25/06/2022 Morning Shift

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JEE Paper -2022

PHYSICS

1. In the following circuit the current through the 

EA 
cell is 20


Also, EB 
20

3. If  and B are unit vectors and  is angle

between them, then choose the correct option
^ ^ ^ ^
(1) A  B  A  B tan  2

3 5
(1) A (2) A ^ ^ ^ ^
4 3 (2) A  B  A  B tan  2

5 4
(3) A (4) A ^ ^ ^ ^
4 5 (3) A  B  A  B cos  2
Sol. Answer (2)
^ ^ ^ ^
5  7.5 5  7.5 (4) A  B  A  B cos  2
Req  
5  7.5 12.5
Req = 3 Sol. Answer (1)

V 5 |A + B|  12  12  2 Cos
I  A
Re q 3
= 2(1  Cos )  2(2Cos2  2) .....(i)
2. Electric field due to a charged sheet at a
distance of l and 4l at points A and B is | A + B |  2 cos  2
(surface change density of sheet is ).
| A - B |  12  1 2  2 Cos
 
(1) EA  , EB  2(1  Cos)  2Sin  2 ......(ii)
0 20
| A - B| Sin  2
   tan  2
(2) E A  EB  | A + B| Cos  2
20
| A - B |  | A + B | tan( 2)

(3) E A  EB  4. Find the ratio of speed for an electron in the
0
third orbit of He+ and third orbit of hydrogen
atom
2 
(4) EA  , EB  (1) 1:1 (2) 1:2
0 0
(3) 2:1 (4) 4:1
Sol. Answer (2) Sol. Answer (3)
Electric field due to thin non conducting sheet Velocity of electron to atomic no. Z and orbit n
is independent of distance from the sheet. is,
Considering as very large thin sheet e2 z
 
20 h n

(1)
 z acceleration at height of 2R is (R is the radius
So,    of earth)
n
(2) g g
For He+ third orbit ; 1  k  (1) (2)
3 4 2
g g
(1) (3) (4)
For H, third orbit ; 2  k  3 9
3
Sol. Answer (4)
1 2
 Acc. Due to gravity at height h
2 1
GM
5. Find the equivalent capacitance between A and g
B. (C = 8f) (R  h)2
GM GM
g 
(R  2R ) 2
9R 2
GM
At surface-: g 
R2
g0
21 27 g 
(1) F (2) F 9
8 4
8. A particle starts moving in the influence at force
24 29
(3) F (4) F F  (10i  5 j )N , if mass of particle is 0.1 kg
7 7
Sol. Answer (3) then its displacement (S ) in t = 2 Sec
a
3C 
c S  ai  bj then the value of is
2  3c b
Ceq 
c 7 (1) 1 (2) 2
3C 
2 (3) 3 (4) 4
3  8 24 Sol. Answer (2)
Ceq   F
7 7 F  10iˆ  5 jˆ
6. In the following figure x length is hanging from
the table. For what maximum value of x the 10iˆ  5 ˆj
a   100iˆ  50 jˆ
chain will not slip 0.1
1 2
 S  ut  at
2
1
0  (100iˆ  50 ˆj )  4
2
 200iˆ  100 ˆj
 a  200; b  100
a 200
(1) 3 m (2) 4 m   2
b 100
(3) 2 m (4) 1 m
9. For O2 ratio of rms speed of molecule and most
Sol. Answer (3) probable speed of molecule is
Let x is the hanging length, so for the chain not
to slip the weight if hanging part must be 3 2
(1) (2)
balanced with force on the part of chain on the 2 3
table
3 2
So we have  xg   ( L  x) g (3)
2
(4)
3
x  (0.5)(6  x) Sol. Answer (3)
1.5x  3 RMS speed (Vrms)=
3RT
So, x = 2m M
7. If on the surface of earth the gravitational 2RT
acceleration is go, then the value of gravitational Most probable speed (Vmp) =
M

