SKKU-CS-009

기초자연과학영역(BSM) 공동시험문제
Basic Science and Mathematics Common Examination
학기 2015년 2학기 시험구분 중간 Mid Term □ 시험시간
60 분/Minutes
Semester Year Semester Exam Type 기말 Final ☑ Exam Time
학과/계열 학번 Student No. 성명
Dept./Division 개인고유번호 PIN No. Name
과목명 일반화학1 학수번호 분반
Subject General Chemistry 1 Course Code GEDB012 Section Number
수업정보 요일 시간 수업담당교수 감독자확인
Class Time Day Time Instructor Proctor’s Signature
※ 답안은 주어진 공간을 활용하여 영어로 작성 / Using languages other than English is not allowed.
유의사항 ※ 연습장 및 사전 사용 불가 / Using extra paper and dictionary is not permitted.
Note ※ 계산기 사용 가능(빌리는 것 불허) / You may use a calculator, but cannot borrow it.
※ 3,6,10,12번은 풀이과정을 보일 것/ Show your solving process for the questions from no.3,6,10, and 12.

H He ( C ) Of the following, which molecule has the largest bond

Li Be B C N O F Ne angle?
Na Mg Al Si P S Cl Ar (A) O3 (B) OF2 (C) HCN (D) H2O (E) More than
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
one of the above have equally large bond angles.
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
( C ) In the molecule XeF2, how many pairs of electrons
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
surround Xe and what is the molecular geometry?
Fr Ra Ac
(A) 4, bent (B) 4, pyramidal (C) 5, linear
(D) 5, bent (E) 6, linear
1. Write ‘T’ for true statement or ‘F’ for false statement in ( ).
[5 pt for right answer, −3 pt for wrong, and 0 pt for no answer] ( C ) As the bond order of a bond increases, the bond energy
_____ and the bond length ____.
( F ) The 3f orbital can contain upto 14 electrons.
(A) increases, increases (B) decreases, decreases
( T ) SO2 (sulfur dioxide) has a dipole moment.
(C) increases, decreases (D) decreases, increases
( F ) Helium has the most negative electron affinity value.
(E) none of these
( T ) As the number of bonds between two carbon atoms
increases, bond length decreases. +
( B ) What is the bond order of He2 ?
( F ) The hybridization of the nitrogen atom in the NO3- is sp3.
(A) 0 (B) 0.5 (C) 1 (D) 1.5 (E) 2
( F ) In ethylene (C2H4), there are 4 σ bonds and 2 π bonds.
( F ) Liquids whose components have high intermolecular forces
( B ) Which one of the following pairs is incorrectly matched?
have relatively high vapor pressure.
<Substance> <Classification>
( F ) A single substance that can crystallize in more than one
(A) sand covalent solid
arrangement is said to be amorphous.
(B) diamond molecular solid
( F ) Raoult's law defines an ideal solution, vapor pressure of
(C) Fe metallic solid
the solution is proportional to the density of the solvent.
(D) CaF2 ionic solid
( F ) The solubilities of any substances in water decrease with
(E) quartz covalent solid
increasing temperature.

( B ) Some solids can be converted directly to the vapor phase

2. Choose the correct answer and write it in ( ). [10 pt each] by heating. The process is called .
(a) fusion (b) sublimation (c) vaporization
( B ) Which of the following lists of atoms are arranged in
(d) condensation (e) distillation
order of decreasing atomic radius?
(A) Li > O > N > F (B) Li > N > O > F
( C ) Which of the following pair would have ideal solution
(C) F > O > N > Li (D) Na > Sr > O > F
behavior?
(E) Ca < Cs < S < Se
(A) ethanol-hexane (B) acetone-water (C) benzene-toluene
(D) water-methanol (E) acetic acid-benezene
( D ) Choose the element with the highest first ionization energy.
(A) Li (B) Be (C) C (D) N (E) O
( D ) Which of the following compounds has the largest expected
van't Hoff factor?
(A) NaCl (B) MgCl2 (C) MgSO4 (D) FeCl3 (E) HCl

(이 부분은 출제자 및 채점자를 위한 공간입니다. / Do not write your answer here: this is only for grading/marking.)
문제번호 1 2 3 4 5 6 7 8 9 10 11 12 합계
Problem No. Total
점수
Score 50 100 20 20 25 25 30 30 25 25 20 30 400
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Copyright ⓒ 2014 College of Science, Sungkyunkwan University (SKKU)
 SKKU-CS-009

