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e .m/t/e.tm .m/t/.(b) e e .m/t/e.tm
/.tm.m/t/e.tm .m(a) Methanol /.tm .m
/ /
t tm
. :
tm. Ethane-1, 2-diol
tm. m/e.tm. me
/.tm.m/t/e.tm
.m .mt.m
t /.tm .m
s: /:p/sts:/: (c) Ethanol s : /:/psts:/: p ss:/t:pss:/ (d) Glycerols:/:/t/.s:/:/t s : /:p/sts:/: s://s:// s : /:/psts:/: s
tptphsttpt p s
tpt ht tpt t
tphttp tphst tptps tptphsttpt ttp ttp p s
tpt ht tpt ttpht
h t h t h t h t p h t ht
h h h h h hht h h [ hv¸¨¦P h h h h h
A / Turn over

b b b ebb b ebb e b b ebb b ebb b ebb

e b e b eb eb e w e w e e b eb
i w evwiwe v i
w weviwiw e
v i i
w e
wviwi w vi i viw
w uv
i
i w evwiwe v i
w weviwiwe iw
w i w i
r
u uvavriuruvi a r rulvaruruv
u a r rulvaruruv
u l ar uriualvarur r
u uvavriuruvi a r r
u uvaruruv ruvru
ar lial
i i lialmilia i lialmilia m i i
lamil lial ar lial
i i lialmilial ila ila
mm m mam am am i m m
tam/atam /atam/at t/at t/at ammtam tam/atam amtam
 bbeebb ee bbee ee bee eewwee bbeebb eebbee
ee w w w i ww i i ee w
iwvviw
vvriuw iw vviwiwvviiw vvriuw
iwvvii uu vvruiuvv viwiwvviw iw vv iwvviiw
iw
u u
rrlualarr u u uu
rrlalar u rrilala r v
uuarruu rru u
uaarru
aar a
ilima
l ii l
iimaa
l ii i lal
imma i i
rr
lialailila a
ilima l
l i il
mm m m
m m m
m mmtaam
t//taea//ttaa t//taea//ttaa //ttaea//ttaa aammtaamm
tte//t aa
/e/ ee//t
tt //ttae
eem e eem e eem e /
eem e/ e e e
t ..mm
6622tt.. m tt.mm/tt..m
. //t..m/m//tt..m 6
t ..mm t .. m tt..m/m//tt..mm tt..m/m//tt..mm
// t / // // // / / / : : / tt /
// ::/// t //
//ss::/ //
:://ss::/
ss:://ss::/ ss:://ss:: ss :: ss
pp : /
: / s ss: : ss
ttttphpttttpp 15. K›øn¯ ttttphpttttpA«ßPÒ
h
p A÷µõ÷©iU
hh ttttphphtttt BÀiøíkhß t t
t ppststttpps ÂøÚ¦›¢x
t t ttphpttttpp öPõkUS® ttttphphttttpp
t
hh h hh
ÂøÍö£õ¸Ò : hh hh hh h hh

b b b b (A) æL¨ Põµ® bbeebb bbeebb(B) Põº£õU]¼U e e bbeebAª»® b bbeebb bbeebb

ee e e e e ee w w w i w w ee e e
v viwiwvviw iw (C) Rm÷hõß vv iwiwvviw iw vv iwiwvviiw (D) A÷µõ÷©iU
u u u vvriuiuvvi Aª»® vviw i wvviw iw vv iwiwvviw
u
iw
rrulualarru u rrulualarr u alarriliala r uuarruu rrulualarru
riulualarruu l a
l a
iproduct i i i l al
ithe a i i i l
i a a rr l l a l
iimiia
l a
i imm m m reaction of anm m m m aldehydeilim l ii primary amines
m aa//ttaam
The mm formed by m Aromatic
a a with m m
m ttaea/:/ttaa ttaea//ttaa / /ttaea//tt aa mmtaam tt
eem e/ /
is /
eem e / eem e tt
// ee/ / t /
eemee / eem
m m m . m m . . m eem m m m m
m m
/:://s/tst::////t
.
.. t . (a) Schiff’s base .. tm
/:://s/tst::////t
. .
:
.
///s/tst::/(b)
:
tt
/// Carboxylic///tacid ..m/m//tt..m
t / //
m .
t/ t.:.////tt. / /
/ /tt.:.////tt..
p sstpp (c) Ketone pp sstpp ttppsstpp
t t s s ::/ss::/
p sst:p:pss: pp sst:p:pss:
p
tt t t tt t t hhtt hh t ttphpttttp p p
tttthhttt tttthhttt
hhtt hht
(d) Aromatic acid
hhtt hht hh ht t h h h h
bb b b bbeebb bbeebb e e bbeebb bbeebb bbeebb
ee e e ee ee w w w i w w e e e e
v v iwiwvviw iw vv iw iwvviw iw v v iwiwvviiw
u
£Sv & II/PART
uu vvriuiuvvi
- II
v vi w
i wvviw iw vv iwiwvviw
u
iw
uaarruu SÔ¨¦ : aarH÷uÝ® u
riulualarru BÖ ÂÚõUPÐUS rrulualarr u alarrilialar ÂÚõ Gs uuarru&US u Pmhõ¯©õP rrulualarru
l l a
l a i Âøh¯ÎUPÄ®. i l
i r r
24 a la a
l l i
iimÂøh¯ÎUPÄ®.imm
m m
i i m m mm a
ilim a
l i il l immii
l
i6x2=12
m m m aa m m
/ /ttaea//ttaa / ttaea//ttaa
/ e e e //ttaeae//tt / t
/ aam/m/ttaam
t / ttaea//ttaa
/ //tt
ee e ee eem e e e e e ee
t . .mm/tt..mm: Answer tany
Note
.
t .mm/tt..mm six questions. .Question
/ t
/ t .m/m///tt..mm No. 24 is..mmCompulsory. t . . m tt..mm/tt..mm t .
t mm/tt..mm
.
