Get Document

You might also like

Download as pdf or txt
Download as pdf or txt
You are on page 1of 8

Version : 3.

2
Date of preparation : 30 September 2023
Previous date : 29 September 2022

SAFETY DATA SHEET


KLEEN MCT105
1. Identification
Product identifier KLEEN MCT105
Other means of identification None.
Recommended use of the chemical and restrictions on use
Recommended use Membrane cleaner
Recommended restrictions None known.
Company/undertaking identification
Veolia Water Technologies and Solutions (India) Private
Limited
(formerly known as SUEZ Water Technologies and
Solutions (India) Private Limited)
#53-C, Hoskote Industrial Area, Chintamani Road,
Hoskote, Bangalore – 562114, Karnataka, India
Tel: +91 80 67021219
Fax: +91 80 27971663
Email: vtc.vwts.apacproductregulatory.all@veolia.com

Emergency telephone
+91 80 67021219

2. Hazards identification
Physical hazards Not classified.
Health hazards Skin corrosion or irritation Category 1B
Serious eye damage or eye irritation Category 1
Environmental hazards Not classified.

Label elements

Signal word Danger


Hazard statement
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
Precautionary statement
Prevention
P260 Do not breathe mist/vapors.
P264 Wash thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301 + P330 +
P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 +
P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 +
P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.

Product: KLEEN MCT105 - Page 1 of 8


Version : 3.2
Date of preparation : 30 September 2023
Previous date : 29 September 2022

SAFETY DATA SHEET


KLEEN MCT105
P363 Wash contaminated clothing before reuse.
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards which do not None known.
result in classification
Supplemental information % of the mixture consists of component(s) of unknown acute hazards to the aquatic environment.
% of the mixture consists of component(s) of unknown long-term hazards to the aquatic
environment.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Hydroxyacetic acid 79-14-1 10- <30
N-hydroxyethylenediamine triacetic 139-89-9 10- <30
acid trisodium salt
Nitrilotriacetic acid,trisodium salt 5064-31-3 0.1- <1
(NTA.Na3)

4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician. Wash
contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
symptoms/effects, acute and include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
delayed blindness could result.
Indication of immediate Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance.

5. Fire-fighting measures
Suitable extinguishing media Foam. Powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

Product: KLEEN MCT105 - Page 2 of 8


Version : 3.2
Date of preparation : 30 September 2023
Previous date : 29 September 2022

SAFETY DATA SHEET


KLEEN MCT105
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not breathe mist/vapors. Do not
emergency procedures touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage


Precautions for safe handling Do not breathe mist/vapors. Do not get in eyes, on skin, or on clothing. Provide adequate
ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene
practices. Avoid prolonged exposure.
Conditions for safe storage, Store locked up. Store in tightly closed container. Store away from incompatible materials (see
including any incompatibilities Section 10 of the SDS). Do not freeze. If frozen, thaw completely and mix thoroughly prior to use.

8. Exposure controls/personal protection


Occupational exposure limits No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield.

Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.

9. Physical and chemical properties


Appearance Liquid
Physical state Liquid.
Form Liquid.
Color Colorless to amber
Odor Slight acetic
Odor threshold Not available.
pH (concentrated product) 3.4
Melting point/freezing point -21 °C
Initial boiling point and boiling 99 °C
range
Flash point > 100 °C P-M(CC)
Evaporation rate < 1 (Ether = 1)

Product: KLEEN MCT105 - Page 3 of 8


Version : 3.2
Date of preparation : 30 September 2023
Previous date : 29 September 2022

SAFETY DATA SHEET


KLEEN MCT105
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 18 mm Hg
Vapor pressure temp. 21 °C
Vapor density < 1 (Air = 1)
Relative density 1.34
Relative density temperature 21 °C
Solubility(ies)
Solubility (water) 100 %
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 28 cps
Viscosity temperature 21 °C
Other information
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
pH in aqueous solution 3.3 (5% SOL.)
Pour point -18 °C
Shelf life 720 days
VOC 10 % (Estimated)

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns.
Symptoms related to the Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
physical, chemical and include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
toxicological characteristics blindness could result.
Information on toxicological effects
Acute toxicity

Product: KLEEN MCT105 - Page 4 of 8


Version : 3.2
Date of preparation : 30 September 2023
Previous date : 29 September 2022

