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Solutions to JEE MAIN – 6 (GEN – 1 & 2) | JEE 2025

PHYSICS
SECTION-1
1.(C)

v1 cos  = v2 sin  1
   = tan −1
ev1 sin  = v2 cos  e
2.(B) Loss in P.E. = Gain in K.E.
1 1
 mgh = mv 2 + Iw2 ; Put, v = wr (no slipping)
2 2
1 1 mr 2 2
 mgh = mw2r 2 +  w
2 2 2
3 1 4 gh
 mgh = mw2 r 2  w =
4 r 3

3.(C) Applying equation of continuity A1v1 = A2v2


V2 = 4 m/s
1 1
Applying Bernoulli equation P1 +V12 = P2 + V22
2 2
1 1
 8000 +  1000  22 =  1000  (4) 2
2 2
 P2 = 2000 Pa

dv 10
4.(A) Viscous force = −A  Fext = −0.01100  = 10−3 N
dx 0.1
Hence to move with constant velocity Fext must be equal to viscous force

2 cos 
5.(C) h= and m = r 2h
gr
2 cos  h h
then h =  m =  ( 2r )  = 2m
2
=
g ( 2r ) 2 2

6.(A) When the planet revolves around the sun, its areal velocity remains constant.
A1 A2 A3 A1 A2 A3
 = = ; = = or 3A1 = 2 A2 = A3
t1 t2 t3 2 3 6

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GMm
7.(C) Weight at earth’s surface = mg =
R2
GMm
Weight at height h above earth’s surface = mg  =
( R + h) 2
40 R2
 =  2R = R + h ; h = ( 2 − 1) R
80 ( R + h)2

8.(C) Particle will acquire the initial velocity


when areas A1 and A2 are equal (see
figure).
For this, t0 = 8s

2  25
9.(B) In half cycle Δv = 2v v=  100 cm/s = m/s
(1/ 2 )
1 2v
Time taken to cover half cycle = sec  aavg = = 8v = 8 m / sec2
4 1/ 4

V (d v)  x 2 x3   dv 
10.(C) a = =  −   ( x − x2 )  = x − x2 
dx  2 3  dx 
 
3
 a = 0 when x = 0, , 1
2

L  ML2  L  
2
3V
11.(C) About the fixed point, MV0 = + M      = 0
2  12  2   2L

Anlysis along y - axis.


12.(C)
1
Sy = u y t − gt 2
2
 780 = 500 sin(53)t − 5t 2
 t 2 − 80t + 156 = 0
 t = 2s, 78 s.
And while going up t = 2s.

13.(C) In configuration (i), total potential energy stored is


 −Gm(2m)   −Gm(3m)   −G(2m)(3m) 
2 2
Gm 11Gm
Ui =  + +  =− (2 + 3 + 6) = −
 a   a   a  a a
−11Gm2
Similarly, in configuration (ii), U f =
2a
11Gm2
 Change in potential energy, U = U f − Ui =
2a
Work done by external agent = 11Gm / 2a
2

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u
14.(B) u cos  =   = 60
2
u 2 sin 2 u 2 sin120 3 u2
R= = =
g g 2g

15.(A)

f1  8 N
 f1 = 0 N , f 2 = 10 N
f 2  50 N

16.(B) Using conservation of energy


1 2
kx − mg sin 30(d + x) = 0
2
Use m = 4kg  g = 10m / s
2

K = 400 N / m and x = 0.20 m


d = 37.5 cm

17.(A) Coordinates of the masses : m1 : (0, 0) m2 : (1, 0) m3 : (0.5, 0.5 3)


50(0) + 100(1) + 150(0.5) 7 50(0) + 100(0) + 150(0.5 3) 3
X CM = = m; YCM = = m
50 + 100 + 150 12 50 + 100 + 150 4
7 3
Coordinates of CM :  , 

