(@bohring Bot) 11 11 23 SR IIT STAR CO SCMODEL (@HeyitsyashXD)

Yashpatil TG~ @bohring_bot
SEC:SR_*CO-SC(MODEL-A,B&C)) Date: 11-11-23

Time: 3 Hrs Max. Marks: 186
11-11-23_SR.IIT_STAR CO
CO-SC(MODEL-A,B&C) _JEE ADV_PTA
PTA-14_SYLLABUS
MATHEMATICS: PRESENTWEEK (100%): Straight line: Two dimensions: cartesian

coordinates, distance between two points, section formulae, shift of
origin. equation of a straight line in various forms, angle between two
lines, distance of a point from a line; lines through the point of
intersection of two given lines, equation of the bisector of the angle
between two lines, concurrency of lines; centroid, orthocentre, incentre
and circumcentre of a triangle. locus problems.
CIRCLES-I: equation of a circle in various forms, equations of tangent,
normal andnd chord. parametric equations of a circle
(Except system of circles)
PHYSICS: PRESENTWEEK (100%): SHM (Including Forced and Damped

Oscillations, Resonance) Linear and angular simple harmonic
motions.
Forced and Damped Oscillation(1D) and resonance
CHEMISTRY: PRESENTWEEK (100%): Thermodynamics & Thermochemistry:

Thermochemistry
Intensive and extensive properties, state functions, First law of
thermodynamics; Internal energy, work (pressure
(pressure-- volume only) and
heat; Enthalpy, heat capacity, standard state, Hess’s law; Enthalpy of
reaction, fusion and vapourization, and lattice enthalpy; Second law of
thermodynamics; Entropy; Gibbs energy; Criteria of equilibrium and
spontaneity.
Narayana IIT Academy 11-11-23_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-ADV_PTA-14_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 14 – 18) Questions with Integer Answer Type 3 0 5 15
Total 18 62
PHYSICS:
Sec – II(Q.N : 24 – 31) 4 -2 8 32
Total 18 62
CHEMISTRY:
Sec – II(Q.N : 42 – 49) 4 -2 8 32
Total 18 62
SR.IIT_*CO SC Page No:2

MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. Consider a triangle  whose two sides lie on the x-axis and the line x  y  1  0 . If the
orthocenter of  is (1, 1) then the equation of the circle passing through the vertices of
the triangle  is
A) x 2  y 2  3 x  y  0 B) x 2  y 2  x  3 y  0
C) x 2  y 2  2 y  1  0 D) x 2  y 2  x  y  0
2. Rectangle ABCD has AB = 5and BC =4, point E lies on AB so that EB=1 point G
lies on BC so that CG = 1 and point F lies on CD so that DF =2, line segment AG
PQ
and AC intersect EF at Q and P respectively then ratio is
EF
13 2 9 10
A) 16 B) 13 C) 82 D) 91
3. If p1, p2 , p 3 be the perpendiculars from the points 2 ,2,,    and 2 ,2
sin2 
respectively on the line x cos   y sin   0 then p1,p2 ,p3 are in:
cos 
A) AP B) GP C) HP D) AGP
4. Let d (P, OA)  min {d (P, AB),d(P,BC),d (P,OC)} where d denotes the distance from the
point to the corresponding line and S be the region consisting of all those points P inside
the rectangle OABC with vertices O(0,0), A(3,0), B(3,2) and C(0,2); which satisfy the
above relation. Then area of the region S is
A) 2 sq units B) 3 sq units C) 4 sq units D) 5 sq units

5. ABCD is a parallelogram whose diagonals AC and BD are 2x  y  3 and
x  2y  3 respectively.
If AC  4 units and area of parallelogram ABCD is 8 sq. units then.
Length of other diagonal BD is…….units
A) 10 3 B) 2 C) 20 3 D) 25 3
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
6. Two straight lines u = 0 and v = 0 passes through the origin and angle between them is
tan-1(7/9). If the ratio of the slope of v = 0 and u = 0 is 9/2, then their equations are
A) y = 3x and 3y = 2x B) 2y = 3x and 3y = x
C) y + 3x = 0 and 3y + 2x = 0 D) 2y + 3x = 0 and 3y + x = 0
7. Consider ABC with Incentre I  2, 0  , Equations of straight lines AI, BI, CI are
A
x  2, y  2  x and x  3 y  2 respectively and cot  2 then which of the following is/are
2
CORRECT
A) Slope of side BC is 2
B) Slope of side BC is 1 2
C) Equation of the locus of centroid of ABC is x  2 y  2

