Chemistry

CHEMISTRY REVISION SHEET [JEE MAINS PART-II]

DAY-01
1. In the Newmann projection for 2,2-dimethylbutane

x and y can respectively be

(a) H and H (b) H and C2H5 (c) C2H5 and H (d) CH3 and CH3

2. Amongst the following, the total number of compounds soluble in aqueous NaOH is

3. How many grams of sucrose (molecular mass = 342) should be dissolved in 100gm water in order to produce a
solution with 105°C difference between the freezing point and boiling point at 1 atm?
(Kf = 2K kg/mol and Kb = 0.5 K kg/mol)
(a) 34.2g (b) 68.4g (c) 17.1g (d) 342g

4. 2.5 gm of a monobasic acid HA in 100 gm water lowers the freezing point by 0.2325 K. If 0.75 gm of same acid
1
15ml M NaOH
requires 5 solution for complete neutralisation. Which is/are correct statement ?
(K f  1.86K kg mol1, Kb  0.25 K kg mol1)
(a) Molecular weight of acid is 250 (b) Degree of ionisation of acid is 25%
o
(c) Vant hoff factor of HA is 1.25 (d) Difference in B.P. and M.P . is 100.2975 C

5. Select the correct order

(a) Bond length = O22  O2  O2  O2
(b) Bond strength = O2  O2  O2  O22
(c) Unpaired electron(s) = O2  O2  O2  O22
(d) No. of antibonding electron(s) = O22  O2  O2  O2
6.

7.

8.

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9.

10.

DAY-02
1. In the following monobromination reaction, the number of possible chiral product(s) is (are)….

2. Amongst the compounds given, the one that would form a brilliant coloured dye on treatment with NaNO 2 in dil.
HCl followed by addition to an alkaline solution of -naphthol is

(a) (b) (c) (d)

3. Equal volumes of 0.1M solution of NaCl and 5M solution of NaCl are kept in a closed vessel (see figure) and
temperature is maintained constant. After equilibrium has been
established, assuming that volumes are additive, which of the following is
(are) true?
(a) Volume of 0.1 M solution is lesser than its original volume
(b) Volume of 0.1 M solution is greater than its original volume
(c) Volume of 5M solution is lesser than its original volume
(d) No change occurs at all

4. Benzene and naphthalene form an ideal solution at room temperature. For this process, the true statement(s)
is(Are)
(A) G is positive (B) Ssystem is positive

(C) Ssurroundings  0 (D) H = 0

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 Chemistry
5. A 0.001 molal solution of a complex MA 9  in water has the freezing point of –0.0054°C. Assuming 100%
–1
ionization of the complex salt and k f for H2O = 1.86 Km , write the correct representation for the complex.
(A) MA 
8 (B) MA  A
7 (C) MA  A
6 2 (D) MA  A
5 3

6.

7.

8.

9.

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DAY-03
1 2
1. Which of the following represent correct reactivity order for SN as well as SN mechanism

2. Match the four starting material (P,Q,R,S) given in List-I with the corresponding reaction scheme (1, 2, 3, 4)
provided in List-II and select the correct answer using the code given below in lists

To the following compound different reagents are added & different products one formed with
different type of intermediate

1
3. The preparation of SO3 (g ) by reaction SO2 (g )  O2 SO3 (g ) is an exothermic reaction. If the
2
preparation follows the following temperature-pressure relationship for its % yield, then for temperature T 1, T2
and T3 the correct is

(a) T3 > T2 > T1 (b) T1 > T2 > T3

(c) T1 = T2 = T3
(d) Nothing could be predicated about temperature through given information

4. Which of the following are correct statements

(a) Entropy of system increases when an ideal gas is expanded isothermally
(b) Gas with higher  has high magnitude of slope in a P(y-axis) v/s (x-axis) curve
(c) Final temperature in reversible adiabatic expansion is lesser than in irreversible adiabatic expansion
(d) Vapourisation at boiling point, G  0

5. Mark out the correct statement(s) regarding electrolytic molar conductivity

(a) It increases as temperature increases
(b) It experiences resistance due to vibration of ions about mean position
(c) Increase in concentration decreases the electrolytic molar conductivity of both strong as well as weak
electrolyte
(d) Greater the polarity of solvent, greater is the electrolytic molar conduction

6.

