BRITISH STANDARD BS EN

1388-2:1996

Materials and articles

in contact with
foodstuffs —
Silicate surfaces —
Part 2: Determination of the release of
lead and cadmium from silicate
surfaces other than ceramic ware

The European Standard EN 1388-2:1995 has the status of a

British Standard

ICS 67.040; 81.040.30

12&23<,1*:,7+287%6,3(50,66,21(;&(37$63(50,77('%<&23<5,*+7/$:
BS EN 1388-2:1996
This British Standard, having
been prepared under the
direction of the Consumer
Products and Services Sector
Board, was published under
the authority of the
Standards Board and comes
into effect on 15 July 1996
© BSI 1 July 2004
The following BSI references
relate to the work on this
standard:
Committee reference CW/47
Draft for comment 94/304312 DC
ISBN 0 580 25501 8
Committees responsible for this
British Standard
The preparation of this British Standard was entrusted to Technical
Committee CW/47, Materials in contact with food, upon which the following
bodies were represented:
Aluminium Federation
Association of Metropolitan Authorities
Association of Public Analysts
British Adhesives and Sealants Association
British Ceramic Gift and Tableware Manufacturers’ Association
British Coatings Federation Ltd.
British Glass Manufacturers’ Confederation
British Importers’ Confederation
British Plastics Federation
British Rubber Manufacturers’ Association Ltd.
British Retail Consortium
British Stainless Steel Association
Catering Utensils Association
Cooperative Union
Cutlery and Allied Trades Research Association
Department of Trade and Industry (Consumer Safety Unit, CA Division)
Department of Trade and Industry (Laboratory of the Government Chemist)
Hotel and Catering International Management Association
Institute of Trading Standards Administration
ITRI Ltd.
Leatherhead Food Research Association
METCOM
Ministry of Agriculture, Fisheries and Food
Packaging and Industrial Films Association
Paper Federation of Great Britain
Pira International
Royal Society of Chemistry
Vitreous Enamel Development Council
The following body was also represented in the drafting of the standard,
through subcommittees and panels:
British Ceramic Research Ltd.
Amendments issued since publication
Amd. No. Date Comments
 BS EN 1388-2:1996

Contents
Page
Committees responsible Inside front cover
National foreword ii
Foreword 2
Text of EN 1388-2 3
List of references 14

© BSI 1 July 2004 i

BS EN 1388-2:1996

National foreword

This Part of BS EN 1388 has been prepared by Technical Committee CW/47 and
is the English language version of EN 1388-2:1995, Materials and articles in
contact with foodstuffs — Silicate surfaces — Part 2: Determination of the release
of lead and cadmium from silicate surfaces other than ceramic ware, published by
the European Committee for Standardization (CEN).
BS 6748:1986, which specifies limits for the release of lead and cadmium from
glassware, glass ceramic ware and vitreous enamel ware, remains current
because it is referred to in UK regulations.
EN 1388-2 was produced as a result of international discussions in which the
United Kingdom took an active part.

Cross-references
Publication referred to Corresponding British Standard
BS 700 Graduated pipettes
ISO 835-1:1981 Part 1:1982 Specification for general requirements
ISO 835-2:1981 Part 2:1982 Specification for pipettes for which no
waiting time is specified
ISO 1042:1983 BS 1792:1982 Specification for one-mark volumetric
flasks
BS 1344 Methods of testing vitreous enamel finishes
ISO 2723:1973 Part 12:1975 Production of specimens for testing
coatings on sheet steel
ISO 2724:1973 Part 13:1975 Production of specimens for testing
coatings on cast iron
ISO 3585:1991 BS 2598 Glass plant, pipeline and fittings
Part 1:1991 Specification for properties of borosilicate
glass 3.3
ISO 3696:1987 BS EN ISO 3696:1995 Water for analytical laboratory
use — Specification and test methods
ISO 4788:1980 BS 604:1982 Specification for graduated glass
measuring cylinders

This publication does not purport to include all the necessary provisions of a
contract. Users are responsible for its correct application.
Compliance with a British Standard does not of itself confer immunity
from legal obligations.

Summary of pages
This document comprises a front cover, an inside front cover, pages i and ii,
the EN title page, pages 2 to 14, an inside back cover and a back cover.
The BSI copyright notice displayed in this document indicates when the
document was last issued.

ii © BSI 1 July 2004

EUROPEAN STANDARD EN 1388-2
NORME EUROPÉENNE
EUROPÄISCHE NORM October 1995

ICS 67.040; 81.040.30

Descriptors: Food industry, human nutrition, food, food-container contact, silicates, lead, cadmium, emission, ceramics, tests, chemical
analysis, samples

English version

Materials and articles in contact with foodstuffs —

Silicate surfaces —
Part 2: Determination of the release of lead and cadmium
from silicate surfaces other than ceramic ware

