Chemical Kinetics

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CfORRGNTS

CHEMICAL KINETICs
"Rate (a)= Change inl) #Rate tauo-+
Change &n tine Rale o xn o (nenctont )
Renolion
enpomenta "quantity Bunntayt ompiex.
Rate = KCRI" Single dap Matilap
Rate (R) = 0xdeN= molec-Rate 4xom RDS
-dCAI-'
adt a3dt
c8) Rate congtamt
> No itexme ofnaction
Rate o< disappeaxance Unit e< K= mol diate ’0xdee moleeu
Rate o appeaance Zoo oHdN lasity
K= mol 's (K=Aate]
# jteqrate law ate K=s-!
ZERO OR DER >n0 (’dependa ony on temp
Kyn Condnde

LRo] -CRT]= Kt -1 staichmbuy cociint


FIRST DRDER!
Roactont eona umad |Product
ntRt] -nCko] =- Kt
|Complaton ne mahi aata
KCRI° R (Ra
Rote Slope= K tiue

tume time 2.303


tin
tine
tyy. ty, =n2
"tiocy Ro-tso, K K
t- 2303, iog
K does not depend on K
iital eoneuation
" tisy.= tso. taoy = 2303
"Avevage
g ()
ulTavg) =iu an whicle conen
Nth ORDER REACTION
1 (n-i) Kt
Uatowt
Coneh.
beomes e imes o antal
=
tawg (RtJ K
’ Volia, fo al ondn ertept m=1 (taug =/HK]
t-ti :308
K logf&) - ’uewe i ündial
vutial Cond
K
"RE = Ro not guen.
-) "t= mty
(ta)/(Role
(tya)a (Ro], 50

(875)
"n # ARHENIUS THEORY
ease e gal
K= Ae
Iziat /netaut a"303 A=Asohuu aito/pu
Cponznial" fadtor
gas conct
ntemp K’ K ( min) K« tomp
u) = Kr +ID2o3 Unk= nA-Ea
RT
# {alox! afeeting RoR
vNatoe of Reaetamt
9303R Ti
iv Tempeatune
Endothemc EDthumie.
Pousens o atalyst
Suyaa aea-Neactant

Ron tohdinate Rrn condnate


AM= -Ve

BH= (aly -(e),


*et
’ Reduees
Catalyut
actiiatbu emuy
9.303 RT

Dh

St

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