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nature water

Article https://doi.org/10.1038/s44221-023-00059-8

Solar steam-driven membrane filtration for


high flux water purification

Received: 29 April 2022 Xueyang Wang 1,4, Zhenhui Lin1,4, Jintong Gao2, Zhenyuan Xu 2,
Xiuqiang Li 3 , Ning Xu1, Jinlei Li1, Yan Song1, Hanyu Fu1, Wei Zhao1,
Accepted: 1 March 2023
Shuaihao Wang 1, Bin Zhu1, Ruzhu Wang 2 & Jia Zhu 1
Published online: 3 April 2023

Check for updates In recent years, interfacial solar steam generation has shown great potential
for desalination with high solar-to-steam conversion efficiency. However,
the freshwater production rate is still limited by the substantial latent heat
of water evaporation and condensation efficiency. Here we designed an
interfacial solar steam-driven reverse osmosis/nanofiltration device that
generates high pressure that pushes water molecules through a filtration
membrane to achieve separation from ions. The solar steam-driven reverse
osmosis device reaches a water production rate as high as 81 kg m−2 h−1
under 12 sun illumination. Moreover, a theoretical model indicates that
there still exists attractive room to further improve the freshwater output
by optimizing the thermal insulation and expansion ratio of the device.
This work paves a new way to design highly efficient miniaturized or
decentralized drinking water devices.

In recent years, with the growth of the population and the rise of indus- separation membrane, has a low theoretical thermodynamic energy.
trialization, freshwater resources have become very scarce1–3. Solar The ideal energy consumption of the thermodynamically constant-
thermal desalination, especially interfacial solar steam generation with pressure RO filtration process for seawater at 35,000 ppm salt is
dramatically improved evaporation efficiency4–18, offers a promising 1.6 kWh m−3 (refs. 47–49). The actual energy spent in the RO stage with a
pathway to alleviate the water crisis with minimum environmental typical water recovery of 50% is ~1.8 kWh m−3 (6.48 kJ kg−1), approaching
impact. Advanced interfacial solar heating techniques show more than the thermodynamic limit49,50.
90% energy efficiency and flourishing application prospects19–35. How- Here, we first combine interfacial solar steam generation technol-
ever, evaporation needs to overcome the vaporization enthalpy of ogy with membrane filtration-based water purification technology
water (which varies slightly around 2,455.6 kJ kg−1), which significantly to improve the water production rate of solar thermal desalination.
limits the solar to freshwater output. Typically, the theoretical water Specifically, the high-temperature high-pressure steam generated by
evaporation rate of the single-stage solar still is about 1.47 kg m−2 h−1 interfacial solar heating pushes water molecules through the RO/NF
under 1 sun illumination32,36. Although some technologies, such as membrane to achieve separation from ions. Compared with the conven-
multi-stage evaporation and low-pressure evaporation, have been tional solar-steam condensation method, the solar steam-driven (SSD)-
developed to increase the water production rate further, the vapori- RO/NF method dramatically reduces the energy required for separation
zation enthalpy of water is still considerable (achieving, for example, since it avoids the direct evaporation of water molecules (Fig. 1a).
a water production rate of 2.94 kg m−2 h−1 under 1 sun illumination for According to the developed theoretical model, the theoretical water
ten-stage evaporation)37–46. production rate of the SSD-RO method is two orders of magnitude
On the other hand, reverse osmosis (RO)/nanofiltration (NF), higher than that of the single-stage solar-steam condensation method,
which realizes the separation of ions and water molecules through a and is comparable to and even greater than that of photovoltaic-driven

1
National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional
Materials, Nanjing University, Nanjing, P. R. China. 2Engineering Research Center of Solar Power and Refrigeration (MOE), Institute of Refrigeration and
Cryogenics, Shanghai Jiao Tong University, Shanghai, P. R. China. 3Key Laboratory for Intelligent Nano Materials and Devices of Ministry of Education, and
Institute for Frontier Science, Nanjing University of Aeronautics and Astronautics, Nanjing, P. R. China. 4These authors contributed equally: Xueyang Wang
and Zhenhui Lin. e-mail: xiuqiang.li@nuaa.edu.cn; jiazhu@nju.edu.cn