Matériaux et articles en contact avec les denrées
alimentaires —
Surfaces silicatées —
Partie 2: Détermination de l’émission de plomb et de
cadmium par les surfaces silicatées autre que les
articles en céramique
Werkstoffe und Gegenstände in Kontakt mit
Lebensmitteln —
Silicatische Oberflächen —
Teil 2: Bestimmung der Abgabe von Blei und
Cadmium aus silicatischen Oberflächen
ausgenommen keramischen Gegenständen

This European Standard was approved by CEN on 1995-10-04. CEN members

are bound to comply with the CEN/CENELEC Internal Regulations which
stipulate the conditions for giving this European Standard the status of a
national standard without any alteration.
Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any
CEN member.
This European Standard exists in three official versions (English, French,
German). A version in any other language made by translation under the
responsibility of a CEN member into its own language and notified to the
Central Secretariat has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Denmark,
Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg,
Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United
Kingdom.

CEN
European Committee for Standardization
Comité Européen de Normalisation
Europäisches Komitee für Normung

Central Secretariat: rue de Stassart 36, B-1050 Brussels

© 1995 All rights of reproduction and communication in any form and by any means reserved in all
countries to CEN and its members.
Ref. No. EN 1388-2:1995 E
EN 1388-2:1996

Foreword Contents
This European Standard has been prepared by a Page
Working Group (3) of CEN/TC 194, Utensils in Foreword 2
contact with food, of which the Secretariat is held by
Introduction 3
BSI, as one of two standards for release of lead and
cadmium. A further Part of this European Standard 1 Scope 3
will be prepared with the following title: 2 Normative references 3
EN 1388-1, Materials and articles in contact with 3 Definitions 4
foodstuffs — Silicate surfaces — 4 Principle 6
Part 1: Determination of the release of lead and 5 Reagents 6
cadmium from ceramic ware.
6 Apparatus 7
The text of the draft was submitted to the unique 7 Samples 8
acceptance procedure and was approved by CEN as 8 Preparation of samples 8
a European Standard.
9 Procedure 9
This European Standard shall be given the status of 10 Expression of results 11
a national standard, either by publication of an
identical text or by endorsement, at the latest by 11 Test report 12
April 1996, and conflicting national standards shall Annex A (informative) Bibliography 13
be withdrawn at the latest by April 1996.
This European Standard has been prepared under a
mandate given to CEN by the European
Commission and the European Free Trade
Association, and supports essential requirements of
the EC Directive(s).
In accordance with the CEN/CENELEC Internal
Regulations, the following countries are bound to
implement this European Standard: Austria,
Belgium, Denmark, Finland, France, Germany,
Greece, Iceland, Ireland, Italy, Luxembourg,
Netherlands, Norway, Portugal, Spain, Sweden,
Switzerland and United Kingdom.

2 © BSI 1 July 2004

 EN 1388-2:1996

Introduction
The problem of lead and cadmium release from ceramic ware requires effective means of control to ensure
the protection of the population against possible hazards arising from the use of improperly formulated,
applied and fired glazes and decorations on the food contact surfaces of ceramic ware used for the
preparation, serving and storage of foodstuffs.
NOTE Articles which are highly coloured or decorated on their food contact surfaces or which have a high surface area/volume ratio
are more likely than other articles to release lead and/or cadmium.
The Council of the European Communities has adopted a specific Directive for the measurement of possible
migration of lead and cadmium from ceramic articles which, in their finished state, are intended to come
into contact with foodstuffs, or which are in contact with foodstuffs, and are intended for that purpose.
In Directive 84/500/EEC, Annex I describes “Basic rules for determining the migration of lead and
cadmium”. In Annex II, atomic absorption spectroscopy is prescribed as the method of analysis.
Technical Committee 194 of the European Committee for Standardization has undertaken the task of
setting up European Standards for methods of test for silicate surfaces on the basis of the Directive and to
harmonize at the same time existing national standards. International Standard ISO 7086-1 was
considered in this work.
Part 1 of this European Standard specifies the method of test for the determination of lead and cadmium
released from ceramic surfaces. Because existing national standards have also established that this
method of test is applicable to glass, glass ceramic and vitreous enamel silicate surfaces, this Part of the
European Standard has been prepared also to specify tests applicable to such silicate surfaces.
An existing national standard includes a test for surfaces with which the mouth is intended to come into
contact, and this European Standard also includes a method of test appropriate to such silicate surfaces.
For homogeneous, i.e. undecorated or unglazed, glassware, such as that made from soda-lime-silicate glass
or borosilicate glass, and glass ceramic ware intended to come into contact with foodstuffs, no raw materials
containing lead and cadmium are used in the manufacture. An exception is crystal glass as defined in the
EC Directive for Crystal Glass (69/493 EEC). From soda-lime-silicate glass and borosilicate glass any
release of lead and cadmium can only result from impurities and normally will be below the current
detection limits of flame atomic absorption spectrometry (FAAS) for lead and cadmium. For uncoloured,
undecorated or unglazed glass articles made from mass-produced soda-lime-silicate glass or borosilicate
glass, it is not essential to test according to this European Standard.

1 Scope
This European Standard specifies a reference method for determining the release of lead and cadmium
from articles with silicate surfaces of glass, glass ceramic and vitreous enamel which are intended to come
into contact with foodstuffs. This European Standard also applies to vitreous enamelled containers and to
parts of equipment intended for industrial use with foodstuffs.
This European Standard specifies also a method of test for determining the release of lead and/or cadmium
from a drinking rim; the drinking rim of ceramic articles can also be tested according to this method.

2 Normative references
This European Standard incorporates by dated or undated reference, provisions from other publications.
These normative references are cited at the appropriate places in the text and the publications are listed
hereafter. For dated references, subsequent amendments to or revisions of any of these publications apply
to this European Standard only when incorporated in it by amendment or revision. For undated references
the latest edition of the publication referred to applies.
ISO 385-1, Laboratory glassware — Burettes — Part 1: General requirements.
ISO 385-2, Laboratory glassware — Burettes — Part 2: Burettes for which no waiting time is specified.
ISO 648, Laboratory glassware — One-mark pipettes.
ISO 835-1, Laboratory glassware — Graduated pipettes — Part 1: General requirements.
ISO 835-2, Laboratory glassware — Graduated pipettes — Part 2: Pipettes for which no waiting time is
specified.

© BSI 1 July 2004 3

EN 1388-2:1996

ISO 835-3, Laboratory glassware — Graduated pipettes — Part 3: Pipettes for which a waiting time of 15 s
is specified.
ISO 1042, Laboratory glassware — One-mark volumetric flasks.
ISO 2723, Vitreous and porcelain enamels for sheet steel — Production of specimens for testing.
ISO 2724, Vitreous and porcelain enamels for cast iron — Production of specimens for testing.
ISO 3585, Borosilicate glass 3.3 — Properties.
ISO 3696, Water for analytical laboratory use — Specifications and test methods.
ISO 4788, Laboratory glassware — Graduated measuring cylinders.

3 Definitions
For the purposes of this standard, the following definitions apply.
3.1
foodware
articles which are intended to be used for the preparation, cooking, serving and storage of food or drinks,
including tanks and vessels
3.2
flatware
articles which cannot be filled and articles which can be filled, the internal depth of which, measured from
the lowest point to the horizontal plane passing through the upper rim, does not exceed 25 mm. Flatware
also includes the test specimens for testing vitreous enamelled equipment, containers and water heaters
3.3
holloware
articles which can be filled, the internal depth of which, measured from the horizontal plane passing
through the lowest point of the upper rim, exceeds 25 mm, excepting holloware items having a filling
volume exceeding 3 l, which are classed as storage vessels
3.4
cooking ware
foodware, specifically intended to be heated in the course of preparation of food and drinks by means such
as steaming, boiling, braising, stewing, roasting, baking or by microwaves
3.5
drinking rim
20 mm wide section of the external surface of a drinking vessel, measured downwards from the upper edge
along the wall of the vessel
3.6
ceramic ware
ceramic articles which are intended to come into contact with foodstuffs; for example, foodware made of
china, porcelain and earthenware, whether glazed or not
3.7
glass
inorganic material produced by the complete fusion of raw materials at high temperature into a
homogeneous liquid which is then cooled to a rigid condition, essentially without crystallization
3.8
glass ceramic
inorganic material produced by the complete fusion of raw materials at high temperature into a
homogeneous liquid which is then cooled to a rigid condition with a certain degree of crystallization

4 © BSI 1 July 2004

 EN 1388-2:1996

3.9
borosilicate glass
glass containing a sufficient amount of boric oxide to influence its properties, in particular producing high
chemical and thermal resistance1)
NOTE In borosilicate glass, lead and cadmium are present only in trace amounts as adventitious impurities. The release of these
elements will be below the limits of detection of the method of test specified in this European Standard.

3.10
soda-lime-silicate glass
glass in which the main constituents are normally sodium oxide, calcium oxide, and silica1)
NOTE In soda-lime-silicate glass, lead and cadmium are present only in trace amounts as adventitious impurities. The release of
these elements will be below the limits of detection of the method of test specified in this European Standard.

