Marks booster challenge #2

Observations structures of the following compounds

The total number of structures/compounds which posses asymmetric

carbon atoms is ___.
Observations structures of the following compounds

The total number of structures/compounds which posses asymmetric

carbon atoms is ___.

Ans: 3
Solution:

Number of compounds containing asymmetric carbons are three.

The strongest acid from the following is

A B

C D
The strongest acid from the following is

A B

C D
Solution:
The correct order of stability for the following alkoxides is

A (B) > (A) > (C)

B (C) > (B) > (A)

C (B) > (C) > (A)

D (C) > (A) > (B)

The correct order of stability for the following alkoxides is

A (B) > (A) > (C)

B (C) > (B) > (A)

C (B) > (C) > (A)

D (C) > (A) > (B)

Solution:
Tautomerism is not exhibited by :

D
Tautomerism is not exhibited by :

D
 Solution:

Six membered cyclic compound cannot accommodate linear character.

Among the given ketones, the one which does not enolize is :

A I

B II

C III

D none of these
Among the given ketones, the one which does not enolize is :

A I

B II

C III

D none of these
Solution:
Which of the following compound is not resonance
stabilized ?

A B

C D
Which of the following compound is not resonance
stabilized ?

A B

C D
 Solution:

Lone pair will not participate in resonance because of bredt’s rule.

Among these canonical structure, the correct order of
stability is

A I > II > III

B III > II > I

C I > III > II

D II > I > III

Among these canonical structure, the correct order of
stability is

A I > II > III

B III > II > I

C I > III > II

D II > I > III

 Solution:

Neutral species is more stable than charged and complete octet

resonance is more stable than incomplete octet resonance.
The non-aromatic compound among the following is

A B

C D
The non-aromatic compound among the following is

A B

C D
Solution:
Which of the following compounds is not aromatic?

A B

C D
Which of the following compounds is not aromatic?

A B

C D
 Solution:

[10] Annulene, although follow (4n + 2)π electron rule, but it is

non-aromatic due to its non planar nature. It is nonplanar due to
repulsion of C - H bonds present inside the ring.
Arrange the following in decreasing acidic strength.

A A>B>C>D B B>A>C>D

C D>C>A>B D D>C>B>A
Arrange the following in decreasing acidic strength.

A A>B>C>D B B>A>C>D

C D>C>A>B D D>C>B>A
 Solution:

The correct order of acid strength is

The correct order of acidity for the following compounds is

A I > II > III > IV

B III > I > II > IV

C III > IV > II > I

D I > III > IV > II

The correct order of acidity for the following compounds is

A I > II > III > IV

B III > I > II > IV

C III > IV > II > I

D I > III > IV > II

 Solution:

Due to ortho effect, ortho substituted benzoic acid is

more acidic than meta & para isomers.
The increasing order of pKb values of the following
compounds is

A I < II < IV < III B I < II < III < IV

C II < I < III < IV D II < IV < III < I

The increasing order of pKb values of the following
compounds is

A I < II < IV < III B I < II < III < IV

C II < I < III < IV D II < IV < III < I

Solution:
Compound from the following that will not produce
precipitate on reaction with AgNO3 is:

A B

C D
Compound from the following that will not produce
precipitate on reaction with AgNO3 is:

A B

C D
Solution:
The correct order of acidity of the following
hydroxyl compound is :

Choose the correct answer from the options given

below:

A E>C>D>A>B B C>E>D>B>A

C D>E>C>A>B D E>D>C>B>A
The correct order of acidity of the following
hydroxyl compound is :

Choose the correct answer from the options given

below:

A E>C>D>A>B B C>E>D>B>A

C D>E>C>A>B D E>D>C>B>A
Solution:
Among the following compounds, the most basic
compound is :

A B

C D
Among the following compounds, the most basic
compound is :

A B

C D
Solution:
Consider the following carbocations.
Select the correct order of stability.

A D>E>C>B>A

B A>B>C>D>E

C E>D>C>B>A

D D>E>C>A>B
Consider the following carbocations.
Select the correct order of stability.

A D>E>C>B>A

B A>B>C>D>E

C E>D>C>B>A

D D>E>C>A>B
 Solution:

+I power of -CH3 is less than -CD3 while +H power of -CH3 is more than -CD3.
Correct stability order is
D>E>C>B>A
Find out the major products from the following
reactions.

D
Find out the major products from the following
reactions.

D
Solution:
Which one of the following compounds is inactive towards SN1 reaction?

A B

C D
Which one of the following compounds is inactive towards SN1 reaction?

A B

C D
Solution:

is inactive towards SN1 as

halogen is attached to bridge head carbon

atom, where formation of carbocation is
not possible.
The major product of the following reaction is

A B

C D
The major product of the following reaction is

A B

C D
Solution:
In the following sequence of reactions :

the product C is :

A C6H5COOH

B C6H5CH3

C C6H5CH2OH

D C6H5CHO
In the following sequence of reactions :

the product C is :

A C6H5COOH

B C6H5CH3

C C6H5CH2OH

D C6H5CHO
Solution:
The end product (Z) of the following reaction is

A A cyanide

B A carboxylic acid

C An amine

D An arene
The end product (Z) of the following reaction is

A A cyanide

B A carboxylic acid

C An amine

D An arene
Solution:
For the given reaction :

What is 'A'?

A B

C D
CH3CH2CH2NH2
For the given reaction :

What is 'A'?

A B

C D
CH3CH2CH2NH2
Solution:
Reaction of propanamide with Br2 / KOH (aq)
produces :

A Ethyl nitrile

B Propylamine

C Propanenitrile

D Ethylamine
Reaction of propanamide with Br2 / KOH (aq)
produces :

A Ethyl nitrile

B Propylamine

C Propanenitrile

D Ethylamine
Solution:
In the above conversion the correct sequence of
reagents to be added is

D
In the above conversion the correct sequence of
reagents to be added is

D
Solution:
The major product ‘P’ formed in the following
sequence of reaction is

A B

C D
The major product ‘P’ formed in the following
sequence of reaction is

A B

C D
Solution: