GROUP 13

Borax
1. If the formula of Borax is Na2B4Ox(OH)y ⋅ zH2O, then x + y + z = _ _ _ _ _ _
2. During the borax bead test with CuSO4, a blue green colour of the bead was observed in oxidising
flame due to the formation of
(A) Cu3 B2
(B) Cu
(C) Cu (BO2 )2
(D) CuO

Boron Halides
3. The Lewis acid character of boron tri halides follows the order:
(A) BCl3 > BF3 > BBr3 > Bl3
(B) Bl3 > BBr3 > BCl3 > BF3
(C) BBr3 > Bl3 > BCl3 > BF3
(D) BF3 > BCl3 > BBr3 > Bl3

COORDINATION COMPOUNDS
Werner’s Theory
4. The volume (in mL) of 0.1 M 𝐴𝑔𝑁𝑂3 required for complete precipitation of chloride ions present in
20 mL of 0.01 M solution of [𝐶𝑟(𝐻2 𝑂)5 𝐶𝑙]𝐶𝑙2 as silver chloride is ____.

Coordination Compounds
5. Which of the following are the example of double salt?
A. 𝐹𝑒𝑆𝑂4 . (𝑁𝐻4 )2 𝑆𝑂4 . 6𝐻2 𝑂
B. 𝐶𝑢𝑆𝑂4 . 4 𝑁𝐻3 . 𝐻2 𝑂
C. 𝐾2 𝑆𝑂4 . 𝐴𝑙2 (𝑆𝑂4 )3 . 24𝐻2 𝑂
D. 𝐹𝑒(𝐶𝑁)2 . 4 𝐾𝐶𝑁
 Choose the correct answer.

A. A and C only
B. A and B only
C. A, B and D only
D. B and D only
6. To inhibit the growth of tumours, identify the compounds used from the following:
A. EDTA
B. Coordination Compounds of Pt
C. D-Penicillamine
D. Cis-Platin

Choose the correct answer from the option given below:

A. B and D Only
B. C and D Only
C. A and B Only
D. A and C Only

Valence Bond Theory

7. The correct order of the number of unpaired electrons in the given complexes is
A. [𝐹𝑒(𝐶𝑁)6 ]3−
B. [𝐹𝑒𝐹6 ]3−
C. [𝐶𝑜𝐹6 ]3−
D. [𝐶𝑟(𝑜𝑥𝑎𝑙𝑎𝑡𝑒)3 ]3−
E. [𝑁𝑖(𝐶𝑂)4 ]
Choose the correct answer from the options given below:

A. E < A < D < C < B

B. E < A < B < D < C
C. A < E, C < B < D
D. A < E < D < C < B
8. Match List I with List II
List-I Complex List-II CFSE (∆0 )
A. [𝐶𝑢(𝑁𝐻3 )6 ]2+ I. -0.6
B. [𝑇𝑖(𝐻2 𝑂)6 ]3+ II. -2.0
C. [𝐹𝑒(𝐶𝑁)6 ]3− III. -1.2
D. [𝑁𝑖𝐹6 ]4− IV. -0.4

Choose the correct answer from the options given below:

A. A(III), B(IV), C(I), D(II)

B. A(I), B(IV), C(II), D(III)
C. A(I), B(II), C(IV), D(III)
D. A(II), B(III), C(I), D(IV)

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9. The correct order of spin only magnetic moments for the following complex ions is
A. [𝐹𝑒(𝐶𝑁)6 ]3− < [𝐶𝑜𝐹6 ]3− < [𝑀𝑛𝐵𝑟4 ]2− < [𝑀𝑛(𝐶𝑁)6 ]3−
B. [𝐶𝑜𝐹6 ]3− < [𝑀𝑛𝐵𝑟4 ]2− < [𝐹𝑒(𝐶𝑁)6 ]3− < [𝑀𝑛(𝐶𝑁)6 ]3−
C. [𝐹𝑒(𝐶𝑁)6 ]3− < [𝑀𝑛(𝐶𝑁)6 ]3− < [𝐶𝑜𝐹6 ]3− − [𝑀𝑛𝐵𝑟4 ]2−
D. [𝑀𝑛𝐵𝑟4 ]2− < [𝐶𝑜𝐹6 ]3− < [𝐹𝑒(𝐶𝑁)6 ]3− < [𝑀𝑛(𝐶𝑁)6 ]3−
10. Cobalt chloride when dissolved in water forms pink colored complex X which has octachedral
geometery. This solution on treating with cone HCl forms deep blue complex, Y which has a Z
geometry. X, Y and Z, respectively, are

A. 𝑋 = [𝐶𝑂(𝐻2 𝑂)6 ]2+ , 𝑌 = [𝐶𝑜𝐶𝑙4 ]2− , 𝑍 =Tetrahedral

B. 𝑋 = [𝐶𝑜(𝐻2 𝑂6 )]2+ , 𝑌 = [𝐶𝑜𝐶𝑙6 ]3− , 𝑍 = Octahedral
C. 𝑋 = [𝐶𝑜(𝐻2 𝑂)6 ]3+ , 𝑌 = [𝐶𝑜𝐶𝑙6 ]3− , 𝑍 = Octahedral
D. 𝑋 = [𝐶𝑜(𝐻2 𝑂)4 𝐶𝑙2 ]+ , 𝑌 = [𝐶𝑜𝐶𝑙4 ]2− , 𝑍 = Tetrahedral
11. 1 L, 0.02M solution of [𝐶𝑜(𝑁𝐻3 )5 𝑆𝑂4 ]𝐵𝑟 is mixed with 1 L, 0.02M solution of [𝐶𝑜(𝑁𝐻3 )5 𝐵𝑟]𝑆𝑂4 .
The resulting solution is divided into two equal parts (X) and treated with excess 𝐴𝑔𝑁𝑂3 solution
and 𝐵𝑎𝐶𝑙2 solution respectively as shown below:
1 L Solution (𝑋)+ 𝐴𝑔𝑁𝑂3 solution (excess) → 𝑌
1 L solution (X) + 𝐵𝑎𝐶𝑙2 solution (excess) → Z
The number of moles of Y and Z respectively are
A. 0.02, 0.02
B. 0.01, 0.01
C. 0.02, 0.01
D. 0.01, 0.02
12. The number of paramagnetic species from the following is
[𝑁𝑖(𝐶𝑁)4 ]2− , [𝑁𝑖(𝐶𝑂)4 ], [𝑁𝑖𝐶𝑙4 ]2−
[𝐹𝑒(𝐶𝑁)6 ]4− , [𝐶𝑢(𝑁𝐻3 )4 ]2+
[𝐹𝑒(𝐶𝑁)6 ]3− 𝑎𝑛𝑑 [𝐹𝑒(𝐻2 𝑂)6 ]2+

Crystal Field Theory

13. The d-electronic configuration of [𝐶𝑜𝐶𝑙4 ]2− in tetrahedral crystal field is 𝑒 𝑚 𝑡2𝑛 . The sum of m and
number of unpaired electrons is
14. The complex with highest magnitude of crystal field splitting energy (∆0 ) is
A. [𝑇𝑖(𝑂𝐻2 )6 ]3+
B. [𝐶𝑟(𝑂𝐻2 )6 ]3+
C. [𝑀𝑛(𝑂𝐻2 )6 ]3+
D. [𝐹𝑒(𝑂𝐻2 )6 ]3+
15. Given below are two statements, one is labelled as assertion A and the other is labelled as Reason R.
assertion 𝐴: [𝐶𝑜𝐶𝑙(𝑁𝐻3 )5 ]2+ absorbs at lower wavelength of light with respect to
[𝐶𝑜(𝑁𝐻3 )5 (𝐻2 𝑂)]3+

Reason R: It is because the wavelength of light absorbed depends on the oxidation state of the
metal ion. In the light of the above statements, choose the correct answer from the options given
below:

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 A. A is false but R is true
B. A is true but R is false
C. Both A and R are true and R is the correct explaination of A
D. Both A and R are true and R is NOT the correct explanation of A
16. Match List-I with List-II.