3.11
vitreous enamel
substantially vitreous inorganic coating bonded to metal by fusion at a temperature above 500 °C
3.12
vitreous enamelled ware
metallic articles coated with vitreous enamel
3.13
storage vessel; tank
article having a capacity of 3 l or more
3.14
test solution
solution used to extract lead and cadmium from silicate surfaces
3.15
extract solution
aqueous acidic solution obtained from the exposure of a silicate surface to the test solution
3.16
sample measuring solution
solution used for measuring the concentration of the analyte, and may be the extract solution or an
appropriately diluted extract solution
3.17
analyte
element or constituent to be determined
3.18
stock solution
solution of appropriate composition containing the analyte, in a known high concentration
3.19
standard solution
solution containing the analyte, in known concentration suitable for the preparation of calibration
solutions
3.20
set of calibration solutions
set of simple or synthetic calibration solutions having different analyte concentrations. The zero number
is, in principle, the solution having zero concentration of the analyte

1)For glass and glass ceramic, it is usual to state the content of chemical elements as oxides, irrespective of the actual existing
type of compound.

© BSI 1 July 2004 5

EN 1388-2:1996

3.21
atomic absorption spectrometry (AAS)
method for determining the concentration of chemical elements based on the measurement of the
absorption of characteristic electromagnetic radiation by atoms in the vapour phase
3.22
optimum working range
range of concentrations of an analyte in solution over which the relationship between absorption and
concentration is linear, or sufficiently closely approximates to linearity so that any divergence at the
prescribed limit of concentration does not discernably affect any analytical determination
3.23
direct method of determination; analytical-curve technique
method consisting of inserting the measure obtained in the analytical function, and deducing from it the
concentration of the analyte
3.24
analytical function; calibration function
function relating the value of the concentration to the characteristic value obtained from the set of
calibration solutions. The graph of this function is called the “analytical curve (calibration graph)”
3.25
bracketing technique
method consisting of bracketing the measured absorbance or intensity of the sample solution between two
measurements made on calibration solutions of neighbouring concentrations
3.26
reference surface area; SR
area intended to come into contact with foodstuffs

4 Principle
Silicate surfaces are placed in contact with 40 ml/l acetic acid solution for 24 h at 22 °C to extract lead
and/or cadmium, if present, from the surfaces of the articles or test specimens.
The proportions of extracted lead and cadmium are determined by flame atomic absorption spectrometry
(FAAS).

5 Reagents
During the determination, use only reagents of recognized analytical grade and only distilled water, or
water of equivalent purity (grade 3 water complying with the requirements of ISO 3696).
It is permissible to prepare proportionately greater quantities of test solution and analytical solutions than
specified in the following clauses.
5.1 Acetic acid (CH3COOH), glacial, density Ô = 1,05 g/ml.
Store this reagent in darkness or in dark coloured bottles.
5.2 Test solution
Acetic acid, 40 ml/l solution.
Add to 500 ml of water by means of a graduated measuring cylinder (6.7) 40 ml ± 1 ml of glacial acetic
acid (5.1) and make up to 1 l. Prepare the test solution freshly prior to use in sufficient quantity to enable
the whole of any group of tests and analyses to be completed.

6 © BSI 1 July 2004

 EN 1388-2:1996

5.3 Analytical stock solutions

5.3.1 Stock lead solution (1 g of lead per litre)
Prepare an analytical stock solution containing 1 000 mg ± 1 mg of lead per litre in the test solution (5.2).
Alternatively, appropriate commercially available lead solutions may be used, provided that the
concentrations of such solutions are known to an equivalent accuracy.
1 ml of this stock solution ç 1 mg of lead.
5.3.2 Stock cadmium solution (1 g of cadmium per litre)
Prepare an analytical stock solution containing 1 000 mg ± 1 mg of cadmium per litre in the test
solution (5.2).
Alternatively, appropriate commercially available cadmium solutions may be used, provided that the
concentrations of such solutions are known to an equivalent accuracy.
1 ml of this stock solution ç1 mg of cadmium.
5.4 Analytical standard solutions
5.4.1 Standard lead solution (0,1 g of lead per litre)
By means of a one-mark pipette (6.4), transfer 10 ml of the stock lead solution (5.3.1) to a 100 ml one-mark
volumetric flask (6.3), make up to the mark with the test solution (5.2) and mix well. Renew this solution
every four weeks.
1 ml of this standard solution ç 0,01 mg of lead.
From this solution, by dilution with test solution (5.2), freshly prepare a suitable range of calibration
solutions (see 9.3.1), using the burette (6.5).
5.4.2 Standard cadmium solution (0,01 g of cadmium per litre)
By means of a one-mark pipette (6.4), transfer 10 ml of the stock cadmium solution (5.3.2) into a 1 000 ml
one-mark volumetric flask (6.3), make up to the mark with the test solution (5.2) and mix well. Renew this
solution every four weeks.
1 ml of this standard solution ç 0,01 mg of cadmium.
From this solution, by dilution with test solution (5.2), freshly prepare a suitable range of calibration
solutions (see 9.3.1), using the burette (6.5).
5.5 Paraffin wax, high melting point.
NOTE Suitable wax is specified in the European Pharmacopoeia.

5.6 Washing agent, commercially available non-acidic manual dishwashing detergent in common dilution.
5.7 Silicone sealant, in a tube or dispenser, enabling a ribbon of silicone sealant approximately 6 mm
diameter to be formed.