(2)
 For O2 molecule A2 B 3

3RT C4
Vnms M  3 D A B C
   2.  3. 4
Vmp 2RT 2 D A B C
M
 Maximum percentage error in D is
10. 5 MHz frequency is transmitted by
D  A B C 
(1) Coaxial   100  2 3 4  100
D  A B C 
(2) Optical fibres
(3) Twisted copper wire 13. Choose the correct option matching entries of
Column-1 and Column-2
(4) None of these
Sol. Answer (3) Column-1 Column-2
5 MHz frequency can be transmitted through
twisted copper wire. (i) AC-Generator (a) Detects
11. Photodiode is reverse biased for which of the current
following reasons?
(ii) Transformer (b) Changes
(1) To increase the sensitivity AC Voltage
(2) To increase the current flow
(iii) Metal (c) Identify the
(3) To decrease depletion width detector resonance
(4) To decrease the potential barrier in circuit

Sol. Answer (1) (iv) Galvanometer (d) Converts

mechanical
energy into
electrical
energy

(1) (i)a, (ii)c, (iii)d, (iv)b

(2) (i)d, (ii)(b), (iii)(c), (iv)(a)
(3) (i)d, (ii)b, (iii)a, (iv)c
Photodiode is reverse biased to facilitate (4) (i)a, (ii)c, (iii)b, (iv)d
collection of photons(defection) through large
Sol. Answer (3)
depletion region. Current sensitivity is
increased in reverse biased photodiodes. (i) AC generator Converts
mechanical
A2 B 3
12. D energy into
C4
electrical
Find the maximum percentage error in D
(ii) Transformer Changes
 2A 3B 4C  AC voltage
(1)     100
 A B C 
(iii) Metal To identify
2A 3B 4C detector resonance
(2)  
A B C in circuit
2A 3B 4C
(3)   (iv) Galvanometer To detect
A B C current
A B C
(4)   (i)d, (ii)(b), (iii)(c), (iv)(a)
A B C
14. Terminal velocity of rain drop of radius r
Sol. Answer (1)
depends on.
According to the given relation,
(1) r 1/ 2 (2) r 3/ 2

(3) r 2 (4) r
(3)
Sol. Answer (3) 3  108
  1.5  108 m/s
2r g (  )
2 4 1
Terminal velocity = VT 
9 Refractive index of medium
 VT  r 2 c 3  108
n   2
 1.5  108
15. If I1  9I, I2  I at point P, phase difference is

and at point Q, phase difference is . Find
2
the difference between the intensity of waves at
P and Q.
(1) 9I (2) 6I
(3) 8I (4) 10I
Sol. Answer (3) Using shell’s law,

Given : 2sin c  1sin90

I1  9I 1
 sin c 
2
I2  I
So, c  30

At P phase difference     17. Current flows through a cross-section of radius
2
R as shown:
At Q phase defence    

I  I1  I2  2 I1I2 cos 


I p  9I  I  2 9I 2 cos  10I
2

IQ  9I  I  2 9I 2 cos 

 10I  6I  4I
 IP  IQ  10I  4I  6I
The value of this current is I. For radial distance
16. Dielectric constant of material is 4 and relative r < R, magnetic field depends on r as :
permeability is 1, then find critical angle for the
(1) B  r1
refraction with the air.
(2) B  r2
(1) 10° (2) 20°
1
(3) B 
(3) 30° (4) 16° r
Sol. Answer (3) (4) B r0
Sol. Answer (1)
  r r  2

 1
c  sin1    30
2

Given, r  4, r  1

Speed of light in medium is

1 
 1 

   3  108 m/s
0  r  0  r   
 0 0 

I
Curren density  J 
1 R 2

0  0  r  r Far r < R
(4)
 Ienclosed = J.A c
 1.47
I vB
=  r 2
R 2
3  108
vB 
Ir 2 1.47
=
R2
v A  v B  2.6  107
Acc. To ampere’s circuital law
  30  107
  2.6  107
 B  dl  0Ienc 1.47
Ir 2 v A  107 [23]
B(2r) = 0
R2
c
0 Ir
B= Br nA v A v B 20.4  107
2R 2   
nB c vA 23  107
18. A teacher uses 3 times the reading of shunted
vB
galvanometer for an experiment
 0.88

