PANINI325C-1 PT2 Advanced 30-12-23

FIITJEE – INTERNAL Phase Test
PHYSICS, CHEMISTRY & MATHEMATICS
QP CODE: 100600 Advanced

Time Allotted: 3 Hours Maximum Marks: 180
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
BATCH – PANINI325C-1_PT2
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. All the section can be filled in PART-A & B of OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.

(i) Part-A (01-04) – Contains Four (04) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and -1 marks for wrong answer.
(ii) PART–A (05–07) contains (3) Multiple Choice Questions which have One or More Than One Correct
answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result
in −1 marks, as a wrong option is also darkened.
(iii) Part-B (01-04) This section contains Two paragraphs. Each paragraph having TWO questions Numerical
answer type with answer XXXX.XX. For each question, enter the correct numerical value. If the numerical
value has more than two decimal places, truncate/round-off the value to TWO decimal places. Each
question carries +3 marks for the correct answer. There is no negative marking.
(iv) Part-B (05-10) This section contains SIX (06) questions. The answer to each question is a NON-
NEGATIVE INTEGER. For each question, enter the correct integer corresponding to the answer. Each
question carries +4 marks for correct answer. There is no negative marking.
Name of the Candidate: ____________________________________________
Batch: ____________________ Date of Examination: ___________________
Enrolment Number: _______________________________________________
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
2 PANINI325C-1_PT2_Advanced
S
SEEC
CTTIIO
ONN –– II :: P
PHHY
YSSIIC
CSS
(PART – A)
(Single Correct Answer Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. Two blocks of masses 5kg and 2kg are placed on a frictionless surface and connected by a
spring. An external kick gives a velocity of 14 m/s to the heavier block in the direction of
lighter one. Calculate the velocity gained by the centre of mass.
(A) 14 m/s (B) 7 m/s (C) 10 m/s (D) zero
2. The acceleration of centre of mass of the system shown in figure will be:
10
(A) 10 m/s2 (B) − m/s2
3
5kg
5
(C) m/s2 (D) –5 m/s 2
40kg
3
3. A round disc of moment of inertia l2 about its axis perpendicular to its plane and passing
through its centre is placed over another disc of moment of inertia l1 rotating with an angular
velocity  about the same axis. The final angular velocity about of the combination of discs
is
I I (I + I )
(A) 2 (B)  (C) 1 (D) 1 2
I1 + I2 I1 + I2 I1
4. On a smooth inclined plane a body of mass M is k

attached between two springs. The other ends of the
springs are fixed to firm supports. If each spring has a M
force constant k, the period of oscillation of the body is k
(assuming the spring as massless)

M 2M Msin  2Msin 
(A) 2 (B) 2 (C) 2 (D) 2
2k k 2k k
Space For Rough Work
(One or More Than One Options Correct Type)

This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
5. Two simple harmonic motions are represented by the equations:

Y1 = 10 sin [3t + /4]
Y2 = 5 [sin 3t + 3 cos 3t]
(A) The amplitude ratio of the two SHM is 1 : 1
(B) The amplitude ratio of the two SHM is 2 : 1
(C) Time periods of both the SHMs are equal
(D) Time periods of two SHMs are different
6. A particle of mass m is projected with a velocity v making an angle of 45 0 with the horizontal.
The magnitude of the angular momentum of the projectile about the point of projection when
the particle is at its maximum height h is
(A) zero (B) mv 3 / ( 4 2 ) g
(C) mv 3 ( 2 ) g (D) m 2gh3
7. The magnitude of gravitational field at distance r1 and r2 from the centre of a uniform sphere
of radius R and mass M are I1 and I2 respectively. Then
I1 r1 I1 r22
(A) if r1 R and r2 R (B) if r1 R and r2 R
I2 r2 I2 r12
I1 r1 I1 r12
(C) if r1 R and r2 R (D) if r1 R and r2 R
I2 r2 I2 r22
(PART – B)
This section contains Two paragraphs. Each paragraph having TWO questions Numerical answer type with
answer XXXX.XX. For each question, enter the correct numerical value. If the numerical value has more than
two decimal places, truncate/round-off the value to TWO decimal places.
Paragraph for Question no. 1 to 2
A disc of radius R = 10 cm is mounted on a light axle with the axle held horizontal, the disc
is made to spin with angular speed 0 = 2 rad/sec It is then lowered gently on to a level table
and released as soon as its rim makes contact with the table top. The disc begins to move
along the table, skidding and picking up speed as it goes. ( Take g = 10 S.I. Units )
1. While the disc skids, its translational and angular acceleration are related as a = k R  , then
k is :....
2. If k = 0.5 is the coefficient of kinetic friction between the rim of the disc and table top, disc
will continue to skid for a time (in milli seconds) =
A rectangular rigid fixed block has a long horizontal edge. A solid homogeneous cylinder of
radius R = 35 cm is placed horizontally at rest. Its length is parallel to the edge such that the
axis of the cylinder and the edge of the block are in the same vertical plane. There is
sufficient friction present at the edge so that a very small displacement causes the cylinder
to roll off the edge without slipping (Take g = 10 S.I.Units)
3. The angle  through which the cylinder rotates before it leaves contact with the edge is
Arccos ( x) , then x = ...
4. The speed of the centre of mass of the cylinder (in m/s ) before leaving contact with the edge
is ........
(PART – B)
(Non – Negative Integer)
5. A particle is subjected to two simple harmonic motions in the same direction having equal
amplitudes and equal frequency. The resulting amplitude is equal to the amplitude of
a
individual motions. If the phase difference between them is , then a =
6
6. Figure shows a uniform disc of radius R from

