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- Mark Scheme /

Question Answer Marks AO Element Notes Guidance

1 saturated hydrocarbon: 2
(remains) orange / no (colour)
change (1)
unsaturated hydrocarbon:
decolourises bromine / goes
colourless (1)

2 1

3 (reaction of) ethene (1) 2


with steam (1)

4 G 1

5 fermentation 1

6 carbon dioxide (1) 2


water (1)

7 to produce more needed 1


products / to produce products
in greater demand
- Mark Scheme /

Question Answer Marks AO Element Notes Guidance

8(a) one mark each for any 2 of: 2


• breakdown of long chain
hydrocarbons / breakdown
of large hydrocarbons
• to short chain hydrocarbons
/ to small hydrocarbons
• by heat / when heated /
thermal (energy)

8(b) C5H10 1

9 1

10(a) circle around OH attached to 1


middle carbon atom

10(b) C3H6O3 1

11 aqueous bromine (1) 2


decolourises / goes colourless
(1)
- Mark Scheme /

Question Answer Marks AO Element Notes Guidance

12 carbon dioxide (1) 2


water (1)

13 C 1

14(a) ethene 1

14(b) 1 mark each for any two of: 2


• anaerobic / no oxygen
• yeast
• room temperature /
quoted values between 10
°C and 40 °C (inclusive)
• pH neutral / pH 7

15 solvent 1

16 D 1

17 compounds with similar 2


chemical properties (1)
same functional group (1)

18 CnH2n+1COOH 1

19(a) substitution 1
- Mark Scheme /

Question Answer Marks AO Element Notes Guidance

19(b) hydrogen chloride 1

20(a) methyl methanoate 1

20(b) CH2O 1

21(a) M1 same (molecular) formula 2


(1)
M2 different structural formula
(1)

21(b) ethanoic acid 1

22 orange to colourless 1

23 addition 1

24(a)(i) M1 methanoic acid (1) 2 structures/names in (i)


and (ii) can be either
M2 structure of methanoic acid
way round
(1)

24(a)(ii) M3 methanol (1) 2 structures/names in (i)


and (ii) can be either
M4 structure of methanol (1)
way round
- Mark Scheme /

Question Answer Marks AO Element Notes Guidance

25 C2H4 / correct displayed formula 4


(1)
steam (1)
1 mark each for any two of:
catalyst
high temperature / heat
high pressure

26 heat / thermal (decomposition) 2


/ high temperature (1)
catalyst (1)

27 C 1

28(a) C3H8O3 1

28(b) correct structure of ethanol 1

28(c) carbon dioxide (1) 2


water (1)

29 F 1

30 D and E 1

31(a) C9H8O 1
- Mark Scheme /

Question Answer Marks AO Element Notes Guidance

31(b) correct carboxylic acid functional 1


group

32(a) group (1) 2


similar (1)

32(b) 1 mark each for any two of: 2


• carbon monoxide
• water
• carbon

33(a) C 1

33(b) D 1

33(c) C 1

33(d) E 1

34(a) B 1

34(b) C 1

34(c) C 1

34(d) D 1
- Mark Scheme /

Question Answer Marks AO Element Notes Guidance

35 fuel / solvent 1

36 C2H4 / correct displayed formula 4


(1)
steam (1)
1 mark each for any two of:
• catalyst
• high temperature / heat
• high pressure

37 D 1

38 B 1

39(a) CnH2n+1OH 1

39(b) any 2 from: 2


• same or similar chemical
properties or reactions
• (contain) the same
functional group
• (consecutive members)
differ by CH2
• physical properties vary in
predictable manner / show
trends / gradually change
- Mark Scheme /

Question Answer Marks AO Element Notes Guidance

39(c) 2

(1)
propan-2-ol (1)

40(a) ethyl butanoate 1

40(b) ethanol (1) 2


butanoic acid (1)

[Total: 84]

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