Nature Water | Volume 1 | April 2023 | 391–398 391


Article https://doi.org/10.1038/s44221-023-00059-8

Solar steam-driven filtration system

RO/NF
Piston Brine membrane

Steam

Pressure

Solar evaporator
Freshwater

Interfacial solar heating

b c 300
1,200

production rate (kg kWh–1)


Theoretical steam

Theoretical water
temperature (K)

1,000
200

800

100
600

400
0
0 10 20 30 0 10 20 30

Solar power density (kW m–2) Solar power density (kW m–2)

Fig. 1 | A schematic and the theoretical water production rate of the b, The theoretical steady-state temperature of steam achieved by interfacial
SSD-RO/NF system. a, A schematic of the SSD-RO/NF system. High-temperature solar heating with ideal thermal insulation. Water was the medium of interfacial
high-pressure steam generated by interfacial solar heating pushes water solar heating to generate steam in the calculation. c, The theoretical water
molecules through the RO/NF membrane to achieve separation from ions. production rate of the SSD-RO method.

RO (PV-RO) (Fig. 1b,c; more details about the model can be found in the thermal conductivity51,52 less than 0.003 W m−1 K−1. The inner wall
Supplementary Figs. 1–6 and Supplementary Note 1). Experimentally of the booster cavity was attached to a waterproof SiO2 nano-aerogel
we achieved up to 81 kg m−2 h−1 under 12 sun illumination by designing felt with thermal conductivity of 0.012 W m−1 K−1 to further suppress
and optimizing the materials, optics, thermals and structures of the heat loss. The transparent glass at the top was made into a double-layer
SSD-RO device. This work is expected to provide a new strategy toward structure, with a vacuum (<5 Pa) between the two glass layers to inhibit
high throughput solar thermal desalination. heat transfer. Also, nylon with low thermal conductivity was selected as
the pressure-sensing piston under the premise of mechanical support.
Design and setup of the SSD-RO/NF device Numerical calculations also show that the expansion ratio of steam in
The design and construction of the SSD-RO/NF device are shown in the booster cavity is an important factor for the water production rate
Fig. 2. This SSD-RO/NF device mainly consists of a booster cavity, pres- of the SSD-RO/NF device. The expansion ratio relates to the amount
sure-sensing piston, seawater cavity, freshwater cavity and cylinder of internal energy of steam converted to mechanical energy for water
(Supplementary Figs. 7 and 8 and Supplementary Tables 1 and 2 for filtration53–55 (Supplementary Fig. 9 and Supplementary Note 2). Con-
the SSD-RO/NF device construction details). The high-temperature sidering the volume of the device and the minimum starting pressure
high-pressure steam is generated by interfacial solar heating in the of the RO/NF membrane, we achieved a maximum steam expansion
booster cavity. Then, the steam pushes the piston below and seawater ratio of 8. Finally, to prevent the condensation of small droplets dur-
through the RO/NF membrane to complete water filtration. According ing evaporation from affecting the transmittance, the inner wall of the
to our theoretical calculations, the thermal insulation performance of transparent glass was treated with O2 plasma and its surface was made
the device determines the temperature and pressure of steam, which super-hydrophilic56 (Supplementary Fig. 10).
further determine the water production rate of the SSD-RO/NF device
(Supplementary Fig. 2). Thus, the thermal insulation of the SSD-RO/ Design of the solar evaporator
NF device has been carefully designed and optimized. Specifically, the To ensure that interfacial solar heating generates high-temperature
vacuum between the sidewall interlayers of the booster cavity and sea- high-pressure steam in the closed booster cavity, in addition to the
water cavity prominently suppresses heat conduction and convection. excellent thermal insulation SSD-RO/NF of the device, the solar evapo-
The vacuum between interlayers was pumped to less than 5 Pa to make rator should provide stable and efficient steam at high temperature and