D) Equation of the locus of centroid of ABC is 2 x  y  2
8. Consider a circle whose radius is 2 and centre is origin. Tangents are drawn from a
point P  ,2  which touches the circle at A  a1 , a2  and B  b1 , b2  . Another pair of
tangents are drawn from the point Q   , 2  which touches the circle at A  a1 , a2 
C  c1 , c2  . Then which of the following is/are CORRECT ?  ,   0
A) b1  b2  c1  c2  0 B)   4
C) If   4 , then 4a2  3a1  0 D) If    , then a2  0

9. If the equation x 2  2 2xy  2y 2  4x  4 2y  1  0 represents the tangents to same
circle then
A) Diameter of the circle is 1 unit
B) Area of the circle is  sq. units
C) Equation of one line passing through centre of the circle is x  2 y  2  0
D) Perimeter of the circle is  sq. units
10. If 1 and 2 are respectively areas of in circle and cirumcircle of triangle formed by
0, 0 2, 0 and 1, 3  then
5
A) 1  2  B) 1  2  
3
C) 31  62  9 D) 21  32   12 where . is G.I.F
A (2, 0) is a point on the circle  x  2    y  3  25 , A line through point A making

2 2
11.
an angle of 45° with the tangent to the circle at A is drawn. Then the equation(s) of the
circle(s) with the centre(s) on this line which are at a distance of 5 2 units from point
A and of radius 3 is/are
A)  x  1   y  7   9 B)  x  3   y  7   9
2 2 2 2
C)  x  9    y  1  9 D)  x  9    y  1  9
2 2 2 2
12. Let X  R 2 be a set satisfying the following properties:

i) If  x1 , y1  and  x2 , y2  are any two distinct elements of X then either x1  x2 and
y1  y2 or x1  x2 and y1  y2 .
ii) There are two elements  a1 , b1  and  a2 , b2  in X so that for any
 x, y   X , a1  x  a2 and b1  y  b2
iii) If  x1 , y1  and  x2 , y2  are two elements of X, then
   0,1,  x2    x1  x2  , y2    y1  y2    X
.
A) All elements of X must be collinear points in R 2 plane
B) Not all elements of X are collinear points in R 2 plane
C) If  x, y   X , then for some    0,1; x  a2    a1  a2  and y  b2    b1  b2 
D) If  x, y   X , then for some 1 , 2   0,1; x  a2  1  a1  a2  and
y  b2  2  b1  b2  , Where 1   2

13.  2
a  max .  x  2   y  3
2
 and b  min.x  2 2 2
  y  3  where (x, y) lies on
the circle x 2  y 2  8x  10y  40  0 then………….
A) a  b  18 B) a  b  178 C) a  b  4 2 D) a  b  72 2
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
14. Let S be the set of points in the Cartesian plane that satisfy x  2  1  y  2  1  1.
If a model of S were built from wire of negligible thickness, then the total length of
wire required would be a b , where a and b are positive integers and b is not divisible
by the square of any prime number. Find the remainder when ‘a’ is divided by 7.
15. In the given figure PQRS is a square of side 2 units. With SR as diameter, a semicircle
is drawn. PTR and QTS are quadrants of circles of radius 2 units. If the shaded area is
n
  3 , then n is
n 1
5
16. Let Obe the centre of the circle x 2  y 2  r 2 , where r  . Suppose PQis a chord of
2
this circle and the equation of the line passing through Pand Q is 2 x  4 y  5 .
If the centre of the circumcircle of the triangle OPQ lies on the line x  2 y  4 , then the
value of r is ___
17. Let Aand Bbe any two points on y-axis and the line y = 2x respectively. Also P
andQbe the feet of perpendicular from A and B on the line y = 2x and y-axis
respectively. If AB passes through the points (1, 3), then the line PQ passes through
y
fixed point  x1 , y1  such that 1 is
x1
18. In ABC , the co-ordinates of the vertex A are (4,-1) and lines x  y  1  0 and 2x  y  3
k
are internal bisectors of angles B and C. Then radius of in-circle of ABC is where
5
k=
PHYSICS Max Marks: 62
SECTION – I
19. The time period of small oscillations of the block shown in figure is____
[Pulley, strings & springs have negligible mass and the strings do not slacken]
6M 5M 7M M
A) 2 B) 2 C) 2 D) 2
K K K 3K
d 2x
20. The motion of a particle is described by 9 2  25 x  80 where x is position
dt
coordinate and t is time. Angular frequency of small oscillations is
A) 5 B) 4 C) 3 D) 5
3 3 4 4
21. A cube having Specific gravity 0.4 and side ‘S’ is floating in a large tank of water. If
the cube is slightly depressed and released, the time period of its SHM is
2S 5S S 2 S
A) 2 B) 2 C) 2 D)
5g 2g g 5 g