List-I Complex List-II Crystal Field

splitting energy
(∆0 )

A. [𝑇𝑖(𝐻2 𝑂)6 ]2+ I. -1.2

B. [𝑉(𝐻2 𝑂)6 ]2+ II. -0.6

C. [𝑀𝑛(𝐻2 𝑂)6 ]3+ III. 0

D. [𝐹𝑒(𝐻2 𝑂)6 ]3+ IV. -0.8

Choose the correct answer from the options given below:

A. A-II, B-IV, C-I, D-III

B. A-IV, B-I, C-III, D-II
C. A-IV, B-I, C-II, D-III
D. A-II, B-IV, C-III, D-I
17. Correct order of spin only magnetic moment of the following complex ions is:
(Given At. No. Fe: 26, Co: 27)
A. [𝐹𝑒𝐹6 ]3− > [𝐶𝑜𝐹6 ]3− > [𝐶𝑜(𝐶2 𝑂4 )3 ]3−
B. [𝐶𝑜(𝐶2 𝑂4 )3 ]3− > [𝐶𝑜𝐹6 ]3− > [𝐹𝑒𝐹6 ]3−
C. [𝐹𝑒𝐹6 ]3− > [𝐶𝑜(𝐶2 𝑂4 )3 ]3− > [𝐶𝑜𝐹6 ]3−
D. [𝐶𝑜𝐹6 ]3− > [𝐹𝑒𝐹6 ]3− > [𝐶𝑜(𝐶2 𝑂4 )3 ]3−

Ligands
18. The denticity of the ligand present in the Fehling’s reagent is ____.

Isomerism
19. The total number of stereoisomers for the complex [𝐶𝑟(𝑜𝑥)2 𝐶𝑙𝐵𝑟]3− (where ox = oxalate) is
A. 3
B. 2
C. 4
D. 1

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20. If 𝑁𝑖 2+ is replaced by 𝑝𝑡 2+ in the complex[𝑁𝑖𝐶𝑙2 𝐵𝑟2 ]2− , which of the following properties are
expected to get changed?
A. Geometry
B. Geometrical isomerism
C. Optical isomerism
D. Magnetic properties
A. A and D
B. A, B and C
C. B and C
D. A, B and D
21. Chiral complex from the following is:

Here en = ethylene diamine

A. 𝑐𝑖𝑠 − [𝑃𝑡𝐶𝑙2 (𝑒𝑛)2 ]2+

B. Trans −[𝑃𝑡𝐶𝑙2 (𝑒𝑛)2 ]2+
C. 𝑐𝑖𝑠 − [𝑃𝑡𝐶𝑙2 (𝑁𝐻3 )2 ]
D. Trans −[𝐶𝑜(𝑁𝐻3 )4 𝐶𝑙2 ]+

Metal Carbonyls
22. The sum of bridging carbonyls in 𝑊(𝐶𝑂)6 and 𝑀𝑛2 (𝐶𝑂)10 is ____.

Classification of Elements and Periodicity in Properties

Electronegativity
23. For compound having the formula 𝐺𝑎𝐴𝑙𝐶𝑙4 , the correct option from the following is
A. Ga is coordinated with CI in 𝐺𝑎𝐴𝑙𝐶𝑙4
B. Ga is more electronegative than AI and is present as a cationic part of the salt 𝐺𝑎𝐴𝑙𝐶𝑙4
C. CI forms bond with both AI and Ga in 𝐺𝑎𝐴𝑙𝐶𝑙4
D. Oxidation state of Ga in the salt 𝐺𝑎𝐴𝑙𝐶𝑙4 is +3
24. The correct order of electronegativity for given elements is
A. P > Br > C > At
B. Br > P > At > C
C. Br > C > At > P
D. C > P > At > Br