6 Apparatus
Use only laboratory glassware, complying with the requirements of appropriate International or European
Standards, where they exist, and made of borosilicate glass as specified in ISO 3585.
6.1 Flame atomic absorption spectrometer, with a detection limit equal to or better than 0,1 mg/l
Pb (in 40 ml/l acetic acid) and 0,01 mg/l Cd (in 40 ml/l acetic acid) where the detection limit is the
concentration of analyte for which the absorbance is three times the standard deviation of the background
noise of the system.
NOTE The background noise of the system may be derived either from a series of absorbance measurements made on a solution
which contains lead, or cadmium, at a concentration distinctly detectable above, but close to, the composition of solvent blanks, or
directly by suitable flame atomic absorption spectrometers measuring the absorbance of a solvent blank.

© BSI 1 July 2004 7

EN 1388-2:1996

6.2 Line sources for lead and cadmium

6.3 One-mark volumetric flasks, capacities 100 ml and 1 000 ml, complying with the requirements
specified for class B or better one-mark volumetric flasks in ISO 1042. Other sizes of one-mark volumetric
flask may also be required.
6.4 One-mark pipettes, capacities 10 ml and 100 ml, complying with the requirements specified for class B
or better one-mark pipettes in ISO 648. Other sizes of one-mark pipette may also be required.
6.5 Burette, capacity 25 ml, graduated in divisions of 0,05 ml, complying with the requirements specified
for class B or better burettes in ISO 385-2.
6.6 Covers, for the articles under test, e.g. plates, watch-glasses, petri dishes of different sizes, and opaque
if no darkroom is available.
6.7 Graduated measuring cylinders, capacities 50 ml and 500 ml, complying with the requirements
specified in ISO 4788. Other sizes of graduated measuring cylinder may also be required.
6.8 Straight edge, strip of metal, or other material, having at least one clearly identifiable edge, cut straight
and which does not deviate from straightness by the equivalent of more than 1 mm in 1 m. The straight
edge may incorporate a spirit level.
6.9 Depth-gauge or rule, calibrated in millimetres, to be used in conjunction with the straight edge (6.8).

7 Samples
The laboratory sample consists of four similar single articles, identical in material, shape, dimensions,
decoration and glaze.
For testing vitreous enamelled tanks and vessels, test specimens prepared according to ISO 2723 or
ISO 2724 are used. These test specimens are tested as flatware.

8 Preparation of samples
8.1 Distinction between flatware and holloware
From a group of identical articles select a single sample and place it on a flat horizontal surface. Place a
straight edge (6.8) on the rim of the article. Where the article has a spout, place the straight edge
horizontally from the lowest point of the spout. Measure the distance between the lowest point in the
interior of the article and the straight edge, h. Articles with h not exceeding 25 mm are deemed to be
flatware, whilst articles with h exceeding 25 mm are deemed to be holloware. If an article is a borderline
case between flatware and holloware, it is classified as flatware.
8.2 Determination of reference surface area; SR for flatware
Invert the sample on graph paper marked in millimetre squares and draw the contour round the rim.
Calculate or measure the area enclosed by the contour and record this as the reference surface area SR in
square decimetres to two decimal places. For circular articles the reference surface area may be calculated
from the diameter of the article. Determine the reference surface area for non-fillable ware in the same
way, measuring the uncovered surface to be extracted [8.4a) or 8.4b)] only.
NOTE This method of measurement gives some compensation for the effect of curvature of the articles.

8.3 Cleaning of the samples

Wash the samples briefly in an aqueous solution at 40 °C ± 5 °C containing 1 ml/l of washing agent (5.6).
Rinse the sample thoroughly with tap water, then with distilled water and allow to drain. Then wipe dry
with clean filter paper.
Do not use any sample which shows residual staining.
If an area of the surface of the sample is not intended to come into contact with foodstuffs in normal use,
other than the interior of any lid [see 8.4a) and 8.4b) respectively], cover this area after the initial washing
and drying with a protective coating, which will withstand the effect of the test solution (5.2) and which
will not release any detectable levels of lead and cadmium into the test solution (5.2) during the test
procedure.
Do not handle the surface to be tested after it has been cleaned or prepared, respectively.

