Professional Documents
Culture Documents
Referensi 1-S2.0-S2095268617309060-Main
Referensi 1-S2.0-S2095268617309060-Main
a r t i c l e i n f o a b s t r a c t
Article history: Expandable rock bolts are widely used in hard rock mines as an efficient ground control product.
Received 21 June 2017 However, capacity and service life can be significantly reduced if the metallic body is subjected to corro-
Received in revised form 20 August 2017 sion. In some hard rock mines in the U.S., highly corrosive ground conditions exist, and it has been
Accepted 29 October 2017
reported that inflatable rock bolts have corroded within a few months after installation. To provide min-
Available online 2 January 2018
ing industry a cost-effective inflatable bolt and combat the corrosion issues, Jennmar Corporation, Inc.,
and its subsidiary Keystone Mining Services, LLC (KMS), analyzed corroded bolt samples, identified root
Keywords:
causes, evaluated properties of various coating materials, and developed a new inflatable rock bolt,
Rock bolt
Hard rock
Python M3TM, that is protected with an innovative PyFlexU2TM coating. The new generation Python M3TM
Corrosive ground condition features improved steel chemistry for reliable performance, modified profile for better inflation, and sur-
Bolt corrosion face preparation and coating application. The PyFlexU2TM is impervious to liquid and air, durable, and UV
resistant. With a flexible, adhesive, and highly corrosion-resistant undercoating, and a very hard sacrifi-
cial surface coating, the PyFlexU2TM coating system provides the Python M3TM superior protection against
chemical corrosion and physical scratch damage. The under-coating has exceptional flexibility and adhe-
sion to prevent coating micro-cracks or fractures after bolt inflation and possesses excellent corrosion
resistance to acids (pH < 3), alkalis (pH > 11), fuels, and salt solvents. The corrosion and scratch resistant
PyFlexU2TM coating offers very effective bolt protection for extra longevity in highly corrosive environ-
ments. The Python M3TM coated with PyFlexU2TM has been tested in the most challenging conditions,
including laboratory corrosion tests in extreme acidic and basic solvents, rock slurry, and borehole
scratch insertion tests. With demonstrated corrosion and scratch resistance, the product has been greatly
welcomed by hard rock mines in the West and is currently installed in large scale. This paper identifies
the root causes of the bolt corrosion, discusses the analysis process, and details laboratory and under-
ground tests carried out on the Python M3TM coated with PyFlexU2TM. The Python M3TM and PyFlexU2TM
are subjects covered by pending U.S. Patent Applications assigned to FCI Holdings Delaware, LLC.
Ó 2018 Published by Elsevier B.V. on behalf of China University of Mining & Technology. This is an open
access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
https://doi.org/10.1016/j.ijmst.2017.12.023
2095-2686/Ó 2018 Published by Elsevier B.V. on behalf of China University of Mining & Technology.
This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
146 K.J. Ma et al. / International Journal of Mining Science and Technology 28 (2018) 145–151
Table 2
Acid digestion and ICP-AES test results.
6
Item Sample # (10 )
Analyte 2 3 5
Calcium 18,200 115,000 18,600
Iron 43,000 21,300 41,400
Magnesium 1330 59,700 11,100
Potassium 3210 19,400 3250
Silicon 266,000 145,000 307,000
Fig. 3. Corroded bolt sample (Omega-AP). Sodium 208 338 228
Nickel 114 35.3 29.5
Zinc 1150 77.9 42.9
Chloride 11.7 12 182
Sulfate 11,000 5680 8760
4. Development of PyFlexU2TM
(1) Coating thickness evaluation per ASTM D 7091. 4.3. Development of PyFlexU2TM coating
(2) Coating integrity evaluation after unrestricted inflation. The
inflated bolt was checked for the appearance of wrinkles, With the Phase I laboratory test results, PyFlex coating material
blisters, delamination, macro-cracks, and cracks or peel-off was identified as the best candidate. The material has exceptional
of the coating material. flexibility and adhesion to prevent coating micro-cracks or frac-
tures after bolt inflation and possesses excellent corrosion resis-
tance to acids (pH < 3), alkalis (pH > 11), fuels, and salt solvents.
To further improve surface hardness and scratch resistance of the
coating against physical damage during bolt insertion in the field,
a very hard sacrificial topcoat (U2) is applied on the unfolded area
of the Python bolt, where deformation is not very demanding dur-
ing bolt inflation.
The combination (PyFlexU2TM) of the corrosion-resistant under-
Fig. 7. Bolt samples with different coatings. coat PyFlex and the scratch-resistant topcoat U2 satisfies coating
K.J. Ma et al. / International Journal of Mining Science and Technology 28 (2018) 145–151 149
Table 3
Mechanical properties of PyFlexU2TM.
Table 4
Corrosion resistant properties of PyFlexU2TM.
design expectations and offers very effective bolt protection for 5.1.2. Long-term immersion test in mine rock slurry
extra longevity in highly corrosive environments. Tables 3 and 4 To approximate corrosion environment in the field, the nine
summarize the mechanical properties and corrosion-resistant representative rock samples were crashed, pulverized, and sieved
properties of the PyFlexU2TM coating. into powder (18-mesh material). A rock slurry was prepared by
mixing the rock powder with distilled water in a water-to-
5. Evaluation of PyFlexU2TM (phase II) powder ratio of 1:3 by weight. The bolt samples (inflated Python
M3TM from production, surface scratched Python M3TM from field,
The Python M3TM bolt coated with the PyFlexU2TM were tested and uninflated Brand AC) were immersed in the nine different rock
rigorously for long term corrosion-resistant performance in labora- slurries for 56 d. To accelerate the corrosion, a thermostatically
tory and for scratch resistance in the field. controlled spot heater was used to maintain a constant high tem-
perature in the range of 85 ± 5 °F. Test results indicate the
5.1. Laboratory testing following:
Fig. 14. Brand AC samples immersed in #8 (top) and #4 (bottom) rock slurry for 56
d.
The PyFlexU2TM production sample had no discernable coating Fig. 16. PyFlexU2TM (left) and Brand AC (right) after insertion test.
damage.
developed. With a flexible, adhesive, and highly corrosion-resistant U2TMTM coating offers the underground hard rock mining industry
undercoat and a very hard sacrificial topcoat, the PyFlexU2TM coat- a viable and cost-effective expandable rock bolt to combat highly
ing system provides the Python M3TM bolt superior protection corrosive environments in an efficient and cost-effective manner.
against chemical corrosion and physical scratch damage.
The Python M3TM coated with PyFlexU2TM has been tested in the References
most challenging conditions, including various long-term corro-
sion tests in extreme solvents (acidic solution, basic solution, and [1] Aziz N, Craig P, Mencik J, Hai F. Rock bolt corrosion–an experimental study. In:
Proceedings of the coal operators conference. Wollongong (Australia):
salt solution) and mine slurry, long-term salt spray, long-term University of Wollongong; 2013. p. 144–51.
UV exposure in the laboratory, and borehole scratch insertion tests [2] Oler O, Chen J. Introduction of a new superior coating on ground support
in the field. It is concluded that the new generation Python M3TM products. In: Proceedings of the 33rd international conference on ground
control in mining. Morgantown (WV): West Virginia University; 2014. p. 4.
rock bolt coated with the corrosion and scratch resistant PyFlex-