22. A particle is executing SHM on a straight line. A and B are two points at which its
velocity is zero. It passes through a certain point P(AP<PB) at successive intervals of
0.5s and 1.5s with a speed of 3m/s. The maximum speed of the particle is
A) 3m/s B) 6m/s C) 3 3m / s D) 3 2m / s
23. Two uniform ropes having linear mass densities m and 4m are joined to form a closed
loop. The loop is hanging over a fixed frictionless small pulley with the lighter rope
above as shown in the following figure (in the figure equilibrium position is shown).
Now if point A (joint) is slightly displaced in downward direction and released. It is
found that the loop performs SHM with the period of oscillation equal to
 150m 
 take l  , g  10m / s 2 
 4 2

A) 1 sec B) 3 sec C) 5 sec D) 7 sec
SECTION – II
cases
24. A bob of mass 2m hangs by a string attached to the block of mass m of a spring block
system. The whole arrangement is in a state of equilibrium. The bob of mass 2m is
pulled down slowly by a distance x0 and released.

3mg
A) For x0  , maximum tension in string is 4mg
k
3mg
B) For x0  , minimum tension in string is mg
k
1 k
C) Frequency of oscillation of system is , for all non-zero values of x0
2 3m
3mg
D) The motion will remain simple harmonic for x0 
k
25. Two blocks are given impulses in opposite directions when the spring (of force
constant K) is in natural length then
A) Speed of centre of mass is V
K
B) The frequency of oscillation =
m
6mV 2
C) The maximum stretch of spring =
K
D) The speed of CM is zero
26. A body of mass m is in a field where its potential energy is given by U  ax3  bx 4
where a and b are positive constants. Then, [The body moves only along x]
A) x = 0 is a point of equilibrium
3a
B) x  is a point of stable equilibrium
4b
3a
C) x  is a point of unstable equilibrium
4b
D) for small displacements from stable equilibrium position the body executes SHM
3a
with angular frequency
2 bm

27. Two independent harmonic oscillators of equal mass are oscillating about the origin
with angular frequencies 1 and 2 and have total energies E1 and E2 respectively.
a
The variations of their momenta p with positions x are shown in figure. If  n 2 and
b
a
 n , then the correct equations is/are:
R
2 E1 E2
A) E11  E22 B)  n2 C) 12  n 2 D) 
1 1 2
28. The end A of a thin uniform semi-circular wire of mass m and radius of curvature R is
pivoted on a smooth hinge in uniform gravitational field and it is released from rest
from the position shown (Diameter AB is along the vertical initially). Select the
CORRECT statements from the following.

A) for small oscillations in its plane about its mean position, its time period is
R
2
2g
B) for small oscillations in its plane about its mean position, its time period is
2R
2 2
g ( 2  4)
C) Angle made by the diametric line AB with vertical in equilibrium is tan 1 (2 /  )
D) The maximum kinetic energy of wire in the subsequent motion after it is released
 4 
from the position shown in the figure is mgR  1  2  1 
  
29. A particle of mass m is attached to one end of a massless spring of force constant k,
lying on a frictionless horizontal plane. The other end of the spring is fixed. The
particle starts moving horizontally from its equilibrium position at time t = 0 with an
initial velocity u0 . When the speed of the particle is 0.5 u0 , it collides elastically with a
rigid wall. After this collision
A) the speed of the particle when it returns to its equilibrium position is u0
B) the time instant at which the particle passes through the equilibrium position for the
m
first time is t   .
k
C) the time instant at which the maximum compression of the spring occurs is
4 m
t
3 k
D) the time instant at which the particle passes through the equilibrium position for the
5 m
second time is t 
3 k