8 © BSI 1 July 2004

 EN 1388-2:1996

8.4 Preparation of articles which cannot be filled

Articles which cannot be filled to 6 mm from overflowing as specified in 9.1.2.1 are regarded as non-fillable.
a) Coat these articles carefully on all surfaces except the reference surface (see 8.2) with melted paraffin
wax (5.5) and test as specified in 9.1.2.2a). Or
b) Apply a ribbon of silicone sealant (5.7), 6 mm wide, to the glazed surface of the article around the
whole perimeter. Inspect the ribbon and ensure that the ribbon of sealant is complete and is in intimate
contact with the glazed surface around the whole perimeter. Check that the height of the sealant ribbon
is approximately 4 mm and is sufficient to allow an adequate bulk of test solution (5.2) to be added. Set
the article aside overnight for the silicone sealant to cure. Test as specified in 9.1.2.2b).
8.5 Drinking rim
Determine the region of the drinking rim by inverting the article on a smooth horizontal surface and
rotating it against a felt-tipped pen fixed at a height corresponding to the boundary of the drinking rim
(see 3.5).
Cover carefully the portion of the external surface of the article that is not to be tested, with melted paraffin
wax (8.4). Cover any handle present in the drinking rim region to be tested, in the same way. It is
permissible for the drinking rim to be cut off and tested separately.

9 Procedure
When lead alone is to be determined, carry out the extraction under normal laboratory lighting conditions.
When cadmium is to be determined, alone or together with lead, carry out the extraction in the dark.
9.1 Extraction
9.1.1 Test temperature
Condition the sample or test specimen and the test solution (5.2) to 22 °C ± 2 °C, prior to 9.1.2.
9.1.2 Contact between the samples and the test solution
9.1.2.1 Fillable samples
Place the sample on a flat, horizontal surface and fill it, by means of a graduated measuring cylinder (6.7),
with the test solution (5.2) to a level, not more than 1 mm below the overflow point. In the case of samples
having a flat or sloping rim, ensure that the distance between the surface of the liquid and the overflow
point does not exceed 6 mm, measured along the sloping rim. In the case of flatware, determine the volume
V of the test solution to an accuracy of 2 % after the extraction (i.e. filling volume). Cover and keep in the
dark, if cadmium is to be determined.
9.1.2.2 Non-fillable samples
a) When prepared according to 8.4a):
Place the samples in a suitable vessel, e.g. a borosilicate glass vessel of suitable size, and add by means
of a graduated measuring cylinder (6.7) the test solution (5.2) to cover the samples completely. Record
the volume V of test solution used (i.e. contact volume) to an accuracy of 2 %. Cover the vessel with a
suitable cover (6.6) and, if cadmium is to be determined, place it in the dark.
b) When prepared according to 8.4b):
Place the article, with sealant, on a flat, horizontal surface, and from a graduated measuring
cylinder (6.7) add the test solution (5.2). Record the volume V of test solution used (i.e. contact volume)
to an accuracy of 2 %. Cover the article and test solution with a suitable cover (6.6) and, if cadmium is to
be determined, place it in the dark.
NOTE Standard articles may be exposed to test solution (5.2) when fitted into a silicone rubber mould in which the articles fit,
forming a watertight seal and so constructed as to encroach 6 mm from the rim of the article and forming a depth of not more
than 7 mm.

9.1.2.3 Lids of receptacles

If an article is provided with a lid, test also the inner surface of the lid on its own.

© BSI 1 July 2004 9

EN 1388-2:1996

9.1.2.4 Drinking rim

Place the prepared sample (8.5) with the rim downwards, in a flat-bottomed vessel. Cover the rim
completely with the test solution.
If the rim has been cut off, place the separated rim in a flat-bottomed vessel not less than 25 mm in height
(e.g. petri dish or beaker) and cover completely with the test solution (5.2). Ensure that the size of the
vessel and the height of the covering test solution are such that the volume of test solution is kept to a
minimum; determine the volume of test solution used to an accuracy of 2 %.
9.1.3 Duration of extraction
Maintain the filled, or immersed, samples at 22 °C ± 2 °C for 24 h ± 30 min under conditions which
preclude evaporative losses.
NOTE Plastic trays with close-fitting lids are suitable containers to prevent evaporative losses from the test vessels. Particular care
should be taken to ensure that evaporative losses of test solution (5.2) are minimized. If necessary, such losses can be checked for by
weighing.

9.2 Sampling the extract solution for analysis (sample measuring solution)
Homogenize the extract solution, by stirring or other method, without loss of solution or abrasion of the
surface being tested.
NOTE A method of homogenizing the extract solution is to remove a quantity by pipette and allow it to run back into, or onto, the
sample several times, avoiding dilution or evaporation loss in the process.
Transfer the extract solution or a part of it into a suitable vessel. This is the sample measuring solution.
Perform the analysis as quickly as possible.
9.3 Calibration and determination
9.3.1 Calibration
Set up the flame atomic absorption spectrometer, having regard to the manufacturer’s instructions, using
wave lengths of 217,0 nm for lead determination, and 228,8 nm for cadmium determination, with
appropriate correction for background absorption effects.
NOTE Where appropriate, a wavelength of 283,3 nm may be used for the analytical confirmation of lead.
Aspirate the zero member of the set of the calibration solutions [i.e. the test solution (5.2)] and adjust zero.
Aspirate the set of calibration solutions, prepared by dilution of the standard solutions (5.4) with the test
solution (5.2).
Suggested ranges: 0,2 mg/l Pb to 10,0 mg/l Pb
0,02 mg/l Cd to 0,5 mg/l Cd

