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    Jis-8502

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    JIS JAPANESE INDUSTRIAL STANDARD Translated and Published by Japanese Standards Association JIS H 8502: Methods of corrosion resistance test for metallic coatings ICS 25,220.40 Descriptors ; metal coatings, testing, corrosion, tests, electroplating Reference number : JIS H 8502 ; 1999 (B) H 8502: 1999 Foreword ‘This translation has been made based on the original Japanese Industrial Standard revised by the Minister of International Trade and Industry through deliberations at the Japanese Industrial Standards Committee in accordance with the Industrial Standardization Law. Consequently JIS H 8502:1988 is replaced with JIS H 8502:1999. Attention is drawn to the possibility that some parts of this Standard may conflict with a patent right, application for a patent after opening to the public, utility model right, or application for a registration of utility model after opening to the public which have technical propertice. ‘The relevant Minister and the Japanese Industrial Standards Committee are not responsible for identifying the patent right, application for a patent after opening to the public, utility model right, or application for registration of utility model after opening to the public which have the said technical properties. Date of Establishment: 1982-11-01 Date of Revision: 1999-08-20 Date of Public Notice in Official Gazette: 1999-08-20 Investigated by: Japanese Industrial Standards Committee Divisional Council on Non-Ferrous Metals JIS 14 8502: 1999, First English edition published in 2001-01 Translated and published by: Japanese Standards Association 41-24, Akasake, Minato-ku, Tokyo, 107-6440 JAPAN In the event of any doubts arising as to the contents, the original JIS is to be the final authority. © JS 2001 ‘Ail rights reserved. Unless otherwise specified, no part of this publication may be reproduced or Uilized in eny form or by emy means, electronic cr mechanical, including photocopying and microfilm, withast permission in writing from the publisher. Printed in japan JAPANESE INDUSTRIAL STANDARD JIS H 8502 : 1999 Methods of corrosion resistance test for metallic coatings Introduction This Japanese Industrial Standard has been prepared based on the corresponding International Standards listed in Remarks to 1 Scope for the corresponding parts, without any modification of technical contents, and added the items not specified in the corresponding International Standards and further the contents specified in the corresponding International Standards (test method of sulfur dioxide, test method of hydrogen sulfide, and test method of mixed gas) with partial modification. 1 Scope This Standard specifies the methods of corrosion resistance test for the metallic coatings and the products coated with metal. Motallic coating contains such plating os electroplating, electroless plating, vapor deposition(’), and hot-dip plating Note @) Vapor deposition means vacuum evaporation, sputtering, ion plating, chemical vapor deposition, and so on. Romarks: The International Standards corresponding to this Standard are listed as follows ISO 4540:1980 Metallic coatings — Coatings cathodic to the substrete — Rating of electroplated test specimens subjected to corrosion teste 180 4541:1978 Metallic and other non-organic coatings — Corrodkote corrosion test (CORR test) 180 8407:1991 Corrosion of metals and alloys — Removal of corrosion products from corrosion test specimens ISO 8565:1992 Metals and alloys — Atmospheric corrosion testing — General requirements for field tests 180 9227:1990 Corrosion fests in artificial atmospheres — Salt spray tests 180 100621991 Corrosion tests in artificial atmosphere at very low concentrations of polluting gas(es) ISO/MDIS 149931998 Corrosion of metals and alloys — Accelerated corrosion testing involving eyclic exposure to salt mist, dry and wet conditions TEC 60068-2-42:1982 Basic environmental testing procedure — Part 2: Tests, Test Ke : Sulfur dioxide test for contacts and connections TEC 60068-2-43:1976 Basic environmental testing procedure — Part 2: Tests. Test Kd : Hydrogen-sulphide test for contacts and connections 2 Normative references The following standards contain provisions which, through reference in this Standard, constitute provisions of this Standard. The most recent editions of the standards indicated below shall be applied. 2 ‘H 8502: 1999 JIS B 7952 Continuous onalyzers for sulfur dioxide in ambient air JIS H 0211 Glossary of terms used in. surface treatments by dry processing JIS H 0400 Glossary of terms used in electroplating JIS K 0101 Testing methods for industrial water JIS K 0103 Methods for determination of sulfur oxides in flue gas JIS K 0104 Methods for determination of oxides of nitrogen in flue gases JIS K 8116 Ammonium chloride JIS K 8142 Iron (Il) chloride hexahydrate JIS K 8145 Copper (ii) chloride dihydrate JIS K 8150 Sodium chtoride JIS K 8180 Hydrochloric acid JIS K 8985 A JIS K 8541 Nitric acid JIS K 8576 Sodium hydromide JIS K 8961 Sulfuric acid JIS P8801 Filter paper (for chemical analysis) JIS Z 2371 Methods of neutral salt spray testing JIS Z8401 Guide to the rounding of numbers etic acid 8 Definitions For the purpose of this Standard, the definitions in JES Hi 0211and JIS H 0400 and the following definitions apply. a) outdoor exposure test The test which a test piece is placed on an exposure frame and then is exposed under atmospheric condition. b) direct outdoor exposure test The outdoor exposure test whieh is carried out outdoore by direct exposure under atmospheric condition. ©) sheltered exposure test The outdoor exposure test which is carried out outdoors under the atmospheric condition but sheltered from snow, rain and sunshine. a) continuous spray test The test which a test piece is exposed to the atmosphere of continuously spraying corrosive liquid. e) neutral salt spray test Continuous spray test with spraying neutral sodium chloride solution: £) acetic acid salt spray test, ASS test Continuous spray test with spraying sodium chloride sclution acidified by acetic acid. g) CASS test (copper-aecelerated acetic acid salt spray test) Continuous spray test with spraying sodium chloride solution acidified by acetic acid in which copper (11) chloride dihydrate was added. h) cyclic test The test in which spraying of corrosive liquid, drying and wetting are repeatedly carried out in order to make the atmosphere similar to natural condition and to accelerate the test. a D k) y m) n) 0) P) a) b) ° a e) a H 8502 : 1998 eyelic neutral salt spray test Cyclic test carried out in the atmosphere of spraying of neutral sodium chloride solution, drying, and wetting. cyclic artificial acid rain test Cyclic test carried out in the atmosphere of spraying of artificial acid rain prepared by adding nitric acid, sulfuric acid, ote jnto neutral sodium chloride solution, drying, and wetting, corrodkote corrosion test ‘The tost which a test piece is applied with corrodkote slurry and is allowed to stand in a humidity chamber after being dried, pollutioning gas corrosion test The test carried out by means of exposing @ test piece in the atmosphere of pollutioning gas. sulfur dioxide gas test Pollutioning gas corrosion test carried out in the atmosphere of sulfur dioxide gas. hydrogen sulfide gas test Pollutioning gas corrosion test. carried out in the atmosphere of hydrogen sulfide gas. chlorine gas test Pollutioning gas corrosion test carried out in the stmosphere of chlorine gas. mixed pollution gas test Pollutioning gas corrosion test carried out in the atmosphere of mixed gas of sulfur dioxide, hydrogen sulfide, nitrogen dioxide, and chlorine gas. Classification of test methods Test methods are classified as follows. Outdoor exposure test method 1) Direct outdoor exposure test method 2) Sheltered exposure test method Continuous spray test method 1) Neutral salt spray test method 2) Acetic acid alt spray tost method, ASS test method 3) CASS test method, Copper-accelerated acetic acid salt spray test method Cyclic test method 1) Cyelie neutral salt spray test method 2) Cyclic artificial acid rain test method Corrodkote corrosion test method Pollutioning gas corrosion test method 1) Sulfur dioxide gas test method 2) Hydrogen sulfide gas test method 3) Chlorine gas test method 4) Mixed pollution gas test method Test piece Test pieces shall be as follows. 