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 Chemistry
7.

8.

9.

10.

DAY-04
1. Two weak acid solutions HA1 and HA2 each with the same concentration and having pKa values 3 and 5 are
0
placed in contact with hydrogen electrode (1 atm, 25 C) and are interconnected through a salt bridge. The emf
of the cell is

(a) 0.21 V
(b) 0.059 V
(c) 0.018 V
(d) 0.012 V
2.

Number of stereoisomer of product (B) is :

(a) 2 (b) 3 (c) 4 (d) 5
3. Ethane gas is obtained in Kolbe’s electrolysis of CH 3COONa according to the following reaction
CH3

2CH3COO  |  2CO2  2e 
CH3
What volume of gas (ethane gas) at S.T.P. would be obtained by a current of 0.5 amp (80% efficient); if the
current is passed for 965 min?
(a) 1.8 L (b) 2.688 L (c) 3.45 L (d) 11.2 L

4. Consider the reaction sequence and pick the correct statements

( i )NaNH ( ii )CH Br H / Pd BaSO Alk ,KMnO
CH3  CH2  C  CH 
2 3

 X 
2 4
Y  4
Z
(A) Z is diol (B) Z is a meso compound and is optically inactive
(C) Z is racemic compound (D) Y is a trans alkene

5. The product of following is

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 Chemistry

(A) (B) (C) (D)

6.

7.

8.

9.

10.

DAY-05
1. Which of the following statement(s) is/are true for [Cu(NO2 )6 ]4 and [Fe(h2O)6 ]3 ?
(a) Both are outer orbital complexes
(b) Both are inner orbital complexes with magnetic moment equal to 1. 73 B. M.
(c) The first complex is paramagnetic with one unpaired electron while later one is paramagnetic with five
unpaired electrons
(d) The first is outer orbital complex and later is inner orbital complexes respectively

2. CrCl3. 6NH3 can exist as a complex 0.1 molal aqueous solution of this complex shows a depression in freezing
0
point of 0.558 C. Assuming 100% ionization of the complex and co-ordination number of Cr is six, the number
of chlorine atoms present in the ionization sphere will be…………?
[(Kf )H2O  1.86 K Kg / mol ]
3. Number of correct statements of following
(1) Usually longer is the hydrocarbon chain of fatty a acid salt, smaller is its CMC
(2) More is gold number of lyophillic sol, more is its protecting power
(3) SnO2 is negatively charged colloid in acidic solutions due to adsorption of SnO32 over SnO2
(4) In thrmite process, Mg wire acts as catalyst in reaction
(5) Mist is an example of aerosol
(6) KClO3  KCl  O2 reaction can be catalysed by MnO2
(7) Flocculation value of [Fe(CN )6 ]4 is more than PO43 for positively charged colloid

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 Chemistry
4. How many of the following compound will give positive test with ammonical silver nitrate.
(i) Ethyne (ii) Formic acid (iii) Formaldehyde
(iv) Benzaidehyde (v) Fructose (vi) Acetal
(vii) Glucose (viii) Maltose (IX) Sucrose

5.

6.

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8.

9.

10.

DAY-06
1. Arrange the following complexes in order of increasing wavelength of visible light absorbed by them
(I) [Cr (H2O)6 ]3 (II) [Cr (en)3 ]3 (III) [Cr (CN )6 ]3 (IV) [Cr (NH3 )6 ]3
(a) I<III<IV<II (b) III<II<IV<I (c) II<I<IV<III (d) I<II<IV<III

2. In which of the following reactions benzaldehyde will form in final product

(a) (b)

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 Chemistry

(c) (d)

3. With reference to the scheme given, which of the given statement(s) about P,Q,R and S is (are) correc?

(a) (P) is soluble in hot aqueous NaOH

(b) (Q) exist in four stereoisomeric forms
(c) Molecules formula of (R) is C5H10I
(d) (S) form silver mirror on treatment with Tollen’s reagent

4. How many of following (including stereoisomer) give iodoform ethyl alcohal,isopropyl alcohol,n-butyl
alcohol,secondary butyl alcohol,isobutyl alcohol,acetophenone,benzophenone.