: :
t
///s/s::// / : : /
//s/s::// /
ss
/
::/ss:: : // t
//t:://// t : /
//s/s:://
:
/ : ://ss::///
/ /
ss sstpp p :
sstppss s
pptstt?tpp AzuøP¯ ttttppttttpp ss
t ttphpttttpp 16. GÆÁøP
t t tttphptttuõxUPøÍ h ttttphphttttp t t p
t p t t t t t
t t
hh h hh h h
Ahº¨¤UP, ~øµªu¨¦
hht hh •øÓ HØÓx hh hh hh hh
uõxUPÐUS C¸ GkzxUPõmkPÒ u¸P.
b ebb Which type ebofbeebores b b ebb eb b ebb b?ebbGive two b ebb
e b e b e w e w e e b e b
i
w w evwiwe
i vi w e
iwviwi w can be
vi w w e
i viwi w
concentrated by froth
uv vi i
wuvviw i
floatation method
i
w w evwiw
i
e
vi iwviwi e iwv
w e w
vi v
uriualvaruru
examples
a r rulvarurfor
u uv such ores. uruv uruv
a r l ar i l ar urialarur r
u uvavriuruv ar rulvaruruv ruvru
u
l lialmilia l l
iamila i i a
l mil ialarilial lialmilia ila ila
i m i m l
iamm i
m
/ a
m
taem/t/atam /ataem/t/atam t/ataem/t/at
am
t amm /at /at amm t/ atam tam/tam
t t e/ /a
t ee/t t
e/mee/ e/ e /
17.
. m etem/m
. e
]¼÷PõßPÎß . m
/me
etem
£¯ßPøÍ
. GÊxP.tm . m/e.tm . me
m e e/m
. m e . m . m etem.
: /t/.st:m/:/t/. :/ t/.st:m/:/t/. s :/t/.s:/:/t
/ t/ tm
. . /t/.tm
:
.
: /t/.tm/:/t/.tm //t.m//t. : / t/.st:m/:/t/.
/ / : :/
s:/tpss:/ / s : /
t p
s:
tphsttptps
Write the p
t p ss:tptps of Silicones. tptphsttptps
tuses t ps t p t t
p psst:ptps: tpst:ps t pt pss:tptps tp
hht h hht hh
t hht h h t tpht
h ht h ht ht ht h ht hht ht h
h h
b ebb18. AønÄa eb÷\º©[PÎÀ b ebb ø©¯ebbAq eb b GߣuøÚ Áøµ¯ÖUPÄ®. e b b ebb b ebb b ebb
e b e w e w e e b eb
i
w w evwiwe
i vi w e
iwviwi w e
vi w e
iwviwi w
uv vi i
wuvviw i
wi w evwiwe
i v i iwviwi e iwvei
w e w
uvavriuruv Define
a r rulvathe
u r uruv term centrallaruratom uvaruruv in co-ordination
l l ar urialarurcompounds. uruvviuruv a r rulvaruruv ruvru
u
a lialmilia liamila i i i
a
l mil i larilial a r lialmilia ila ila
i m i m l a
iamm i
m
tt aem/t/atam taem/t/atam /ataem/t/at
am
amm amm tam tam/tam
e/ / a e/t/a
e e e/ t
m e e/ t/at e/ t/at
/
e t/at e/ t/a / e e/ t/ate
e .m/t/e.tm m/.tm e e .m/t/e.tm
/.tm.m/t/e.tm
19. .mFCC A»SU /.TmiÀ tm .m Põn¨£k®/.tm
/ t
.AqUPÎß
: / t
. GsoUøP°øÚU
tm. m/e.tm . me PnUQkP.
/.tm.m/t/e.tm
.m .mt.m
t /.tm .m
s: /:p/sts:/: Calculatepsthe s : /:/psts:number
/: p ss:/t:psins:/ an FCC unit s:cell. /:/t/.s:/:/t s: /:p/sts:/: s://s:// s : /:/psts:/: s
tptphsttpt tpt ht tpt
of atoms t
tphttp tphst tptps tptphsttpt ttp ttp p s
tpt ht tpt ttpht
h t ht h t h t p h t ht
h h h h h hht h h h h h h h h
A
b b b ebb b ebb e b b ebb b ebb b ebb
e b e b e b eb e w e w e e b eb
i w evwiwe v i
w weviwiw e
v i i
w e
wviwi w vi i viw
w uv
i
i w evwiwe v i
w weviwiwe iw
w i w i
r
u uvavriuruvi ar rulvaruruv
u a r rulvaruruv
u l ar uriualvarur r
u uvavriuruvi a r r
u uvaruruv ruvru
ar lial
i i lialmilia i lialmilia m i i
lamil lial ar lial
i i lialmilial ila ila
mm m mam am am i m m
tam/atam /atam/at t/at t/at ammtam tam/atam amtam
 bbeebb ee bbee ee bee eewwee bbeebb ee bbee
ee w w w i ww i i ee w
iwvviw
vvriuw iw viw
v iwvviiw vvriuw
iwvvii uu vvruiuvv viwiwvviw iw vviwiwvviiw
u u
rrlualarru u uu
rrlalar u rrilala r v
uuarruu rruuaarruu
aar a
ilima
l ii l
iimaa
l ii i lal
imma i i
rr
lialailila a
ilima l
l i il
mm m m
m m m
m mmtaam
t//taea//ttaa t//taea//ttaa //ttaea//ttaa aammtaamm
tte//t aa
/e/ ee//t
tt //ttae
eem e eem e eem e /
eem e/ e e e
t ..mm tt.. m tt.mm/tt..m
. //t..m/m//tt..m 7
t ..mm t .. m tt..m/m//tt..mm 6622 t..m
t m//tt..mm
// t / // // // / / / : : / tt /
// ::/// t //
//ss::/ // /
:://ss::/
ss:://ss::/ ss:://ss:: ss :: ss
pp : /
: / s ss: : ss
ttttphpttttpp 20. Cøn ttAª»&Põµ ttphpttttpp CµmøhPÒ hh ttttphphtttt GßÓõÀ GßÚttttpp?ststttpps t ttphpttttpp
t ttttphpttttpp
hh h hh h hh hh hh h hh h
What is conjugate Acid-Base pairs ?