Aspirate test solution (5.2) after each calibration solution and record the absorbance values obtained.
9.3.2 Determination
Set up the spectrometer as described before. Aspirate distilled water and then test solution (5.2) and make
sure that the absorbance is zero. Aspirate the sample measuring solutions (9.2), interspersed with test
solution (5.2). Measure the absorbance values of the sample measuring solutions.
If the mass concentration of lead in the sample measuring solution exceeds 10 mg/l, or if the mass
concentration of cadmium exceeds 0,5 mg/l, dilute a suitable aliquot portion of the extract solution with test
solution to give a mass concentration of lead less than 10 mg/l, and a mass concentration of cadmium of less
than 0,5 mg/l, so that the signals are in the optimum working range. Measure each sample measuring
solution at least three times, and use the mean value for calculation.
To increase accuracy, especially when repeated measurement of a calibration solution with a mean metal
concentration indicates minimal drift, employ the bracketing technique (3.25). For this purpose, following
a preliminary test yielding approximate values for the mass concentrations of lead and/or cadmium in the
calibration solutions, use calibration solutions in which the metal ions are present in mass concentrations
as closely as possible above and below those of the sample measuring solution.

10 © BSI 1 July 2004

 EN 1388-2:1996

10 Expression of results
10.1 Bracketing technique
The lead or cadmium concentration, C0, expressed in milligrams per litre of the extract solution, is given
by equation (1):

A 0 – A1
C 0 = [( --------------------
-) × (C 2 – C 1 ) + C 1 ] × d (1)
A 2 – A1

where
A0 is the absorbance corresponding to lead or cadmium in the sample measuring solution;
A1 is the absorbance corresponding to lead or cadmium in the lower bracketing solution;
A2 is the absorbance corresponding to lead or cadmium in the upper bracketing solution;
C1 is the lead or cadmium concentration of the lower bracketing solution, in milligrams per litre;
C2 is the lead or cadmium concentration of the upper bracketing solution, in milligrams per litre;
d is the factor, if the sample extract solution was diluted.

10.2 Calibration curve technique

Read the lead or cadmium concentration, expressed in milligrams per litre of the sample measuring
solution, directly from the calibration curve.
10.3 Calculation of release of lead and cadmium for flatware and non-fillable articles and test
specimen
The lead or cadmium released per unit surface area from flatware and non-fillable articles or test
specimens, R0, is expressed in milligrams per square decimetre and given by equation (2):

C0 × V
R 0 = ------------------
- (2)
SR

where
C0 is the lead or cadmium concentration, expressed in milligrams per litre, of the sample extract
solution, calculated as specified in 10.1 or 10.2;
V is the volume, in litres, of test solution used for the extraction (9.1.2 and 9.1.3 respectively);
SR is the reference surface area (8.2), expressed in square decimetres, of the article.

10.4 Calculation of release of lead and cadmium from the drinking rim
Calculate the release of lead or cadmium from the drinking rim of an article, a0, T, in milligrams per article
by means of equation (3):

a0, T = ¶0 × V (3)

where
¶0 is the mass concentration of lead or cadmium, in milligrams per litre, of the extraction solution,
determined as specified in 9.1.2.4;
V is the volume of the test solution, in litres, used for the extraction.

© BSI 1 July 2004 11

EN 1388-2:1996

10.5 Calculation of release of lead and cadmium for receptacles with lids
The release of lead or cadmium is calculated from both container and total inner surface of the lid,
separately, in milligrams per container and per lid, respectively. Both values shall be added and the sum
shall be related, depending on the case concerned, to the surface area, expressed in milligrams per square
decimetre, or to the volume of the container alone, expressed in milligrams per litre.
10.6 Reporting
For holloware, report the results to the nearest 0,1 mg/l for lead, and to the nearest 0,01 mg/l for cadmium.
For flatware (and non-fillable articles and test specimens), report the results to the nearest 0,1 mg/dm2 for
lead, and to the nearest 0,01 mg/dm2 for cadmium.
For a drinking rim, report the release to the nearest 0,1 mg per rim for lead, and to the nearest 0,01 mg per
rim for cadmium.
If a receptacle with lid was tested, report the sum of the two extract values to the nearest 0,1 mg/l
or 0,1 mg/dm2 respectively for lead, and to the nearest 0,01 mg/l or 0,01 mg/dm2 respectively for cadmium.
10.7 Comparison with permissible limits
An article is deemed to comply with specified permissible limits, when these are not exceeded by the values
of lead and/or cadmium released, determined as specified in this European Standard.
For receptacles with lids, the permissible limit for the lead and/or cadmium release, in milligrams per
square decimetre or in milligrams per litre, is deemed to be the value applying to the container alone.
If the results from an article exceed specified permissible limits, but by not more than 50 %, the article
concerned is nevertheless deemed to comply with the permissible limits if at least three other similar
articles tested under the conditions specified in this European Standard provide results such that the
arithmetic mean of lead, or of cadmium, released from these articles does not exceed the permissible limit
or limits and none of the articles exceeds the permissible limit or limits by more than 50 %.