5.

6.

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8.

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 Chemistry
DAY-07
1.

CD : Fixed wall, EF : SPM, Fixed wall : allows the pressure transfer but no mass transfer. If 16 gm Helium
present in ABCD chamber calculate the length of this chamber in cm if no osmosis takes place through SPM
EF. Assume 75% ionization of K4 [Fe(CN )6 ]

2. Consider the following complexes [V(CO)6 ] [Cr(CO)6 ] and [Mn(CO)6 ] . Then incorrect statement(s) about
metal carbonyls is/are.
(A) ‘C – O’ bond is strongest in the cation and weakest in the anion
(B) ‘C – O’ bond order is less in the cation than in anion.
(C) ‘C – O’ bond is longer in the cation than in anion or neutral carbonyl.
(D) ‘M – C’ bond order is higher in the cation than in anionic or neutral carbonyl.

3. Identify the correct options related with the physical properties of the unknown compounds (X), formed as major
product and (Y) as minor product in the given reaction

(A) Water solubility of [Y] is greater than [X] (B) Boiling point of [Y] is greater than [X]
(C) Melting point of [Y] is greater than [X] (D) [X] is more volatile than [Y]

4. In which of the following pair first acid is stronger acid than second
(A) Fumaric acid, maleic acid (B) Salicylic acid, benzoic acid
(C) Picric acid, phenol (D) Formic acid, benzoic acid

5. Which of the following produce Cr2O3 along with O2

(a) Heating (NH4)2Cr2O7 (b) Heating K2Cr2O7
(c) Reaction of Al2O3+Cr (d) None
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7.

8.

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 Chemistry
10.

DAY-08
1. For zero order reaction A  3B plot of concentration vs time is as follows

Find half life period in minutes if the initial concentration of A be 1 M

2. Which is/are correct order as per property given

(1)

(2)

(3)

(4)
How many statement are correct

(100  103 ) –1
3. For a given reaction ln k   4 then s o for the reaction is (in cal mol )
T

4. Given that the normal energy of the reactant and product are 40J and 20J respectively and threshold energy of
the uncatalysed reaction is 120 J, if the rate of uncatalysed reaction at 400 K becomes equal to the rate of
catalysed reaction at 300k, then what will be the activation energy of the catalysed forward and backward
reactions respectively?
(a) 80 J, 60 J (b) 60 J, 80 J (c) 80 J 100 J (d) 50 J, 70 J

5. The mole fraction of a solute in a solution is 0.1. At 298K, molarity of this solution is the same as its molality.
–3
Density of this solution at 298 K is 2.0g cm . The ratio of the molecular weights of the solute and solvent,
 MWsolute 
  , is
 MWsolvent 

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 Chemistry

6.

7.

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DAY-09
1. 0.1 M KI and 0.2 M AgNO3 `are mixed in a 3 : 1 volume ratio. The depression of freezing point of the resulting
solution will be K f (H2O)  1.86KKgmol  1
(a) 3.72 K (b) 1.86 K (c) 0.93 K (d) 0.279 K

 
2. Consider a cell Ag | Ag (xc1 )|| Ag (yc 2 ) |Ag . Given that C2 = 10C1 and x and y is the degree of dissociation of
y
log  
AgNO3 in aqueous solution of concentration c1 and c2 in the two half cells. Then the value of  x  in terms of
the emf (E) of the cell will be (T= 298 K)
E E E E
1 1
(a) 0.059 (b) 0.059 (c) 0.059 (d) 0.118


3. Which of the following statements is not true about the complex ion [CrCl (NO2 )(en)2 ] ?
(A) It has two geometrical isomers cis and trans
(B) cis and trans forms are not diastereomers to each other
(C) Only the cis isomer displays optical activity
(D) It has three optically active isomers : d, l and trans forms

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 Chemistry
4. In acidic medium 4 mole of KMnO4 quantitatively oxidise x mole of SnC2O4 . The value of x is