Ionization Enthalpy
25. For elements B, C, N Li, Be, O and F, the correct order of first ionization enthalpy is
A. 𝐿𝑖 < 𝐵𝑒 < 𝐵 < 𝐶 < 𝑂 < 𝑁 < 𝐹
B. 𝐵 < 𝐿𝑖 < 𝐵𝑒 < 𝐶 < 𝑁 < 𝑂 < 𝐹
C. 𝐿𝑖 < 𝐵𝑒 < 𝐵 < 𝐶 < 𝑁 < 𝑂 < 𝐹
D. 𝐿𝑖 < 𝐵 < 𝐵𝑒 < 𝐶 < 𝑂 < 𝑁 < 𝐹
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26. Given below are two statements:

Statement I: The decrease in first ionization enthalpy from B to Al is much large than that from Al to
Ga.

Statement II: The d orbitals in Ga are completely filled.

In the light of the above statements, choose the most appropriate answer from the options given
below

A. Statement I is incorrect but Statement II is correct.

B. Both the statements I and II are correct
C. Statement I is correct but statement II is incorrect
D. Both the statements I and II are incorrect

Electron Gain Enthalpy

27. For electron gain enthalpies of the elements denoted as ∆𝑒𝑔 𝐻, the incorrect option is:
A. ∆𝑒𝑔 𝐻(𝐶𝑙) < ∆𝑒𝑔 𝐻(𝐹)
B. ∆𝑒𝑔 𝐻(𝑆𝑒) < ∆𝑒𝑔 𝐻(𝑆)
C. ∆𝑒𝑔 𝐻(𝐼) < ∆𝑒𝑔 𝐻(𝐴𝑡)
D. ∆𝑒𝑔 𝐻(𝑇𝑒) < ∆𝑒𝑔 𝐻(𝑃𝑜)

P BLOCK ELEMENTS GROUP 17

Reactions of HALOGENS
28. The correct group of halide ions which can be oxidized by oxygen in acidic medium is
A. 𝐵𝑟 − 𝑎𝑛𝑑 𝐼 −
B. 𝐵𝑟 − only
C. 𝐼 − only
D. 𝐶𝐼 − , 𝐵𝑟 − 𝑎𝑛𝑑 𝐼 − only
29. When 𝐶𝑢2+ ion is treated with KI, a white precipitate, X appears in solution. The solution is titrated
with sodium thiosulphate, the compound Y is formed. X and Y respectivley are
A. 𝑋 = 𝐶𝑢2 𝐼2 , 𝑌 = 𝑁𝑎2 𝑆4 𝑂5
B. 𝑋 = 𝐶𝑢2 𝐼2 , 𝑌 = 𝑁𝑎2 𝑆4 𝑂6
C. 𝑋 = 𝐶𝑢𝐼2 , 𝑌 = 𝑁𝑎2 𝑆4 𝑂3
D. 𝑋 = 𝐶𝑢𝐼2 , 𝑌 = 𝑁𝑎2 𝑆4 𝑂6

Oxyacids of Halogens
30. Sum of oxidation states of bromine in bromic acid and per bromic acid is

Group 18
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 Noble Gases
2−
31. XeF4 reacts with 𝑆𝑏𝐹5 𝑡𝑜 𝑓𝑜𝑟𝑚 [𝑋𝑒𝐹𝑚 ]𝑛+ [𝑆𝑏𝐹𝑦 ] 𝑚 + 𝑛 + 𝑦 + 𝑧 =?.
32. Inert gases have positive electron gain enthalpy. Its correct order is
(A) Xe < Kr < Ne < He
(B) He < Ne < Kr < Xe
(C) He < Xe < Kr < Ne
(D) He < Kr < Xe < Ne
Ans. C

