JEE MAINS Test 05

Discussion 01/05/2022

IIT BY: Ram Niwas Sir

Jee-Main Test - 5 Discussion

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1. Which of the following statement is incorrect?

𝑎 H2O2 reduces 𝐌𝐧𝐎−𝟏

𝟒 both in acidic and basic medium

𝑏 H2O2 oxidises Fe+2 both in acidic medium

𝑐 H2O2 oxidises Mn+2 ions in basic medium

𝑑 H2O2 oxidises I2 in both acidic and basic medium

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2. Which of the following is not an example of industrial waste

𝑎 Fly ash 𝑏 Gypsum

𝑐 Mud and tainlings 𝑑 D.D.T

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3. Which of the following statements about quantum number is incorrect?

𝑎 azimuthal quantum number defines the penetrating power of orbitals for a

particular principal quantum number
𝑏 Zeeman effect can be explained by using magnetic quantum number

𝑐 In hydrogen like system, energy of electron is absolutely governed by principal

quantum number
𝟏 𝟏
𝑑 Spin quantum number +
𝟐
and −
𝟐
represent clockwise and anticlockwise
rotation of electron respectively

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4. Which of the following order is correct

𝑎 S > O > Se > Te [electron affinity]

𝑏 N < P < As [electron affinity]

𝑐 electronegativity of F at pauling scale > electronegativity of F at mulliken scale

𝑑 C2H2 < C2H4 < C2H6 (electronegativity of C)

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5. Regarding hydrolysis of BF3, few points are given
(i) It undergoes partial hydrolysis
(ii) Three moles of hydraacid are formed as intermediate from one mole of
BF3
(iii) As compared to reactant (B–F) bond length increases in one of the
product
(iv) In a balanced reaction out of four moles of BF3, three moles will
undergo hydrolysis.
How many of these statements are correct

𝑎 1 𝑏 2

𝑐 3 𝑑 4

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6. Which of the following statement is correct?

𝑎 for N2→𝐍𝟐+ bond order decreases and magnetic nature does not change

𝑏 for CO → CO+ bond order decreases and magnetic nature changes

𝑐 for O2→𝐎−𝟐
𝟐 spin multiplicity decreases and magnetic nature changes

𝑑 for B2→𝐁𝟐+ bond order increases and magnetic nature does not changes

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7.At 25°C, 500 ml 0.25M Na2CO3 aq. solution is mixed with 500 ml 0.25M H2CO3
solution. Approx value of pH of the resulting solution will be [Given of 𝐊 𝐚 𝟏
of H2CO3 = 10–7, 𝐊 𝐚 𝟐 of H2CO3 = 10–11]

𝑎 7 𝑏 11

𝑐 9 𝑑 2

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8.For a reaction C(graphite) + 2H2(g)→ CH4(g), ΔH° = –75 KJ at 300K and 1 atm. The
𝐉
standard entropies of C(graphite), H2(g) and CH4(g) are 6, 130.6 and 186.2
𝐊 𝐦𝐨𝐥
𝐉
respectively. Suniv 𝐢𝐧 for the reaction will be
𝐊

𝑎 –81 𝑏 169

𝑐 –169 𝑑 81

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9. The radius of Ag+ ion is 126 pm, while of I– ion is 216 pm. The edge length of
unit cell of AgI will be, if AgI crystallizes as FCC structure.

𝑎 171 pm 𝑏 684 pm

𝑐 789.84 pm 𝑑 2369.38 pm

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10. In a conductivity cell, the two platinum electrodes, each of area 20 cm2 are
fixed 2.5 cm apart. The cell contained 0.01M of NH4Cl salt. If the two
electrodes are one fourth dipped into the solution which has a resistance of
100Ω, the molar conductance of salt solution in Ω cm mol is

𝑎 125 𝑏 500

𝑐 31.25 𝑑 62.5

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 𝐃−𝐝
11.The equation 𝛂 = is correctly matched for
𝐧−𝟏 𝐝
Where D = Theoretical vapour density
d = Observed vapour density

𝐧 𝐧
𝑎 𝐀 𝐠 ⇌ 𝐁 𝐠 + 𝐂𝐠
𝟐 𝟑
𝐧 𝐧
𝑏 𝐀 𝐠 ⇌ 𝐁 𝐠 + 𝐂𝐠
𝟐 𝟒
𝐧 𝟐𝐧
𝑐 𝐀 𝐠 ⇌ 𝐁 𝐠 + 𝐂𝐠
𝟑 𝟑

𝑑 All the above

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12. In a glass tube of uniform cross-section, HCl gas is sent from one end and a
mixture of NH3, He and Ar gases are sent from another end at the same time,
the white fumes of NH4Cl will appear first

𝑎 At the middle of the tube 𝑏 At the NH3 end

𝑐 Closer to NH3 end 𝑑 Closer to HCl end

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13. The impure sample of Na2C2O4 weighing 0.20gm is dissolved in aq. solution
of H2SO4 and solution is titrated at 70°C, requiring 45 ml of 0.02M KMnO4
solution. The end point is over run and back titration is carried out with 10
ml of 0.1M oxalic acid solution. Find percentage purity of Na2C2O4 in sample.