11 Test report
The test report shall contain:
a) a reference to this European Standard;
b) an identification of the articles or test specimens tested, including their type, origin and designation;
c) the place and date of sampling;
d) the date of receipt and date of testing the sample;
e) for holloware, record the filling volume (9.1.2.1);
for flatware, record both the filling volume and the reference surface area (8.2);
for non-fillable articles (8.4), record the contact volume (9.1.2.2) and the reference surface area (8.2);
f) the number of samples tested;
g) each single result, in accordance with 10.6, and the mean value for each article or test specimen,
expressed as milligrams of lead and/or cadmium per square decimetre of surface area for flatware, or
milligrams of lead and/or cadmium per litre of volume for holloware;
h) for a container with a lid, the sum of the two extract values, i.e. for the container and for the lid, tested
separately;
i) for a drinking rim, the release of lead and/or cadmium in milligrams per article rim.
NOTE Any unusual features noted during the determination should also be reported.

12 © BSI 1 July 2004

 EN 1388-2:1996

Annex A (informative)
Bibliography
[1] EC Council Directive, dated 15 October 1984, on the approximation of the laws of the member states
relating to ceramic articles intended to come into contact with foodstuffs (84/500/EEC). Official Journal of
the European Communities, No. L 277/12.
[2] EC Council Directive, dated 15 December 1969, on the approximation of the laws of the member states
relating to crystal glass (69/493/EEC). Official Journal of the European Communities, No. L 326/36.
[3] ISO 7086-1:1982, Glassware and glass ceramic ware in contact with food — Release of lead and
cadmium — Part 1: Method of test.

© BSI 1 July 2004 13

BS EN 1388-2:1996

List of references

See national foreword.

14 © BSI 1 July 2004

blank
BS EN
1388-2:1996
BSI — British Standards Institution
BSI is the independent national body responsible for preparing
British Standards. It presents the UK view on standards in Europe and at the
international level. It is incorporated by Royal Charter.

Revisions
British Standards are updated by amendment or revision. Users of
British Standards should make sure that they possess the latest amendments or
editions.
It is the constant aim of BSI to improve the quality of our products and services.
We would be grateful if anyone finding an inaccuracy or ambiguity while using
this British Standard would inform the Secretary of the technical committee
responsible, the identity of which can be found on the inside front cover.
Tel: +44 (0)20 8996 9000. Fax: +44 (0)20 8996 7400.
BSI offers members an individual updating service called PLUS which ensures
that subscribers automatically receive the latest editions of standards.

Buying standards
Orders for all BSI, international and foreign standards publications should be
addressed to Customer Services. Tel: +44 (0)20 8996 9001.
Fax: +44 (0)20 8996 7001. Email: orders@bsi-global.com. Standards are also
available from the BSI website at http://www.bsi-global.com.
In response to orders for international standards, it is BSI policy to supply the
BSI implementation of those that have been published as British Standards,
unless otherwise requested.

Information on standards
BSI provides a wide range of information on national, European and
international standards through its Library and its Technical Help to Exporters
Service. Various BSI electronic information services are also available which give
details on all its products and services. Contact the Information Centre.
Tel: +44 (0)20 8996 7111. Fax: +44 (0)20 8996 7048. Email: info@bsi-global.com.
Subscribing members of BSI are kept up to date with standards developments
and receive substantial discounts on the purchase price of standards. For details
of these and other benefits contact Membership Administration.
Tel: +44 (0)20 8996 7002. Fax: +44 (0)20 8996 7001.
Email: membership@bsi-global.com.
Information regarding online access to British Standards via British Standards
Online can be found at http://www.bsi-global.com/bsonline.
Further information about BSI is available on the BSI website at
http://www.bsi-global.com.

Copyright
Copyright subsists in all BSI publications. BSI also holds the copyright, in the
UK, of the publications of the international standardization bodies. Except as
permitted under the Copyright, Designs and Patents Act 1988 no extract may be
reproduced, stored in a retrieval system or transmitted in any form or by any
means – electronic, photocopying, recording or otherwise – without prior written
permission from BSI.
This does not preclude the free use, in the course of implementing the standard,
of necessary details such as symbols, and size, type or grade designations. If these
details are to be used for any other purpose than implementation then the prior
BSI written permission of BSI must be obtained.
389 Chiswick High Road Details and advice can be obtained from the Copyright & Licensing Manager.
London Tel: +44 (0)20 8996 7070. Fax: +44 (0)20 8996 7553.
Email: copyright@bsi-global.com.
W4 4AL