5. Following graph is plotted between characteristics ‘X’ and ‘Y’ for three species A, B and C

Now consider the following statements, related to the above graph:

th
(1) If ‘X’ is the velocity of electron and ‘Y’ is 1/n (where ‘n’ is n Bohr orbit of three hydrogen like species A, B
and C), then radii of these species must increase in the order C < B < A
(2) If ‘X’ is the de-Broglie wavelength () of three charged species A, B and C (having same amount of
1
charge) and ‘Y’ is (where ‘V’ is accelerating potential difference), then the mass of these species
V
must increase in the order C < B < A
(3) If ‘X’ is the volume of same amount of three ideal gases A, B and C and ‘Y’ is the temperature in Kelvin,
then the pressure of these gases must increase in the order C < B < A
1
(4) If ‘X’ is the pressure of the same amount of ideal gases A, B and C and ‘Y’ (where V is the volume of
V
these gases), then temperature of these gases must increase in the order TC  TB  TA . What is the
correct code for correct statements in increasing order of their codes given?

6.

7.

8.

9.

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 Chemistry
10.

DAY-10
1. The following reaction gives

(A) (B)

(C) (D)

2. The correct statement about main reduction products is

(Ignore ethyl alcohol formed in any reaction as a side product)

(a) p, q, r are identical compounds (b) q, r, s are identical compounds
(c) r, s, t are identical compounds (d) p, r, t are identical compounds

3. Which of the following options is/are are incorrect

3
(a) [Co(OH2 )6 ] has low spin because of P. E. > Δ0
4
(b) [Fe(CN )6 ] has low spin, because Δ0 > P. E.
2
(c) [Zn(H2O)6 ] is coloured due to d – d transition
(d) [Co(EDTA)] is optically inactive due to presence of plane of symmetry

– 
4. I2(s)/I (0.1M) half-cell is connected to H (aq)|(H2 1atm)Pt half-cell and its cell potential is found to be 0.7714
EIo / I   0.535V , 
V. If 2 the pH of H / H2 half-cell will be…………

5.

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6.

7.

8.

8.

10.

DAY-11
1. A complex of metal M n  has the following electronic distribution in d orbitals

The neutral M has a ground state electronic configuration of [ Ar ]4s 2 3d 6 . Which of the following complexes is
consistent with the electronic distribution of M n  (as described above)?
(a) [M(CN )6 ]4 (b) [MF6 ]3 (c) [MF6 ]4 (d) [M(CN )6 ]3

2. 3–Amino–2,3–dimethyl butan–2–ol when treated with NaNO2 / HCl gives product (X). (X) on treatment with
LiAlH4 forms (Y). (Y) on heating with conc. H2SO4 forms (Z). Calculate the molecular weight of (Z)

3. Isomers of hexane, based on their branching, can be divided into three distinct classes as shown in the figure.

The correct order of their boiling point is

(a) I>II>III (b) III>II>I (c) II>III>I (d) III>I>II

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4.

5.

6.

7.

8.

9.

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ANSWER KEY

DAY-01
1 2 3 4 5 6 7 8 9 10
BD 4 B ABCD ABCD B BCD ABCD BCD ABC

DAY-02
1 2 3 4 5 6 7 8 9 10
5 C A BCD C ABC 6 0 3 64

DAY-03
1 2 3 4 5 6 7 8 9 10
C C B ABC ACD C AD ABC AD ABC

DAY-04
1 2 3 4 5 6 7 8 9 10
B B B AC C ABCD BC 3 C A

DAY-05
1 2 3 4 5 6 7 8 9 10
AC 2 3 7 B B C D D D

DAY-06
1 2 3 4 5 6 7 8 9 10
B ABC ABD 5 C ABCD ACD ABC 19 D

DAY-07
1 2 3 4 5 6 7 8 9 10
5 A ABCD BCD B C C A B D

DAY-08
1 2 3 4 5 6 7 8 9 10
8 4 8 B 9 C D B AC ABCD

DAY-09
1 2 3 4 5 6 7 8 9 10
D C BD 5 123 4 3 A D D

DAY-10
1 2 3 4 5 6 7 8 9 10
D C ACD 3 A C A C B C

DAY-11
1 2 3 4 5 6 7 8 9
C 84 B BCD ABC BD ACD ACD 50

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