4 8502 : 1999 6.1 Handling of test piece When handling a test piece, use gloves instead of handling with the bare hands 5.2 Sampling of test piece Test pieces shall be either sampled from the significant surface of the product or the product itself, When it is difficult to test or judge on the product, a test piece replacing it may be used. ‘The test piece shall be the one capable of representing(*)() the produets 58 Size of test piece The size of a test piece is preferably 150 mm x 70 mm or 100 mm x 100 mm. The agreement between the parties concerned with delivery, however, can choose other size of test piece. 5.4 Treatment before test a) Wipe well the test pico with = solvent(") adequate for dirt, or rub(*) fully the surface to be tested with fine powder of magnesium oxide or precipitated calcium carbonate stuck on water-moistened abeorbent cotton, then rinse it with water, and take off water on it with a clean cloth or blotting paper. b). The exposed substrate such as cut end or end surface of a test piece where is not to be tested shall be protected with applying a coating(®) stable enough under the test condition ©) When cross cut sect is necessitated, follow Note ("). Notes (°) The composition of material, condition for manufacturing, and the finishing condition before metallie coating are preferably the same as those for products. ©® Carry out the pretreatment and metallic coating in the same bath and under the same condition as those for products, and further it is recommendable to carry out the procedures simultaneously with the products in order that the working conditions can similarly influence on tho test piece () Ethanol, benzine, or gasoline is recommendable. (®) In case of applying conversion treatment (for instance, chromate treatment on galvanized sheet) or of coating with paint after metallic coating, it is preferable to avoid this procedure. (@) Insulating tape may be used. () On about half surface of a test piece, as shown in Fig. 1, eat two X- shaped flaws crossing each other by about 70 degrees and measuring 50 mm length using a bite or diamond cutter. It is preferable to hold its edge at a definite angle of 35 to 45 degrees to the test surface, and to keep constant the depth and dimension of the cut. 5 #1 8502 : 1999 Scratch, Coated place Fig. 1. Way to cut the scratch 6 Outdoor exposure test method 6.1 Direct outdoor exposure test method 6.1.1 Summary Place a teat pioce on 2 exposure frame, expose it directiy to atmospheric condition, and check the corrosion resistance of metallic coatings. 6.1.2 Conditions of site for exposure Exposure site shall satisfy the following conditions. a) Principally, the testing area shall be exposed to the full effects of the weather. b) The plants or shrubs growing in the vicinity of exposure frame shall be 0.2 m or less. ©) The place where chemicals are used for plant growth in the vicinity of the exposure frame shall be avoided 6.1.3 Exposure site Exposure site shall satisfy the following conditions a) The site where test pieces ean be periodically observed and environmental factors are measured. b) The site where the safety countermeasures against theft, damage, or other obstructions are completely furnished 6.1.4 Exposure frame Exposure frame shall be as follows. 2) The main material of exposure frame is aluminum alloy, wood, or steel applied adequate rust prevention, and the frame must be firmly constructed, b) The exposure surface faces southwards at an angle of 90 to 45 degrees from horizontal, and depending on its purpose, other orientations and angles, for instance vertically and northwards, are permissible. ©) The earth's surface shall be suitably covered to avoid influences radiated from the earth. @) The lowest end of exposure surface shall be at least 0.5 m above the earth's surface. 6 H 8502 : 1999 6.1.5 Attaching of test pieces The test pieces shall be attached s0 as not to allow them to touch each other nor to give influences to the others. 6.1.6 Duration of exposure Tho duration of exposure is at least one month, and it is recommended to take 8 months, 6 months, 1 year, 2 years, 5 years, 10 years, or 20 years. In any case, the time when exposure was started shell be noted in the record. 6.1.7 Measurement of weather factors The measurements of environmental factors are as follows. a) Items to be measured Environmental factors necessary for analysis of the results obtained from outdoor exposure test shall be as follows, and they are principally measured and recorded every day during test period. For factors considered to be unimportant depending on its purpose, the measurement of the factor can be omitted. For the items from 1) to 5), the records provided by the neighbouring meteorological weather stetion can be used. 1) The maximum air temperature (°C), the minimum air temperature (°C), averaged air tomperature (°C) 2) The maximum relative humidity (%) the minimum relative humidity (%1, averaged relative humidity (%e) 8) Wind direction 4) Wind speed (m/s) 5) Amount of precipitation (mm/a) 6) Duration of precipitation (h) 7) Number of precipitations (times/d) 8) Time of wetness (h) 9) Particles of sca salt (mgNaCl(100 em?-d)} 10) Concentration of sulfur dioxide (ppm) or concentration of sulfur trioxide {mg/(m*-d)] 11) Concentration of nitrogen dioxide (ppm or [mg/(m*d)]) b) Measuring method The measuring methods of environmental factors are as follows. 1) Measurement of air temperature Attach a maximum and minimum thermometer or automatically recording thermometer to the instrument sereen placed on or near the exposure frame to measure the temperature. 2) Measurement of humidity At the same place as mentioned at 1), use an automatically recording hygrometer, and measure the humidity. 3) Measurement of wind direction Use an anemoscope. 4) Measurement of wind speed Use an anemometer. 5) Measurement of amount of precipitation Use a pluviometer. 6) Measurement of duration of precipitation Record the start time of raining and stop time of raining, and calculate the duration of precipitation. 7 H 8502 : 1999 7) Measurement of number of precipitations Measure the number of precipitations per day 8) Measurement of the time of wetness Measure the time of wetness por day. 9) Measurement of particles of sea salt For the measurement of sea-salt particles, employ the method in Annex 1 or other methods recomnized effectiveness. 10) Measurement of concentration of sulfur dioxide and sulfur trioxide For the measurement of concentration of sulfur dioxide, employ the turbidimetry specified in JIS K 0103. For the measurement of concentration of sulfur trioxide, follow Annex 2 or Annex 3. 41) Measurement of concentration of nitrogen dioxide For the measurement of concentration of nitrogen dioxide, follow Salzmann method specified in JIS K 0104 or fallow Annex 3. 6.1.8 Judgement Judgement shall follow 11. 