3. [20 pt] What is the energy of one mole of photon of blue 8. [30 pt] Consider the following chemical structure:
light that has a wavelength of 453 nm?
[NA = 6.02×1023 mol-1, h = 6.626×10-34 m2‧kg/s, c = 3.00×108 m/s]
E = NA × hc/λ
23 -34 8 -9
= (6.02×10 ) × {6.626×10 × 3.00×10 / 453×10 } J/mol
5
= 2.64×10 J/mol From its Lewis structure determine the following:

4. [20 pt] Enter the empty spaces for all the possible quantum (1) What is the hybridization of the indicated atoms?
3 3 2
O ( sp ), C-1 ( sp ), C-2 ( sp ), and C-4 ( sp )
numbers.
(2) How many sigma (σ) bonds are in the molecule? ( 13 )
Orbital n l m (3) How many pi (π) bonds are in the molecule? ( 3 )
5d 5 2 -2, -1, 0, 1, 2
3p 3 1 -1, 0, +1 9. [25 pt] Arrange the following each groups in order of
2s 2 0 0 increasing boiling points.
(Group 1) H2O, HF, NH3, CH4
(Group 2) H2O, H2S, H2Se, H2Te
5. [25 pt] Draw the possible Lewis structure(s) with formal (Group 3) CH4, SiH4, GeH4, SnH4
charge(s) for N3¯ (azide ion). (Group 1) CH4 < NH3 < HF < H2O
(Group 2) H2S < H2Se < H2Te < H2O
(Group 3) CH4 < SiH4 < GeH4 < SnH4

6. [25 pt] Consider the following: Li(s) + ½ I2(g) → LiI(s) ∆H 10. (1) [10 pt] X rays of wavelength 1.54 Å were used to
= -292 kJ. LiI(s) has a lattice energy of –753 kJ/mol. The analyzed silver (Ag) crystal. A reflection was produced at θ =
ionization energy of Li(g) is 520. kJ/mol, the bond energy of 19.3°. Assuming n = 1 and sinθ = 0.33, calculate the distance d
I2(g) is 151 kJ/mol, and the electron affinity of I(g) is –295 between the planes of atoms producing this reflection.
kJ/mol. Use these data to determine the heat of sublimation of d = nλ / 2sinθ = 1×1.54 Å / 2× sin(19.3°)
Li(s). = 2.33 Å = 233 pm.

(b) [15 pt] Silver with atomic mass of 107.9 g/mol crystallizes in
a cubic closest packed (fcc) structure. The radius of a silver
atom is 144 pm. Calculate the density of solid silver.
Since 4 silver atoms are included in the unit cell volume of
-23 3
6.74×10 cm , the density is
Density = mass / volume
23
= (4 atoms)×(107.9 g/mol)×(1 mol/6.22×10 atoms)
-23 3
6.74x10 cm
7. [30 pt] The following is a molecular orbital energy level = 10.6 g/cm3
diagram for a homonuclear diatomic molecule, X2, in which X
is from H to N. 11. [20 pt] Arrange the lowest to the highest total vapor pressure
for the following solutions at 25 oC. c = mol fraction. The vapor
(1) What is the bond order of N2+? pressures of H2O and methanol are 23.8 torr and 143 torr,
( 2.5 ) respectively. ( C ) < ( B ) < ( A ) < ( D )
(A) pure water
(2) Compare the bond strengths of N2, (B) a solution of glucose in water with c(glucose) = 0.01
2-
and N2 . (C) a solution of sodium chloride in water with c(NaCl) = 0.01
2-
( N2 ) > ( N2 ) (D) a solution of methanol in water with (c)(methanol) = 0.2.

o
(3) Is B2 paramagnetic or diamagentic? 12. [30 pt] At -31 C, can salting icy roads with CaCl2 be
effective in melting the ice? Assume i = 3.00 for CaCl2 and the
( Paramagnetic )
solubility of CaCl2 in cold water is 74.5 g per 100.0 g water.
Estimate the molality of a saturated CaCl2 solution in cold water
(4) Among the following, which is the and the expected freezing point of water. (CaCl2 = 110.98 g
most stable homonuclear diatomic -1 o
mol , Kf(H2O) = 1.86 C kg/mol)
species? The molality of a saturated CaCl2 solution
- + - -
B2, N2 , B2 , C2, B2 ( N2 )
= (74.5 CaCl2 / 100.0 g H2O) x (1000g / kg) x (1 mol CaCl2
/ 110.98 g CaCl2) = 6.71 mol CaCl2 / kg H2O
o
DTf = iKfm = 3.00 x 1.86 x 6.71 = 37.4 C
Assuming these conditions, a saturated CaCl2 solution should
o
melt ice at -31 C.

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Copyright ⓒ 2014 College of Science, Sungkyunkwan University (SKKU)