SAFETY DATA SHEET


KLEEN MCT105
Product Species Test Results
KLEEN MCT105
Acute
Dermal
LD50 Rabbit > 5000 mg/kg (Calculated according to
GHS additivity formula)
Inhalation
LC50 Rat > 5 mg/l, 4 Hours (Calculated according to
GHS additivity formula)
Oral
LD50 Rat 4923 mg/kg (Calculated according to GHS
additivity formula (Category 5))
Components Species Test Results
Hydroxyacetic acid (CAS 79-14-1)
Acute
Inhalation
LC50 Rat 3.6 mg/L, 4 Hour
Oral
LD50 Rat 2040 mg/kg
N-hydroxyethylenediamine triacetic acid trisodium salt (CAS 139-89-9)
Acute
Inhalation
LC50 Rat > 10.05 mg/l, 4 Hour
Oral
LD50 Rat 1780 mg/kg
Nitrilotriacetic acid,trisodium salt (NTA.Na3) (CAS 5064-31-3)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
Inhalation
LC50 Rat > 5 mg/l, 4 Hours
Oral
LD50 Rat 1100 mg/kg
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.
IARC Monographs. Overall Evaluation of Carcinogenicity
Nitrilotriacetic acid,trisodium salt (NTA.Na3) Possibly carcinogenic to humans. 2B
(CAS 5064-31-3)
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure

Product: KLEEN MCT105 - Page 5 of 8


Version : 3.2
Date of preparation : 30 September 2023
Previous date : 29 September 2022

SAFETY DATA SHEET


KLEEN MCT105
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged exposure may cause chronic effects.

12. Ecological information


Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Product Species Test Results
Aquatic
Crustacea LC50 Daphnia magna 1890 mg/L, 48 hour (pH adjusted)
NOEL Daphnia magna 1060 mg/L, 48 hour (pH adjusted)
Fish 0% Mortality Fathead Minnow 2000 mg/L, 96 hour (pH adjusted)
Persistence and degradability No data is available on the degradability of any ingredients in the mixture.
- COD (mgO2/g) 335 (calculated data)
- BOD 5 (mgO2/g) 70 (calculated data)
- BOD 28 (mgO2/g) 105 (calculated data)
- Closed Bottle Test (% 23 (calculated data)
Degradation in 28 days)
- Zahn-Wellens Test (% 27 (calculated data)
Degradation in 28 days)
- TOC (mg C/g) 150 (calculated data)
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Hydroxyacetic acid -1.11
Nitrilotriacetic acid,trisodium salt (NTA.Na3) -10.1
Bioconcentration factor (BCF)
Nitrilotriacetic acid,trisodium salt (NTA.Na3) 3
Mobility in soil No data available.
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.

13. Disposal considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information


IATA
Basic shipping requirements:
UN number UN3265
Proper shipping name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Hydroxyacetic acid)
Hazard class 8
Packing group II
Special transport Read safety instructions, SDS and emergency procedures before handling.
precautions and conditions
IMDG
Basic shipping requirements:
UN number UN3265
Proper shipping name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Hydroxyacetic acid)
Hazard class 8

Product: KLEEN MCT105 - Page 6 of 8


Version : 3.2
Date of preparation : 30 September 2023
Previous date : 29 September 2022

SAFETY DATA SHEET


KLEEN MCT105

Packing group II
Marine pollutant No
EmS No. F-A, S-B
Special transport Read safety instructions, SDS and emergency procedures before handling.
precautions and conditions
SEA (Annex II of MARPOL 73/78 Not established.
and the IBC Code)
IATA; IMDG

15. Regulatory information


Safety, health and environmental regulations specific for the product in question
Controlled Narcotic & Psychotropic Precursors List
Not regulated
CWC (Chemical Weapons Convention Act 2000, Schedules 1-3)
Not regulated
Hazardous Chemicals, Schedule 2: Threshold Quantities at an Isolated Storage (Manufacture, Storage and Import of
Hazardous Chemical Rules 1989, as amended).
Not regulated
Hazardous Chemicals, Schedule 3: Threshold Quantities in an Industrial Installation (Manufacture, Storage and Import of
Hazardous Chemical Rules 1989, as amended).
Not regulated
List of Hazardous Chemicals (Manufacture, Storage and Import of Hazardous Chemical Rules, Schedule I (Part II)).
Not regulated
Ozone Depleting Substances (ODS) (Ozone Depleting Substances (Regulation and Control) Rules 2000, Schedule 1).
Not regulated
International regulations
Stockholm Convention
Not applicable.
Rotterdam Convention
Not applicable.
Montreal Protocol
Not applicable.
Kyoto protocol
Not applicable.
Basel Convention
Not applicable.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Industrial Chemicals (AICIS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)

Product: KLEEN MCT105 - Page 7 of 8


Version : 3.2
Date of preparation : 30 September 2023
Previous date : 29 September 2022

SAFETY DATA SHEET


KLEEN MCT105

Country(s) or region Inventory name On inventory (yes/no)*


Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date Feb-12-2014
Revision date 30/09/2023
Version # 3.2
References: No data available
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. Information contained in this material data
sheet is believed to be reliable but no representation, guarantee or warranties of any kind are
made as to its accuracy, suitability for a particular application or results to be obtained from them.
It is up to the manufacturer/seller to ensure that the information contained in the material safety
data sheet is relevant to the product manufactured/handled or sold by him, as the case may be.
The government makes no warranties expressed or implied in respect of the adequacy of this
document for any particular purpose.
Revision information Other information, including date of preparation or last revision: Disclaimer
GHS: Classification

Product: KLEEN MCT105 - Page 8 of 8

You might also like