nB
or  1.12
nA

20. A block of mass 0.5 kg with velocity 12m/s

compresses a spring by 30cm when its velocity
(1) Shunt resistance is double the resistance of
galvanometer is halved. Find the spring constant.
(2) Shunt resistance is half of the resistance of Sol. Answer (600 N/m)
galvanometer
Conservation of energy states at
(3) Shunt resistance has the value equal to that
2
of galvometer 1 1 v  1
mv 2  m    kx 2
(4) None of these 2 2 2 2
Sol. Answer (2)
1  1 1
‘I’ is 3 times reading of shunted galvanometer mv 2 1    kx 2
2  4 2
So, I = 3Ig
Now Ig ⋅Rg = (I – Ig) Rshunt 3
mv 2  kx 2
4
IgRg = (3Ig – Ig) Rshunt
Rg 3mv 2 3  0.5  122
Rshunt = k 
2 4x 2 4  (0.3)2
19. The difference of speed of light in the medium 216
A and B (VA – VB) is 2.6 x 107 m/s. If the k  600 N/m
0.36
refractive index of medium B is 1.47, then the
ratio of refractive index of medium A is - 21. If the current is 2A then the energy in
15 seconds is 300 Joule. Find the energy if
(1) 1.303 (2) 1.4
current is 3A and time is 10 seconds (integer
(3) 1.5 (4) 1.12 type)
Sol. Answer (4) Sol. Answer (450)
v A  v B  2.6  10 7
H  2Rt

nB  1.47 300  (2)2 (R )(15) ........(1)

nA H '  (3)2 (R )(10) ..........(2)

?
nB
(1)
c (2)
n
v

(5)
 300 4  15 a
 u (17)
H' 9  10 2

300  9  10 *consider u = 0 (as starting from rest at t = 0)

 H'   450 joule
4  15 a
So, S9th  (17)  (2)(17)  34 m
22. A soap bubbles of radius 6 cm and 9 cm 2
respectively placed in contact with each other. 24. Find i in the circuit given below :
Find the radius of curvature of interface is.
(1) 18 (2) 16
(3) 12 (4) 14
Sol. Answer (1)

Sol. Answer (2A)

Pressure difference at common interface is,
4T 4T
P  
R1 R2

4T 4T 4T
so,  
Rcomm. R1 R2

1 1 1
  
Rcomm. R1 R2

1 1 1
  
Rcomm. 6 9

1 1 1 5 and 5 are in parallel connection

   
32 3

1 3  2
  
3 6 

 Rcomm.  18 cm

23. If a mass travels 2m in its first second then the

distance travelled by it in 9th second
Sol. Answer (34)
2.5 and 2.5 are in series connection
a
Snth  u  (2n  1)
2
a
 S1st  u  ((2  1)  1)
2

a a
2u (2  1)  u  ......(1)
2 2

a Have 5 and 5 are in parallel connection.

S9th  u  ((2  9)  1)
2 5
  2A
2.5

(6)
25. Statement 1: Davisson Germer Experiment 26. Wattless current flows through AC circuit, then
established wave nature of electron. the circuit is
Statement 2: If electron has wave nature they (1) RLC (2) R only
show interference and diffraction. (3) L only (4) RC only
(1) S1 is true S2 is false Sol. Answer (3)
(2) S1 is false S2 is true A current is said to be wattles if the average
(3) S1 & S2 both true power consumed by the circuit is zero
(4) S1 & S2 both false  Pavg   Vrms rms cos 
Sol. Answer (3) Wattless component of current
S1 and S2 both true
rms sin   wattless
Davisson Germer experiment experimentally
In the given combination
configured de-broglie hypothesis of wave-
particle duality. In 1989, wave nature of a beam Only L (inductor) connected across a AC
of electron was experimentally demonstrated in source will have zero average power.
a double slit experiment, similar to that used for
the wave nature of light.