6.1.9 Report The test report shall contain the following particulars. a) Conditions of exposure site (such as angle of exposure) b) Sampling method, shape, quantity, dimensions, and symbol of test piece ¢) Environmental factors observed during exposure ) Duration of exposure (start time of exposure, and so on) e) Results of judgement, 6.2 Sheltered exposure test method 6.2.1 Summary Place a test piece on a exposure frame, expose it undor the atmospheric condition but being sheltered from snow, rain and sunshine, and check the corrosion resistance of metallic coatings. 6.2.2 Conditions of site for exposure Exposure site shall satisfy the following conditions. 2) The testing area shall be exposed to the full effects of the weather except of snow, rain, and sunshine. b) The plants or shrubs growing in the vicinity of exposure frame shall be 0.2 m or less. ©) The place where chemicals are used for plant growth in the vicinity of the exposure frame shall be avoided. 6.2.3 Exposure site Exposure site shall satisfy the following conditions. a) The site where test pieces can be periodically observed and environmental factors are measured. b) The site where the safety countermeasures against theft, damage, or other obstructions are completely furnished. 6.2.4 Exposure frame Exposure frame shall be as follows. 8 H 8602 : 1999 a) The main material of exposure frame is aluminum alloy, wood, or etool applied adequate rust prevention, and the frame must be firmly constructed. b) The exposure surface is inclined by any one of 0°, 30°, 45°, 60°, and 90° to the vertical. ©) The carth’s surface shall be suitably covered to avoid influences radiated from the earth. 4) The lowest end of exposure surface shall be at least 0.5 m above the earth's surface. e) The roof or cover is inclined and its height is 3 m or less. 6.2.5 Attaching of test pieees The test pieces shall be attached so as not to allow them to touch each other nor to give influences to the others. 62.6 Duration of exposure ‘The duration of exposure is at least one month, and it is recommended to take 3 months, 6 months, 1 year, 2 years, 5 years, 10 years, or 20 years. In any ease, the time when exposure was started shall be noted in the record. 6.2.7 Measurement of environmental factors ‘The measurements of environmental factors are as follows. a) Items to be measured Environmental factors necessary for analysis of the recuits obtained from outdoor exposure test shall be as follows, and they are principally meesured and recorded every day during test period. For factors vonsidored to be unimportant depending on its purpose, the measurement of the factor con be omitted. For the items from 4) to 5) the records provided by the neighbouring meteorological weather station can be used. 1) The maximum air temperature (°C), the minimum air temperature (°C), averaged air temperature (°C} 2) The maximum relative humidity (%), the minimum relative humidity (%), averaged relative humidity (%) 8) Wind direction 4) Wind speed (V/s) 5) Amount of precipitation (mm/d) 6) Duration of precipitation dh) 7) Number of precipitations (times/d) 8) Time of wetness (h) 9) Particles of sea salt [mgNeCV(100 em*d)] 10) Concentration of sulfur dioxide (ppm) or concentration of sulfur trioxide {mg/(m*-d)} 11) Concentration of nitrogen dioxide (ppm or [mg/(m?-d)]) >) Measuring method The measuring methods of environmental factors are a& follows. 9 1H 8502 : 1999 1) Measurement of atmospheric temperature Attach a maximum and minimum thermometer or automatically recording thermometer to the jnstriament screen placed on or near the exposure frame to measure the temperature. 2) Measurement of humidity At the same place as mentioned at 1), use an automatically recording hygrometer, and measure the humidity. 3) Measurement of wind direction Use an anemoscope. 4) Measurement of wind speed Use an anemometer. 5) Measurement of amount of precipitation Use # pluviometer. 6) Measurement of duration of precipitation Record the start time of raining and stop time of raining, and calculate the duration of precipitation. 7) Measurement of number of precipitations Measure the number of precipitations per day. 8) Measurement of the time of wetness Measure the time of wetness per day. 9) Measurement of particles of sea salt For the measurement of sea-salt particles, employ the method in Annex 1 or other methods recognized effectiveness. 10) Measurement of concentration of sulfur dioxide and sulfur trioxide For the measurement of concentration of sulfur dioxide, employ the turbidimetry specified in JIS K 0108 or the like. For the measurement of concentration of sulfur trioxide, follow Annex 2 or Annex 8. 11) Measurement of concentration of nitrogen dioxide For the measurement of coneentration of nitrogen dioxide, follow Salzmann methed specified in JIS K 0104 or follow Annex 3. 6.2.8 Judgement Judgement shall follow 11. 6.2.9 Report The test report shall contain the following particulars. a) Conditions of exposure site (such as angle of exposure) b) Sampling method, shape, quantity, dimensions, and symbol of test piece c) Environmental factors observed during exposure d) Duration of exposure (start time of exposure, and s0 on) ) Results of judgement 7 Continuous spray test method 7.1 Neutral salt spray test method 7.11 Summary Employ a salt spray tester, spray neutral sodium chloride solution, and check the corrosion resistance of metallic coatings under the sprayed condition. 7.1.2 Preparation procedures of test solution Test solution shall be prepared in the following sequence. 10 H 8502: 1999 a) Put suitable emount of pure water(*) into a container made of synthetic resin or glass. b) Use sodium chloride of guaranteed grade specified in JIS K 8150 or of the grade equal or suporior to this, and dissolve it in the water to make a concentration of 50 £5 g per liter of test solution ¢) Control its pH to 6.5 by adding the solution of either sodium hydroxide specified in JIS K 8576 or hydrochloric acid specified in JIS K $180. a) Stir it sufficiently, control it to 25 °C, and adjust its specific gravity to 1.029 to 1.036(*) measuring with a hydrometer. e) Put a cover on the prepared solution to prevent dust. Notes (*) This pure water shall have a conductivity of 20 wS/em (or 2 mS/m) or less at 26 +2 °C. 1 pSiem or less is preferable, ) Measure the concentration of sodium chloride solution by either d) of 7.1.2or the following method: Dilute 5 ml of taken solution with 100 nil of pure water, mix them well, take 10 mi aliquot using a pipet, add 40 ml of pure water and 1m] of potassium chromato solution (1 wir %) (chloride free), and agitate well. Then, titrate it with 0.1 mol silver nitrate solution, and confirm the required amount of the titrant is from 3.4 ml to 5.1 ml 7.1.8 Apparatus The apparatus required for this test shall be in accordance with JIS Z 2371, and composed of a thermostatic and humidistatic test vessel equipped with spraying tower or spraying nozzle, tank for salt solution, holder of test piece, container for sprayed solution and co on, and reservoir for salt solution, eir saturator, supplier of compressed air, exhaust systom and s0 on, all of which must satisfy the following requirements. a) ‘The material of the apparatus shall not give any influences on the corrosiveness of salt solution, and not be easily corroded itself, b) The test vessel shall have at least 0.2 m? capacity. ¢) The salt colution shall not be directly sprayed on the test piece, and the drops of the salt solution formed on the ceiling of the vessel shall not fall on the test piece. 