Nature Water | Volume 1 | April 2023 | 391–398 392


Article https://doi.org/10.1038/s44221-023-00059-8

Pressure
sensor
High pressure steam
Temperature Sink
sensor

Booster cavity

Vacuum insulation Water


Seawater inlet
Sink cavity
Pressure-
sensing piston

Freshwater
RO/NF
cavity/outlet
membrane

Cylinder 20 cm

Fig. 2 | The design and setup of the SSD-RO/NF device. A schematic (left) and to insulate against heat conduction and convection. The pressure sensor and
photograph (right) of the SSD-RO/NF device. The SSD-RO/NF device is composed thermocouples were attached in the booster cavity to monitor the temperature
of a booster cavity, pressure-sensing piston, seawater cavity, freshwater cavity, and pressure of the steam.
RO/NF membrane and cylinder. The vacuum in the sidewall interlayers was used

high pressure. To obtain this unique evaporator, it is essential to care- experimental setup. Thermocouples located at the above evaporator
fully tailor structures for both high temperature/pressure resistance (T-steam) and evaporative ethanol medium (T-bulk) were attached
and heat localization, in addition to general considerations of optical to monitor the internal temperature of the booster cavity. A pressure
design and water supply. We developed an evaporator consisting of a detector (P-steam) is mounted on the upper right side of the booster
top solar absorber and bottom thermal insulator (Fig. 3a). As the pivotal cavity to detect the real-time pressure of steam. The output of fresh-
part of the evaporator, the top solar absorber needs to have microme- water (M-freshwater) was measured by a quality balance. In the proof-
tre-sized pores for vapour escape, efficient solar absorption, water of-concept test, ethanol was chosen as the medium of interfacial solar
supply and high temperature/pressure resistance. Therefore, carbon heating in the booster cavity because the vaporization enthalpy of
foam was chosen as the initial substrate for solar absorber fabrication ethanol is ~920 kJ kg−1, which is much less than that of water, and high
because of its porous structure and high temperature/pressure resist- pressures are more likely to occur at low temperatures59. The transient
ance. To enhance hydrophilicity and solar absorption57,58, the original pressure behaviour of ethanol steam in the booster cavity under various
surface of carbon foam was coated with multi-walled carbon nano- solar power densities is shown in Fig. 4b. The final steady-state pres-
tubes (CNTs). Scanning electron microscopy (SEM) images are shown in sures reached 0.21, 0.34, 0.60, 0.84, 0.97 and 1.12 MPa under 2, 3, 5, 8,
Fig. 3b,c. Water contact angle measurement shows that the surface of 10 and 12 suns, respectively. The experimental steady-state tempera-
the carbon foam/CNTs becomes hydrophilic, which is ideal for efficient ture of steam is shown in Fig. 4c, which agrees well with our COMSOL
water supply (Fig. 3d). Figure 3e suggests that the carbon foam/CNTs simulation. The minor deviations are probably due to uncertainties in
achieves a high solar absorption of 98.7% (from 280 to 2,500 nm) after the experimental measurements and simplifications in the model (see
coating CNTs, compared with the 92.4% solar absorption of the original model details in Supplementary Note 4). Notably, the temperature of
carbon foam (see Methods for more details about fabrication). Due to the bulk ethanol increased only slightly under various solar densities,
the excellent thermal stability of carbon foam/CNTs, after annealing at which means that most energy is utilized for the generation of high-
200, 400 and 600 °C for 2 h successively, its porous structure retains temperature high-pressure steam (Supplementary Figs. 12 and 13).
integrity (Fig. 3f–h), and its solar absorption has been maintained at Then, we studied the water production performance of the SSD-
~98% (Fig. 3e). Thermogravimetry (TG) also provides direct evidence RO/NF device using simulated seawater with 10,000 mg l−1 NaCl. The
of its excellent thermal stability, revealing almost no weight loss below work process of the SSD-RO/NF device is shown in Supplementary
600 °C. The conventional carbon black/non-woven absorber initially Figs. 14–16. The results show that RO membrane filtration started at
decomposes at ~70 °C and almost completely decomposes at ~500 °C 12 suns, and the water production rate reached 81 kg m−2 h−1 (with a
(Fig. 3i). Additionally, a bottom stand should have a low density for ratio of the water production rate to the incident solar flux of
floating and low thermal conductivity for heat localization. After careful 6.75 kg kWh−1). The NF membrane is started at 5 suns, with water pro-
analysis and screening, high-temperature resistant aluminium silicate duction rates of 40, 78.2, 134.5 and 180.4 kg m−2 h−1 under 5, 8, 10 and
foam with a low thermal conductivity of <0.03 W m−1 K−1 was selected 12 suns, respectively (Fig. 4d). Moreover, the SSD-RO/NF device showed
for bottom floating and thermal insulation. In a closed system with an uncompromised stabilized water production rate after six cycles
high solar concentrations, the heat localization of the solar evapora- (Fig. 4e,f). The ion rejections of the SSD-RO/NF device were evaluated
tor is vital to achieving the high temperature of the solar evaporator. under 12 suns with 10,000 ppm feed solutions. The results show that
COMSOL simulations show that the temperature of the evaporator the rejections of Ca2+, Mg2+, SO2− + −
4 , Na and F are 99.98%, 99.96%, 99.98%,
increases by ~100 °C in a closed system when the thermal conductivity 99.5% and 99.97%, respectively, in the SSD-RO device. The ion concen-
of the solar evaporator decreases by an order of magnitude (from 0.4 trations in purified water are below the World Health Organization
to 0.04 W m−1 K−1) (Fig. 3j, Supplementary Note 3 and Fig. 11). standards for drinking water60 (Fig. 4g). The rejections reached 97.6%,
97%, 97.3%, 73.5% and 97.3% for Ca2+, Mg2+, SO2− + −
4 , Na and F in the SSD-NF
Performance of the SSD-RO/NF device device (Fig. 4g). A comparison of the performance of our SSD-RO device
With the desired design of the SSD-RO/NF device and evaporator, the with several recent works on passive solar steam evaporation
performance of the SSD-RO/NF device was next characterized with and condensation is shown in Fig. 4h and Supplementary Table 3. The
a high-powered solar simulator. Figure 4a shows a schematic of the water production rate of the SSD-RO device is much higher than