 12 4 
18.(C) Using conservation of momentum along
dotted line
m(6) = 2mv cos30
 v = 2 3m / s

r
19.(C) N cos  = m   2
2
N sin  = mg
r2 2 g cot  2 g
cot  = ; 2 = =
2g r r 3

2
I C ω2 mR 2 . (vcm
2
/ R2 )
K rot 5 2
20.(C) = = =
K rot + Ktrans IC ω + mvcm 2 mR 2 (v 2 / R 2 ) + mv 2
2 2 7
cm cm
5

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SECTION-2
1.(85) r1 = a + b + c = (4 − 3)iˆ + (−1 + 2 − 3) ˆj = iˆ − 2 ˆj
r2 = a + b − c = (4 − 3)iˆ + (−1 + 2 + 3) ˆj = iˆ + 4 ˆj
r1. r2 (i − 2 ˆj )·(iˆ + 4 ˆj ) 1 − 8 −7
cos  = = = =
r1r2 5 17 85 85

2.(1)

vrain = v12 / v22

vrain = v cos 30(− ˆj ) + v sin 30iˆ


vman = 0.5iˆ ; vrain/man = vrain − vman
= v cos30(− ˆj ) + (v sin 30 − 0.5)iˆ
v
Since rain falls vertically = 0.5, v = 1 m/s
2
1 GmM 1
3.(2) m(5ve2 ) − = 0 + mv 2
2 R 2
2GM
Where = Ve
R
8GM 2GM
On solving, V = =2 = 2ve
R R
4.(3) Velocity of B = Velocity of A
Point A moves on a circle x + y = R ; R = 0.5m
2 2 2

dy − x dy − x dx R sin 37º
Differentiating = or = =− (−4) = (tan 37º )  4 = 3 cm/s
dx y dt y dt R cos37º

5.(10) KE = PEA − PEP = mghA − mghB


= mg (2 − 1) = 110 1 = 10 J
6.(100) T = N + 30 g … (i)
T + N = 50 g … (ii)
 N = 100 Newtons.

7.(3) Point of contact has acceleration = R − a2 = a1   = 3rad / s 2

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fR
8.(1) f =mg  =
IC
ω0 ω0 R
= t  t=
2 2g
9.(8) When 2kg block is about to lift off tension in string = 20 N
20
(x) extension in spring = = 0.5 m
40
Applying conservation of energy.
1 1
(−5 g ) x + kx 2 + (5)v 2 = 0
2 2
v = 2 2m / s

v v
10.(36) oil g + Hg g = vdg
2 2
oil + Hg
 =d
2
13.6 + .8
=d
2
 d = 7.2

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CHEMISTRY
SECTION-1
1.(B) BaCl2 + Na 2CO3 → BaCO3  + 2NaCl
 
100 mL, 0.1 M 100 mL, 0.3 M
 20 meq  60 meq
 consumed  20 meq. consumed
0 meq left 40 meq. left → Neutralized by HCl
 meq. of HCl = 0.5 1 V = 40  V = 80 mL

2.(B) Observe that salt will act as reducing agent against K 2Cr2O7
gmeq. of KH3 (C2O4 )2 = gmeq. of K 2Cr2O7
2− −
1 mol KH3 (C2O4 )2  2 mol C2O4  4 mol of e 's

(C2O42− → 2CO2 + 2e− )


 1  1
 (4  p) =  6   500  10−3  p= = 0.25
 3  4

3.(B) NH3 + H2O → NH4OH


2NH4OH + H2SO4 → (NH4 )2 SO4 + 2H2O
mmol of H2SO4 present in 100 mL = 50 mmol
So, for 0.25 M H2SO4 solution, 25 mmol of it has to be neutralized by ammonia. Moles of NH4OH
to neutralize 25 mmol of H2SO4 = 2  25 = 50 mmol
−3
Thus, volume of NH3 at STP = 50 10  22.4 L = 1.12 L

4.(C) h1 = h0 + KE1  KE1 = h (1 − 0 )


h2 = h0 + KE2  KE2 = h (2 − 0 )
KE1 2 1 − 0
 = =  0 = 2 2 − 1
KE 2 1  2 − 0

5.(C) H – C – H bond angle in CH 4 is 109°28’


Cl – B – Cl bond angle in BCl3 is 120°
F – I – F bond angle in IF7 is 72° (equatorial)

I – I – I bond angle in I3 is 180°
Hence order is IV > II > I > III.