4) Don't reuse the salt solution which fell from the test piece. e) The compressed air used for spraying salt solution shall be free from oil or dirties, and its pressure be in the range from 70 kPa to 167 kPa(”). f) The container for sprayed solution shall be clean one with 80 cm* of horizontal area for solution collecting, and be placed at least at 2 locations to confirm the uniformity of spraying. For instance, in the vicinity of test piece, one is placed neer the spray tower or spray nozzle, and the other remote from it. ) For the sprayed quantity of solution, 1.0 ml to 2.0 ml of the salt solution shell be collected per hour into each container throughout the period of spraying. h) The temperature in test vessel shall be kept at 35 +2 °C, that in salt solution tank at 35 +2 °C, and that in air saturator at 47 +2 °C. i H 8502 : 1999 Note (!®) Apply any pressure within this range, and it is preferable to keep the pressure constant during the test. 1.4 Holding of test piece During the test, the location of test piece in the test vessel shall conform to the following eonditions("). a) Hold the test piece co that the surface forms at an angle of 20 degrees (allowable limit: from 16 to 80 degrees) to the vertical, and place it at the position or the @irection where it is expoged only to the free fall of spray of salt solution. b) The test pieces shall be placed so that they do not disturb the free fall of salt spray on other test pieces. ©) The test pieces shall net come into contact with other objects than the frame a) The drops of salt solution from the test pieces do not fall on other test pieces. e) The pressed stamp for recognition or mounting hole shall be faced downwards. Note () When the products are tested, the items not satisfying shall conform to the agreement, between the parties concerned with delivery. 721.5 Procedures After conditioning the temperature in test vessel at 35 °C, that in galt colution tank at 35 °C, and thet in air saturator at 47 °C, keep the pressure of compressed air with w! ich salt solution is sent to the spraying nozzle at 70 kPa to 167 kPa, and then begin to spray. a) Test conditions Test conditions shall be as shown in Table 1 b) Duration of test The duration of test shall be subjected (o the agreement between the parties concerned with delivery. Recommended periods are § h, 16 b, 24h, 48 h, 96h, 240 h, 480 h, and 720 hh, and spraying shall not be interruptod during the prescribed test period, ©) Treatment after test At the end of the test period, open the cover of the test vessel lest the drops of salt solution should fall on the test piece, take out the test piece lest the target surface for ovaluation should be damaged, immediately Finco its surface to remove salt stack on the surface of the test piece with water, and then take away the corrosion product at the area except the corroded portion using a brush or sponge. To remove the corrosion product, employ such mechanical measures as brushing, ultrasonic radiation, water spraying, or chemical measures as shown in Attached Table 1 12 ‘H 8502: 1999 Table 1 Test conditions for neutral salt spray test method Items While preparing ‘While testing Concentration of sodium chloride g/f 505 S045 pH 65 65 to72 ‘Amount of epray mi/B0 em*th x 15 £05 ‘Temperaturs in tost veesal *c - ape? ‘Temperature in selt water tank °C 2 | 352 ‘Temperature in sir sturator °C ~ | are Pressure of compressed sir kPa x 10 to 167 7.16 Judgement method Judgement method shall follow 11. In case of sine and cadmium coatings, however, the corrosion defects shall be judged on the generation of red rust or of white corrosion products with the naked eyes. 7.1.7 Report The test report shall contain the following particulars. a) Name and type of test epparatus b) Sampling method, shape, quantity, dimensions, symbol of test piece ©) Test conditions 1) Concentration of sodium chloride 2) pH 3) Amount of spray 4) Temperature (test vessel, salt water tank, air eaturator) 5) Pressure of compressed air d) Duration of test e) Result of judgement 7.2 Acetic acid salt spray test method, ASS test method 7.2.1 Summary Employ a salt spray tester, spray sodium chloride solution acidified by acetic acid, and check the ‘corrosion resistance of metallic coatings under the spraying condition. 7.2.2 Preparation procedures of test solution Test solution shall be prepared in the following sequence. a) Put suitable amount of pure water(®) into a container made of synthetic resin or glass. b) Use sodium chloride of guaranteed grade specified in JIS K 8150 or equal or superior to this, and dissolve it in water to make a concentration of 50 = 5 g per liter of test solution. B +H 8502 ; 1999 ©). Stir it sufficiently, control it to 25 °C, and adjust its specific gravity to 1.026 to 1.036@) measuring with a hydrometer. €) Use acetic acid of guaranteed grade specified in JIS K 8355 or equal or cuperior to this, and dissolve it by adding 1 mi per liter of sodium chloride solution, agitate it well, ‘and measure its pH. If the pH is 3.1 or higher at 25 °C, add acetic acid more, agitate it well, and measure its pH again. Repeat these procedures until its pH reaches 3.0 at 26 °C ©) Put a cover on the prepared solution to prevent dust. 7.2.8 Apparatus The apparatus required for this test shall be in accordance with JIS Z 2871, and composed of a thermostatic and humidistatie test vessel equipped ‘vith spraying iower or spraying nozzle, tank for salt solution, holder of tes! piece, Container for sprayed eclution and so on, and resorvoir for salt solution, air eaturator, supplier of compressed air, exhaust system, and so on, all of which must satiely the following requirements. a) The material of the apparatus shell not give any influences on the corrasiveness of calt solution, and not be easily corroded itself. b) The test vessel shall have at least 0.2 m? capacity ©) The selt solution shall not be sprayed directly on the test piose, and the drops of the salt solution formed on the ceiling of the vessel ehell not fall on the test piece. a) Don’t reuse the salt solution which fell from the test piece. fe) Tho compressed air used for opraying salt solution shall be free from ofl or dirtics, and its pressure be in the range from 70 kPa to 167 kPa(*) f) The container for sprayed solution shall be clean one with 80 em* of horizontal area for solution collecting, and be placed at least at 2 locations to confirm the Gniformity of spraying. For instance, in the vicinity of test piece, one is placed near the spray tower or spray nozzle, and the other remote from it. 4g) For the sprayed quantity of solution 1.0 ml to 2.0 ml of the salt solution shall be collected per hour into each container throughout the period of spraying. bh) ‘The temperature in test vessel shall be kept at 35 +2 °C, that in salt solution tank at 35 +2 °C, and that in air saturator at 47 +2 °C. 7.2.4 Holding of test piece During the test, the location of test piece in the test vessel shall conform to the following conditions(”). a) Hold the test piece eo that the surface forms at an angle of 20 degrees (allowable Jimit: from 18 to 30 degrees) to the vertical, and place it at the position or the direction where it is exposed only to the free fall of spray of salt solution. b) The test pieces shall be placed so that they do not disturb the free fall of salt solution on other test pieces c) The test pieces shall not come into contact with other objects than the frame. 4) The drops of salt solution from the test pieces do not fall on other test pieves. «) The pressed stamp for recognition or mounting hole shall be faced downwards. 