(7)
25/06/2022 Morning Shift

Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

Mathematics JEE Solutions 2022

Mathematics

ab bc c a K1  K 2
1.   , then (a, b, c) are the = 8
7 8 9 42  ( 3)2
R
sides of ABC, then find where R is
r
circumradius and r is inradius
5
(1) (2) 3
2

1
(3) 1 (4)
2
Sol. Answer (1)  radius of circle = 4 units
ab bc c a Centre of circle = mid point of AB = (1, -2)
   k (say)
7 8 9
 equation of circle is (x  1)2  (y  2)2  4 2
 a  4 k , b  3 k , c  5k  s  6 k
 x 2  y 2  2x  4y  11  0
2
  s(s  a)(s  b)(s  c )  6k
3. If g : (0,  )  R is differentiable function
 6k 2 abc 60k 3 5
r    k and R    k  cos x  sin x
s 6k 4 24k 2 2 e x  1  xe x  xg ( x )
 x e x
 1
 g( x )
( e x
 1)2 
dx  x
e 1
c
 
R 5
Here 
r 2 for all x > 0, here c = constant

2. Circle C touch the lines L1  4 x  3 y  k1  0,  

(1) g is decreasing in  0, 
L2  4 x  3 y  k2  0, k1, k 2  R. If a lines  4

passing the centre of circle intersect at L1 at  

(2) g is increasing in  0, 
(–1, 2) and L2(3, –6) then equation of circle is  4
(1) x2 + y2 – 2x + 4y – 11 = 0  
2 2
(3) g + g is increasing in  0, 
(2) x + y + 2x – 4y – 11 = 0  2
(3) x2 + y2 – 2x + 6y – 11 = 0  
(4) g – g is decreasing in  0, 
(4) x2 + y2 – 2x – 4y + 11 = 0  2
Sol. Answer (1) Sol. Answer (2)
 (-1, 2) lies on line L1 = 0 g : (0,  )  R is differentiable
 K1 = 10  cos x  sin x e x  1  xe x  xg ( x )
and (3, -6) lies on line L2 = 0  x e x
 1
 g(x ) 
( e x
 1)2 
dx  x
e 1
c
 
 K2 = -30 Differentiating to x :
Distance between lines L1 and L2

(1)
 dy y 2
cos x  sin x e x  1  xe x (g ( x )  xg ( x )(e x  1)  x( x )e x
 2
x  (x)   dx x  y 2  xy
ex  1 (e x  1)2 (e x  1)2
(cos x  sin x ) xg ( x ) dy xdv
 x   x Put y  vx  v
ex  1 (e  1) dx dx

 g ( x )  cos x  sin x xdv v 2

 v 
dx 1 v 2  v
 
 g ( x )  0  x   0, 
 4 xdv v 2 v 2  v  v 3  v 2
 2
v 
dx 1 v  v 1 v 2  v
 
 g(x) increase in  0, 
 4 v2 v 1 dx
 d
4. f(x) be a polynomial function such that f(x) + v (v 2  1) x

f (x)  1 1  dx
f(x) + f(x) = x5 + 64, value of lim    2
x 1 x 1  dv  x
 v v  1
(1) –15 (2) 15
 –log x + tan–1 v = log x + C
(3) 60 (4) –60
y y
   log    tan1    log x  C
Sol. Answer (1) x x
Let p( x )  a5 x 5  a4 x 4  a3 x 3  a2 x 2  a1x  a0 x 1 
Put  C
y 1 4
p( x )  5a5 x 4  4a4 x 3  3a3 x 2  2a2 x  a1
y y 
p( x )  20a5 x 3  12a4 x 2  6a3 x  2a2  tan1    log    log x 
x x 4
 p( x )  p( x )  p( x )  a5 x 5  x 4 (a4  5a5 )  
Put y  3 x   log 3  log x 
 x 3 (a3  4a4  20a5 ) 3 4
 x 2 (a2  3a3  12a4 )  
 log x   log 3  log 3 x 
 x(a1  2a2  6a3 ) 12 12
(a0  a1  2a2 )
6. f : R  R, g : R  R be two function defined