which a hole of radius R/2 has been cut out
from left of the centre and is placed on right of (-R/2,0) (-R/2,0)
the centre of disc. The centre of mass of
resulting disc is at a distance R/n from centre
of uniform disc. Find the value of n
7. figure shows two blocks of masses 4kg and 4 kg resting on

a horizontal surface and a spring constant k = 100 N/m
4kg 4kg K=100 N/m
attached to a fixed wall. All the three lie along the same line.
The space between the two blocks is smooth, while the 1 2
space between the block 2 and wall is rough (  = 0.5 ) . If
the 4kg block is given a velocity of 11 m/s, then the 0.1m
maximum compression of the spring is (collision between
the two blocks is perfectly elastic) (in cm)
8. A system (L shaped) of two identical rods of mass m P

and length l are resting on a peg P shown in the figure. l l
If the system is displaced in its plane by a small angle
kl
, then period of oscillation is given by 2 . Find
3g
the value of k2/8 =
9. The M.I. of a body (initially at rest) about a given axis is 1.2 kgm2. In order to produce a
rotational K.E. of 1500 J, an angular acceleration of 25 rad/s2 must be applied about that
axis for a period of (in sec)
10. Three particles, each of mass m, are situated at the vertices of an equilateral triangle of side
length a. The only forces acting on the particles are their mutual gravitational forces. It is
desired that each particle moves in a circle while maintaining the original mutual separation
a. Find the initial velocity that should be given to each particle.  take a =
GM 
16   
S
SEEC
CTTIIO
ONN –– IIII :: C
CHHE
EMMIIS
STTR
RYY
(PART – A)
1.
6
Conc. in ‘M’ 4
Y
Time (in sec)

What is the equilibrium constant KC of the reaction X ( g) 2 Y ( g) according to above
figure?
3 2
(A) (B)
2 3
8 3
(C) (D)
3 8
2. Which of the following has the highest pH value?

(A) 10–8 M HCl (B) 10–2 M KOH
-4
(C) 10 M HNO3 (D) 10-3 M NaCl
3. For which of the following reaction, the equilibrium constant (Kp) and the equilibrium
pressure Pequm ( ) are identical, i.e. K p = Pequm ?
(A) C ( s ) + O2 ( g) CO2 ( g) (B) CaCO3 ( s ) CaO ( s ) + CO2 ( g)

(C) 2 Zn ( s ) + O2 ( g) 2 ZnO ( s ) (D) 2KClO3 ( s ) 2KCl ( s ) + 3 O2 ( g)
4. CH3COOH ( aq) CH3COO− ( aq) + H+ ( aq )

Which of the following characteristic of the above system decreases on increasing
temperature?
(A) Degree of dissociation() (B) Ionization constant(Ka)
+
(C) Concentration of H ion (D) Concentration of CH3COOH

5. The rate equation of a reaction is

Rate = k[A]2[B]
Which of the following activity(ies) can increase the rate of reaction by two times of its
original value?
(A) Increasing conc. of ‘B’ by two times keeping the conc. of A fixed.
(B) Increasing conc. of A by 2 times keeping the conc. of B fixed
(C) Increasing the temperature by 10oC
(D) Decreasing volume of reaction container to half of its original value
6. 2KClO3 ( s ) 2KCl ( s ) + 3 O2 ( g)
Which of the following can make the above reaction proceed towards forward direction from
equilibrium state?
(A) Decreasing pressure (B) Adding KCl
(C) Adding inert-gas at constant pressure (D) Removing KClO3
7. Which of the following property(ies) of group-14 elements decreases on moving down the
group?
(A) Stability of +4 oxidation state (B) Thermal stability of dichlorides
(C) Acidic nature of oxides (D) Size of atoms
(PART – B)
Aqueous solutions of salts of different types may be acidic, neutral or basic. It depends on the
nature of salts which on hydrolysis produce acids and bases which may be strong or weak.
Aqueous solutions of the salts of strong acids and strong bases and that of weak acids and weak
bases have fixed pH which does not change on dilution. They are temperature dependent. Consider
a base CH3NH2 which ionization constant(Kb) is 10–4 and an acid HCN which ionization constant(Ka)
is 10–10.
Answer the following questions on the basis of above write up.
1. If the equilibrium constant Kc of the following reversible reaction is written as 10-x, what is x?
CH3NH3+ ( aq) + H2O ( ) CH3NH2 ( aq) + H3O+ ( aq)
2. What is the pH of 10–2 M HCN at 25oC?