30. A rod of length L is supported by two ideal strings of length  such that the system
hangs in a vertical plane.(strings are connected to the ends of the rod)
Case 1 : Rod is kept horizontal and displaced slightly perpendicular to the plane and
allowed to oscillate.
Case 2 : Rod is given a small twist about its central axis and then allowed to oscillate.
(strings are connected to ends of rod) Let T1, T2 be the periods of oscillations in the two
respective cases. Identify correct statements:
  L 
A) T1  2 B) T1  2 C) T2  2 D) T2  2
g 2g 6g 3g
31. On x  y plane, the potential energy of a particle of mass ' m ' varies with r as
U  kmr 2 where k = a positive constant, r = distance from the origin, m = mass of

particle. Two particles A and B of masses ' m ' and '2m ' respectively, rotate about the
origin in concentric circular paths of radii R and 2R. Time taken by them to complete
one round about the origin is TA and TB .
While the particles are rotating, they are given a very small push radially outward.
They start oscillating (radially inward and outward) about their original circular path
with time period  A and  B respectively.
Choose the correct:
A) TA  TB B)  A   B C) 2TA  TB D) 2 A   B

SECTION – III
32. A small particle is tied by the help of two light strings to vertical walls with the
parameters as shown in the figure ( g   2 ) . The time period of the small oscillations of
the particle if it is displaced perpendicular to the plane of the paper slightly is x sec, the
value of x is
33. A uniform plank of mass m = 1kg free to move in the horizontal direction only, is
placed at the top of solid cylinder of mass 2m and radius R. The plank is attached to a
fixed wall by means of a light spring of spring constant k = 7 N/m. There is no slipping
between the cylinder and the plank, and between the cylinder and the ground. The time
period of small oscillations of the system in sec (to the nearest integer) is
34. Two light springs of force constants k1 and k 2 and a block of mass m are in one line
AB on a smooth horizontal table such that one end of each spring is fixed on rigid
supports and the other end is free as shown in the figure.
The distance CD between the free ends of the spring is 60 cm. If the block moves along
AB with a velocity 120 cm/s in between the springs, calculate the period of oscillation
of the block (in second).
(Take, k1  1.8 N / m, k2  3.2 N / m, m  200 g )
(Write the nearest integer of the answer)

35. A spring-block system is resting on a frictionless floor as shown in the figure. The
spring constant is 2.0 Nm 1 and the mass of the block is 2.0 kg. Ignore the mass of the
spring. Initially the spring is in an unstretched condition. Another block of mass 1.0 kg
moving with a speed of 2.0 ms 1 collides elastically with the first block. The collision
is such that the 2.0 kg block does not hit the wall. The distance, in metres, between the
two blocks when the spring returns to its unstretched position for the first time after the
collision is _________.
(Write the nearest integer of the answer)
36. A uniform solid cylinder of mass m and radius R is in equilibrium on an inclined plane
by the action of a light spring of stiffness k (gravity and reaction force acting on it). If
the angle of inclination of the plane is  , then angular frequency (in rad/sec) of small
oscillations of the cylinder is (no slipping anywhere) (m = 8kg, K = 12N/m)

CHEMISTRY Max Marks: 62
SECTION – I
37. A compound ‘X’ in crystalline form shows co-ordination number of ‘8’ for each
molecule. Each molecule is found to involve in H-bonding with all its nearest
neighbours. At a given pressure ( P0 ) and temperature ( T0 ), compound ‘X’ undergoes a
structural transformation, where its co-ordination number changes to ‘6’ & strength of
H-bonding increases by 20%. At P0 & T0 , the average strength of H-bonding is 4 kJ/mol
in co-ordination number ‘8’. Find ΔH  kJ / mol  related to change in extent & strength
of H-bonding per mole of compound due to structural change.
A) 3.2 B) 14.4 C) 4 D) 1.6
38. Which is incorrect about isothermal process involving an ideal gas between same initial
and final states.
A) |Wreversible expansion| > |Wirreversible expansion|
B) |Wreversible expansion| > |Wtwo step irreversible expansion|
C) |Wtwo step irreversible compression| > |W single step irreversible compression|
D) |W two step irreversible expansion| > |W one step irreversible expansion|
39. 2 moles of a mono atomic ideal gas expands such that P  K 0 V , ‘ K 0 ’ is constant. If
volume expands by 60%, find S (in cal/k). ( n e x  2.3 log10 x , log10 2  0.3 ,
R  2 cal / mol  k )
A) – 4.83 B) + 7.36 C) + 9.66 D) – 5.22

40. The specific heats of I 2 vapourand I 2 solid are 0.03 & 0.05 cal/g respectively. The heat
of sublimation of I 2S is 20 cal/g at 2000 C . Find U (in cal/g) at 2500 C ?
[Assume solid I 2 has negligible volume] [ R  2cal / mol  k ]