But this is equal to x5 + 64 1  2e 2 x

by f ( x )  loge ( x 2  1)  e  x  1 and g ( x )  x
a5  1  a4  5  a3  0  a2  60
 range of , if the inequality
 a1  120 and a0  64
 (  1)2    5 
f  g   f  g     
  p( x )  x 5  5 x 4  60 x 2  120 x  64  3    3 

p( x ) (1)   (0, 2) (2)   (2, 3)

lim  p(1)  5(1)4  20(1)  120 – 120  15
x 1 x  1
(3)   (3, 4) (4)   R
5. If y = y(x) be the solution of given equation
y2 dx + (x2 – xy + y2) dy = 0 and this curve also Sol. Answer (2)
passes through (1, 1). Line intersect at 2x
f ( x )  ln( x 2  1)  e  x  1  f ( x )   e x  0
y  3 x at  , 3  then find the value of 1 x 2

loge  3x  g(x ) 
1  e2 x
 e  x  e x  g ( x )  e  x  e  x  0
ex
 
(1) (2)  f is  and g ( x ) is 
2 4

    (  1)2     5 
(3)
6
(4)
12
 f  g 
 3    f  g    3  
  
Sol. Answer (4)

(2)
  (  1)2   5 
 g    g     (3) (4) None of these
3  3  4
 
Sol. Answer (3)
(  1)2 5
   
3 3 sin x  ecos x
I  (1  cos x )(ecos x  e  cos x )
2
dx …(1)
 a 2  5  b  0 0

a a
 (   2)(   3)  0
Use  f ( x ) dx   f (a  x ) dx
0 0
Here   (2, 3)

7. If E1 and E2 are two conditional probability sin x  e  cos x
 E  1 E  3
I  (1  cos2 x )(e  cos x  ecos x )
dx …(2)
0
event such that P 1   ,P 2   ,
 E2  2  E1  4 
sin x
1
P  E1  E2   , then
(1) + (2)  2I   1  cos2 x
dx
8 0

(1) P  E1  E2   P (E1 )  P (E2 )    

2I       I 

 4 4 4
(2) P  E1  E2   P (E1 )  P (E2 )
9. f(x) = x3 + x – 5
(3) P  E1  E2   P (E1 )  P (E2 ) f (g ( x ))  x, find g '(63)

(4) P  E1  E2   P (E1 )  P (E2 ) (1)

1
(2)
1
49 48
Sol. Answer (4)
1 1
 E  P (E1  E2 ) (3) (4)
1 17 16
P 1    P (E2 ) 
E
 2 P ( E 2 ) 4
Sol. Answer (1)
 E  1 E  3 1 f(x) = x3 + x – 5, f(g(x) = x
P 1   ,P 2   and P (E1 ) 
E
 2 8 E
 1 4 6
 g is f 1  g (f ( x ))  x
7
 P (E1  E2 )  {by inclusion-exclusion} 1
24  g (f ( x )  f ( x )  1  g (f ( x ) 
f ( x )

1
f ( x )  3 x 2  1  g (f ( x ) 
3x 2  1
Now put x = 4  f(4) = 43 + 4 – 5 = 63

1 1
 g (63)  
3(4)2  1 49

P  E1  E2  10. y = y(x) be the solution  (x + 1) y – y = e3x

1 4
= P (E1 )  P  E1  E2  (x + 1)2 y(0) = , then x =
3 3
for the curve y =

y(x) is
1 1 1
  
6 8 24 1 1
(1) (2)
1 1 9e 4 9e 4
Thus P  E1  E2     P (E1 )P (E2 )
4 6 e4 e 4
(3) (4)

sin x  ecos x
9 9
8.  (1  cos2 x )(ecos x  e  cos x )
dx
Sol. Answer (2)
0

dy  1 
  y  e3 x ( x  1)
(1) (2)  dx  x  1 
2

(3)
 1
  ( x 1)dx 1   2 100 
I.F. e  1    
( x  1) 2   3  
 100 
3 2
1 1
( x  1) 
Solution is y   e3 x dx  c 3

 2 100 
y e3 x 1  100  2 1    
  c, y (0)  c0   3  
( x  1) 3 3
100
y e3 x ( x  1)  e3 x 2
  y  98  2   
( x  1) 3 3 3

 4 1  [S] = 98
y    4
 3  9e
13. an  19n  12n. Find
 31a9  a10 
  57a8
11. If a and b are unit vector and acute angle
between them is , then Sol. Answer (4)

     31(199  129 )  (1910  1210 )

(1) a  b  a  b tan  
2 57(198  128 )

     199 (31  19)  129 (31  12)

(2) a  b  a  b tan =
2 57(198  128 )
   
