Periodic Classification PYQs

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Q) (a) State Mendeleev’s Periodic Law

(b) Why did Mendeleev leave some gap in the periodic table?
(c) If the letter ‘R’ was used to represent elements in the group, then
hydride and oxide of carbon would be represented as
(d) What are isotopes (CBSE 2020)

a) (a) Mendeleev’s periodic law states that the properties of element are the
periodic function of their atomic masses.
(b) Mendeleev left some gaps in the periodic table, because he predicted the
existence of few more element that had not been discovered at that time.
(C) RH4, RO2
(d) Atoms of element with similar chemical properties but different
atomic masses.
Q) Answer the following, based on elements with atomic number 3 to 9 :
(a) Name the element with smallest atomic radius.
(b) Name the element which shows maximum valency.
(c) Name the element which is a metalloid.
(d) Name the element which is most electropositive.
(e) Write the chemical formula of the compound formed when
the elements of atomic number 6 and 8 react together. (CBSE 2019)

a) Elements: Li, Be, B, C, N, O, F


(a) Element with smallest atomic radius - Fluorine (F)
(b) Element with maximum valency - Carbon (C)
(c) Element which is metalloid - Boron (B)
(d) Element which is most electropositive - Lithium (Li)
(e) Compound formed when C(6) & O(8) react together CO and CO2
Q) (a) The modern periodic table has been evolved through the early attempts of
Dobereiner, Newland and Mendeleev. List one advantage and one limitation of
all three attempts.
(b) Name the scientist who first of all showed that atomic number of an element
is a more fundamental property than its atomic mass.
(c) State Modern Periodic law. (CBSE 2018)

a) (a) Dobereiner Periodic Table:


Advantage: To predict the atomic mass of middle element in each triad.
Limitation: Dobereiner could identify only three triads.

Newland Periodic table:


Advantage: Every eighth element had properties similar to that of first;
correlated the properties of elements with their atomic mass.
Limitation: It was only applicable up to Calcium.
Mendeleev’s Periodic Table
Advantage: Elements with similar properties could be grouped. He
predicted the existence of new elements that had not been discovered
Limitation: No fixed position for hydrogen/ position of isotopes. Atomic
masses do not increase in a regular manner.

(b) Name of the scientist who first of all showed that the atomic number
of an element is a more fundamental property than its atomic mass was
Henry Moseley.

(c) Modern periodic law states that Properties of elements are a periodic
function of their atomic number.
Q) What is periodicity in properties of elements with reference to the
Modem periodic Table? Why do all the elements of the same
group have similar properties? How does the tendency of
elements to gain electrons change as we move from left to right
in a period? State the reason of this change? (CBSE 2017)

a) Properties which reappear at regular intervals are called periodic properties,


and the phenomenon is known as the periodicity of elements.

Elements in the same group or column have the same number of electrons
in their outermost shell. Hence, elements of the same group have similar
properties. On moving across a period from left to right, the tendency to gain
electrons increases. This is due to an increase in the nuclear pull
and a decrease in atomic size.
Q) An element 'X' belongs to 3rd period and group 16 of the Modern periodic Table.
(a) Determine the number of valence electrons and the valency of 'X'.
(b) Molecular formula of the compound when 'X' reacts with hydrogen
and write its electron dot structure.
(c) Name the element 'X' and state whether it is metallic or non-metallic.
(CBSE 2016)

a) Electronic configuration of X= 2, 8, 6
(a) Valence electrons = 6 & Valency = 2

(b) Formula = H2X

(c) X is sulphur and it is a non - metal.


Q) An element 'X' has mass number 35 and number of neutrons 18.
Write atomic number and electronic configuration of 'X'. Also write
group number, period number and valency of 'X'. (CBSE 2016)

a) Atomic no. of X = 35–18 = 17


Electronic configuration = 2, 8, 7

Group number = 17

Period number = 3

Valency = 1
Q) Taking the example of an element of atomic number 16, explain how
the electronic configuration of the atom of an element relates to its
position in the modern periodic table and how valency of an element
is calculated on the basis of its atomic number. (CBSE 2015)

a) Electronic configuration: 2,8,6.