A) 19.12 B) 14.88 C) 23.12 D) 12.19

41. Neon gas at 10 atm, 1 lit and 300 k is expanded isoentropically till final pressure equals
to 1 atm. Find out H of system?
(Given log10 2  0.3 , R  8.3 J / K / mol )
A) -15 Cal B) -12 Cal C) -10 Cal D) -9 Cal
SECTION – II
cases
42. Consider the reaction :
2A  g   B g   2C g  , ΔH  30K cal / mol at 1atm, 300K
If 5 moles of ‘A’ reacts with 2.5 moles of ‘B’ at 1 atm & 300K, then which of the
following is /are correct?
(R = 2 cal / mol-K)
A) workdone  1.5 k cal B) q  75 k cal C) ΔU  35 k cal D) ΔU  70.5 k cal
43. For the spontaneous cyclic process shown below, which of the following is/ are correct
relations?
C
A
[Note : Both A  B and C  A are reversible steps while B  C is irreversible]
A) ΔH for complete process is zero
B) ΔS  A  B  ΔS  B  C   ΔS  C  A 
C) ΔS of system for complete process is smaller than ΔS (Surroundings)
D) ΔS  B  C  may be negative

44. Identify the correct statements among the following
A) Enthalpy of combustion of graphite is numerically equals to enthalpy of formation

of CO2 gas
B) Enthalpy of atomisaton of white phosphorus is numerically equals to enthalpy of

sublimation of it.
C) Enthalpy of ionization of sodium is numerically equals to electron gain enthalpy of

sodium ion.
D) Enthalpy of hydration is always exothermic in nature.
45. Which of the following options consist of both intensive and extensive parameters?
A) P H of solution, temperature and volume.
B) Pressure, Specific heat capacity, molar internal energy
C) Resistance, molar mass, vapour density
D) Density, mass and temperature.
46. Identify the correct options in case of isothermal free expansion of real gas?
A) Q   ve B) U  ve C) W = 0 D) S  ve
47. A gas is expanded from volume V0 to 4V0 by following two ways: (from same initial
state)
i) 1st using reversible isothermal expansion from V0 to 2V0 , then using reversible
adiabatic expansion from 2V0 to 4V0
ii) 1st using reversible adiabatic expansion from V0 to 2V0 , then from 2V0 to 4V0 using
reversible isothermal expansion
Identify the correct options?
A) Work done in (i) process > work done in (ii) process
B) Heat absorbed in (i) process > heat absorbed in (ii) process
C) Change in internal energy is same in both the processes
D) Change in entropy is same in both the processes

48. Which of the following statements is/are correct with reference to second law of
thermodynamics?
A) It is impossible to convert all the absorbed heat into work by heat engine operating
in cycles.
B) A natural process in an isolated system is always accompanied by an increase of

entropy.
C) A heat engine has 100% efficiency while it is operating in reversible conditions.
D) Practical efficiency of heat engine is less than theoretical efficiency when the engine
operates in irreversible conditions.
49. Select the correct statement(s)
A) For a reversible process ΔS (universe) may be greater than ΔS (surroundings)
B) For an irreversible process ΔS (surroundings) may be zero
C) For a reversible process ΔG (system) may be zero
D) For a spontaneous process ΔS (universe) may be less than ΔS (system).
SECTION – III
50. A gaseous compound ‘A’ undergoes parallel reaction in following manner :
B g   C g  ΔH I  81kJ / mol
I 1atm,300k 
Ag  II
D g   2E g  ΔH II  63kJ / mol
1atm,300k 
The mole fraction of E in the mixture found to be 0.2 after complete reaction of 2
moles of ‘A’ taken initially in an empty container. The heat released (kJ) at 1atm & 300k
 x  10 
is ‘x’. Find ?
2

51. The bond dissociation enthalpy of 3C-2e bond in B2 H6 is 455 kJ/mol. Given
 
Δf H0 BH3 g   100kJ / mol , ΔH atomization  B  s    565 kJ / mol , ΔH B.D.E.  H 2 g    436 kJ / mol .
 
