EC PROBLEM: Usrr The equilibrium constant for the reaction of chlorine gas with phosphorus trichloride to form phosphorus pentachloride is 33 at 250°C. If an experiment is initiated with concentrations of 0.050 M PCI, and 0.015 M Cl,, what are the equilibrium concentrations ofall three gases? Clg) + PCh(g) = PCl(g) eCeC GIVEN: K = 33; T= 250°C Initial concentrations: [PCI3]=0.050 M; [Cl,]=0.015 M Clg) + PCh(g) = PCl¢g) REQUIRED: Equilibrium concentrations: [PCI3]; [Cl,]; [PCl.] SOLUTION: a, Pcl, PCI, Initial Concentration OO1sM —00SOM OM Change in Concentration =x = ts Final Concentration A We your caloulatny, te solve for 2? mndead of mamuay walmg + OTA% CHEMICAL EQUILIBRIUMpaf rom aa : [PCL] SOLUTION: x = ejay = 33 Gos — HG x = 0.00075 — 0.050x —0.015x + x? 33 x = 0.025 — 1.65x — 0.495x + 33x? 33x? — 3.145x + 0.025 =0 3.145) + V(3.145)? — (4)(33)(0.025) 383) _ 3.145 + V9.89 - 33 - 66 eC 3dx4~ 3. aS, + 0. 035 cal ualotor MODE 3 5: EQN D3: ax* ZR + FO Input yoeke valutG on your ny tuioking. * ” o, Pc, Pcl, Initial Concentration DoIsM 005M OM ‘Change in Concentration * * + Final Concentration oos-2 00s0-» x z —b+ Vb’ — 4ac a 2a when az?+be+-e=0 2,b,e constants, nee a0 DBick =” Thm yo will We gt x value, Yak will ea ven Xy" mal” xy” or a vt whe Ik wo powve eaLhaentOve way {Slee for Bt. 3. 1s, + 0-025 *O wy = 0. OFS & 0-097 abel a vthen we ’ > dio. x, + 6 | 0- 0088 | ceuekite tre vdNe 4” it will Mm to ponte CD ros value: Trem input he value 0g x to uonwalrovinen, —j eu GEN, K=33;T=250¢ Ina concentrations: (PC 20.050. C0015 REQUIRED: aul concer tons (PC (PO) sowmon. a mm eu