b b b b bbeebb bbeebb e e bbeebb bbeebb bbeebb

ee e e e e e e w w w i w w ee e e
iwiwvviw iw21. ÂøÚ÷ÁP©õØÓ v v iwiwvviw iw |a_PÒ GßÓõÀ vv iwiwvviiw GßÚ ? uvviuiuvvi i w
i wvviw iw v v iwvviw
iw iw
v v rrulualarru u rrulualarr u u u rr v v rrulualarru u
riulualarruu l a a l a
l a i i l
i alarriliala rruuarruu
a l a a
i What l i i
iimare catalytic poisons i imm ? i mm m m a
ilim a
l ii l l iimiil
m
/ /
mm
ttaea//ttaa
m
/ /
mm
ttaea//ttaa / ttaea//tt
/ e
a a
t a
t a mmtaam
/ t //ttaa//ttaam
mm
eem e eem e eem
m eem// ee/ eemee eem
m m m . mm . . m m mm
/:://22.
m m . .
/tt.:.:////tt A]m÷hõøÚ //// :
m
..///tt
ttGÆÁõÖ
/
. .
¦÷µõ¨÷£ÚõP : /
: /
. t t
//tt:://// ©õØÖÁõ´ ?//tt..m/m//tt..m / / t
/
m
..///tt.
t /
.
/ /
/ tt.:.////tt..
/
p sstppss pp sst:p:pss: ttpp sstppss
t t s s :://ss::/
p p p sst:p:p/ss:: pp sst:p:pss:
hhtt hht
p
tt t t How will ttyou tt t t
hh hht convert acetone hhtt hinto t
h propane ? httttphphttttp h tttthhttt h h tttthhttt
h h
bb b b b b bb bbeebb e e bbeebb bbeebb bbeebb
e e e e 23. íõº÷©õßPÒ ee ee GßÓõÀ GßÚ ee?w Euõµn® u¸P. w w i w w e e ee
v v iwiwvviw iw v viwiwvviw iw v v iwiwvviiw
u uu vvriuiuvvi v vi w
i wvviw iw vv iwiwvviw
u
iw
uaarruu Whatrruare u
uaarruHormones ? aGive u
rrulualarr example. ilalarrilialar uuarruu rrulualarru
lala i l
i l i l l a i i i a a r r l a la
iimiila
l iim imm m m mm iliml i il
/ /
m m
ttaea//ttaa
m
//
m m
ttaea//ttaa / ttaea//tt
/ e
aa
t a
t a mmtaam
/ t / /ttaa//ttaam
m m
//tt
eem¤ßÁ¸® e eem e eem eem/ / e e / e e ee e e
t .
24.
.mm/tt..m ÂøÚÁ›ø\°À
tt.mm/tt..m
.
EÒÍ
/ t
/ ..m/m//tt..m
t
A ©ØÖ® B ÷\º©[PøÍU
. m
. m t . . m
PshÔP.
t .
t mm/tt..mm
. t .
t mm/tt..mm
.
: :
t /
///s/s::// CH3CH2 NO : : /
//s/s→ /
:://Sn/HCl A  /
CH:3:COCl
ss
/ss:: → B/
: // t
//t:://// t : /
//s/s:://
:
/ : ://ss::///
/ /
ss ss p :
sstppss s
pptstttpp ss
ttphpttttpp ttphpttttpp ttttphphttttp ttphpttttpp
2
t t tt h h t t p
t p t t t t t
t t t t
hh h Identify hh the h compounds A and B in the following hht hh sequence of reactions. hh hh hh h
b ebb CH3CH2 NO2ebb→ b b
Sn/HCl
A 
CH3COClb
b eb → B eb b ebb b ebb b ebb
e b e e b e w e w e e b e b
i
w w evwiwe
i vi w e
iwviwi w e
vi w w e
i viwi w
uv vi i
wuvviw i
i
w w evwiw
i
e
vi wiwviwi e iwv
e w
vi v
uriualvaruru a r rulvaruruv
u a r rulvaruruv
u i l ar urialarur r
u uvavriuruv ar rulvaruruv ruvru
u
l lialmilia l l i
iamila £Sv & III /mPART i a
l mil - III ialarilial lialmilia ila ila
i m i l
iamm i
m
/ a
m
taem/t/:atamH÷uÝ® BÖt/atÂÚõUPÐUS amt/atam /ataem/t/at
t
am
t amm / t
a /at ammt/ atam tam/tam
SÔ¨¦ /met e/me e/ e
Âøh¯ÎUPÄ®. / ÂÚõ /a
t ee/t
Gs &US Pmhõ¯©õP t
e/mee/ e/ e e/
etem me
etm 33
m . m e . . m . e e/m m e . m e .