(3) a  b  a  b 199  12  129  19
=
    57(198  128 )
(4) a  b  a  b tan 
12  19(198  128 )
= 4
Sol. Answer (2) 57(198  128 )
 
a  b 1 14. f : N  R be a function, f(x + y) = 2f(x)  f(y) for
natural number x and y if f(1) = 2 and
 2
 a  b  1  1  2cos  10
512 20
 f (a  k )  3
(2  1) , then the value of ‘a’
 2 k 1
and a  b  2  2cos  is _______
  Sol. Answer (a = 4)
ab 1  cos  
     tan f(x  y)  2f(x)f(y), x,y  N ----- (i)
ab 1  cos  2
and
1 5 19 65
12. , , , , ...100 terms and S is the sum of f(1) = 2
3 9 27 81
this series, then find the values of [s] where [] f(2) = 23
is greatest integer function. f(3) = 25
Sol. Answer (98) 10 10
512 20
Now,  f(a  k) = 2f(a) f(k) 
3
(2  1)
1 5 19 65 k 1 k 1
S     100 terms
3 9 27 81
 (220  1)  512 20
= 2f(a)  2  (2  1)
32 3 2  3 2 
2 2 3 3
 3  3
        100 terms
 3   32   3
3

= f(a) = 128
 2  2   2 
2 3
  1     1       1       100 terms  a4
 3    3     3  
1 1 1 k
15.     10  , then find
 2  2 2  2  310 22  39 2  3 210  310
 100       100 terms  the remainder when k is divisible by 6.
 3  3  

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Sol. Answer (5) 32 2
 8  2(3  2 2)  3 2  4
1 1 1 k 4 2
    10 
2  310 22  39 2  3 210  310
18. If A is 3 × 3 Matrix having the elements from the
1 set {–1, 0, 1}. Find the number of matrices A for
 G.P. with a 
2  310 which the sum of the elements is 5.
Sol. Answer (414)
1   3 10 
    1
2  310  2    a1 a2 a3 
  2 1  1    3  2 
10 10
   
 11 10   10 10  A   b1 b2 b3 
3  2 23   2 3 
 2  1 c c
   1 2 c3 
 where a1, a2, a3, b1, b2, b3, c1, c2, c3  {–1, 0, 1}

k  310  210  35  25 3 5

 25   275 

 211

(6 k1  5) (6 k2 1) Now a1  a2  a3  b1  b2  b3  c1  c2  c3  5
k = (6k1 + 5) (6k2 + 1) Possible cases:
= 6(6k1k2 + k1 + 5k2) + 5 (i) five 1, No – 1, four 0

 Hence reminder = 5 9!
 matrics
16. f(x) = x3 + 3x2 + 2x + 9, find point of inflection 5! 4!

(  2  )
P(, ) and calculate
5 (ii) six 1, one – 1, two 0
Sol. Answer (2) 9!
 matrics
f ( x )  x 3  3 x 2  2x  9 6! 2!

f ( x )  3 x 2  6 x  2 (iii)seven 1, two – 1, No 0

f ( x )  6 x  6  0  x  1    1 9! 9! 9!
So ANS =  
5! 4! 6! 2! 7! 2!
So   1  3  2  9  9
= 126 + 252 + 36
(  2  )
So 2 = 414
5
17. y = m1x + c1, y = m2x + c2, m1  m2 are two    
19. If a  3, b  4 and q lies between 
common tangents of x2 + y2 = 2 and parabola y2 3 4
= x then find the value of |8m1m2|     2  
the find (b  a )  ( b  a )  4(a  b )2
Sol. Answer (0.24)
1 Sol. Answer (576)
tangent to y2 = x is y  mx  …(1) 
4m a  3, b  4
(1) is tangent to x2 + y2 = 2      
then c2 = r2(1 + m2) (b  a )  (b  a )  2(b  a )
    2  
1
16m 2
 2 1 m2   (b  a )  (b  a )  4(a  b )2
   
