Conductance of pure H2O = 18.

62 µohm -1cm-1
Conductance of BaSO4 solution = 176.4 µohm -1cm-1

Table 1: To determining Specific and equivalent conductance of KCl solution of various

concentrations

Specific Equivalent
Observation Concentration, √C conductance conductance, Λ
No. C (N) LS (Ω-1cm2eq-1)
(µΩ-1cm-1)
01 0.001 0.03 189 189
02 0.005 0.07 633 126.6
03 0.01 0.10 1172 117.2
04 0.05 0.22 5765 115.3
05 0.1 0.32 11180 111.8
06 0.25 0.50 26620 106.48

Equivalent Conductance (Λ) vs √C

200
180
160
140 f(x) = − 110.714345114345 x + 150.610964656965
(Ω-1cm2eq-1)

120 R² = 0.415850875040444
100
Λ

80
60
40
20
0
0 0.1 0.2 0.3 0.4 0.5 0.6

√C (N)

Figure 1: Graph for determining ɅKCl at infinite dilution

Calculation:

K = (176.4-18.62) µohm -1cm-1

Concentration of BaSO4:
k ×1000
CBaSO4 =
Ʌ
(k × 1000)
=
¿¿
(1000 1.5778 10−4 )
=
(127.2+160)
= 5.4910-4 N

Solubility product:
Ksp = C2 = 3.014×10-7 mol2L-2
From the intercept of the graph,
Equivalent conductance at infinite dilution, Ʌo = 147 Ω-1cm2eq-1

Result:
Equivalent conductance of KCl solution at infinite dilution, Λ°KCl =147 Ω-1cm2eq-1
The solubility product of BaSO4, Ksp= 3.014×10-7 mol 2L2