14 H 8502 : 1999 7.2.5 Procedures After conditioning the temperature in test vessel at 35 °C, that jn salt solution tank at 36 °C, and that in air saturator at 47 °C, keep the pressure of compressed air with which salt solution is sent to the spraying nozzle ot 70 kPa to 167 kPa, and then begin to spray. a) Test conditions Test conditions shall be as chown in Table 2. b) Duration of test The duration of test shall be subjected to the agreement between the parties concerned with delivery. Recommended periods are 8 h, 16h, 24 h, 48 b, 96 b, 240 h, 480 h, and 720 h, and epraying shall not be interrupted during the prescribed test period. ©) Treatment after test At the end of the test period, open the cover of the test vossel lest the drops of salt solution should fall on the test piece, take out the test piece lest the target surface for evaluation should be damaged, immediately rinse its surface to remove salt stack on the surface of the test piece with water, and then take sway the corrosion product at the area except the corroded portion using a brush or sponge, To remove the corrosion product, employ such mechanical measures os brushing, ultrasonic radiation, water spraying, oF chemical measures as shown in Attached Table 1. Table 2 Test conditions for acetic acid salt spray test method tems While preparing | _ While testing Concentration of sodium chloride git 5055 | sor pi 3.0 3.110 8.8 Amount of spray ml/80 om" = 15405 ‘Temporature in test vessel c - 3542 ‘Temperature in salt water tank °C - 3542 ‘Temperature in air saturator °C = 4742 Pressure of compressed air__kPa = 10 to 167 7.2.6 Judgement method Judgement method shall follow 11 7.2.7 Report The test report shall contain the following particulars. a) Name and type of test apparatus b) Sampling method, shape, quantity, dimensions, symbol of test piece ©) Test conditions 1) Concentration of sodium chloride 2) pH 3) Amount of spray 4) Temperature (test vessel, salt water tank, air saturator) 5) Pressure of compressed air 4) Duration of test e) Result of judgement 15 HaH02 : 1999 7.3 CASS test method 73.1 Summary Employ a CASS tester, spray the acetic acid-acidified sodium UNoride solution added copper (ID) chloride dihydrate, and check the corrasion resistance of metallic coatings under the spraying condition. 1.8.2 Preparation procedures of test solution Test solution shall be prepared in the following sequence. a) Put suitable amount cf pure water(®) into a container made of synthetic resin oF glass. bb) Use sodium chloride of guaranteed grade specified in JIS K 8160 or of the grade equal or superior to this, and dissolve it in water to make a concentration of 50 +5 g per liter of test solution, ©) Stir it aufficiently, control it to 26 °C, and adjust its specific gravity to 1.029 to 036) measuring with a hydrometer. 4) Use copper (IN) chloride dihydrate of guaranteed grade specified in JTS K 8145 of of the grade equal or superior to this, and dissolve it by adding 0.26 + 0.02 per liter of sodium chloride solution. This solution is equivalent, when prepared, to 0.205 + 0.015 g of copper (II) chloride per liter. @) Use acetic acid of guaranteed grade specified in JIS K 8365 or of the grade equal or superior to this, and dissolve it by adding 1 ml per liter of the solution tnentioned above, agitate it well, and measure its pH. Ifthe pH is 3.1 or higher at 25 °C, add acetic acid more, agitate it, and measure its pH again. Repeat these procedures until its pH reaches 3.0 at 25 °C. Put a cover on the prepared solution to prevent dust. 7.8.8 Apparatus The epparatus required for this test shall be in accordance with TS Z 2371, and composed of a thermostatic and humidistatic test vessel equipped With spraying tower or epraying nozzle, tank for salt solution, holder of test piece, vontainer for eprayed solution and so on, and reservoir for salt solution, air saturator, supplier of compressed air, exhaust system, and so on, all of which must satisfy the following requirements a) The material of the apparatus shall not give any influences on the corrosiveness of salt solution, and not be easily corroded itself. hb). ‘The test vessel shall have at least 0.2 m? capacity @) The salt solution shall not be directly sprayed on the test piece, and the drops Of the salt solution formed on the ceiling of the vessel shall not Zall on the test piece. @) Don't reuse the calt solution which fell from the test piece. e) ‘The compressed air used for spraying salt solution shall be free from oil er dirties, and its pressure be in the range from 70 kPa to 167 Pal”). 4 The container for sprayed solution shail be clean one with 80 cm? of horizontal ares for solution collecting, and be placed at least at 2 locations to confirm the Uniformity of spraying. For instanca, in the vicinity of test piece, one is placed near the spray tower or sprey nozzle, and the other remote from it. 16 H 8502 : 1999 g) For the sprayed quantity of solution, 1.0 ml to 2.0 ml of the salt solution shall be collected per hour into each container throughout the period of spraying. h) The temperature in test vessel shall be kept at 50 + 2 °C, that in salt solution tank at 60 +2 °C, and that in air saturator at 63 £2 °C. 7.3.4 Holding of test piece During the test, the location of test piece in the test ‘vessel shall conform to the following conditions(™). a) Hold the test pioce eo that the surface forms at an angle of 20 degrees (allowable limit: from 15.60 30 degrees) to the vertical, and place it at the position or the direction where it is exposed only to the free fall of spray of salt solution. b) The test pieces shall be placed so that they do not disturb the free fall of salt solution on other test pieces. ) The test pieces shall not come into contact with other objects than the frame. 4) The drops of salt eolution from the tost pieces do not fall on other tast pieces. e) The pressed stamp for recognition or mounting hole shall be faced downwards. 7.8.5 Procedures After conditioning the temperature in test vessel at 50 °C, thai in salt solution tank at 60 °C, and that in air saturator at 63 °C, keep the pressure of compressed air with which calt colution is sent to the spraying nozzle at 70 kP2 to 167 kPa, and then begin to spray. a) Test conditions Test conditions shall be as shown in Table 3. b) Duration of test ‘The duration of test shall be eubjected to the agreement between the parties concerned with delivery. Recommended periods are 2h, 4h, 8 h, 16h, 24h, 48 h, 96 h, and spraying shall not be interrupted during the prescribed test period. c) Treatment after test At the end of the test period, open the cover of the test vessel lest the drops of salt solution should fall on the test piece, take out the test piece lest the target surface for evaluation should be damaged, immediately rinse its surface to remove salt stack on the surface of the test piece with water, and then take away the corrosion product at the area except the corroded portion using a brush or sponge. To remove the corrosion product, employ sueh mechanical measures as brushing, ultrasonic radiation, water spraying, or chemical measures as shown in Attached Table 1. wu 8502 : 1999 ‘Table 3 Test conditions for CASS test method While preparing | _ While testing Concentration of sodium chloride g/d poz 5045 Concentration of copper (11) ebloride (CuCl 2:0) gi | 0.26 +0.02 - oH 3.0 30 10 32 Amount of spray mV60 cm'¢h 15205 ‘Temperature in test vessel 76 O42 ‘Temperature im salt water tank °C so+2 ‘Temperature in air saturator °C Pressure of compressed air KPa 7.3.6 Judgement method Judgement method shall follow 11. 