of
reaction then with increase in
(b) 069/k temperature.
(c) 0.29/k (a) k, will increase
faster than ko, but always will[AIIMS 2010|
() 0 10k than k2 remain less
57. During the (b) k, will increase
faster than k,
2A +BC+ kinetic study of the
D, following results were reaction (c) k, will
increase faster than k, and
obtained (d) k, will
increase faster than k, becomes equal to k2
and
than k, becomes greater 5
 (b)51. (41.c) 31. 21.
(d)11. (d) 1.
(d) (a)

52.(d) 42.(a) 32.(d) (d)22. 12.(a)

(c) 2.

53.(C) 43.(b) 33.(b) (b)23. 13.(b)

(a) 3.

54.(c) 44.(b) 34.(b) 24.(c) 14.(b)

(d) 4.

55.(d) 45.(b) (d)35. 25.(b) 15.(a)

(b) 5.
Answers

56.(c) 46.(b) 36.(c) 26.(d) 16.(a)

(d)6.

57.(d) 47.(a) 37.(b) 27.(c) 17.(a)

(d)7.

(b)58. 48.(b) (d)38. 28.(a) 18.(a)

(b)8.

59.(c) 49.(d) 39.(C) 29. 19.(c)

(b)9.
(a)

(a)60. (b)50. 40.(d) 30.(a) (b)20. 10.(c)