NEET

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Chemistry
DPP: 4
Coordination Compounds

Q1 Which of the following is incorrectly matched? Q5 According to CFT, Δo is called

(A) Pairing energy
(B) Crystal field excitation energy
(C) Crystal field splitting energy
(D) Resonance energy

(A) 1 (B) 2 Q6 Among the following, which one has higher

(C) 3 (D) 4 CFSE?
(A) [Zn(NH3 )4 ]
2+

Q2 The hybridised orbitals used by silver in the (B) [Zn(OH)4 ]

2−

+
complex [Ag(NH3 )2 ] are of the type (C) [Zn(CN)4 ]
2−

(A) sp2 (D) [Zn(H2 O)4 ]2+

(B) sp
Q7 The complex, and
2− 2−
(C) sp3 [Co(SCN)4 ] [PtCl4 ]

(D) dsp
2
have
(A) Linear structures
Q3 Hybridisation, shape and magnetic moment of (B) Tetrahedral and square planar structure
K3 [Co(CO3 ) ]
3
is respectively
(A) d , octahedral, 4.9 BM
2 3
sp
(C) Square planar and tetrahedral structures
(B) sp3 , octahedral, 4.9 BM
2
d
respectively
(C) dsp , square planar, 4.9BM
2

(D) Tetrahedral and octahedral structures

(D) sp3 , tetrahedral, 4.9 BM respectively

Q4 Which of the following statements are correct? Q8 The electron distribution in n

d coordination
2+ 2+
I. [Ni(H2 O) ]
6
and [Ni(NH3 ) ]
6
have same complexes depends on magnitude of crystal
value of CFSE field splitting, (Δ0 ) and pairing energy (P) . The
2+ 2+
II. [Ni(H2 O)6 ] and [Ni(NH3 )6 ] have same condition which favours formation of high spin
value of magnetic moment complexes is
2+ 2+
III. [Ni(H2 O) ]
6
and [Ni(NH3 ) ]
6
have (A) t42 g e0g
same hybridization of nickel
(B) Δo > P
(A) I and III only
(C) Δ0 < P
(B) II and III only
(D) Δo = P
(C) I and II only
(D) All of these

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−

Q9 Among the following complexes the one which (I) [Ni(CN)4 ]

2

shows zero crystal field stabilization energy

−

(II) [NiCl4 ]
2

(CFSE) is (III) Ni(CO)4

3+
(A) [Fe(H2 O)6 ] (IV) [Ni(H2 O)6 ]
2+

2+
(B) [Co(H2 O)6 ] (A) I only (B) IV only
(C) [Co(H2 O)6 ]
3+
(C) II, III and IV (D) II and IV
(D) [Mn(H2 O)6 ]
3+

Q15 The magnetic moment of [MnX4 ]

2
is 5.9BM .
Q10 The complex [Pt (NH3 ) ]
4
2+
has _____ The geometry of the complex ion is: (X =

structure monodentate halide ion)

(A) Square planar (B) Tetrahedral (A) Tetrahedral
(C) Pyramidal (D) Pentagonal (B) Square planar
(C) Both are possible
Q11 The crystal field splitting energy for octahedral
(D) None of these
complex (Δo ) and that for tetrahedral complex
(Δt ) are related as
(A) Δt = 4/9Δ0

(B) Δt = 0.5Δo

(C) Δt = 0.33Δo

(D) Δt = 9/4Δ0

Q12 Among the following ions, which one has

the highest paramagnetism?
3+
(A) [Cr(H2 O)6 ]
2+
(B) [Fe(H2 O)6 ]
2+
(C) [Cu(H2 O)6 ]
2+
(D) [Zn(H2 O)6 ]
−2 −
Q13 Amongst Ni(CO)4 , [Ni(CN)4 ] and [NiCl4 ]
−
(A) Ni(CO)4 and [NiCl 4 ] are diamagnetic
−
and [Ni(CN)4 ] is paramagnetic
− −−
(B) [NiCl4 ] and [Ni(CN)4 ] are diamagnetic
and Ni(CO)4 is paramagnetic
−
(C) Ni(CO)4 and [Ni(CN)4 ] are diamagnetic
−2
and [NiCl4 ] is paramagnetic
−−
(D) Ni(CO)4 is diamagnetic and, [NiCl 4 ]
−

and [Ni(CN)4 ] are paramagnetic

−

Q14 There are four complexes of Ni. Select the

complex(es) which will be attracted by
magnetic field

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Answer Key
Q1 (C) Q9 (A)

Q2 (B) Q10 (A)

Q3 (B) Q11 (A)

Q4 (B) Q12 (B)

Q5 (C) Q13 (C)

Q6 (C) Q14 (D)

Q7 (B) Q15 (A)

Q8 (C)

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