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Shubham Javir Fy Chemistry
Shubham Javir Fy Chemistry
REPORT ON
“Ionization, Prepare a Chart
Displaying Phenomena”
SUBMITTED TO THE
SHIVAJI POLYTECHNIC,
ATPADI
IN THE PARTIAL FULFILLMENT OF THE REQUIREMENTS
OF
DIPLOMA IN
COMPUTER TECNOLOGY
SUBMITTED BY
Prof. Ms.Bhagat.A.H
(2023-2024)
SHIVAJI POLYTECHNIC, ATPADI
CERTIFICATE
Date :
Place : Atpadi
Exam Seat No
What Is Ionization Energy?
In more technical terms, we can describe ionization energy as the minimum energy that an
electron in a gaseous atom or ion has to absorb to come out of the influence of the nucleus. It
is also sometimes referred to as ionization potential and is usually an endothermic process.
What we can deduce further is that ionization energy gives us an idea of the reactivity of
chemical compounds. It can also be used to determine the strength of chemical bonds. It is
measured either in units of electronvolts or kJ/mol.
If the nucleus is positively charged, then the electrons are strongly attracted to it.
If an electron lies near or close to the nucleus, then the attraction will be greater than
the one when the electron is further away.
If there are more electrons between the outer level and the nucleus, the attraction
forces are less.
When there are two electrons in the same orbital, they experience some form of
repulsion. Now, this creates disturbances in the attraction of the nucleus. In essence,
ionization energy will be less in paired electrons as they can be removed easily.
The energy of an electron in ‘n’th orbit is calculated by the Bohr model of an atom as,
��=−2�2��4(4���)2ℎ2×�2�2=�×�2�2�/����=−13.6×�2�2��/
����=−2.18×10−18×�2�2�/����
Ionization energy for the removal of an electron from a neutral atom can be calculated by
substituting the orbit number of the electron before transition as ‘n1‘ and the orbit number of
the electron after transition as ‘∞'( infinity) and ‘n2‘ in Bohr’s energy equation.
Also Read:
��1=−�×�2�2��2=−�×�2∞2
Δ�=��2−��1=�×�2(1�2−1∞2)=����������������
Since,
For hydrogen, the first orbit energy is –2.18 × 10– 18 J/atom (or – 1312.3 KJ/mole), and the
ionization energy is + 2.18 × 10–18 J/atom (or + 1312.3 KJ/mole).
The energy needed for the removal of the second electron away from the unipositive ion is
second ionization energy, and so on.
For example:
Because of the enhanced stability of half-filled and fully-filled orbitals, the removal of
electrons from such systems will have relatively higher ionization than other atoms and ions.
For example, helium is more stable due to completely filled s-orbital than hydrogen. So, the
first ionization energy of helium (2372 KJ/mole) is more than that of hydrogen (1312
KJ/mole).
The first ionization energy of nitrogen (1402KJ/mole) is more than that of its near
neighbours, carbon (1086 KJ/mole) and oxygen (1313KJ/mole), because of the higher
stability due to half-filled orbitals. Chromium has half-filled s- and d-orbitals and so has
much more first ionization than titanium.
Also Read:
Whereas, if we move from top to bottom, the ionization energy decreases. This is mainly due
to the presence of more electron shells in the elements as we move down the group.
Additionally, the electrons are placed at a greater distance from the attractive forces of the
nucleus.
Answer:
Ionization energy = E
=ℎ�=ℎ��=6.6×10−34×3×108242×10−9=19.8242×1017=8.18×1015�/����
2. How much energy is required to ionize an H atom if the electron occupies n = 5 orbit?
Compare your answer with the ionization enthalpy of the H atom (energy required to remove
the electron from n =1 orbit).
Answer:
Ionization refers to the electron being out of the atom or to the infinite orbit. The energy of
the electron in the hydrogen atom is given by,
Δ�=2.18×10−18×11{1�12−1�22})�/����
a) For ionization from n = 1 to n = ∞,
Δ�=2.18×10−18×11{112−1∞2})=2.18×10−18×11{1−0}=2.18×10−18�/����
b) For ionization from n = 5 to n = ∞,
Δ�=2.18×10−18×11{152−1∞2})=2.18×10−18×11{125−0}=2.18×10−18×125�/����
The energy required for ionization from the fifth orbit is 25 times lesser than that required for
ionization from the first orbit.
3. Calculate the wavenumber for the shortest wavelength transition in the Balmer series of
atomic hydrogen.
Answer:
The shortest wavelength corresponds to the highest energy. The highest energy is equal to the
ionization energy from that orbit. The balmer series belongs to the second orbit.
Δ�=2.18×10−18×11{122−1∞2})=2.18×10−18{0.25−0}=2.18×10−18×0.25�/����
Ionization energy = E
=ℎ�=ℎ��=6.6×10−34×3×108�=5.7×10−19�/����
Shortest wavelength
=�=19.85.7×10−7�=347��
4. Arrange the following elements, whose electronic configurations are given below, in
increasing order of first ionization energy.
Answer:
The first ionization in the given elements is related to the removal of the s-electron. Higher
the attraction of the nucleus on the electron, difficult it is to remove, and so, the higher the
first ionization energy.
The electron to be removed in [Ar] 3d10 4s2 4p2 is in the 4th orbit, while in others, it is in the
third orbit. As the attraction of the nucleus decreases with increasing orbit number, [Ar]
3d10 4s2 4p2 will have the lowest ionization energy.
Among the rest, [Ne] 3s2 3p3 is more stable due to half-filled orbitals. Hence, this will have
the highest ionization energy.
Among [Ne] 3s2 3p1 and [Ne] 3s2 3p2, the nuclear charge is more in [Ne] 3s2 3p2, increasing
the attraction of the nucleus on the s-electron. So, this will have higher ionization energy than
[Ne] 3s2 3p1.
The order of the increasing order of ionization energy of the atoms is as follows:
[Ar] 3d10 4s2 4p2 < [Ne] 3s2 3p1 < [Ne] 3s2 3p2 < [Ne] 3s2 3p3
5. The correct order of ionization energy for the following species is:
Answer:
All, He, Li+, and H– have two electrons in the first orbital. But the nuclear charge is different
in them. Ionization is directly related to the attraction of the electron by the nucleus. Hence,
the higher the nuclear charge, the higher the ionization energy.
So, the order of nucleus charge = order of ionization energy = H– < He < Li+
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