𝑎 75 𝑏 83.75

𝑐 90.25 𝑑 None of these

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14. Final product of the following reaction is

Br2 Sn+HCl NaNO2 ,HCl H3PO2 KMnO4

⎯⎯
Fe
⎯→⎯⎯⎯⎯ →⎯⎯⎯⎯⎯
5°C
→⎯⎯⎯Δ
⎯→⎯⎯⎯⎯
Δ
→?

𝑎 𝑏

𝑐 𝑑

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15. Which of the following statements is not correct

𝑎 Teflon is fully fluorinated polymer

𝑏 Dacron is classified as condensation polymer

𝑐 Orlon is prepared by polymerization of CH2 = CH–CN

𝑑 Nylon 6,6 is obtained by heating caprolactam with water of a high temperature

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16. Which drug is used as anti fertility drug

𝑎 Penicillin 𝑏 Ofloxacin

𝑐 Erythromycin 𝑑 Novestrol

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17. A white crystalline solid (x) gives following chemical test
(i) It liberates CO2 with NaHCO3
(ii) It forms a coloured dye on diazotization and coupling with β–naphthol
(iii) With Br2 water it forms white precipitate of 2,4,6 - tri bromo aniline X
can be

𝑎 𝑏

𝑐 𝑑

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18.
Major product [P] is

𝑎 𝑏

𝑐 𝑑

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19. The geometries of the ammonia complexes of Ni2+, Pt2+ and Zn2+,
respectively, are

𝑎 octahedral, square planar and tetrahedral

𝑏 square planar, octahedral and tetrahedral

𝑐 tetrahedral, square planar and octahedral

𝑑 octahedral, tetrahedral and square planar

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20. The order of the oxidation state of the phosphorus atom in H3PO2, H3PO4,
H3PO3, and H4P2O6 is

𝑎 H3PO3 > H3PO2 > H3PO4 > H4P2O6

𝑏 H3PO4 > H3PO2 > H3PO3 > H4P2O6

𝑐 H3PO4 > H4P2O6 > H3PO3 > H3PO2

𝑑 H3PO2 > H3PO3 > H4P2O6 > H3PO4

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21. Number of compounds which can evolve CO2 on heating are
O
||
; H3 C — CH— COOH; H3C — C — CH2 — C — OH ;
| ||
NO2 HN
O O
|| ||
CH3 — CH— COOH ; Ph — CH — CH2 — COOH; HO — C — C — OH
| |
CH2 — COOH OH
CH3—CH2–COOH

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22. Find the number of molecules which are soluble in KOH

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23. For the given compound

If x = Number of stereo isomers and y = Number of chiral centers

Then what is the value of |x – y| is

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24. Number of compounds which are more reactive than CH3 — CH— Cl
by SN2 mechanism? |
CH3

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25. Find total number of bidentate ligands (X) for which complex M(X) can show
geometrical as well as optical isomerism en (ethylenediamine), OX–2
(oxylate), dipy (dipyredine), phen (phenanthroline), gly–1 (glycinato), acac–1
(acetylacetonate), bcac–1 (benzoylacetonate), pn (propylenediamine).

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26. Find the number of elements which are extracted by carbon reduction
method Fe, Sn, Zn, Pb, Na, Au, Ag.

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 𝐝𝐢𝐬𝐩𝐫𝐨𝐩𝐨𝐫𝐭𝐢𝐨𝐧𝐚𝐭𝐢𝐨𝐧
27.𝐗𝐞𝐎𝟑 + 𝐍𝐚𝐎𝐇 → 𝐀
𝐁 + 𝐂 ↑ + 𝐃 ↑ +𝐇𝟐 𝐎
Bond order of (Xe–O) bond in [B] is..............

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28. Calculate volume (in lt) occupied by 1 mol of vander waal gas at 2 atm, 500
K. (Given a = 2.5 atm 2 mol–2, b = 0.0625  mol–1 , R = 0.08 -atm/K–mol)

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29. For the coagulation of 80 ml of ferric hydroxide sol, 20 ml of 0.25 M KCl is
required. The coagulation value of KCl will be

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30. Which of the following compounds are amphoteric in nature?
PbO, PbO2, Be(OH)2, Zn(OH)2, Ga2O3, B2O3, CO, SnO, SnO2, Al(OH)3, SiO2, CO2.

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THANK YOU