Nature Water | Volume 1 | April 2023 | 391–398 393


Article https://doi.org/10.1038/s44221-023-00059-8

a b c

Thermal insulator
floating

d e 100 i
100
After contact

Spectral instensity (a.u.)


98
80
Absorption (%)

102.2° Carbon foam

Weight (%)
96 60
Carbon foam/CNTs
After 200 °C
94 After 400 °C 40

After 600 °C Carbon black


20 /non-woven
92
Carbon foam Carbon foam Carbon foam
/CNTs 0 /CNTs
90
500 1,000 1,500 2,000 2,500 25 200 400 600

Wavelength (nm) Temperature (°C)

f g h j

400

Temperature (°C)
300

200
1 sun
2 suns 4 suns
100 3 suns 5 suns
0.01 0.04 0.10 0.40

K (W m–1 K–1)

Fig. 3 | Designs and characterizations of the solar evaporator of the SSD- that the solar absorption of the carbon foam/CNTs remains at ~98%. f–h, SEM
RO/NF device. a, A schematic of the solar evaporator of the SSD-RO/NF device images of the carbon foam/CNTs after high-temperature annealing at 200 °C
that consists of a top solar absorber (carbon foam/CNTs) and a bottom thermal (f), 400 °C (g) and 600 °C (h). Its porous structure retains integrity after high-
insulator (aluminium silicate foam). b, A SEM image of the carbon foam/CNTs. temperature annealing. Scale bar, 500 μm. Inset: optical photos of carbon
Scale bar, 500 μm. c, A high-resolution SEM image of CNTs on the carbon foam. foam/CNTs. Scale bar, 1 cm. i, TG curves of the carbon foam/CNTs and carbon
Scale bar, 200 nm. d, Water contact angles for the carbon foam and carbon black/non-woven. j, The simulated temperature of the solar evaporator with
foam/CNTs, suggesting that the carbon foam is hydrophobic while the carbon various thermal conductivities in the closed system. The dashed lines refer to
foam/CNTs is super-hydrophilic, as a water drop rapidly infiltrates into it in the temperature of the solar evaporator when the thermal conductivity is 0.04
only 2 ms. e, The solar absorption spectra of the carbon foam, carbon foam/ and 0.4, respectively. Much more energy is localized in the solar evaporator
CNTs and carbon foam/CNTs after high-temperature annealing, suggesting with lower thermal conductivity.