33. The difference between electron gain enthalpies will be maximum between :
(A) Ne and F
(B) Ar and F
(C) Ne and Cl
(D) Ar and Cl

D AND F BLOCK ELEMENTS

Compounds of Chromium
34. In chromyl chloride, the number of d-electrons present on chromium is same as in (Given at no. of Ti
: 22, V : 23, Cr : 24, Mn : 25, Fe : 26)
A. V (IV)
B. Mn (VII)
C. Fe (III)
D. Ti (III)
35. A solution of 𝐶𝑟𝑂5 in amyl alcohol has a …. Colour
A. Green
B. Orange-Red
C. Yellow
D. Blue

Compounds of Manganese
36. Highest oxidation state of Mn is exhibited in 𝑀𝑛2 𝑂7 . The correct statements about 𝑀𝑛2 𝑂7 are
A. Mn is tetrahedrally surrounded by oxygen atoms
B. Mn is octahedrally surrounded by oxygen atoms
C. Contains 𝑀𝑛 − 𝑂 − 𝑀𝑛 bridge
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 D. Contains Mn – Mn bond.

Choose the correct answer from the options given below

A. A and C only
B. A and D only
C. B and D only
D. B and C only
37. 𝐾𝑀𝑛𝑂4 oxidises 𝐼 − in acidic and neutral/faintly alkaline solution, respectively to
A. 𝐼2 𝑎𝑛𝑑 𝐼𝑂3−
B. 𝐼𝑂3− 𝑎𝑛𝑑 𝐼2
C. 𝐼𝑂3− 𝑎𝑛𝑑 𝐼𝑂3−
D. 𝐼2 𝑎𝑛𝑑 𝐼2

Important Trends
38. Which of the following statements are correct?
A. The 𝑀3+ /𝑀2+ reduction potential for iron is greater than manganese.
B. The higher oxidation states of first row d-block elements get stabilized by oxide ion
C. Aqueous solution of 𝐶𝑟 2+ can liberate hydrogen from dilute acid
D. Magnetic moment of 𝑉 2+ is observed between 4.4 – 5.2 BM

Choose the correct answer from the options given below:

A. (B), (C) only

B. (A), (B), (D) only
C. (C), (D) only
D. (A), (B) only

Reactions of d block metals

39. Which halogen is known to cause the reaction given below?

2𝐶𝑢2+ 4𝑥 − → 𝐶𝑢2 𝑋2 (𝑠) + 𝑋2

A. Only Iodide
B. Only Bromine

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 C. All halogens
D. Only Chlorine
40. In ammonium – phosphomolybdate, the oxidation state of Mo is + _____
41. Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason
(R).

Assertion (A): 𝐶𝑢2+ in water is more stable than 𝐶𝑢+ .

Reason (R): Enthalpy of hydration for 𝐶𝑢2+ is much less than that of 𝐶𝑢+

In the light of the above statements, choose the correct answer from the options given below:

A. Both (A) and (R) are correct and (R) is the correct explanation of (A).
B. (A) is correct but (R) is not correct.
C. (A) is not correct but (R) is correct
D. Both (A) and (R) are correct but (R) is not the correct explanation of (A).
42. Prolonged heating is avoided during the preparation of ferrous ammonium sulphate to
A. Prevent hydrolysis
B. Prevent reduction
C. Prevent breaking
D. Prevent oxidation
43. A solution of 𝐹𝑒𝐶𝑙3 when treated with 𝐾4 [𝐹𝑒(𝐶𝑁)6 ] gives a Prussian blue precipitate due to the
formation of
A. 𝐾[𝐹𝑒2 (𝐶𝑁)6 ]
B. 𝐹𝑒[𝐹𝑒(𝐶𝑁)6 ]
C. 𝐹𝑒3 [𝐹𝑒(𝐶𝑁)6 ]2
D. 𝐹𝑒4 [𝐹𝑒(𝐶𝑁)6 ]3

