- Mark Scheme /

Question Answer Marks AO Element Notes Guidance

1 1
B-5

2 2 (CO) 1

3 218 (2) 2
If two marks not scored, allow 1
mark for Cu = 1 x 64 / 64 OR F
= 4 x 19 / 76

4 2 (Na) (1) 2
2 (Na2O) (1)

5 20 (g) 1

6 C4H6O2
1

7(a) 2 (F2) (1)

2
4 (HF) (1)

7(b) gain of oxygen / addition of 1

oxygen

8 calcium chloride (1) 2

water (1)

9(a) 3.5 (%) 1

 - Mark Scheme /

Question Answer Marks AO Element Notes Guidance

9(b) oxygen 1

9(c) one mark each for any 2 of: 2

• more aluminium in Earth /
less aluminium on moon
• less iron in Earth / more
iron on moon
• more oxygen in Earth / less
oxygen on moon
• more silicon in Earth / less
silicon on moon

10 150 (2) 2
if two marks not scored, allow 1
mark for H = 2x1 / 2 OR O =
6x16 / 96

11(a) hematite (1) 1

11(b) 2 (Fe) (1) 2

3 (CO2) (1)

11(c) breakdown of a compound (1) 2

by heat / when heated / using

thermal energy (1)
 - Mark Scheme /

Question Answer Marks AO Element Notes Guidance

rd
11(d) 3 box down ticked (it reacts 1
rd
box down ticked (it reacts
with impurities in the iron ore to
form slag)

12(a) carboxylic acid 1

12(b) C5H10O2
1

13 3 (Fe) (1) 2
2 (O2) (1)

14(a) 5 (%) 1

14(b) iron 1

14(c) one mark each for any 2 of: 2

• more iron in whole / less
iron in crust
• more magnesium in whole
/ less magnesium in crust

• less oxygen in whole / more

oxygen in crust
• less silicon in whole / more
silicon in crust

15(a) 2 (H2O) (1)

2
2 (HBr) (1)
 - Mark Scheme /

Question Answer Marks AO Element Notes Guidance

15(b) loss of oxygen 1

16(a) one mark each for any 2 of: 2

• breakdown of long chain
hydrocarbons / breakdown
of large hydrocarbons
• to short chain hydrocarbons
/ to small hydrocarbons
• by heat / when heated /
thermal (energy)

16(b) C5H10
1

17(a) 0.9 (%) 1

17(b) oxygen 1
 - Mark Scheme /

Question Answer Marks AO Element Notes Guidance

17(c) one mark each for any 2 of: 2

• more iron in (whole) Earth
/ less iron in oceans / no
iron in oceans
• more magnesium in (whole)
Earth / less magnesium in
oceans
• less oxygen in (whole)
Earth / more oxygen in
oceans
• more silicon in (whole)
Earth / less silicon in
oceans / no silicon in
oceans

18(a) circle around OH attached to 1

middle carbon atom

18(b) C3H6O3
1

19 171 (2) 2
If two marks not scored,
allow 1 mark for C = 4 x12 / 48
OR O = 4 x 16 / 64

20(a) 2 1
 - Mark Scheme /

Question Answer Marks AO Element Notes Guidance

20(b) M1 but-1-ene (1) 3

M2 C=C (both C atoms should
have 4 bonds) (1)
M3 Displayed formula of
but-1-ene (1)

20(c) CH2
1

21 M1 H 3.66 / 1 2
P 37.80 / 31
O 58.54 / 16
OR H = 3.66 P = 1.22 O =
3.66
OR H:P:O 3:1:3 (1)
M2 H3PO3 (1)

22(a) neutralises both acids AND 1

alkalis

22(b) 2NaOH + Al 2O3 → 2NaAlO2 2

+ H2O
M1 NaAlO2 on the right hand
side (1)

M2 equation fully correct (1)