. Âøh¯ÎUPÄ®. . t
/.tm/:/t/. m t m
/t/.s:/:/t /. m
. /t/.tm. .
tm:/t/.tm /t6x3=18 m/t. m .
tm:/t/.m t
//: t/.st:m/:/t/. :/ t
s:/pss: six questions.
:
/
s: s / t
. m
/ts:/:Compulsory. s:/:pss:/ s:/ s: / /
t . . / :/ t/
s:/tpss:/
.
s:
ttpphsttptpsNote : Answer ttpphst tptany tphsttptpQuestion s:/t:is
p s ps t ps
ht ht ht t p
h
No. 33
t p p s
t ht tp ht
t
tphttp ttp tt p
ht tpht tp ttph
t
h h h h h hht h h h h h h h h
25. L¤èåº m÷µõ¨è öuõS¨¦ •øÓø¯ £ØÔ SÔ¨¦bÁøµP.
b b b ebb b ebb e b b eb b ebb b ebb
e b e b eb eb e w e w e e b eb
i
w w evwiwe
i
Write a
vi iwviwi
note
w e w e on Fischer tropsch
vi w e
iwviwi w synthesis.
uv vi i
wuvviw i
wi w evwiwe
i v i iwviwi e iwvei
w e w
uvavriuruv a r rulvaruruv
u a r rulvaruruv
u i l ar urialarur r
u uvavriuruv a r rulvaruruv ruvru
u
a lialmilia l l
iamila i i a
l mil i
a larilial lialmilia ila ila
i m i m l
mtiamm÷ÁÖ£õkPÒ tamm/atam amam i
26. ta mm / a am
»õ¢uÚõ´kPÒ,
t at amt/atam
BUiÚõ´kPÒ & CÁØÔØS /
t taem/t/atam Cøh÷¯¯õÚ
a am t/ate
e/ /a
t eH÷uÝ®
e / t ‰ßÔøÚ /
et/
e e / GÊxP. e e/ m e e/ t/at e/ t/a /
e t/aee/t e/t e/t e/
/ t
.m.m/t/e.tm .m /.tm.m/t/e.tm
.m
/ /
t tm
. .m/t/.tm
:
.
tm. m/e.tm. me
/ t
. .m/t/e.tm
m .m .mt.m /.tm.m/t/e.tm.m
/:/psts:/: differences between s:/t:pss:/ Lanthanoids :/t Actinoids. s:/:/ts:/: ://s://
:/t/.s:and t /:/psts:/: s
s: /:p/sts:/: Write anypss:three t p s s: / / p s s p ss :
h t tptphsttpt h t tpt ht tpt h t tphttp
h t tphst tptps
p h t tptphsttpt ttp ttp ht tpt ht tpt ttpht
h h h h h hht h h [ hv¸¨¦P h h h h h
A / Turn over

b b b ebb b ebb e b b ebb b ebb b ebb

e b e b eb eb e w e w e eb eb
i w evwiwe v i
w weviwiw e
v i i
w e
wviwi w vi i viw
w uv
i
i w evwiwe v i
w weviwiwe iw
w i w i
r
u uvavriuruvi a r rulvaruruv
u a r rulvaruruv
u l ar uriualvarur r
u uvavriuruvi ar r
u uvaruruv ruvru
ar lial
i i lialmilia i lialmilia m i i
lamil lial ar lial
i i lialmilial ila ila
mm m mam am am i m m
tam/atam /atam/at t/at t/at ammtam tam/atam amtam
 bbeebb ee bbee ee bee eewwee bbeebb ee bbee
ee w ww i ww i i ee w
iwvviw
vvriuw iw viw
v iwvviiw vvriuw
iwvvii uu vvruiuvv viwiwvviw iw vviwiwvviiw
u u
rrlualarru u uu
rrlalar u rrilala r v
uuarruu rruuaarruu
aar a
ilima
l ii l
iimaa
l ii i lal
imma i i
rr
lialailila a
ilima l
l i il
mm m m
m m m
m mmtaam
t//taea//ttaa t//taea//ttaa //ttaea//ttaa aammtaamm
tte//t aa
/e/ ee//t
tt //ttae
eem e eem e eem e /
eem e/ e e e
t ..mm
6622tt.. m tt.mm/tt..m
. //t..m/m//tt..m 8
t ..mm t .. m tt..m/m//tt..mm tt..m/m//tt..mm
// t / // // // / / / : : / tt /
// ::/// t //
//ss::/ //
:://ss::/
ss:://ss::/ ss :://ss:: s s:: ss
pp : /
: / s ss: : ss
ttttphpttttpp 27. [Pt(NO2t)(H ttphpt2tttpO)(NH
t
p
3)2]Br GßÓ hh ttttphphtAønÂÀ
ttt t t
t ppststttpps
¤ßÁ¸ÁÚÁØøÓU
t t ttphpttttpp
PshÔP.