[Assume 1 -   ]
Chemical equilibrium is dynamic in nature. The reactions(forward and backward) do not stop even
at equilibrium. The concentration of reacting species remains constant at equilibrium. Consider the
following equilibrium in which the equilibrium concentration of X(g) is 0.4 mol L–1 and that of Y(g) is
0.8 mol L–1.
X ( g) Y ( g)
3. What is the value of the equilibrium constant KP of the reaction?
4. How many moles of X should be added at equilibrium so that the concentration of Y

becomes 0.9 mol L-1 at new equilibrium?
(PART – B)
1
5. part of the reactant in a zero order reaction is consumed in one minute. What is the half-
8
life period of the reaction in minute unit?
6. One mole of each of gases SO3, NO, NO2 and SO2 are taken in a one litre vessel for
reaction.
SO3 ( g) + NO ( g) SO2 ( g) + NO2 ( g)
The equilibrium state is attained after 50%(mole) of the reactants undergo reaction. What is
the equilibrium constant KC of the reaction.
7. What is the pH of a buffer solution which contains CH3COOH and CH3COONa in the molar
ratio of 10 : 1?
(Ka of CH3COOH = 10–5)
8. A thermodynamic system containing one mole of an ideal gas undergoes compression to

th
1
of its initial volume reversibly and isothermally at TK. How much work in joule unit is
10
done on the system?
[Given: 2.303 RT = 6 J mol–1]
9. How many silicon atom(s) is/are present in a metal pyrosilicate?
10. What is the pH of 0.1 M solution of NaHS?

[Given: K a1 of H2S = 10−7 ,K a2 of H2S = 10−11 ]
S
SEEC
CTTIIO
ONN –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
(PART – A)
 x2 −1   2x   2x  
If for x  −1, cos  2  + sin −1 
−1
1. 2 
− tan −1  2  = , then x is equal to
 x +1 1+ x   x −1 3
(A) − 3 (B) − 2
(C) –2 (D) none of these
2. If cos −1 x + cos −1 y + cos −1 z = , then

(A) x 2 + y 2 = z 2 (B) x 2 + y 2 + z 2 = 0
(C) x 2 + y 2 + z 2 = 1 − 2 xyz (D) none of these
3. Equation of parabola having it’s focus at S (2, 0) and one extremity of it’s latus rectum as
(2, 2) is
(A) y2 = 4 ( 3 − x ) (B) y2 = 4 (1 − x )
(C) y2 = 8 ( 3 − x ) (D) none of these
3
4. The arithmetic mean of two positive numbers a and b exceed their geometric mean by and
2
6
their geometric mean exceed their Harmonic mean by , then the quadratic equation
5
whose roots are a and b:
(A) x 2 − 15x + 36 = 0 (B) x 2 − 36x + 15 = 0
(C) x 2 + 15x − 36 = 0 (D) x 2 + 15x + 36 = 0

5. If Sn = cot-13 + cot-17 + cot-113 + cot-121 + ,…..n terms then

5 
(A) S10 = tan −1 (B) S =
6 4
4 11
(C) S6 = sin−1 (D) S20 = cot −1
5 10
6. The adjoining figure shows the graph of y = ax2 + bx + c , then

y
x
O
(A) a  0 (B) b2  4ac

(C) c  0 (D) a and b are of opposite sign
7. An arithmetic sequence consists of ten positive integers. The sum of the terms in the
sequence lies in the interval (180, 190). If the fifth term in the sequence is 17. Then which of
the following statement(s) is/are correct?
(A) Common difference of sequence equals 3.
(B) Second term in the sequence is 8.
(C) Number of prime numbers in the sequence is 5.
(D) No term in the sequence is perfect square.
(PART – B)
Let  and  be any two non-negative values of cos x for which