7.3.7 Report ‘The test report shall contain the following particulars. a) Name and type of test apparatus b) Sampling method, shape, quantity, dimensions, symbol of test piece c) Test conditions 1) Concentration of sodium chloride 2) Concentration of copper (Ll) chloride 38) pH 4) Amount of spray 5) Temperature (vost vessel, salt water tank, air saturator) 6) Pressure of compressed air d) Duration of test e) Result of judgement 8 Cyelie test method 8.1 Cyclic neutral salt spray test method 8.1.1 Summary Employ a cyclic neutral salt spray tester, carry out repeatedly the sequential exposure of a test piece to the atmosphere of spraying of neutral sodium chloride solution, drying, and wetting, and check the corrosion resistance of metallic coatings. 8.1.2 Preparation procedures of test solution Test solution shall be prepared in the following sequence. fa) Put suitable amount of pure water(*) into a container made of synthetic resin or glass. 18 E8502 : 1999 b) Use sodium chloride of guaranteed grade specified in JIS K 8150 or of the grado equal or superior to this, and dissolve it in water to make a concentration of 50 +6 g per liter of test solution. ©) Control its pH to 6.5 by adding the solution of either sodium hydroxide specified in JIS K 8576 or hydrochloric acid specified in JIS K 8180. d) Stir it sufficiently, control it to 25 °C, and adjust its specific gravity to 1.029 to 1,036(*) measuring with a bydrometer. e) Put a cover on the prepared solution to prevent dust. 8.1.3 Apparatus The apparatus required for this test shall be composed of the test vessel equipped with spraying tower or spraying nozzle, tank for salt solution, holder of test piece, container for eprayed solution, temperature controlling device and so on, and a reservoir for salt solution, supplier of compressed air, humidifying device, supplying device for dried air, exhaust system, and so on, all of whieh must set up the specified test conditions and must satisfy the following requirements. a) The test vesse] shall have at least 0.2 m* capacity, and preferably 0.4 m* or larger, and its shape and dimensions are optional. b) The ceiling or cover of the test vessel shall be so constructed that the drops of the salt sclution formed on it do not fall on the test piece. c) The corrosive material shall not be used for the apparatus. 4) The apparstus shall be so constructed that the temperature in test vessel and spraying of salt solution are not influenced from outside atmosphere, and thet the salt solution whieh fell from a tost piece is not used again for the test. e) The test piece holder shall he capable of holding the test piece at the specified angle, 1) The container for sprayed solution shall be clean one with 80 cm? of horizontal area for solution collecting, and be placed at least at 2 locations to confirm the uniformity of spraying. For instance, in the vicinity of test piece, one is placed near the spray tower or spray nozzle, and the other remote from it. g) Humidifying device shall be capable of setting the specified humid condition. h) Tho supplying device for dried air shall be capable of setting the specified drying condition. i) Exhaust system shall be such that the spraying of salt solution is not influenced by outside atmospheric pressure. j) The maintenance of test apparatus shall be carried out to achieve the specified condition. 8.1.4 Holding of test piece During the test, the location of test piece in the test vessel shall conform to the following conditions("). a) Principally, hold the test piece so that the surface to be evaluated forms at an angle of 20 degrees (allowable limit: from 15 degrees to 80 degrees) to the vertical, and place it at the position or the direction where it is exposed only to the free fall of spray of salt solution, 19 H 8502 ; 1999 b) The test pieces shall be placed so that they do not disturb the free fall of salt solution on other test pieces. ©) The test pieces shall not come into contact with other objects than the freme. 4) The drops of selt solution from the test pieces do not fall on other test pieces ©) The preseed stamp for recognition or mounting hole shall be faced downwards. 1.5 Procedures After confirming that the spraying conditions have been Sbtained in advance, stop the spraying temporarily, then put the test piece into the test vessel, and start the test. 2) Test conditions Test conditions shail be es shown in Table 4. b) Duration of test The duration of test shall be subjected to the agreement between the parties concerned with delivery. Recommended periods are 8 cycles (24 hi, 6 cycles (48 h), 10 cycles (80 h), 30 eycles (240 h), 60 cycles (480 h), and 120 cycles (960 h), and principal the test chall be continued without interruption throughout the test duration. ©) Treatment after test At the end of the test period, open the cover of the test ‘vessel lest the drops of salt solution should fall on the test piece, take out the test piece lest the target surface for evaluation should be damaged, immediately vince its surface to remove salt stack on the surface of the test piece with water, and then take eway the corrosion product at the area except the corroded portion using a brush or sponge. To remove the corrosion product. employ such mechanical measures as brushing, ultrasonie radiation, water spraying, or chemical measures as shown in Attached Table 1. ‘Table 4 Test conditions for cyclic neutral salt spray test method Items Conditions 1 Spray of salt solation a) Temperature °C 3541 b) Concentration of sodium chloride gil B05 2 Drying a) Temperature °C eott b) Relative bumidity RH 20 to 80 3 Wetting a) Temperature °C B01 b) Relative humidity %RH 95 min, {4 Time and content of one cycle A 8 Salt solution spraying 2] Drying 4] Wetting 2) (These times include the time for reaching the specified temperature for each condition) 20 H 8502 : 1999 ‘Table 4 Test conditions for cyclic neutral salt spray test method (concluded) Teens Conditions [5 Time to reach the specified condi- tion min (This means period taken for tem- perature and humidity to reach the specified values pnce the test condi- {30 oF less from spraying to drying '15 or less from drying +o wetting 30 or less from wetting to spraying! humidity (Principally, mist conditions are attained ‘slmost instantaneously once this con~ Gition begins.) tion has begun.) Principally, hold test piece eo that the surface to be evaluated forms at an langle of 20 dogress (allowable limit: from 15 degrees to 30 degrees) to the vertical |6 Angle at which test pioce is hold. 8.1.6 Judgement method Judgement method shall follow 11 In case of zine and cadmium coatings, the corrosion defects chall be judged on the generation of red rust or of white corrosion products with the naked eyes: 8.1.7 Report The test report shal! contain the following particulars. a) Name and type of test apparatus b) Sampling method, shape, quantity, dimensions, symbol of test piees ©) ‘Test conditions 1) Conditions for spray of salt solution (temperature, concentration of sodium chloride) 2) Conditions for drying (temperature, relative humidity) 3) Conditions for wetting (temperature, relative humidity) 4) Duration of cyclic test (h) e) Result of judgement 8.2 Cyclic artificial acid rain test method 8.2.1 Summary Employ a cyclic spray tester, carry out repeatedly the sequential exposure of a test piece to the atmosphere of spraying of artificial acid rain prepared by adding nitrie acid and sulfurie acid into neutral sodium chloride solution, drying, and wetting, and check the corrosion resistance of metallic coatings. 