1  4(b  a )2  4(a  b )2
 m 4  m2  0
32
2 2
2  4  a b (sin2   cos2 )
 1 1 1 9  
  m2     
 2 32 4 32
 4  9  16  576
12 3 3 1 1
m    m2    only 20. Consider:
2 4 2 4 2 2 2
P1 : ~(P  ~ q)
3 1
  8 m1m2  8 
4 2 2 P2 : (P  ~q)  ((~P)  q)
If P  ((~P)  q) is false then
(1) P1 is true, P2 is false
(5)
 (2) P1 is false, P2 is true If P  ((~P)  q) is false
(3) Both P1 and P2 are true then P is true and

(4) Both P1 and P2 are false ~P  q is false

Sol. Answer (4)  q is false

P1 : ~(P  ~q)  P1 is false and P2 is also false

P2 : (P  ~q)  ((~P)  q)

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Shift

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Chemistry JEE Solutions 2022

Chemistry

1. Strongest oxidising agent is

(1) Mn+3 (2) Ti+3
(3) Fe+3 (4) Cr3+
4. Which of the following are isoelectronic
Sol. Answer (1)
(1) HF and H2O (2) CH4 and SF6

(1) Mn3   [Ar]3d4 
e
[Ar]3d5 (3) O2 and O3 (4) H2 and F2

(2) Ti3   [Ar]3d1 Sol. Answer (1)

Total no. of electrons present in HF is 10 and
(3) Fe 3  [Ar]3d5
also in H2O it is 10, So these are isoelectric
(4) Cr 3   [Ar]3d3 species
5. In which of the following bond order increases-
 Mn3+ will have a very high tendency to
undergo reduction, hence, it will behave as (1) CO  CO  (2) N2  N2 
very strong oxidising agent.
(3) H2  H2  (4) O 2  O 2 
2. The product formed on reaction of AgCl with
aq. NH3. Sol. Answer (1)

(1)  Ag(NH3 )4  Cl (2)  Ag(NH3 )2 Cl2  Bond order = 3 Bond order = 3.5
In CO, the e– is removed from the *2s , so the
(3)  Ag(NH3 )2  Cl (4)  Ag(NH3 )Cl
no. of antibonding e– decreases and bond
Sol Answer (3) order increases.
AgCl(s) 2NH3 (aq)  [Ag(NH3 )2 ]Cl(aq)
( White) colourless

3. Find intermediate in the following reaction.

R  CONH2  Br2 
NaOH
 R  NH2 6.
(dilute)
(1) R-CN (2) R-NC
A & B can be separated by.
(3) R-NCO (4) R-COOH
(1) Chromatography
Sol. Answer (3)
(2) Fractional distillation
(3) Mass spectrometry
(4) NMR
Sol. Answer (2)

(1)
 9. Which of the following is a natural sweetener?
A is ortho-nitro phenol & B is para-nitro phenol.
(1) Bithional (2) sucralose
A has less boiling point than B due to intra
molecular hydrogen bonding. So they can be (3) Alitame (4) Lactose
separated by fractional distillation. Sol. Answer (4)
Alitame and sucralose are artificial sweetener.
7.
Bithionol is added to soap to impart antiseptic
properties.
Lactose that is found in the milk is also called
(1) (2) as Milk sugar. This is a natural sweetener.
10. Why micelle is not formed when concentration
(3) (4) of micelle/colloid is less

Sol. Answer (1) (1) micelle is not formed as the concentration

is less than CMC
(2) Less hydrophilic
(3) Amount of soap is less
(4) None of these
Sol. Answer (1)
Micelle is an example of associated colloidal
sol. When we have low concentration of soap
molecules, it just behave like strong electrolyte
but at higher Conc. [CMC] it shows colloidal
8. behaviour because of formation of aggregates.
11. Electron deficient species is
(1) B2H6 (2) LiH
(3) CCl4 (4) PH3
The intermediate X is Sol. Answer (1)

(1) (2)

(3) (4)
B2H6 is electron deficient because octet of
boron is not complete. To complete octet boron
Sol. Answer (1) and hydrogen form 3C–2e– bond and still after
that it remains electron deficient.
12. Effect of eutrophication is
(1) B.O.D of water decreases