t ttttphpttttpp
hh h hh h hh hh hh h hh h
(A) ø©¯ E÷»õP Aq/A¯Û
b b b b (B) AønÄ bbeeGs bb bbeebb e e bbeebb bbeebb bbeebb
ee e e e e e e w w w i w w ee e e
v viwiwvviw iw v v iw
iwvE÷»õP
v iw iw vv iwiwvviiw
u u u vvriuiuvvi v vi w
i wvviw iw v v iwvviw
iw
u
iw
(C) ø©¯
rrulualarru u A¯Û°ß rrulualarr u BU]á÷ÚØÓ Gs
alarriliala r uuarruu rrulualarru
riulualarruu l
ithe a
l a i i i l a
l a i i
im2m)(H2O)(NH3)2]Brmmidentify i l
i a a rr l l a l
iimiia
l a
i imm complex, [Pt(NO m m iliml ii
m aa//ttaam
For m m a the following. m
m m a//ttaa ttaea//tt a mmtaam m
/ / taeae//ttaaCentral metal
t(a) /
eemee
ttaatom/ion
/ eem / / e t a
t
// ee/a / t /
eemee /tt eem
eem m m m . . m eem m m
m m
.. t . . m m m
.. t . . .
tt /. tt ./ .m/m//tt..m m m .
t/ t.:.////tt. m
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/ /
p sstpp (c) Oxidation pp sstpp ttpp t ttpp s s :://ss::/
p s s :: ss:
p p pp sst:p:pss:
p
tt t t t
tt t number of central t
hhtt hh metal ion hhttttphphttttp p p
tt t t t tt t t
hhtt hht hhtt hht hhtt hht hhtt hht

bb b b bbeebb ªß Cµmøh bbeAkUS bb e e bbeebb bbeebb bbeebb

ee e e 28. öíÀ®÷íõmì ee ee w e £ØÔ SÔ¨¦ w w i w w ÁøµP. e e e e
v v iwiwvviw iw v viwiwvviw iw v v iwiwvviiw
u uu vvriuiuvvi v vi w
i wvviw iw vv iwiwvviw
u
iw
uaarruu Writerrua u
uaarrnote u on Helmholtz u
rrulualarrelectrical double ar
alarriliallayer. uuarruu rrulualarru
lala i l
i l i l a
l a i i i l
i a a r r l a la
iimiila
l iim imm m m mm iliml i il
/ /
m m
ttaea//ttaa
m
/ /
mm
ttaea//ttaa / ttaea//tt
/ e
aa
t a
t a mmtaam
/ t / t
/ aa//ttaam
t
m m
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ee e ee e ee GÊxP. ee / / e e / e e e e ee
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/
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: // t
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:
/ : ://ss::///
/ /
ss ss p :
sstppss s
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t ttphpttttpp
t ttttphpttttpp h h ttttphphttttp t t p
t p t t t t t
t t t tttphpttttpp
hh h hh h hht hh hh hh hh h
b e30. b _Âmhº A¯Û b ebbJßÔß Aø©¨ø£z b ebb u¸P. eb b ebb b ebb b ebb
e b b e b e b e w e w e e b e b
i
w w evwiwe
i Give the vistructure w e
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i viwi ion.
uv vi i
wuvviw i
i
w w evwiw
i
e
vi wiwviwi e iwv
e w
vi v
uriualvaruru a r rulvaruruv
u a r rulvaruruv
u i l ar urialarur r
u uvavriuruv ar rulvaruruv ruvru
u
l lialmilia l l
iamila i i a
l mil ialarilial lialmilia ila ila
i m i m l
iamm i
m
31. t/GzvÀ a
m
taem/t/atam A]m÷hmøh /a am
taem/t/atGÆÁõÖ GzvÀ t taem/t/atam
/aA]m÷hõ A]m÷hmhõP t amm /at ©õØÖÁõ´ /at?amm t/ atam tam/tam
t e/ /a
t ee/t t
e/mee/ e/ e /
. m etem/me
. . m
/me
etem
. t .
m m/e.tm . me
m e e/m
. m e . m . m etem.
: /t/.st:m/:/t/. How will you :/ .tm/:/t/. Ethylacetate
t/convert s :/t/.s:/:into
/ /t Ethylaceto /acetate
t . . /t/.tm
tm:
. ?
: /t/.tm/:/t/.tm //t.m//t. : / t/.st:m/:/t/.
/ / s: : :/
s:/tpss:/ / s : /
t p
s:
tphsttptps t p
s:
tphst tptps t tphsttptps
p t ps t p t t
p psst:ptps: tpst:ps t t
p pss:tptps tp
hht h 32. EnÄ h£uÚ¨ ht h hht h h t tpht
h ht h ht ht ht h ht hht ht h
ö£õ¸mPÒ GߣøÁ ¯õøÁ ?h C¸ h GkzxUPõmkPÒ u¸P.
b ebb What are food b ebbpreservatives ?ebbGive eb b e b b ebb b ebb b ebb
e b eb e two examples. w e w e e b eb
i
w w evwiwe
i vi w e
iwviwi w e
vi w e
iwviwi w
uv vi i
wuvviw i
wi w evwiwe
i v i iwviwi e iwvei
w e w
uvavriuruv a r rulvaruruv
u a r rulvaruruv
u i l ar urialarur r
u uvavriuruv a r rulvaruruv ruvru
u
a lialm i lia l l
iamila i i a
l mil ÷uøÁ¯õÚlial÷|µ©õÚx ar lial lialmilia ila ila
i m i m mtiamm i i
33. J¸
tt a90%mm •uÀ
tam{øÓÁøh¯z
ÁøP ÂøÚ¯õÚx
tam
taem/÷uøÁ¯õÚ
99% {øÓ Eøh¯m
ataem/t/ata ÷£õ» Cµsk
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amm tam tam/tam
e/ / a e / /
t a e/t/a
e
t/a ÷|µzøu¨ e e/ t
m
/
e e/ t/at am
e/ t/a©h[S GÚU PõmkP.