It has six valence electrons hence, group number is 16
It has 3 shells hence, period number is 3
Valency = 8 – 6 = 2
Q) Two elements ‘P’ and ‘Q’ belong to the same period of the modern
periodic table and are in Group 1 and Group 2, respectively. Compare
their following characteristics in tabular form: (CBSE 2015)
(a) Number of valence electrons (b) The sizes of their atoms
(c) Their metallic character (d) Their tendencies to lose electrons

a)
Valence electrons 1 2
Q) (a) Define the following terms : valency & atomic size
(b) How do the valency and the atomic size of the elements vary while
going from left to right along a period in the modern periodic table?
(c) Write the number of horizontal rows in the modern periodic table. What
are these rows called? (CBSE 2014)

a) (a) Valency - The combining capacity of an atom or the number of unpaired


electrons in the outermost shell of the atom is called valency.
Atomic size - it is the distance measured from the outermost shell of an
atom to the center of the nucleus.
(b) When we move from left to right along a period, valency increases till
group 14 and then decreases & atomic size decreases.
(c) ​The modern periodic table consists of 7 horizontal rows called periods.
Q) Consider two elements 'A' (Atomic number 17) and 'B' (Atomic number 19) :
(i) Write the positions of these elements in the modern periodic table giving
justification.
(ii) Write the formula of the compound formed when 'A' combines with 'B.'
(iii) Draw the electron dot structure of the compound and state the nature of
the bond formed between the two elements. (CBSE 2014)

a) (i) Electronic configuration of A = 2, 8, 7


number of valence electrons in A are 7 hence A lies in group 17
number of shells in A are 3 hence A lies in period 3

Electronic configuration of B = 2, 8, 8, 1
number of valence electrons in B are 1 hence A lies in group 1
number of shells in B are 4 hence A lies in period 4
(ii) When A is combined with B = compound AB is formed

(iii) Ionic bond is formed between A & B

Electron dot structure

- +
B + A = [A] [B]
Q) Given below are some elements of the modern periodic table:
Be(4), ​F(9), ​Si(14), ​K(19), ​Ca(20)
(i) Select the element that has one electron in the outermost shell and write
its electronic configuration.
(ii) Select two elements that belong to the same group.
(iii) Select two elements that belong to the 2nd period. Which one of the two
has bigger atomic size? (CBSE 2013)

a) (i) Potassium, electronic configuration of K = 2, 8, 8, 1


(ii) ​Be & Si belong to same group (group 14) as they both have same
number of valence electron i.e. 4

(iii) Be & F belong to 2nd period as they both have same number of
shells i.e 2 & Be has bigger atomic size than F
Q) Write the number of periods the modern periodic table has. How do the
valency and metallic character of elements vary on moving from left to
right in a period? How do the valency and atomic size of elements vary
down a group? (CBSE 2013)

a) The modern periodic table has 7 periods.


When we move from left to right along a period, valency increases till
group 14 and then decreases & metallic character decreases.

When we move down the group, valency does not change but atomic
size increases.
Q) An element E has following electronic configuration: 2, 8, 6
(a) To which group of the periodic table does element E belong?
(b) To which period of the periodic table does element E belong?
(c) State the number of valence electrons present in element E.
(d) State the valency of the element E. (CBSE 2012)

a) (a) E have 6 valence electron hence it belongs to group 16


(b) E have 3 shells hence it belongs to period 3

(c) E have 6 valence electron

(d) Valency of E is = 8-6 = 2


Q) Why do all the elements of the
(a) same group have similar properties
(b) same period have different properties? (CBSE 2012)

a) (a) Since all the elements in a group has the same number of valence
electrons they exhibit similar properties to one another.

(b) Similarly elements in the same period have different valence


electrons and hence they exhibit different properties.
Q) Na, Mg and Al are the elements having one, two and three valence
electrons respectively. Which of these elements
(i) has the largest atomic radius.
(ii) is least reactive? Justify your answer stating the reason for each.
(CBSE 2012)

a) (i) Na has the largest atomic radius, as we move from left to right in a
period the nuclear charge increases and it pulls the electrons closer to the
nucleus. This increased attraction will cause the atomic size to reduce.

(ii)Since Al is smaller in size it has higher attractive force therefore it tends


to hold the electron together with a stronger force hence it is least reactive.
Q) (a) Which two criteria did Mendeleev use to classify the elements
in his periodic table?

(b) State Mendeleev’s periodic law.

(c) Why could no fixed position be given to hydrogen in


Mendeleev’s periodic table?

(d) How and why does the atomic size vary as you go:
(i) from left to right along a period?
(ii) down a group? (CBSE 2009)
A)
(a) Mendeleev used two criteria for classifying elements:

- The elements in the periodic table are arranged according to the


increasing order of their atomic mass.

- The formulae of their hydrides and oxides were also used to classify
them in the periodic table.

(b) Mendeleev's periodic law is that the chemical properties of the


elements are periodic functions of their atomic mass.

(c) Hydrogen displayed both the property of alkali metals and halogens.
(d) Atomic size variation

- From left to right the nuclear charge increases and hence the atomic
size decreases.

- From top to bottom the atomic size increases as new shells are added
to the atom.

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