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  • Perhitungan VDW

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    Oktavira Nanda
    9 views19 pages
    The document contains calculations of liquid and vapor molar volumes (Vl and Vv) for hydrogen, methane and water at different temperatures and pressures using the Peng-Robinson equation of state. Vl and Vv values were calculated along with associated percentage errors compared to reference values. In general, errors were lowest for methane and highest for water.

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    The document contains calculations of liquid and vapor molar volumes (Vl and Vv) for hydrogen, methane and water at different temperatures and pressures using the Peng-Robinson equation of state. Vl and Vv values were calculated along with associated percentage errors compared to reference values. In general, errors were lowest for methane and highest for water.

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    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as xlsx, pdf, or txt
    9 views19 pages

    Perhitungan VDW

    Uploaded by

    Oktavira Nanda
    The document contains calculations of liquid and vapor molar volumes (Vl and Vv) for hydrogen, methane and water at different temperatures and pressures using the Peng-Robinson equation of state. Vl and Vv values were calculated along with associated percentage errors compared to reference values. In general, errors were lowest for methane and highest for water.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
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    of 19

    CH4

    Tc 190.555 K P 1037.6 kPa eksperimen


    Pc 4595 kPa T 149.95 K NIST
    Vc 173 cm3/mol
    0.173 L/mol
    R 8.314 L.kPa/K.mol

    a 230.4406 kPa L2/mol


    b 0.043098 L/mol P
    T
    R

    pers kubik menjadi


    v3 - 1.244605 v2 + 0.22209 v -

    1 -1.244605 0.22209 -0.009572


    v1= 1.038095 1.038095 -0.214377 0.008006
    1 -0.20651 0.007713 0

    v2= 0.15756
    V3= 0.048951

    didapat VL 0.048951 L error 9.236%


    VV 1.038095 L
    5.413%
    VL= 0.044812 L
    Vv= 0.98479 L

    1037.6 kPa
    149.95 K
    8.314 L.kPa/K.mol

    0.009572 = 0 v 1.038095
    hasil 0
    CH4

    Tc 190.555 K P 4504.2 kPa eksperimen


    Pc 4595 kPa T 189.9 K NIST
    Vc 173 cm3/mol
    0.173 L/mol
    R 8.314 L.kPa/K.mol

    a 230.4406 kPa L2/mol


    b 0.043098 L/mol

    pers kubik menjadi


    v3 - 0.393621 v2 + 0.051161 v -

    1 -0.393621 0.051161 -0.002205


    v1= 0.159814 0.159814 -0.037366 0.002205
    1 -0.233807 0.013796 0

    v2= 0,116537-0,0119981itdk ada akar real lagi V2= 0.116537 -


    V3= 0,116537+0,0119981i V3= 0.116537 +

    didapat VL 0,116537+L error #VALUE!