/
e t/at e/ t/a / e e/ t/ate
e m/e.tm .m/t/.tm e e .m/t/e.tm
/.tm.m/t/e.tm .m /.tm.case
/t
.m
/ /
t m
treaction
. :
.
tm. m/e.tm. me
/.tm.m/t/e.tm
.m .mt.m
t /.tm .m
s: /:p/sts:/: 99% is twice
Show that
s : /:/psts:the
in
/: of first order
p ss:/t:pss:/ the time
s: /:/t/.s:of/:/t 90% of the reaction.
required for the
s: /:p/sts:/: s://s://
completion of
s : /:/psts:/: s
tptphsttpt p s
tpt ht tpt time required t
tphttp for the completion
tphst tptps tptphsttpt ttp ttp p s
tpt ht tpt ttpht
h t h t h t h t p h t ht
h h h h h hht h h h h h h h h
A
b b b ebb b ebb e b b ebb b ebb b ebb
e b e b e b eb e w e w e e b eb
i w evwiwe v i
w weviwiw e
v i i
w e
wviwi w vi i viw
w uv
i
i w evwiwe v i
w weviwiwe iw
w i w i
r
u uvavriuruvi a r rulvaruruv
u a r rulvaruruv
u l ar uriualvarur r
u uvavriuruvi a r r
u uvaruruv ruvru
ar lial
i i lialmilia i lialmilia m i i
lamil lial ar lial
i i lialmilial ila ila
mm m mam am am i m m
tam/atam /atam/at t/at t/at ammtam tam/atam amtam
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ee w ww i ww i i ee w
iwvviw
vvriuw iw vviwiwvviiw vvriuw
iwvvii uu vvruiuvv viwiwvviw iw vviwiwvviiw
u u
rrlualarr u u uu
rrlalar u rrilala r v
uuarruu rruuaarruu
aar a
ilima
l ii l
iimaa
l ii i lal
imma i i
rr
lialailila a
ilima l
l i il
mm m m
m m m
m mmtaam
t//taea//ttaa t//taea//ttaa //ttaea//ttaa aammtaamm
tte//t aa
/e/ ee//t
tt //ttae
eem e eem e eem e /
eem e/ e e e
t ..mm tt.. m tt.mm/tt..m
. //t..m/m//tt..m 9
t ..mm t .. m tt..m/m//tt..mm 6622 t..m
t m//tt..mm
// t / // // // / / / : : / tt /
// ::/// t //
//ss::/ // /
:://ss::/
ss:://ss::/ ss:://ss:: ss :: ss
pp : /
: / ss ss: : ss
ttttphpttttpp ttttphpttttpp hh ttttphpht£Sv
ttt & IV/PART t t
t ppststt-tppIV
t t ttphpttttpp
t ttttphpttttpp
hh h hh h hh hh hh h hh h
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b bee b b b b b b bb e b b e e b b e e b b b b bbeebb
ee e e e e ee w e w w i w w ee e e e e
v viwiwvviw iwNote : Answer v v iwvviw
iw iwall the questions. vv iwiwvviiw
u u u vvriuiuvvi v vi w
i wvviw iw v v iwvviw
iw
u
iw
rrulualarru u rrulualarr u alarriliala r uuarruu rrulualarru
riulualarruu l
iim al a i i i l a
l
imm a i i i l
i a a rr l l a l
iimiia
l a
i mm m m iliml ii
m
/ /
mm
ttaea//ttaa
m
/ /
mm
ttaea//ttaa / ttaea//tt
/ e
a a
ttaa mmtaam
/ t / /ttaa//ttaam
m m
34. ee(A) e ¦»zy´ø©¯õUPÀ eem e •øÓ°øÚ eemJ¸ GkzxUPõmkhß
m eem// ee/ ÂÁ›UPÄ®.ee ee eem
m m m m . mm . . m mm m m
m m
.. t .
/:://s/tst::////t
. .. tm
/:://s/tst::////t
. .
::
. t
///s/tst:://// t
/ ./ .m/m//tt..m
t t / //
m .
t/ t.:.////tt. / /
/ /tt.:.////tt..
p sstpp p p sstpp ttppsstpp AÀ»x ss:://ss::/
t t p sst:p:pss: pp sst:p:pss:
p
tt t t tt t t hhtt hh t ttphpttttp p p
tttthhttt tttthhttt
hhtt hht hhtt hht hh ht t h h h h
(B) (i) ¤ßÁ¸® ÷\º©[PÎÀ íõ»áßPÎß BU]á÷ÚØÓ b {ø»ø¯U
bbeebb bbee b b bbee b b b
eewweeb b bbeebb bbeebb
ee ePsk¤iUPÄ®.
e ee w w w i e e e e
v v iwiwvviw iw v v iwiwvviw iw v v iwiwvviiw
u uu vvriuiuvvi v vi w
i wvviw iw vv iwiwvviw
u
iw
uaarruu u
rrulualarru(1) OF2 laarriulualarr (2) I2O4 ilialarrilialar u uuarruu rrulualarru
lala i i i l i a a r r l a la
iimiila
l iim imm m m mm iliml i il
/ /
m m m
ttaea//ttaa (ii) ¤ßÁ¸® / /
m m
ttaa
ttaea/ÂøÚPøÍ
/ / ttaea//tt
/ e
aa
t a
t a mmtaam
/ t / t
/ aa//ttaam
t
m m
//tt
eem e eem e §ºzv eem ö\´P. eem/ / e e / e e e e ee
t . .mm/tt..m tt..mm/tt..m /t
/ t..m/m//tt..m . m
. m t . . m tt..mm/tt..mm t .
t mm/tt..mm
.
