DAV PG College Karnal

BSC-II (Physical Chemistry)

TM= 20

Timings= 1.5 hr

Q1) Compulsory Questions (2 marks each)

i) Define Zeroth law,

(ii) Differentiate b/w extensive and intensive property. ) Define state function and path function.

iii) Define state function and path functions.

iv) What is inversion temperature?

SECTION A (6 Marks)

Q2) a) Define first law of thermodynamics. Derive it's mathematical expression. (3)

b) Derive the expression for work done in reversible isothermal expansion. (3)

OR

Q3)-a) Differentiate b/w Reversible and Irreversible process (3)

b) Define Joule Thomson coefficient. (3)

SECTION-B (6 Marks )

Q4) a) Calculate work done during reversible isothermal Expansion of 4 moles of ideal gas from 1 L to
10 L at 298 K. (R= 8.314 J/K/mol) (3)

b) Derive relationship between Cp and Cv. (3)

OR

Q5: a) Define Isochoric process b) Isobaric process. c) Adiabatic process. (6)