    VV 0.159814 L 22.473%
    VL= 0.07898 L
    Vv= 0.13049 L

    0.002205 = 0 v 0.159814
    hasil 0

    0.011998 i
    0.011998 i
    H2O

    Tc 647.286 K P 3.5282 kPa eksperimen


    Pc 22089.75 kPa T 299.96 K NIST

    R 8.314 L.kPa/K.mol

    a 553.1023 kPa L2/mol


    b 0.030453 L/mol

    pers kubik menjadi


    v3 - 706.8689 v2 + 156.766138859 v -

    1 -706.8689 156.766138859 -4.773948


    v1= 0.185396 0.185396 -131.01609181 4.773948
    1 -706.6835 25.7500470515 0

    v2= 706.6471
    V3= 0.03644

    didapat VL 0.03644 L error 101.567%


    VV 706.6471 L 0.146%
    VL= 0.018078 L
    Vv= 705.6200 L

    4.773948 = 0 v 0.185396
    hasil 0
    H2O

    Tc 647.286 K P 20324 kPa eksperimen


    Pc 22089.75 kPa T 640.24 K NIST

    R 8.314 L.kPa/K.mol

    a 553.1023 kPa L2/mol


    b 0.030453 L/mol

    pers kubik menjadi


    v3 - 0.292358 v2 + 0.02721424381 v -

    1 -0.292358 0.02721424381 -0.000829


    v1= 0.141427 0.141427 -0.0213456629 0.00083
    1 -0.15093 0.00586858093 0

    v2= 0,0755377-0,0125369tdk ada akar real lagi V2= 0.075538 -


    V3= 0,0755377+0,0125369i V3= 0.075538 +

    didapat VL 0,0755377L error #VALUE!


    VV 0.141427 L 40.291%
    VL= 0.037568 L
    Vv= 0.10081 L

    0.000829 = 0 v 0.141427
    hasil 0

    0.012537 i
    0.012537 i
    H2

    Tc 32.98 K P 12.979 kPa eksperimen


    Pc 1293 kPa T 15.012 K NIST

    R 8.314 L.kPa/K.mol

    a 24.53051 kPa L2/mol


    b 0.026508 L/mol

    pers kubik menjadi


    v3 - 9.642793 v2 + 1.8900155435 v -

    1 -9.642793 1.8900155435 -0.0501


    v1= 0.044154 0.044154 -0.423815628 0.064738
    1 -9.598639 1.4661999158 0

    v2= 9.443377
    V3= 0.155262

    didapat VL 0.044154 L error 66.737%


    VV 9.443377 L 0.546%
    VL= 0.026481 L
    Vv= 9.3921 L https://webbook.nist.gov/cgi/fluid.cgi?Action=Load&ID=C1333740&Typ

    0.0501 = 0 v 0.044154
    hasil 0
    =Load&ID=C1333740&Type=SatP&Digits=5&THigh=&TLow=&TInc=&RefState=DEF&TUnit=K&PUnit=MPa&DUn
    &TUnit=K&PUnit=MPa&DUnit=mol%2Fl&HUnit=kJ%2Fmol&WUnit=m%2Fs&VisUnit=uPa*s&STUnit=N%2Fm
    Pa*s&STUnit=N%2Fm
    H2

    Tc 32.98 K P 805.74 kPa eksperimen


    Pc 1293 kPa T 30.011 K NIST

    R 8.314 L.kPa/K.mol

    a 24.53051 kPa L2/mol


    b 0.026508 L/mol

    pers kubik menjadi


    v3 - 0.336175 v2 + 0.030444699 v -

    1 -0.336175 0.030444699 -0.000807


    v1= 0.050051 0.050051 -0.014320905 0.000807
    1 -0.286124 0.0161237936 0

    v2= 0.208963
    V3= 0.077161

    didapat VL 0.050051 L error 35.333%


    VV 0.208963 L 8.507%
    VL= 0.036984 L
    Vv= 0.19258 L https://webbook.nist.gov/cgi/fluid.cgi?Action=Load&ID=C1333740&Typ

    0.000807 = 0 v 0.050051
    hasil 0
    =Load&ID=C1333740&Type=SatP&Digits=5&THigh=&TLow=&TInc=&RefState=DEF&TUnit=K&PUnit=MPa&DUn
    &TUnit=K&PUnit=MPa&DUnit=mol%2Fl&HUnit=kJ%2Fmol&WUnit=m%2Fs&VisUnit=uPa*s&STUnit=N%2Fm
    Pa*s&STUnit=N%2Fm
    ComponenT (K) Vl Error Vv Error
    Hidrogen 15.012 0.044154 66.7% 9.443377 0.5%
    30.011 0.050051 35.3% 0.208963 8.5%
    Methane 149.9 0.048951 9.2% 1.038095 5.4%
    189.9 - 0.159814 22.5%
    Water 300 0.03644 101.6% 706.6471 0.1%
    640.24 - 0.141427 40.3%

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