Important Properties of Lanthanoids

44. Which one amongst the following are good oxidizing agents?
A. 𝑆𝑚2+
B. 𝐶𝑒 2+
C. 𝐶𝑒 4+
D. 𝑇𝑏 4+

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 Choose the most appropriate answer from the options given below:

A. C only
B. D only
C. A and B only
D. C and D only
45. Which of the following elements have half-filled f-orbitals in their ground state?
(Given: atomic number Sm – 62; Eu = 63; Tb = 65; Gd = 64, Pm = 61)
Choose the correct answer from the options given below:
A. A and B only
B. C and D only
C. B and D only
D. A and E only

Qualitative Analysis
Borax Bead Test
46. Given below are two statements:
Statement I: Upon heating a borax bead dipped in cupric sulphate in a luminous flame, the
colour of the bead becomes green.
Statement II: The green colour observed is due to the formation of copper (I) metaborate In the
light of the above statements, choose the most appropriate answer from the options given
below:
A. Both Statement I and Statement II are false
B. Both Statement I and Statement II are true
C. Statement I is false but Statement II is true
D. Statement I is true but Statement II is false

Group 16
Oxygen
47. Given below are two statements:
Statement I: Chlorine can easily combine with oxygen to from oxides: and the product has a
tendency to explode.
Statement II: Chemical reactivity of an element can be determined by its reaction with oxygen
and halogens.
In the light of the above statements, choose the correct answer from the options given below

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 (A) Both the statements I and II are true
(B) Statement I is true but Statement II is false
(C) Statement I is false but Statement II is true
(D) Both the Statements I and II are false

Chemical Bonding and Molecular Structure

VSEPR Theory
48. For OF2 molecule consider the following:
(A) Number of lone pairs on oxygen is 2.
(B) FOF angle is less than 104.5°.
(C) Oxidation state of O is −2.
(D) Molecules are bent 'V ' shaped.
(E) Molecular geometry is linear.
Correct options are:

A. C, D, E only
B. B, E, A only
C. A, C, D only
D. A, B, D only

49. Amongst the following, the number of species having the linear shape is

𝑋𝑒𝐹2 , 𝐼3+ , 𝐶3 𝑂2 , 𝐼3− , 𝐶𝑂2 , 𝑆𝑂2 , 𝐵𝑒𝐶𝑙2 𝑎𝑛𝑑 𝐵𝐶𝑙2⊖

50. The number of species from the following carrying a single lone pair on central atom Xenon is
𝑋𝑒𝐹5+ , 𝑋𝑒𝑂3 , 𝑋𝑒𝑂2 𝐹2 , 𝑋𝑒𝐹5− , 𝑋𝑒𝑂3 𝐹2 , 𝑋𝑒𝑂𝐹4 , 𝑋𝑒𝐹4

51. The maximum number of lone pairs of electrons on the central atom from the following species
is...... ClO3−, XeF4, SF4 and l3−

Bond Length
52. The bond dissociation energy is highest for
A. Cl2
B. I2
C. Br2
D. F2

Oxy Acids
53. Sum of π -bonds present in peroxodisulphuric acid and pyrosulphuric acid is

Hydrogen Bonding
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54. In an ice crystal, each water molecule is hydrogen bonded to _____ neighbouring molecules.

Dipole Moment
55. Among the following compounds, the one which shows highest dipole moment is

A.

B.

C.

D.