state-of-the-art solar steam evaporation and condensation systems. of 144.55 kg m−2 h−1. When the SSD-NF device generated a pressure of
Although not within the scope of this work, it shows similar perfor- 0.7 MPa under concentrated 12 suns on 21 June 2022, the water produc-
mance compared with PV-RO technologies (Supplementary Table 4 tion rate reached 245.07 kg m−2 h−1. The Na+ rejections of the SSD-RO
and Fig. 17). These results indicate that the SSD-RO/NF device is capable and SSD-NF devices are 99.5% and 72% (Supplementary Fig. 19). The
of high water production rates in which RO/NF filtration is driven by NaCl concentration in the feed solution is 10,000 ppm. The water
interfacial solar steam generation. production cost of the laboratory-level SSD-RO desalination system
To further demonstrate the performance in its practical applica- was estimated using the life cycle cost method to be about US$11.79/
tion, an outdoor experiment was conducted in Nanjing, China. As tonne (Supplementary Note 5 and Table 5).
shown in Supplementary Fig. 18, a Fresnel lens was used to concentrate
sunlight onto the device. The real-time solar irradiation during the Model simulation and calculation
experiment was recorded by a meteorological station. When natural To gain insights into the present experiment and obtain a guideline
sunlight was concentrated to 16 suns on 1 July 2022, the SSD-RO device for further improving the water production rate of the SSD-RO/NF
generated a pressure of 1.1 MPa and reached a water production rate device, we used a theoretical model consisting of COMSOL simulation

Nature Water | Volume 1 | April 2023 | 391–398 394


Article https://doi.org/10.1038/s44221-023-00059-8

a b c
200
1.2 2 suns 3 suns 5 suns
8 suns 10 suns

Steam temperature (°C)


150
12 suns

Pressure (MPa)
0.8

P-steam 100

Experimental
0.4
T-steam 50 Simulated

T-bulk 0 0
0 30 60 90 0 2 4 6 8 10 12
Time (min) Solar power density (kW m–2)

d 200 e 100

80

Water production rate


Water production rate
150
SSD-NF

(kg m–2 h–1)


(kg m–2 h–1)
SSD-RO 60
100

40

50
20

0
0
2 4 6 8 10 12 1 2 3 4 5 6
M-freshwater
Solar power density (kW m–2) SSD-RO cycle

f g h
5 suns 8 suns
NF RO 100 Condensation
200 10 suns 12 suns 100

Purified water production


Evaporation
Water production rate

80 Our work

rate (kg m–2 h–1)


150
(kg m–2 h–1)

Rejection (%)

10
60
100
40

50 1
20

0
0
1 2 3 4 5 6 F–
Ca2+ Mg2+ SO42– Na+ 1,000 10,000
SSD-NF cycle
Solar power density (W m–2)

Fig. 4 | Performance of the SSD-RO/NF device. a, A schematic of the SSD-RO/NF device under various solar power densities. e, The water production
experimental setup. The pressure of the steam (P-steam), the temperature of rate of the SSD-RO device under 12 sun illumination over six cycles. f, The water
the steam (T-steam), the temperature of the bulk (T-bulk) and the mass of the production rate of the SSD-NF device under various solar power densities over
produced freshwater (M-freshwater) during the test were carefully monitored six cycles. g, The rejection of five primary ions for the SSD-RO/NF device for
and recorded. b, The real-time pressure of steam in the booster cavity under concentrations in the feed solutions of 10,000 ppm. h, A comparison of the
various solar power densities. c, The measured and simulated steady-state water production rate of the SSD-RO device with previous passive solar steam
temperature of steam in the booster cavity under various solar power densities. evaporation and condensation works. A complete list of the results reported in
The data are presented as mean ± s.d. (n = 5). d, The water production rate of the this graph is given in Supplementary Table 3.

and numerical calculation. The COMSOL simulation takes the thermal illumination. When the expansion ratio is further increased (from 5
insulation of the SSD-RO device as input and predicts the steady-state to 6), the water production rate increases from 124.5 to 131.1 kg kWh−1
temperature of the steam. The numerical model calculates the water under 30 sun illumination. Clearly, further improvements in water
production rate of the SSD-RO device on the basis of the simulated production rate are achieved by further optimizing the thermal
steady-state temperature of the steam. As shown in Fig. 5a (where the insulation and expansion ratio of the device. More details about the
heat transfer coefficient is h = 5 and the emittance ε = 0.86, describ- model can be found in Supplementary Note 4, Figs. 20 and 21, and
ing the actual thermal insulation of our designed device, red line), Tables 6 and 7.
the simulated steady-state temperature is in good agreement with
the experimental measurements (Fig. 4c). It is found that, when we Conclusions
further reduce h and ε, the simulated steady-state temperature of the We successfully developed an SSD-RO/NF device for water purification.
steam and the water production rate increase observably under the After careful designs and experiments, the SSD-RO device is demon-
same solar power density (Fig. 5a,b). For example, when the thermal strated to have a water production rate of up to 81 kg m−2 h−1 under
insulation reaches h = 1, ε = 0.15, the simulated steady-state tempera- 12 sun illumination, much higher than previous works on passive solar
ture is increased from 553 to 646 K, and the corresponding water steam evaporation and condensation. Future devices with better ther-
production rate is increased from 107.1 to 124.5 kg kWh−1 under 30 sun mal insulation designs and a more rational expansion ratio to achieve