: :
t
///s/s::// / : : / /
//s/s:://P +NaOH+H sOs::/→ / s s :: /
: // t
//t:://// t : /
//s/s:://
:
/ : ://ss::///
/ /
ss s s p :
sstppss s
pptstttpp ss
ttttphp2httttp
(1)
t ttphpttttpp
t t tttphpttttpp 4 h h t t p
t p t t t t t
t t t tttphpttttpp
hh h hh h
(2) XeF6+H2O →
hht hh hh hh hh h
b ebb b ebb b ebb eb b ebb b ebb b ebb
e b e b e b e w e w e e b e b
i
w w evwiwe
i vi w e w e
iw(3)viwi Cu+Ahº Hv2iwiSOviwi4 → w e w
uv vi i
wuvviw i
i
w w evwiw
i
e
vi wiwviwi e iwv
e w
vi v
uriualvaruru a r rulvaruruv
u ar rulvaruruv
u i l ar urialarur r
u uvavriuruv ar rulvaruruv ruvru
u
l ilia l i
iamilaprocess with an a
ilamm il larilial ialmilia ila ila
l (a)miliaExplain m zone refining m i l m example. li
iamma i l
m
/ taem/t/atam
a /ataem/t/atam /ataem/t/at
t t amm /at /at amm t/ atam tam/tam
t t e / /a
t ee/t t
e/mee/ e/ e /
. m etem/me
. . m
/me
etem
. t .
m m/e.tm. mOR e
m e e/m
. m e . m . m etem.
: /t/.st:m/:/t/. :/ t/.st:m/:/t/. s /:/t/.s:/:/t t/ . . /t/.tm
tm:
.
: /t/.tm/:/t/.tm //t.m//t. : / t/.st:m/:/t/.
/ / : :/
/pss:/following compounds. / s : /
t p
s:
tphsttptps (b) (i) tptFind pss:tptps the oxidation tptstate pstptps of Halogen inpss:the
ht t t t
p t t
p psst:ptps: tpst:ps t t
p pss:tptps tp
hht h hht hh
t hht h h t tpht
h ht h ht ht ht h ht hht ht h
(1) OF2 (2) I2O4
h h
b ebb b ebb b ebb e b b ebb b ebb b ebb
e b e b eb e w e w e e b eb
i
w w evwiwe
i
(ii) w
vi
e
iwvComplete
i i
w w e the following
vi w e w
iwviwi reactions. viwuvviw
uv
i i
wi w evwiwe
i v i iwviwi e iwvei
w e w
uvavriuruv ar rulvaruruv
u a r rulvaruruv
u i l ar urialarur r
u uvavriuruv a r rulvaruruv ruvru
u
a lialmilia (1) P4+NaOH+H l l i
iamila 2O → i a
l mil ialarilial lialmilia ila ila
i m i m l
iamm i
m
tt aem/t/atam taem/t/atam /ataem/t/at
am
amm amm tam tam/tam
e/ / a e/t/a
e e e/ t
m e e/ t/at e/ t/at
/
e t/at e/ t/a / e e/ t/ate
e (2)
.m/t/e.tm
XeF +H O →
.m/t/.tm e e .m/t/e.tm
/.tm.m/t/e.tm .m /.tm .m6 2
/t/.tm :
.
tm. m/e.tm. me
/.tm.m/t/e.tm
.m .mt.m
t /.tm .m
s: /:p/sts:/: s : /:/psts:/: Cu+conc. H SO p ss:/t:pss:→ /
s: /:/t/.s:/:/t s: /:p/sts:/: s://s:// s : /:/psts:/: s
tptphsttpt p s (3)
tpt ht tpt t
tphttp
2 4
tphst tptps tptphsttpt ttp ttp p s
tpt ht tpt ttpht
h t ht h t h t p h t ht
h h h h h hht h h [ hv¸¨¦P h h h h h
A / Turn over

b b b ebb b ebb e b b ebb b ebb b ebb

e b e b e b eb e w e w e e b eb
i w evwiwe v wi weviwiw e
vi w i e
wviwi w vi i viw
w uv
i
i w evwiwe v i
w weviwiwe iw
w i w i
r
u uvavriuruvi a r rulvaruruv
u ar rulvaruruv
u l ar uriualvarur r
u uvavriuruvi a r r
u uvaruruv ruvru
ar lial
i i lialmilia i lialmilia m i i
lamil lial ar lial
i i lialmilial ila ila
mm m mam am am i m m
tam/atam /atam/at t/at t/at ammtam tam/atam amtam
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ee w w w i ww i i ee w
iwvviw
vvriuw iw vviwvviiw
iw vvriuw
iwvvii uu vvruiuvv viwiwvviw iw vviwiwvviiw
u u u
rrlualarr u uu
rrlalar u rrilala r v
uuarruu rruuaarruu
aar a
ilima
l ii l
iimaa
l ii i lal
imma i i
rr
lialailila a
ilima l
l i il
mm m m
m m m
m mmtaam
t//taea//ttaa t//taea//ttaa //ttaea//ttaa aammtaamm
tte//t aa
/e/ ee//t
tt //ttae
eem e eem e eem e /
eem e/ e e e
t ..mm
6622tt.. m tt.mm/tt..m
. //t..m/m//tt..m 1 0
t ..mm t .. m tt..m/m//tt..mm tt..m/m//tt..mm
// t / // // // / / / : : / tt /
// ::/// t //
//ss::/ //
:://ss::/
ss:://ss::/ ss:://ss:: ss :: ss
pp : /
: / s ss: : ss
ttttphpttttpp 35. (A) (i)ttttphphtøh÷£õ÷µÛß ttpp
t hh ttttphphtttt
ÁiÁø©¨ø£ ÂÁ›UPÄ®.
