JEE (MAIN + ADVANCED) : LEADER COURSE

SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

1. MC0174
Ans. (4)
Sol. O2 : N2
Mass 1 : 4

1 4
Molar :
32 28

®
1 4
molecules ´ NA : ´ N A Þ 7 : 32
32 28
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

2. MC0171
Ans. (3)
Sol. 10% of 75 kg = 7.5 kg is 11 H

If replaced by 12 H then wt = (7.5 × 2) = 15 kg

So gain is = 7.5 kg

®
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains
3. MC0172
Ans. (2)
Sol. M2CO3 + 2HCl ® 2MCl + H2O + CO2
¯
æ 1 ö 1
ç m.w ÷ molers (M.W)
molers
è ø

®
1
= 0.01186
M.W

M.W = 84.3
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains
4. MC0168
Ans. (3)
12x 6
Sol. Cx H y O z = Þ y = 2x
y 1
To burn 1 molecules xHy
æ yö y
C xH y + ç x + ÷ O 2 ® xCO 2 + H 2 O
èH ø 2

®
æ yö
O2 = ç x + ÷ : O = 2 æ x + y ö
è 4ø ç 4 ÷ø
è
æ yö
2ç x + ÷
4ø x + y 3x
z= è Þ z= =
x 4 2
From given options C2H4O3 ® Emp. form
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains
5. MC0169
Ans. (4)
Sol. (1) 2NH4NO3 ® 2N2 + 4H2O + O2

1 1
mol mole
80 80

(2) Ba(N3)2 ® Ba + 3N2

®
1 3
mole mole
221 221

(3) (NH4)2Cr2O7 ® N2 + 4H2O + Cr2O3

¯
1 1
mole moles
221 252
(4) 2NH 3 ® N2 + 3H2

1 1
mol ® mole ® maximum
17 34
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains
6. MC0162
Ans. (4)
Sol. In one mole CH4 there are 5 moles of atoms

1
% C(by mole) = ´ 100 = 20%
5

®
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

7. MC0163
Ans. (3)
Sol. N2 + 3H 2 ® 2NH 3
2
3 rd 56gm 10 gm ´R
3
2 mole 5 mole
­L.R.

®
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

8. MC0164
Ans. (3)
Sol. AB2(moles mass = MA + 2MB)
5(MA + 2MB) = 125 gm Þ MA + 2MB = 25 ...(1)
10(2MA + 2MB) = 300 Þ MA + MB = 15 ...(2)
MB = 10 gm

®
MA = 5 gm
MB = 10 × 10–3 kg/mole
MA = 5 × 10–3 kg/mole

 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

9. MC0165
Ans. (3)
Sol. (1) C3H8 + 5O2 ® 3CO2 + 4H2O

5
1 gm moles
44

®
mole
44

(2) P4(s) + 5O2 ® P4O10(s)

5
1 gm mol
124

1
mol
124

(3) 4Fe + 3O2 ® 2Fe2O3

1gm
1 3 1
mol ´ mol ® least
56 4 56
(4) 2Mg + O2 ® 2MgO
1gm
1 1
mole moles
24 2 ´ 24
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

10. MC0167
Ans. (2)
Sol. CxHy + O2 ® CO2 + H2O
25gm ¯ ¯
88 gm 9 gm
2 moles 0.5 mole

®
POAC for = C : x × moles of CxHy = 1 × 2 ...(1)
y × mole of CxHy = 2 5 0.5 ...(2)
x 2
= emp. for mole: C 2 H 2
y 1
24
wt. of carbon = ´ 25 = 24 gm
25
H = 2gm
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

11. MC0156
Ans. (2120 to 2140)
Sol. NaClO3(s) + Fe(s) ® O2(g) + NaCl(s) + FeO(s)
¯ ¯
1´ 492
20 moles n O2 =
0.082 ´ 300
wt = 20 × 106.5 = 20 moles

®
= 2130 gm
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

12. MC0159
Ans. (3)
Sol. The third option statment is Avogadro's Law

®
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

13. MC0217
Ans. (1)
Sol. Cl 2
PV 1´ 20 ´10-3
n= =
RT .083 ´ 273

1´ 20 ´10-3
Number of chlorine atom = ´ 2 ´ 6.023 ´1023

®
.083 ´ 273
= 1.06 × 1021
» 1...... × 1021
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

14. MC0218
Ans. (18)

7
Sol. C 2H 6 + O2 ® 2CO2 + 3H2O
2
3
0.3 mol
30

®
= 0.1 mol molecule = .3 × 6.023 × 1023
= 18.069 × 1022
» 18 Ans.
 JEE (MAIN + ADVANCED) : LEADER COURSE
SUBJECT : CHEMISTRY
Topic : Mole Concept - I Exercise : JEE-Mains

15. MC0221
Ans. (464))
13
Sol. C4H10 + O2 ® 4CO2 + 5H2O
2
72 gm
1
´ 4mol = 4 mol

®
5
4
= ´ 58
5
= 46.4
= 464 × 10–1
Ans = 464