Nature Water | Volume 1 | April 2023 | 391–398 395


Article https://doi.org/10.1038/s44221-023-00059-8

a 700 b
h = 1, ε = 0.15, V2/V1 = 6
h = 1, ε = 0.15
140 h = 1, ε = 0.15, V2/V1 = 5
h = 1, ε = 0.86

Predicted water production


Steam temperature (K)
600 h = 5, ε = 0.86 h = 1, ε = 0.86, V2/V1 = 5
h = 5, ε = 0.86, V2/V1 = 5

rate (kg kWh–1)


120
500

100
400

300 80
0 10 20 30 0 10 20 30

Solar power density (kW m–2) Solar power density (kW m–2)

Fig. 5 | Analysis and simulation of the SSD-RO device performance. a, The is described by h = 5 and ε = 0.86 . b, The predicted water production rate of the
simulated temperature of the steam with various thermal insulations, including SSD-RO device with various thermal insulations and expansion ratios. V2/V1 is the
conduction and convection. The actual thermal insulation of the device (red line) expansion ratio.

higher water production rates are desired. It is also believed that this Data availability
strategy could improve the decentralized economic feasibility and The data generated or analysed during this study are included in this
reliability of solar thermal desalination devices and contribute solidly published article and its supporting information files. Source data are
to the global water–energy nexus. provided in this paper. Supplementary figure source data are also avail-
able on Figshare at https://doi.org/10.6084/m9.figshare.22188103.v1.
Methods
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Nature Water | Volume 1 | April 2023 | 391–398 397


Article https://doi.org/10.1038/s44221-023-00059-8

Acknowledgements Additional information


We acknowledge the micro-fabrication centre of the National Supplementary information The online version contains supplementary
Laboratory of Solid State Microstructures (NLSSM) for technique material available at https://doi.org/10.1038/s44221-023-00059-8.
support. J.Z. acknowledges support from the XPLORER PRIZE.
This work was jointly supported by the National Natural Science Correspondence and requests for materials should be addressed to
Foundation of China (nos. 51925204, 52102262, 52003116 and Xiuqiang Li or Jia Zhu.
92262305), Natural Science Foundation of Jiangsu Province (nos.
BK20220035 and BK20200340), National Key Research and Peer review information Nature Water thanks Jianhua Zhou and the
Development Program of China (no. 2022YFA1404704), Program for other, anonymous, reviewers for their contribution to the peer review
Innovative Talents and Entrepreneur in Jiangsu Province and Jiangsu of this work.
Planned Projects for Postdoctoral Research Funds (no. 2020Z018)
and Nanjing University of Aeronautics and Astronautics Startup Fund Reprints and permissions information is available at
(4017-YQR22012). www.nature.com/reprints.

Author contributions Publisher’s note Springer Nature remains neutral with regard to
J.Z., X.L. and X.W. conceived and planned this research. X.W., Y.S., W.Z. jurisdictional claims in published maps and institutional affiliations.
and S.W. did the experiments. X.W., Z.L., J.G., Z.X., N.X., J.L. and H.F.
contributed to the thermal model and theoretical calculation analysis. Springer Nature or its licensor (e.g. a society or other partner) holds
X.W., Z.L., N.X., J.L., B.Z., X.L., R.W. and J.Z. organized the data and exclusive rights to this article under a publishing agreement with
wrote the paper. All authors discussed the results and approved the the author(s) or other rightsholder(s); author self-archiving of the
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terms of such publishing agreement and applicable law.
Competing interests
The authors declare no competing financial interests. Readers are © The Author(s), under exclusive licence to Springer Nature Limited
welcome to comment on the online version of the paper. 2023

Nature Water | Volume 1 | April 2023 | 391–398 398

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