x
If Δf H0  B2 H6 g    x kJ / mol , find ?
4
52. For a perfectly crystalline solid C p ,m  aT 3 , where a is constant. If C p ,m is 0.42 J / K-
mol at 10K, molar entropy at 10K is x J / K-mol. Find out the value of 50x.
53. Calculate the equilibrium pressure (in Pascal) for the conversion of graphite to diamond
at 250 C . The densities of graphite and diamond may be taken to be 2.20 and 3.40 g/cc
respectively, which are independent of pressure.
0
Given: G298 (C(graphite)  C(diamond))=2900 J / mol.
(Represent the answer in scientific notation as x  10 y and find the value of y)
Initial pressure is 1 bar.
54. An equilibrium is achieved at constant P of 1 atm&constant , ‘T’ of 300K in reaction
A  g   2B g  , K P  1atm .Initially vessel had 1 mol of A only. Find ΔU (kJ) for the
process?
( ΔH r  10 kJ / mol ) (Take 1 lt.atm  100J ).[ 17  4.1 ] (R = 8 J / K / mol)

SPACE FOR ROUGH WORK



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SEC:SR_*CO-SC(MODEL-A,B&C)) Date: 11-11-23

MATHEMATICS: PRESENTWEEK (100%): Straight line: Two dimensions: cartesian

PHYSICS: PRESENTWEEK (100%): SHM (Including Forced and Damped

CHEMISTRY: PRESENTWEEK (100%): Thermodynamics & Thermochemistry:

SR.IIT_*CO SC Page No:2

lies on BC so that CG = 1 and point F lies on CD so that DF =2, line segment AG

A) 2 sq units B) 3 sq units C) 4 sq units D) 5 sq units

SR.IIT_*CO SC Page No:3

If AC  4 units and area of parallelogram ABCD is 8 sq. units then.

Length of other diagonal BD is…….units

C) Equation of the locus of centroid of ABC is x  2 y  2

C  c1 , c2  . Then which of the following is/are CORRECT ?  ,   0

SR.IIT_*CO SC Page No:4

A (2, 0) is a point on the circle  x  2    y  3  25 , A line through point A making

12. Let X  R 2 be a set satisfying the following properties:

SR.IIT_*CO SC Page No:5

SR.IIT_*CO SC Page No:7

A) 1 sec B) 3 sec C) 5 sec D) 7 sec

SR.IIT_*CO SC Page No:8

A) Speed of centre of mass is V

D) The speed of CM is zero

SR.IIT_*CO SC Page No:9

SR.IIT_*CO SC Page No:10

C) Angle made by the diametric line AB with vertical in equilibrium is tan 1 (2 /  )

A) the speed of the particle when it returns to its equilibrium position is u0

SR.IIT_*CO SC Page No:11

U  kmr 2 where k = a positive constant, r = distance from the origin, m = mass of

Choose the correct:

SR.IIT_*CO SC Page No:12

(Write the nearest integer of the answer)

(Write the nearest integer of the answer)

SR.IIT_*CO SC Page No:14

A) 3.2 B) 14.4 C) 4 D) 1.6

A) |Wreversible expansion| > |Wirreversible expansion|

B) |Wreversible expansion| > |Wtwo step irreversible expansion|

C) |Wtwo step irreversible compression| > |W single step irreversible compression|

D) |W two step irreversible expansion| > |W one step irreversible expansion|

A) – 4.83 B) + 7.36 C) + 9.66 D) – 5.22

[Assume solid I 2 has negligible volume] [ R  2cal / mol  k ]

SR.IIT_*CO SC Page No:15

(Given log10 2  0.3 , R  8.3 J / K / mol )

A) -15 Cal B) -12 Cal C) -10 Cal D) -9 Cal

2A  g   B g   2C g  , ΔH  30K cal / mol at 1atm, 300K

A) workdone  1.5 k cal B) q  75 k cal C) ΔU  35 k cal D) ΔU  70.5 k cal

[Note : Both A  B and C  A are reversible steps while B  C is irreversible]

A) ΔH for complete process is zero

C) ΔS of system for complete process is smaller than ΔS (Surroundings)

SR.IIT_*CO SC Page No:16

A) Enthalpy of combustion of graphite is numerically equals to enthalpy of formation

B) Enthalpy of atomisaton of white phosphorus is numerically equals to enthalpy of

C) Enthalpy of ionization of sodium is numerically equals to electron gain enthalpy of

D) Enthalpy of hydration is always exothermic in nature.

A) P H of solution, temperature and volume.

B) Pressure, Specific heat capacity, molar internal energy

C) Resistance, molar mass, vapour density

D) Density, mass and temperature.