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Pertemuan 10-11 ch05 - Oxidation Reduction Reactions
Pertemuan 10-11 ch05 - Oxidation Reduction Reactions
Pertemuan 10-11 ch05 - Oxidation Reduction Reactions
5 Oxidation-Reduction
Reactions
1
Kimia Dasar FMIPA 2016
kimdas2016
• Fe2O3
▪ O: -2; Fe: +3
• Na2CO3
▪ Na: +1; O: -2; C: +4
• V(OH)3
▪ O: -2; H: +1; V: +3
• K2Cr2O7
▪ K: +1; O: -2; Cr: +6
5.2 The ion–electron method creates balanced net ionic equations for redox reactions 12
Balancing Redox Reactions: (Cont.)
5. Balance charges by adding electrons to the
more positive side
6. Find the least common multiple of electrons for
the two half- reactions. Multiply each reaction
by the factor needed to achieve the LCM of
electrons
7. Add the half reactions, canceling like
substances that appear on both sides
5.2 The ion–electron method creates balanced net ionic equations for redox reactions 13
Setarakan reaksi redoks berikut pada kondisi asam
MnO4- + H2SO3 → SO42- + Mn2+
5.2 The ion–electron method creates balanced net ionic equations for redox reactions 17
Setarakan dalam kondisi basa
5.2 The ion–electron method creates balanced net ionic equations for redox reactions 19
Balance, Using the Ion-Electron Method
5.2 The ion–electron method creates balanced net ionic equations for redox reactions 20
Balance, Using the Ion-Electron Method
5.2 The ion–electron method creates balanced net ionic equations for redox reactions 21
Balance, Using the Ion-Electron Method
5.2 The ion–electron method creates balanced net ionic equations for redox reactions 22
Setarakan persamaan reaksi redoks berikut pada kondisi basa
5.2 The ion–electron method creates balanced net ionic equations for redox reactions 26
Your Turn!
5.2 The ion–electron method creates balanced net ionic equations for redox reactions 27
Reactions Of Metals In Non-oxidizing Acids
• Metals can be replaced in a compound by hydrogen
ion when they react with acid
• In this case, H+ is reduced so that the metal can be
oxidized
• Only metals more active than H can undergo this
single-replacement type reaction
• Cu(s) + H+ →No Reaction
• Fe(s) + 2H+(aq) →Fe2+(aq) + H2(g)
• HNO3:
▪ (conc) NO3- + 2H+(aq) + e- → NO2(g)+ H2O(l)
▪ (dil) NO3(aq)- + 4H+(aq)+ 3e- → NO(g) + 4 H2O(l)
▪ (v.dil): NO3(aq)- + 10H+ + 8e- → NH4(aq)+ + 3H2O(l)
• H2SO4:
▪ (hot, conc.) SO42- + 4H+(aq) + 3 e- → SO2(g) + 2H2O(l)
▪ (hot, conc, with strong reducing agent)
▪ SO4(aq)2- + 10H+(aq) + 8e- → H2S(g) + 4H2O(l)
• A + BC → AC + B
• Metal A can replace metal B if it is a more active
metal, or
• Nonmetal A can replace nonmetal C if it is more
active than C.
• An activity series arranges metals according to
their ease of oxidation (Table 5.2)
5.4 A more active metal will displace a less active one from its compounds 30
Learning Check: Metal Activity
5.4 A more active metal will displace a less active one from its compounds 31
Activity Series
5.4 A more active metal will displace a less active one from its compounds 32
Learning Check:
• Cu + ZnSO4 → NR
5.4 A more active metal will displace a less active one from its compounds 34
Oxygen Reacts With Many Substances
The products depend, in part, on how much oxygen
is available
• Combustion of hydrocarbons
▪ O2 plentiful; CH4 + 2O2→ CO2 + 2H2O
▪ O2 limited: 2CH4 + 3O2 → CO + 4H2O
▪ O2 scant: CH4 + O2 → C + 2H2O
• Organic compounds containing O also produce
carbon dioxide and water
▪ C2H5OH + 3O2 → 2CO2 + 3H2O
5.6 Redox reactions follow the same stoichiometric principles as other reactions 40
Your Turn!
5.6 Redox reactions follow the same stoichiometric principles as other reactions 41