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BOYSEN Plasolux Glazing Putty B311 PDF
BOYSEN Plasolux Glazing Putty B311 PDF
2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Xn; Harmful
R10: Flammable.
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.09.2013 Version number 1 Revision: 02.09.2013
(Contd. of page 1)
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
· Code letter and hazard designation of product:
T Toxic
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.09.2013 Version number 1 Revision: 02.09.2013
(Contd. of page 2)
· Dangerous components:
CAS: 64742-81-0 Kerosine (petroleum), hydrodesulfurized 10-25%
EINECS: 265-184-9 Xn R65
Index number: 649-423-00-8 Asp. Tox. 1, H304
CAS: 8008-20-6 Kerosine (petroleum) 2,5%
EINECS: 232-366-4 Xn R20-48-65; Xi R38; F R11; N R51/53
Index number: 649-404-00-4 R66-67
Flam. Liq. 2, H225; Asp. Tox. 1, H304
CAS: 22464-99-9 Zirconium 2-ethylhexanoate 2,5%
EINECS: 245-018-1 2-ethylhexanoic acid zirconium salt
Xn R20/21-65; Xi R36/37/38; N R51/53
R10
Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Chronic 2,
H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335
CAS: 64742-82-1 Naphtha (petroleum), hydrodesulfurized heavy 2,5%
EINECS: 265-185-4 T Carc. Cat. 2, Muta. Cat. 2 R45-46; Xn R65
Index number: 649-330-00-2 Flam. Liq. 3, H226; Carc. 1B, H350; Asp. Tox. 1, H304
CAS: 96-29-7 2-butanone oxime 2,5%
EINECS: 202-496-6 Xn R21; Xi R41; Xi R43
Index number: 616-014-00-0 Carc. 2, H351; Eye Dam. 1, H318; Acute Tox. 4, H312;
Skin Sens. 1, H317
· Additional information:
For the wording of the listed risk phrases refer to section 16.
CAS: 471-34-1 calcium carbonate 25-50%
EINECS: 207-439-9
CAS: 14807-96-6 Talc (Mg3H2(SiO3)4) 10-25%
EINECS: 238-877-9
CAS: 1332-58-7 Kaolin 2,5-10%
CAS: 13463-67-7 titanium dioxide 2,5-10%
EINECS: 236-675-5
CAS: 8001-26-1 Linseed oil 2,5-10%
CAS: 68953-58-2 bis(hydrogenatedtallowalkyl)dimethylammoniumbentonite 2,5%
EINECS: 273-219-4 Ditallowdimethylammonium
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.
(Contd. of page 4)
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored
at the workplace.
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
(Contd. of page 5)
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Oral LD50 >5000 mg/kg (rat)
Dermal LD50 >3000 mg/kg (rab)
· Primary irritant effect:
· on the skin: Cause mild irritation
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Carcinogenic.
The product can cause inheritable damage.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
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(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.09.2013 Version number 1 Revision: 02.09.2013
14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1263
· UN proper shipping name
· ADR 1263 PAINT, special provision 640E
· IMDG, IATA PAINT
· Transport hazard class(es)
· ADR
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· National regulations:
· Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H350 May cause cancer.
H351 Suspected of causing cancer.
H411 Toxic to aquatic life with long lasting effects.
R10 Flammable.
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R21 Harmful in contact with skin.
R36/37/38 Irritating to eyes, respiratory system and skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R45 May cause cancer.
R46 May cause heritable genetic damage.
R48 Danger of serious damage to health by prolonged exposure.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
· Department issuing MSDS: Safety, Health and Environment Department
· Contact: Gretchen A. Fontejon- g_fontejon@boysen.com.ph
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
(Contd. on page 10)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.09.2013 Version number 1 Revision: 02.09.2013
(Contd. of page 9)
LD50: Lethal dose, 50 percent
· * Data compared to the previous version altered.
02.09.2013
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