82.2 Preparation procedures of test solution Test solution shall be prepared in the following sequence. a) Put suitable amount of pare water(®) into a container made of synthetic resin or glass. ‘Use sodium chloride of guaranteed grade specified in JIS K 8150 or of the grade ‘equal or superior to this, and dissolve it in water to make a concentration of 50 +5 g per liter of test solution. b) ° d) 8) by) 2a H 8502: 1999 Control its pH to 6.5 by adding the sclution of either sodium hydroxide specified in JTS K 8576 or hydrochloric acid specified in JIS K 8180. Stir it sufficiently, control it to 25 °C, and adjust its specific gravity to 1.029 to 1.036) measuring with a hydrometer. ‘Add 12 mal of nitric acid specified in JIS K 8541 and 17.3 mi of sulfuric acid gpocified in J1S K 8951 into 10/ of the above prepared solution, agitate it well, and further add about 317 ml of 10 % sodium hydroxide solution, and control its pH to 3.5 at 35 + 2°C. Put a cover on the propared solution to prevent dust. 8.2.3 Apparatus ‘The apparatus required for this test shall be composed of the test vessel equipped with spraying tower or spraying nozzle, tank of solution for test, holder of test piceo, container for sprayed solution, temperature controlling device ‘and so on, and a reservoir for solution, supplior of compressed air, humidifying device, supplying device of dried air, exhaust system, and so on, ell of which must set up the specified test conditions and must satisfy the following requirements a) b) °) d) e) 8) h) i? dD ‘The test vessel have at least 0.2 m* capacity, and preferably 04 m? or larger, and its shape and dimensions are optional. The ceiling and cover of the test vessel shall be 90 constructed that the drops of the salt solution formed on them do not fall on the test piece. ‘The corrosive material shall not be used for the apparatus ‘The apparatus challl be so constructed that the temperature in test vessel and spraying of salt solution ere not influenced from outside etmosphore, and that the salt solution which fell from ¢ test piece is not used again for the test. ‘The test piece holder shall hold the test piece at the specified engle ‘The container for sprayed solution shall be clean one with 80 cm* of horizontal area for solution collecting, and be placed at least at 2 locations to confirm the Gniformity of spraying. For instance, in the vicinity of test piece, one is placed near the spray tower or spray nozzle, and the other remote from it. Humidifying device shall be capable of setting the specified humid condition. ‘The supplying device for dried air shall be eapable of setting the specified drying condition. Exhaust system shell be such that the spraying is not influenced by outside atmospheric pressure. ‘The maintenance of test apparatus shalll be carried out to achieve the specified condition, 8.2.4 Holding of test piece During the test, the location of test piece in the test vessel shall conform to the following conditions(”). a) Principally, hold the test piece so that the surface to be evaluated forms at an angle of 20 degrees (allowable limit: from 15 to 30 degrees) to the vertical, and place it at the position or the direction where it is exposed only to the free fall of spray of salt solution, 22 H 8502; 1999 b) The test piccos shall be placed so that they do not disturb the free fall of salt solution on other test pieces. ©) The tost pieces shall not come into contact with other objects than the frame. 4) The drops of salt solution from the test pieces do not fall on other test pieces e) The pressed stamp for recognition or mounting hole shall be faced downwards. 8.2.5 Procedures After confirming that the spraying conditions have been obtained in advance, stop the spraying temporarily, then put the test piece in the test vessel, and start the test. a) Test conditions Test conditions shall be as shown in Table 5. b) Duration of test The duretion of test shall be subjected to the agreement between the parties concerned with delivery. Recommended periods are 3 eycles (24 h), 6 eycles (48 h), 10 cycles (80 b), 30 cycles (240 h), 60 cycles (480 h), and 120 cycles (960 b), and principally the test shall be continued without interraption throughout the test duration. ©) Treatment after test “At the end of test period, open the cover of the test vessel lost the drops of salt solution should fall on the test piece, take out the test piece lest the target surface for evaluation should be damaged, immediately rinse its surface to remove salt stack on the surface of the test piece with water, and then talse away the corrosion product. at the area except the corroded portion using 2 brush or sponge. To remove the corrosion product, employ such mechanical measures as brushing, ultrasonic radiation, water spraying, or chemical messures as shown in Attached Table 1. Table 5 Test conditions for cyclic artificial acid rain test method Items Conditions 1 Spray a) Temperature °C 9542 b) Composition of spray solution 5 % neutral sodium chloride v0: solution (pH 6.5) Nitric acid ml 32 Sulfuric acid rl 3 ©) pH 35 (The value of pH is controlled with adding about 317 m] of 10 % sodium hydroxide solution.) 12 Drying a) Temperature °C e021 b) Relative humidity %RH 20 to 30 23 H 8502: 1999 ‘Table 5 Test conditions for cyclic artificial acid rain test method (concluded) Tiers Conditions 3. Wetting a) Temporature °C sot b) Relative humidity RH 95 min | ») Rilstrebemdiy FER | ee 4 Time and content of one cycle hk 8 ( Artificial acid rain 2 [ Drying 4 Wetting 2 (These times include the time for reaching the specified teraperature for each condition.) 5 Time to reach the specified econdi- 30 or less from spraying to drying tion main 15 or less from drying to wetting (This means period taken for tem-|36 or Joss from wetting to spraying srature and humidity to reach the Period valny ence the teet conde | RRBApHIY, mist conditions are attained almect instantaneously once this con- tion has begun.) — dition begins.) [5 Angle at which test piece is hold. |Principally, hold a test piece so that the| surface to be evaluated forms at an| langle of 20 degrecs (allowable limit: from 15 te 30 degrees) to the vertical. 8.2.6 Judgement method Judgement method shall follow 11 8.2.7 Report The test report shall contain the following particulars. a) Name and type of test apparatus b) Sampling method, shape, quantity, dimensions, symbol, of test piece ¢) Tost conditions 1) Conditions for epray of acid rain (temperature, pH) 2) Conditions for drying (temperature, relative humidity) 3) Conditions for wetting (temperature, relative humidity) 4) Duration of cyelie test ch) e) Result of judgement 9 Corrodkote corrosion test method 9.1 Summary Apply corrodkote slurry to the one side surface of a test piece, dry it, allow it to stand in a humidity chamber, and check the corrosion resistance of metallic coatings. 9.2 Employed chemicals and its preparation 2) Copper nitrate solution Dissolve 2.5 g of copper nitrate in pure water, and dilute it to 500 ml. 24 18502 : 1999 b) Iron (IIT) chloride hydrate solution Dissolve 2.5 g of iron (Iil) chloride hexshydrate specified in JIS K 8142 in pure water, and dilute it to 500 ml. ‘This solution must not be used when 2 weeks or longer has elapsed after preparation, ¢) Ammonium ehloride solution Dissolve 50 g of ammonium chloride specified in JIS K 8116in pure water, and dilute it to 500 ml. 9.3 Preparation of corrodkote slurry Mix 7 ml of copper nitrate solution {9.2 a)], 38 ml of iron{l[1) chloride hydrate solution [9.2 by], and 10 ml of ammonium chloride solution [9.2 e)]. Add 30 g of Kaolin clay, and agitate them sufficiently with a glass rod until they become uniform, Prepare this corrodkote slurry when it is about to be used. 9.4 Apparatus The apparatus employed for this test shall be composed of, o humidity chamber, holder of test piece, heating device for the chamber, generator of humidity, and its control device, and they shail satisty the following requirements, 2) ‘The material of the apparatus shall not influence the corrocivencss of = test piece. b) The wator drops formed on the ceiling of the humidity chamber or test-piece holder chall not fall on the test piece. ©) The exposure zone, on Which a test piece is placed, of the humidity chamber shall be kept at 38 +2 °C temperature and 80 to 90 % relative humidity. During the test, condensed water shall not take place on the test piece. Remarks: When stirring is needed in the chamber, install a fan for stirring so as to allow wind to circulate crossing on water surface, 9.5 Procedures 2) Applying of corrodkote slurry Apply sufficiently the corrodkote slurry (9.8) with a brush on the target surface for evaluation of a test piece propared at 9.3 jn a manner to draw a circle, Then, spread slightly the slurry to one direction with moving of a brush so as to apply the slurry uniformly and smoothly), and allow it to stand for one hour to dry in the atmosphere of 20 + 5 °C temperature and 50 % or less relative humidity. Note (%) The thickness of corrodkote slurry is principally 0.08 mm to 0.2 mm. b) Exposure in humidity chamber Place the dried test piece a) in the humidity chamber immediately, expose it considering 16 h to be one cycle. When carrying out repeatedly continuous tests, at each time, remove the corredkote slurry according to 9.6, apply a new corrodkote slurry to expose. Moreover, during the test, the following requirements must be satisfied. 1) Test pieces shall not come into contact with each other. 2) The material for test-piece holder shall be non-metallic one. 3) The test pieces shall not come into contact with other objects than the test- piece holder. 25 H 8502 : 1989 9.6 Treatment after exposure After exposure, immediately take out carefully the tes: piece, wesh out the corrodkote slurry in running water using @ claen soft cloth or sponge, and dry it by taking off water with a clean soft sbeerbing cloth or paper. In the case of the test piece with iron substrate, in order to reappear the Corrosive defect(""), expose the test piece for another 2 hours in the humidity chamber(') after washing, and then take it out. Notes () Corrosive defects mean rust, blister, rack, which bas reached the substrate, and a stain on the surface is excluded, 04) During the reappearance of corrosive defect, 100 % relative humidity in the chamber is permissible. 9.7 Judgement method Judgement method shall follow Annex 4. 98 Report The test report shall contain the following particulars. a) Name and type of test apparetus >) Sampling method, shape, quantity, dimensions, symbol of test piece ¢) Test conditions 1) Temperature 2) Relative humidity d) Duration of test (h) e) Result of judgement 10 Pollutioning gas corrosion test method 10.1 Sulfur dioxide gas test method 10.1.1 Summary Employ a pollutioning gas corrosion tester, and check the corrosion resistance of metallic coatings by exposing a test piece to the atmospheric condition of sulfur dioxide gas. 10.1.2 Gas for test The sulfar dioxide ges for test shall be 100 % liquefied gas in a bomb or the diluted one in a bomb. 10.1.3 Apparatus The apparatus for this test is composed of, the test vessel equipped with control device of temperature and humidity and with test-piece holder, gas bomb of sulfur dioxide gas, quantitatively diluting device of sulfur dioxide, control device of concentration, exhaust system, and so on, and they shalll satisfy the following requirements. a) The material of apparatus shall not be that which gives influence on the corrosiveness of the sulfur dioxide gas, and which is corroded by the gas b) The drops formed on the ceiling of the test vessel shall not fall on other test pieces. ©) Test vessel shall be equipped with an air circulator by which the air is agitated near the test piece at a wind speed of 0.1 to 0.5 mis. 26 ‘H 8502 ; 1999 4) The concentration of sulfur dioxide shall be controlled within the range of 0.1 ta 100 ppm (volumetric ratio). ¢) When the volume of test vessel is smaller than 300 J, atmospheric gas (cirt sulfur dioxide gas) shall be sent at 2 rate of at least 1/15 its volume per minute. When the volume is 300 ! or larger, sending of gas shell follow the agreement between the parties concerned with delivery. f) During testing, there shall be no leakage of sulfur dioxide gas from the apparatus. 10.1.4 Holding of test piece During the test, the location and holding method of a test piece in the test vessel shall conform to the following conditions("), a) Place vertically the target surface for evaluation of a test picee. However, the test piece may be placed at a different angle according to the agreement between the parties concerned with delivery. b) Test pieces shall not come into contact with other objects than the test frame. ‘Test pieces shall not come into contact with each other, and they are at least 20 mm. apart from one another. c) Keep test pisces at least 100 mm apart from the wall of test vessel, and at least 200 mm from the ceiling. a) Arrange the test. pieces in the vessel so that they do not shield one another from the flow of gas. e) The corrosion product of a test piece shall not fall on other test pieces. f) The pressed stamp for recognition or mounting hole shall be faced downwards. 10.1.5 Procedures When tho temperature and humidity in the test vessel have reached the specified condition, put the test-pieee holder with test pieces into the test vessel, and cover it, Introduce sulfur dioxide gas, and control the concentration of the gas to obtain the specified concentration. In this case, it is preferable to control the concentration of sulfur dioxide gas by means of an automatic controlier('*]. When there is no automatie controller, confirm the concentration of the gas in the vessel by, for example, @ detecting tuba, and contro} the flow rate of sulfur dioxide gas and of air in order to obtain the specified value. Note (¥) This shall be the one which has been calibrated by ultraviolet fluorescent- type detector specified in JIS B 7952 2) Test conditions Test conditions shall be as shown in Table 6 Standard concentration of sulfur dioxide gas follows Table 6, and the select of concentration is left to the agreement between the parties concerned with delivery. ‘The test condition shall be confirmed at least once a day. If regular running of the apparatus is possible for several days, the confirmation onee a few days is permissible b) Duration of test The duration of test shall be subjected to the agreement between the parties concerned with delivery. Recommended durations are 4h, 8h, 16h, 24h, 48h, 96 b, and 240 h. The test shall be continued without interruption or opening the test vessel throughout the test duration, aT H 8502: 1999 ¢) Treatment after test At the end of the test, exhaust the sulfur dioxide gas in the veesel, Open the cover of the test voesel so that the drops of the solution do not fall on the test piece, take out the test piece Jost the condition on the target surface for evaluation is damaged, remove the corrosion product found at other Places than corroded point using a brush or sponge, and dry it. To remove forrosion product, employ such mechanical measures as brushing, ultrasonic radiation, water spraying, or chemical measures as shown in Attached Tsble 1 fable 6 Test conditions for sulfur dioxide gas test method tems [condition Ai | Condition A2| Condition AS Concentration of sulfur dioxide gas 4 ppm (by volumetric ratio) nese ae wae [Temperature

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