6.(D) NH4SH(s) NH3 (g) + H2S(g)


0.70 + P P
Now, 0.70 + 2P = 0.84  P = 0.07
KP = (0.70 + P)P = 0.77  0.07 = 0.0539 0.05

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7.(B) Applying pressure favours solidification of molten iron.

8.(D) As we know electron affinity of Cl > F > S > O.


9.(A) T1  T2  T3

10.(B) I. K.E. of molecule is zero at 0 Kelvin.


II. Gravity has no effect on pressure exerted by a gas.
III. (V – nb) full term reflects the actual volume available for the gas molecules to move.

11.(C) IE  Zeff , IE  penetration effect

12.(C) SO2 contains both p − p and p − d bonds.


CO2 contains only p − p bonds.
NO−2 contains only p − p bond.
NO3− contains only p − p bond.
SO2Cl2 contains two p − d bonds.
POCl3 contains two p − d bonds.
SO32− contains only p − d bond.
CO32− contains only p − p bond.
1240 1240
13.(B) Use E = = = 3.1eV
(in nm) 400
 3.1 = W0 + KE(1eV)  W0 = 2.1eV = 2110−1 eV

19
14.(D) C6 H14 ( ) + O2 (g) → 6CO2 (g) + 7H2O( )
2
c HC6H14 = [6  (−193) + 7  (−286)] − [−193] = − 2967 kJ / mol

c HC6H14 −2967
Calorific value of hexane = = = − 34.5 kJ / g
MC6H14 86

15.(B) Ba(NO3 ) 2 (aq) → Ba 2+ (aq) + 2NO3− (aq)


xM 2x M

Na 2CO3 (aq) → 2Na + (aq) + CO32− (aq)


1.010−4 M 210−4 M 1.010−4 M

BaCO3 (s) Ba 2+ (aq) + CO32− (aq)


BaCO3 is precipitated if [Ba 2+ ][CO32− ]  K sp

(x) (1.0 10−4 )  5.110−9  x  5.110−5 M

16.(D) Buffer consists of a weak acid and its salt having common anion or a weak base and its salt having
common cation.
+
SO, here NH4OH is a weak base having common cation NH4 with its salt NH4Cl.

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Similarly, CH3COOH is a weak acid and CH3COONa is its salt having common anion CH3COO .
In case of NaCN and HCl solution,
NaCN + HCl → Na + + Cl− + HCN
t =0 4 mmole 2mmole 0 0 0
t = 2 mmole 0 2 mmole 2 mmole 2 mmole
Now, HCN and NaCN are present in solution and acts as a buffer.
17.(A) During neutralisation of a weak acid by a strong base we can get an acidic buffer solution if reaction is
[salt]
completed by 9.09% to 90.9%. For an acidic buffer pH = pKa + log
[W.A]
Now
At 50% neutralisation ; [salt] = [W.A] ; pH = pKa
1
At 25% neutralisation ; [salt] = [W.A] ; pH = pKa − log3 = 4.52
3
At 75% neutralisation ; [salt] = 3[W.A] ; pH = pKa + log3 = 5.48
At 100% neutralisation stage we will obtain an aq. solution of salt of W.A / S.B then pH  7.00.
 dG 
18.(C) Using dG = VdP − SdT    =V
 dP T

19.(C) H = U + (PV) = U + (P2 V2 − P1V1 ) = 50 L - bar = 50  0.1 kJ = 5.0 kJ

20.(A) On addition of SCN− and Fe3+ , reaction shifts in forward direction due to common ion effect.

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SECTION-2
1.(56) Smix = − R  ni ni = 0.7  8 = 5.6 = 56 10−1 JK −1

2.(40) meq. of NaOCl = meq. of NaCrO2

NaOCl+1 → Cl− (n-factor = 2)


+3 +6
Cr O−2 → Cr O42− (n-factor = 3)
 2  0.15  V = 3  0.2  20  V = 40 mL

3.(3) Radial nodes = n − − 1


For 3s, number of radial nodes = 3 – 0 – 1 = 2
For 4p, number of radial nodes = 4 – 1 – 1 = 2
For 5d, number of radial nodes = 5 – 2 – 1 = 2

4.(2) Molecules having zero dipole moment are CCl4 and .