23(a) methanoic acid 1

 - Mark Scheme /

Question Answer Marks AO Element Notes Guidance

23(b) CH2O2
1

24(a) 1
2.5 x 10 / 0.0025 (1)

24(b) 1
1.25 x 10 / 0.00125 (1)

24(c) 20 (1) 1

24(d) 40 (1) 1

25(a) yellow 1

25(b) 4Na + O2 → 2Na2O 2

M1 species (1)
M2 balancing (1)

26(a) M1 450 (1) 3

M2 1-2 (1)
M3 vanadium(V) oxide (1)

26(b) SO3 + H2SO4 → H2S2O7 1

26(c) water 1
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Question Answer Marks AO Element Notes Guidance

27 P4O10 + 6PCl 5 → 10POCl 3 2

M1 all formula correct and on

the correct sides of the arrow
(1)
M2 equation fully correct (1)

28 (NH4)2SO4
1

29(a)(i) mol of K 1
= 2.34 /
39 =
0.06(00)
(1)
29(a)(ii) mol of H2 1
= 0.06 / 2
=
0.03(00)
(1)
29(a)(iii) volume 1
of H2 =
0.03 x 24
000 =
720 cm
3
(1)
3
(1
)

30(a) Mr MgSO4 = 120 (1)

1

30(b) mol MgSO4 = 2.40 / M1 = 2.40 1

/ 120 = 0.02(00) (1)
30(c) 0.02(00) / 0.02(00) = 10.1 1
40 / 0.02(00) = 7 and x = 7 (1)

31(a) M r Ca(NO3)2 = 164 (1) 1

 - Mark Scheme /

Question Answer Marks AO Element Notes Guidance

31(b) mol Ca(NO3)2 = 2.46 / 164 = 1

0.015(00) (1)

31(c) 0.015(00) / 0.015(00) = 1 1

0.0600 / 0.015(00) = 4 and x =
4 (1)

32(a) white 1

32(b) silver chloride 1

32(c) +(aq) + Cl (aq) → 3

Ag
AgCl(s)
M1 AgCl (as only product) (1)
+ and Cl (as only
M2 Ag reactants) (1)
M3 state symbols (1)

33 Mg + H2SO4 → MgSO4 + H2
1

34(a) mol Na = 1
0.345 /
23 =
0.015(00
)
(1)
34(b) mol 1
NaOH =
M1 =
0.015(00
)
(1)
 - Mark Scheme /

Question Answer Marks AO Element Notes Guidance

34(c) M2 x 1
1000 / 50
=
0.015(00
) x 20
= 0.3(00)
(1)
34(d) M 1 M r NaOH = 40(1)
2
M2 M4 x M3 = 40 x 0.3= 12.(0)
(g / dm
3
) (1)

35(a)(i) lilac flame 1

35(a)(ii) Any two from 2

• solid disappears
• blue solution
• bubbles / effervescence /
fizzing

35(a)(iii) white precipitate 1

35(b) 2+(aq) + SO 3
Ba 4 (aq) →
BaSO4(s)

M1 BaSO4 on the right (1)

2+ and SO
M2 ONLY Ba
4 on
the left (1)
M3 state symbols (1)
 - Mark Scheme /

Question Answer Marks AO Element Notes Guidance

36(a) CaCO3 + 2HNO3 → Ca(NO3)2 2

+ H2O + CO2

M1 H2O and CO2 as product

(1)
M2 rest of equation correct (1)

36(b) M1 fizzing / effervescence (1) 2

M2 solid disappears / dissolves
(1)

37 60 1

38 3+(aq) + 3OH (aq) → 3

Fe
Fe(OH)3(s)
M1 Fe(OH)3 (as only product)
(1)
3+ and 3OH (as only
M2 Fe reactants) (1)
M3 state symbols (1)

39 M1 GaCl 3 (1)
2
M2 Ga2(SO4)3 (1)

40 lithium 1

[Total: 112]