MOT
56. In which of the following processes, the bond order increases and
Paramagnetic character changes to diamagnetic one?
A. 𝑂2 → 𝑂2+
B. 𝑂2 → 𝑂22−
C. 𝑁𝑂 → 𝑁𝑂 +
D. 𝑁2 → 𝑁𝑂+
57. The bond order and magnetic property of acetylide ion are same as that of
A. 𝑂2+
B. 𝑁2+
C. 𝑁𝑂 +
D. 𝑂2−

Group 15
Compounds of Nitrogen
58. The incorrect statement regarding the reaction given below is

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 (A) The product ‘B ’ formed in the above reaction is p -nitroso compound at low temperature
(B) ‘B ’ is N -nitroso ammonium compound
(C) The reaction occurs at low temperature
(D) The electrophile involved in the reaction is NO+
59. Given below are two statements :
Statement-I: Methane and steam passed over a heated Ni catalyst produces hydrogen gas.
Statement-II: Sodium nitrite reacts with NH4Cl to give H2O, N2 and NaCl.
In the light of the above statements, choose the most appropriate answer from the options
given below:
(A) Statement I is incorrect but Statement II is correct
(B) Both the statements I and II are incorrect
(C) Statement I is correct but Statement II is incorrect
(D) Both the statements I and II are correct

Oxides of Nitrogen
60. Match List I with List II
List I List II
Oxide Type of bond
A. 𝑁2 𝑂4 I 1 N = 0 bond
B. 𝑁𝑂2 II 1 N – O – N bond
C. 𝑁2 𝑂5 III 1 N – N bond
D. 𝑁2 𝑂 IV N bond

Choose the correct answer from the options given below :

(A) A−III, B−I, C−II, D−IV

(B) A−II, B−IV, C−III, D−I
(C) A−III, B−I, C−IV, D−II
(D) A−II, B−I, C−III, D−IV

Oxy acids of Phosphorous

61. Which of the Phosphorus oxoacid can create silver mirror from AgNO3 solution?
(A) (HPO3)n
(B) H4P2O5
(C) H4P2O6
(D) H4P2O7

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62. The number of P−O−P bonds in H4P2O7, (HPO3)3, and P4O10 are respectively
(A) 0, 3, 6
(B) 0, 3, 4
(C) 1, 2, 4
(D) 1, 3, 6
63. One mole of P4 reacts with 8 moles of SOCl2 to give 4 moles of A, x mole of SO2 and 2 moles of B. A, B
and x respectively are
(A) 𝑃𝑂𝐶𝑙3 , 𝑎𝑛𝑑 2 𝑆2 𝐶𝑙2
(B) 𝑃𝐶𝑙3 , 𝑎𝑛𝑑 4 𝑆2 𝐶𝑙2
(C) 𝑃𝐶𝑙3 , 𝑎𝑛𝑑 2 𝑆2 𝐶𝑙2
(D) 𝑃𝑂𝐶𝑙3 , 𝑎𝑛𝑑 4 𝑆2 𝐶𝑙2
64. The ratio of sigma and π bonds present in pyro phosphoric acid is

Answer Key.
1. 17 23. B 45. C
2. C 24. C 46. A
3. B 25. D 47. A
4. 4 26. B 48. D
5. A 27. B 49. 5
6. A 28. C 50. 4
7. A 29. B 51. 3
8. B 30. 12 52. A
9. C 31. 11 53. 8
10. A 32. C 54. 4
11. B 33. C 55. D
12. 4 34. B 56. C
13. 7 35. D 57. C
14. B 36. A 58. B
15. A 37. A 59. D
16. C 38. A 60. A
17. A 39. 1 61. B
18. 4 40. 6 62. D
19. A 41. A 63. B
20. D 42. D 64. 6
21. A 43. D
22. 0 44. D

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Fill Your Answers
Q1 Q23 Q45
Q2 Q24 Q46
Q3 Q25 Q47
Q4 Q26 Q48
Q5 Q27 Q49
Q6 Q28 Q50
Q7 Q29 Q51
Q8 Q30 Q52
Q9 Q31 Q53
Q10 Q32 Q54
Q11 Q33 Q55
Q12 Q34 Q56
Q13 Q35 Q57
Q14 Q36 Q58
Q15 Q37 Q59
Q16 Q38 Q60
Q17 Q39 Q61
Q18 Q40 Q62
Q19 Q41 Q63
Q20 Q42 Q64
Q21 Q43
Q22 Q44

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