5.(750) Reaction will be in equilibrium when


G = 0
But G = H − TS
H
Thus, T=
S
H = − 30 kJ mol−1
1 3 
S = S(XY3 ) −  S(X 2 ) + S(Y2 ) 
2 2 
1 3 
= 50 −   60 +  40 = 50 − 30 + 60 = − 40 JK −1 mol−1
2 2 
− 30 1000 J mol−1
T= = 750 K
40 JK −1mol−1
Hence, at 750 K, reaction would be in equilibrium.

6.(5) Balanced equation is 6Br2 + 12NaOH → 10NaBr + 2NaBrO3 + 6H2O


10 mol NaBr  6mol Br2
10
3 mol of Br2   3 = 5 mol of NaBr
6

7.(1) w ABCD = Area enclosed


w ABCD = PV  x=1

8.(2) H 2 PO4− + H 2O HPO42− + H3O+


Acid Conjugate
base
pH is given by Henderson-Hasselbalch equation

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[HPO24− ]
pH = pK a + log
[H 2 PO−4 ]
[HPO24− ]
7.40 = 7.10 + log
[H 2 PO4− ]
[HPO24− ] [HPO 24− ] 2 [H 2 PO4− ]
 log = 0.30 = log 2  =  = 1: 2
[H 2 PO−4 ] −
[H 2 PO 4 ] 1 [HPO24− ]

9.(43) HA + BOH A− B+ + H2O


Since at equivalence point, total volume is 40 ml and both acid and base are of same molar strength,
initial volume of weak acid must be 25 ml.
HA + BOH A− B+ + H2O
mmoles initially 25  0.1 15  0.1
mmoles left 10  0.1 – 15  0.1
10  0.1 15  0.1
conc.
40 40
[salt]
pH = pKa + log
[acid]
[15 / 40]
4.48 = pKa + log = pKa + log3 − log 2; pKa = 4.3 = 4310−1
[10 / 40]
10.(2) In 3 and 5, entropy increases.

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MATHEMATICS
SECTION-1
1 1 1 1 4
1.(C) + =1  = 1−  e2 =
e 2
e2 e 2 4 3
2.(B) Given sides of triangle : x + y − 4 = 0, y − 2 = 0, x − 1 = 0
Clearly Δ ABC is a right angled triangle, Right angled at A.

 mid point of BC will be the circumcentre


2 + 1 3 + 2 3 5
circumcentre   ,   , 
(P)  2 2  2 2
2 2
3   5  1
circumcentre =  − 1 +  − 2  =
(PA) 2   2  2
 equation of circumcircle of ABC :
2 2 2
 3  5  1 
x −  + y −  =    x 2 + y 2 − 3x − 5 y + 8 = 0
 2  2  2 
3.(A) equation of tangent of slope ‘m’ to circle centred at ( − g , − f ) having radius ‘a’ is :

( y + f ) = m( x + g )  a 1 + m2
Given, g = − 1, f = 2, a = 3
 equation of tangent of slope ‘m’ to given circle.

( y + 2) = m ( x − 1)  3 1 + m2

 y = m ( x − 1)  3 1 + m2 − 2
4.(B) Equation of BC : y = 0  side BC is along X – axis.
Since (2, 0) is the mid point of BC  C  ( 4, 0 )

 

A   2cos , 2sin   1, 3
 3 3
( )
 0 + 4+ 1 0 + 0 + 3   5 1 
Centroid   ,    , 

 3 3  3 3
k 2 − 2k 1
1
5.(C) Points are collinear, so: 1 − k 2k 1 =0  2k 2 + k − 1 = 0 so k = −1 and . But for
2
−4 − k 6 − 2k 1
1 1  1   9 
k= , points are  , 1 ,  , 1 and  − , 5  which is a contradiction as given points
2 2  2   2 
are distinct.