t t
t ppststttpps
t t ttphpttttpp
t ttttphpttttpp
hh h hh hh hh hh h hh h
(ii) GzvÀ ÷£õ÷µm ÷\õuøÚø¯ GÊxP.
b b b b bbeebb bbeebb AÀ»x e e bbeebb bbeebb bbeebb
ee e e e e e e w w w i w w e e e e
v v iwvviw
iw iw v v iwvviw
iw iw vv iwiwvviiw
u u u vvriuiuvvi ¤øn¨¤ß v vi w
i w
iw
wvviußø©PøÍ vv iwiwvviw
u
iw
(B) E÷»õPU
rrulualarru u Põº÷£õøÚÀPÎÀ rrulualarr u Põn¨£k®
alarriliala r uuarruu rrulualarru
riulualarruu iiml a
l a i
ÂÁ›UPÄ®. i i l a
l
imm a i i i l
i a a rr l l a l
iimiia
l a
i m m m m iliml ii
m
/ /
mm m
ttaea//ttaa(i) Describe//ttathe
m m
a//ttaastructure of Diborane. / ttaea//tt
/ e
a a
ttaa mmtaam
/ t / /ttaa//ttaam
m m
eem e (a)
eemee eem
m eem// ee/ eemee eem
m m m . mm . . m m m m
m m
.. t .
/:://s/tst::////t
. (ii) Write m
.. /tt . .
/:://s/tst::///ethylborate test.///tt ////
: : /
.
: :
t t
/ ./ .m/m//tt..m
t t / //
m .
t/ t.:.////tt. / /
/ /tt.:.////tt..
p sstpp p p sstpp ttpp sstppss OR
t t s s :://ss::/
p sst:p:pss: pp sst:p:pss:
p
tt t t tttthhtt t hhtt hh t ttphpttttp p p
tttthhttt tttthhttt
hhtt hht h h
(b) Describe the nature of bonding in metallic
t t
hh hcarbonyls. h h h h
bb b b bbeebb bbeebb e e bbeebb bbeebb bbeebb
e e e e e e ee w w w i w w e e e e
iw iwvviw iw 36. (A) åõmQ v v iwiwvviw iw©ØÖ® L¤µõ[PÀ v v iwiwvviiwSøÓ£õkPøÍ vvi
vvriuiuÂÍUSP. i w
i wvviw iw vv iwiwvviw iw
v v u uu uu v v u
uaarruu
la a rrulualarru l a
l a rrulualarr
i i l
i alarrilialar r ruuarruu
a la a rrulualarru
l iim l i i i imm i AÀ»x m m mm a
ilim a
l i il l iimiil
/ /
m m m
a//ttaa (i) §ä¯ ÂøÚUS
ttae(B) / /
mm
ttaea//ttaa Cµsk Euõµn[PÒ / ttaea//tt
/ e
a a
t a
t a mmtaam
/ t / t
/ aa//ttaam
t
m m
//tt
eem e eem e eem u¸P.e// ee/ e e e e ee
mm/tt..m . mm/tt..m t ..m/m//tt..m emm mm/tt..mm . mm/tt..mm
t . . tt . / / t . m
. m t . . tt.. t t .
: :
t
///s/s::// / (ii) ÷uõÀ
s : : / /
//s/s::// £uÛkuÀ ss©ØÖ® / /
::/ss:: Cµ¨£º öuõȼÀ ::// t
//t:://// t TÌ©[PÒ :://s/s:://GÆÁõÖ s:://ss::///
/ / / /
ss s ? ttttppttttpp sstppss s sttpp sttpp
ttttphpttttpp t thtttpp
tttphp£¯ß£kQÓx p p
tttthhtt t t p
t p t t hht hht
t ttpp t
hh h hh hh hh h h hhtt hh
(a) Explain Schottky and Frenkel defects.
b ebb b ebb b ebb OR eb b ebb b ebb b ebb
e b e b e b e w e w e eb e b
wi w evwiwe
i vi w e
iwGivev i w w e
i two examples vi w w e
i forvi wi w
uv vi i
wuvviw i
i
w w evwiw
i
e
vi iwviwi e iwv
w e w
vi v rulvaruruv urialarur uvavriuruv rulvaruruv ruvru
(b) (i) zero order reaction.
uriualvaruru a r rulvaruruv
u l a r u i i l ar r
u ar u
l lial(ii) i lia How colloids i liamilaare used in mtanning i a
l mil of leather ialarilial and in Rubber lialmilia ila ila
i m m l
iamm i
m
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