2 cos x, | cos x | and 1 − 3 cos2 x are in G.P. Then
1. The minimum value of |  −  | is
2. If the sum of all values of cos x is equal to S, then –S is equal to
Let P ( x ) be a quadratic polynomial with real coefficients such that for all real x the relation
2 (1+ P ( x ) ) = P ( x − 1) + P ( x + 1) holds, if P ( 0) = 8 and P ( 2) = 32 , then
3. The sum of all the coefficient of P ( x ) is:
4. If the range of P ( x ) is m,  ) then the value of –m is:
(PART – B)
5. If 9x2 + 4y2 + 2kxy + 4x − 2y + 3 = 0 represents parabola then k is __________
5
Find the sum of all the integeral roots of (log5 x ) + log5x   = 1
2
6.
x
7. The maximum possible value of positive integer k for which both roots of the quadratic
equation x2 –2kx + k2 + k –5 = 0 are less than 5 is
8. If (m2 -3) x2 + 3mx + 3m + 1= 0 has roots which are reciprocals of each other, then the
positive value of m equals to
9. If , ,  are roots of the cubic x 3 − 4x − 7 = 0 , then 3 + 3 + 3 =
90
r 8191
10. If S =  , then the value of  S will be
r =1 (r 4
+ r +1
2
) 819
FIITJEE INTERNAL TEST

BATCH: PANINI325C-1
PHASE TEST–2: Advanced
Code: 100600
JEE ADVANCED LEVEL
ANSWER KEY
ANSWER KEYS
Physics
PART – A
1. C 2. B 3. C 4. A
5. AC 6. BD 7. AB
PART – B
1. 0.5 2. 13.33 (range: 13.32 to 13.34)
3. 0.57 (range : 0.56 to 0.58) 4. 1.41 (range : 1.40 to 1.42)
5. 4 6. 4 7. 200 8. 4
9. 2 10. 4
Chemistry
PART – A
1. C 2. B 3. B 4. D
5. ABC 6. AC 7. AC
PART – B
1. 10 2. 6 3. 3 4. 0.15
5. 4 6. 9 7. 4 8. 6
9. 2 10. 9
Mathematics
PART – A
1. A 2. C 3. A 4. A
5. ABD 6. ACD 7. ABCD
PART – B
1. 0.52 (range 0.51 to 0.53) 2. 0.17 (range 0.16 to 0.17)
3. 19.00 4. 17.00 5. 6 6. 6
7. 3 8. 4 9. 21 10. 5

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FIITJEE – INTERNAL Phase Test

PHYSICS, CHEMISTRY & MATHEMATICS

QP CODE: 100600 Advanced

B. Filling of OMR Sheet

C. Marking Scheme For All Two Parts.

Name of the Candidate: ____________________________________________

Batch: ____________________ Date of Examination: ___________________

Enrolment Number: _______________________________________________

4. On a smooth inclined plane a body of mass M is k

(One or More Than One Options Correct Type)

5. Two simple harmonic motions are represented by the equations:

Paragraph for Question no. 1 to 2

Paragraph for Question no. 3 to 4

6. Figure shows a uniform disc of radius R from

7. figure shows two blocks of masses 4kg and 4 kg resting on

8. A system (L shaped) of two identical rods of mass m P

Space For Rough Work

Time (in sec)

2. Which of the following has the highest pH value?

(A) C ( s ) + O2 ( g) CO2 ( g) (B) CaCO3 ( s ) CaO ( s ) + CO2 ( g)

4. CH3COOH ( aq) CH3COO− ( aq) + H+ ( aq )

(One or More Than One Options Correct Type)

5. The rate equation of a reaction is

Paragraph for Question no. 1 to 2

2. What is the pH of 10–2 M HCN at 25oC?

Paragraph for Question no. 3 to 4

3. What is the value of the equilibrium constant KP of the reaction?

4. How many moles of X should be added at equilibrium so that the concentration of Y

8. A thermodynamic system containing one mole of an ideal gas undergoes compression to

9. How many silicon atom(s) is/are present in a metal pyrosilicate?

10. What is the pH of 0.1 M solution of NaHS?

Space For Rough Work

2. If cos −1 x + cos −1 y + cos −1 z = , then

(One or More Than One Options Correct Type)

5. If Sn = cot-13 + cot-17 + cot-113 + cot-121 + ,…..n terms then

Space For Rough Work

6. The adjoining figure shows the graph of y = ax2 + bx + c , then

(A) a  0 (B) b2  4ac

Paragraph for Question no. 1 to 2

Let  and  be any two non-negative values of cos x for which

1. The minimum value of |  −  | is

2. If the sum of all values of cos x is equal to S, then –S is equal to

Paragraph for Question no. 3 to 4

3. The sum of all the coefficient of P ( x ) is:

Space For Rough Work

4. If the range of P ( x ) is m,  ) then the value of –m is:

5. If 9x2 + 4y2 + 2kxy + 4x − 2y + 3 = 0 represents parabola then k is __________

9. If , ,  are roots of the cubic x 3 − 4x − 7 = 0 , then 3 + 3 + 3 =

FIITJEE INTERNAL TEST

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Batch: __ Date of Examination: _