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Physics
Nuclei
All positive charges and almost all masses of an atom are concentrated in a very
small space called the nucleus. The nucleus is composed of protons and neutrons.
They are called nucleons.
Composition of Nucleus
Atomic number:The number of protons in the nucleus of an elemental atom is
called the elemental atomic number (Z).
Atomic number = Number of protons + Number of neutrons
Atomic number = Number of electrons + Number of neutron
Isotopes:
The atoms of the same elements having the same atomic number but different mass
numbers are called isotopes.
Isobars:
The atoms with a different element have the same mass number, but the different
atomic number shows similar physical properties but different chemical properties.
Ex: C614 , N 714
Isotones:
Iso diaphers:
Iso diaphers are nuclides with the same isotopic number (A-2Z). They differ in the
same way that neutrons and protons do (n-p).
Isosteres:
Isosteres' are molecules that have the same atomicity and number of electrons.
Atomicity = total number of atoms in molecules
Iso-Electronic Species:
The molecules or ions with same number of electrons are called isoelectronic species
Mass number: The total number of protons and neutrons present in the nucleus of
anelement is called the mass number (A) of the element.
A = Z + N
Size of Nucleus:Size of the nucleus R A1/3
R R0 A1/3
Where, empirical constant R0 1.1 1015 m
Radioactivity Law According to this law, the decay rateof radioactive atoms at a
given time is proportional to the number of atoms present at that time.
Nuclear force: The force that acts within the nucleus orbetween nucleons is called
nuclear force. Nuclear force is the strongest force in nature.
● It's a very short-distance force of attraction
● It's not central. Non-conservative force.
● It is neither gravitational or electrostatic force. It's free.
● 100 times the electrostatic force and 1038 times the gravity.
Mass defect
The difference between the total mass (M) of all nucleons and the mass (m) of the
nucleusis called a mass defect.
m M m
m Zm p ( A Z )mn mn
Radioactivity:
When a particular nucleus emits the radiation spontaneously, such certain nuclei are
known to be radioactive and this phenomenon of disintegration of nuclei
spontaneously is called radioactivity.
Types of Radioactive radiation
● Alpha rays: The rays which bends towards the negative plate by carrying the
positive charge.
● Beta rays: The rays which bends towards the positive plate by carrying the
negative charge.
● Gamma rays are uncharged rays that pass straight through the electric field.
Beta radiation:
Gamma Radiation:
It involves the emigration of electromagnetic energy from a snippet’s nucleus.
During gamma radiation, no patches are emitted; therefore, it doesn't beget the
vacillation of atoms.
60
Co27 Ni28
60
e01 2 00
Radioactive disintegration:
Converting one radioactive nuclei into another by emitting the 𝛂, 𝛃 and 𝛄 rays.
Methods of Radioactive disintegration:
● Alpha decay: Emission of an alpha particle, decreases the atomic number by
2 units and mass number by 4 units.
238
U 92 He24 Th90
234
● Gamma decay: Emission of γ-rays does not affect the atomic and mass
numbers.
Beta Rays:
The inner nucleus releases extremely energetic electrons known as beta particles.
They have a negligible mass and a negative charge. A neutron in the nucleus splits
into a proton and an electron when a beta particle emits. As a result, the electron is
rapidly emitted by the nucleus. Beta particles have a higher penetration power than
alpha particles and can easily pass through the skin. Even though their ionisation
power is low, beta particles can be dangerous and any contact with the body should
be avoided.
Gamma Rays:
Gamma rays are waves that originate at the high-frequency end of the
electromagnetic spectrum and have no mass. They have the greatest penetrating
power. They are the most penetrating but least ionising, and keeping them out of the
body is extremely difficult. Gamma rays have a high energy density and can travel
through thick concrete and thin lead.
Rate of disintegration:
The number of atoms of radioactive elements that disintegrate in a unit time.
DN
Rate of decay = N
dt
dN
(Or) kN
dt
Where, k= decay constant
2.303 N
k log 0
t Nt
Here, N 0 =number of atoms initially
Half-life period t 1 :
2
For a first-order reaction, the rate constant can be mathematically expressed as
follows:
2.303 [ R]
k log 0
t [ R]
From the definition of reaction half-life, at t t1/2 ,[ R] [ R]0 / 2 . Substituting these
values in the expression for the first-order rate constant, the following equation is
obtained:
k
2.303
log
R0
t1/2 [ R]0 / 2
Rearranging the expression to find the value of t1/2 :
2.303 0.693
t1/2 log(2)
k k
Thus, the half-life of a first-order reaction is given by 0.693 / k .
The amount of time required by a radioactive substance (or one half the atoms) to
disintegrate or transform into a different substance.
t 1 0.693 / k
2
Half life is related to the total time as, T n t 1
2
n
1
Where, n is calculated from the relation Nt N 0
2
N 0 = initial amount.
N1 = amount after time T.
n = number of half-lives.
Average Life
2
1
1: et 1/2
2
log ee1/2 t1/2
log 02
t1/ 2
0.693
t1/2
1
k
1 1
1.44 t1/ 2
k 0.693 / t1/ 2
Nuclear Reactions:
Nuclear Fusion: The reaction in which two or more elements fuse together to form
a large element, by releasing a large amount of energy.
H12 H 22 H 32 He24 H11 n10 21.6Mev
Application of Radioactivity:
● Estimation of age (Dating Technique)
Carbon dating technique.
Uranium dating technique.
● Medical use
In therapeutic procedures.
Imaging procedure.
Carbon Dating:
Carbon dating is one of the most widely used methods in archaeology for dating
organic objects up to 50,000 years old. This method is based on the idea of carbon-
14 isotopes radiatively decaying over thousands of years. Scientists have discovered
that radioactive molecules decay at a specific rate determined by the atomic number
and mass of the decaying atoms.
The ratio of radioactive isotopes to the estimated initial concentration of these
isotopes at the time of the organism's death can be used to calculate the approximate
age of the decaying material. Scientists have concluded that the ratio of Carbon-12
to Carbon-14 isotopes in the atmosphere has changed very little, implying that the
relationship between these two should be very similar to how it is today.
Radioactive series:
Any of four independent sets of unstable heavy atomic nuclei that decay through a
series of alpha and beta decays until a stable nucleus is obtained. These four chains
of consecutive parent and daughter nuclei start and end among elements with atomic
Important Formulas:
c2
A
Zm p ( A Z )mn M Z
XA
0.693 log e 2
● Half life of a radioactive substance: T1/2