(2)
 (2) Biodiversity of living organism decreases
(3) B.O.D of water increases 15. Products are
(4) Breakdown of organic compound.
Sol. Answer (2)
Eutrophication is a phenomenon in which
organic/mineral enriched water bodies support (1)
the growth of dense plant population, which
cause depletion in oxygen level in water body
which kill the aquatic life and hence cause (2)
reduction of biodiversity.
13. Which among the following has highest ionic
mobility in solution
(3)
(1) Be2+ (2) Mg2+
(3) Ca2+ (4) Sr2+
Sol. Answer (4)
(4)
High ionic mobility implies high ionic
conductance.
More is the charge density on the ion, more is
the hydration and hence, more will be the
Sol. Answer (1)
hydrated radii, which results in low ionic
mobility
 Charge density decreasing order
Be 2  Mg2  Ca 2  Sr 2

 Increasing order of ionic mobility

Be 2  Mg2  Ca 2  Sr 2

14. Complex “X” is formed by leaching of Au, after

reaction with Zn, Complex ‘Y’ is formed.
Identify X and Y.
[Au(CN)2 ] [Au(CN)4 ]
(1) (2)
[Zn(CN)4 ]2 [Zn(CN)4 ]2
16. Which of the following is incorrect about
[Au(CN)3 ] Tyndall effect
(3) (4) None of these
[Zn(CN)4 ]2 (1) Density difference must be minimum

Sol. Answer (1) (2)  difference must be maximum

Leaching is carried out by 0.2 or 0.5% NaCl (3) Refractive index difference must be
followed by reaction with Zn dust that works maximum
like reducing agent. (4) None of these
4Au(8)  8CN (aq)  2H2O(ag)  O2 (g) Sol. Answer (2)
 Tyndall effect is observed when
4[Au(CN)2 ] (aq)  4OH (aq) (i) Diameter of the dispersed particles is not
much smaller than the wavelength of the
(X)
light used.

2n(s)  2[Au(CN)2 ](aq)  (ii) The refractive indices of the dispersed
phase and the dispersion medium differ
2Au(s)  [Zn(CN)4 ]2 (aq) greatly in magnitude
(Y) 17. Which of the ore does not have sulphide in
them?
(1) Baryte (2) Copper pyrites
(3) Galena (4) Zinc blende
(3)
Sol. Answer (1) ZM
Sol. d 
The formula of ores is, Na  a3
Copper pyrite = CuFeS2 a  2(rNa  rCl )
Zinc blende = ZnS
a
Galena = Pbs rNa  rCl   
2
Baryte = BaSO4
4  58.5
18. Free radical polymerization is seen in?  43.1 
6.023  1023  a3
1
 4  58.5 3
Sol a 
 6.023  10  43.1 
23

 a  2.08  10 8 cm
Addition polymerization occurs by free radical
mechanism  a  208pm
19. Find the number of atoms of N in 681 gms of 22. 0.01 mmoles, 1L H2SO4 solution is given 50%
C7H5N3O6 of this solution is taken out and 500 ml water is
Sol. Molar mass of C7H5N3O6 added to make 1L solution. Further, 0.01
mmoles of H2SO4 is added to this solution. Find
= 12 × 7 + 5 × 1 + 3 × 14 + 6 × 16 out the final mmoles of H2SO4 in terms of 10–3
= 227 gm/mole mmoles?
W = 681 gms Sol. Answer (15)

681 Initial mmoles = 0.1

n 3
227 After 50% of solution is taken out m moles of
50
1 mole compound contains 3 mole N atoms H2SO4 (remaining)  0.01 = 0.005
100
3 mole compound contains 9 mole N atoms
Further 0.6 m moles of H2SO4 are added new
No. of N atoms = 9 NA mmoles of H2SO4 = 0.005 + 0.01 = 0.015
20. For He+ & H in 3rd orbit ratio of de-Broglie =15 × 10–3
wavelength?
23. What is IUPAC name of Ethylidene chloride?
he h M  VH
Sol.   H Sol.
h mHe VHe h

MHe  4  mH

Z
V  2.18  106  m/s
n

VHe ZHe n 24. Phenol reacts with Conc. HNO3 to give which
  H major product?
VH Z nHe
Sol.
VHe 2 3
 
VH 1 3
He 1 1
 
H 4 2
He H
 0.125 or 8
H He

21. Density of NaCl is 43.1 g/cc. Find the distance

between Na+ and Cl– ions?

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