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6.(C) Third vertex  ( x1 , y1 )

x1 + 4 − 9 y1 − 3 + 7
= 1  x1 = 8 ; = 4  y1 = 8
3 3
8 8 1
1 183
Area = 4 −3 1 =
2 2
−9 7 1

7.(C) (a 2 + b2 ) x 2 − 2(bc + ad ) x + c 2 + d 2 = 0
Roots are equal  D = 0

4(b2c 2 + a 2 d 2 + 2abcd ) − 4(c 2 + d 2 )(a 2 + b 2 ) = 0

 a2c2 + b2d 2 − 2ac  bd = 0


a b
 (ac − bd )2 = 0  =
d c
8.(B) 3x 2 − 2 x + p = 0

and 6x2 −17 x + 12 = 0  6x2 − 9x − 8x + 12 = 0  3 x ( 2 x − 3) − 4 ( 2 x − 3) = 0


4 3
 ( 3x − 4 )( 2 x − 3) = 0  x= ,
3 2
2
4 4 16 8 8
3  − 2   + p = 0  p=− + =−
3 3 3 3 3
27 27 15
−3+ p = 0  p = 3− =−
4 4 4
8 15 −32 − 45 −77
p1 + p2 = − − = =
3 4 12 12
9.(B)  + 22 = −a
 . 2 2 = 23 = b

(  + 22 )
3
= − a3

(
3 + 86 + 63  + 2 2 = − a3)
b
+ 2b2 + 3b ( −a ) = −a3
2
 2a3 − b ( 6a − 1) + 4b2 = 0

c
10.(B) H.M. =
2
=
2. 
(
 a  = − 2c = −2 8 + 2 5 = 4 )
 + −
b
a
b − 4+ 5 ( )

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 2 3a2
11.(C) b2 = a 2 1 −   b2 = ...(i)
 5 5
x2 y2
Let ellipse be + =1
a2 b2
(–3, 1) lies on it
9 1
 2
+ =1
a b2
9 5
 2
+ =1 (using equation (i))
a 3a 2
32 32
 a2 = and b 2 =
3 5
x2 y2
 equation is + =1
 32   32 
   
 3  5 
12.(B) Here, a2 + 2  a2 + 1

or (
a 2 + 1 = a 2 + 2 1 − e2 )( ) or (
a2 + 1 = a2 + 2 ) 56
or 6a2 + 6 = 5a2 + 10 or a2 = 10 − 6 = 4 or a = 2

Latus rectum =
(
2 a2 + 1 ) = 2  5 = 10
a2 + 2 6 6
13.(C) For given slope there exist two parallel tangents to the ellipse. Hence, there are two values of c.
Distance between foci 3
14.(A) Given that =
Distance between two direction 2
2ae 3 3
 =  e2 =
2a e 2 2

b2 3 b 1
 1+ 2
=  =
a 2 a 2

2  (1 5) − 1
29 28
15.(D)  (1  5) n
= (1  5) 2
+ (1  5)3
++ (1  5) 29
= (1  5) 
 0.5 
 = 2k − 2(1 5)
2

n=2

16.(B) Let a be the first term and r the common ratio of the G.P. Then, the sum is given by
a
= 57 …(1)
1− r
Sum of the cubes is 9747. Hence
a3 + a3r 3 + a3r 6 += 9747
a3
 = 9747 …(2)
1− r3
Dividing the cube of (1) by (2) we get

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a3 (1 − r 3 ) (57)3
=
(1 − r )3 a3 9747

1 − r3 1+ r + r2
or = 19 or = 19 or 18r 2 − 39r + 18 = 0
(1 − r ) 3
(1 − r ) 2

2 3 2
or (3r – 2) (6r – 9) = 0 or r = or =
3 2 3
3
[ r  , because 0 < | r | < 1 for an infinite G.P.]
2
17.(A) Any tangent is, y = mx  18m2 − 9
In this case, m = −1
Thus, tangent is, y + x = 3

1 x2 y 2
18.(C) Tangent in terms of m for y = 4 x is y = mx + 2
and for + = 1 tangent
m 8 2
1 1
is, y = mx  8m2 + 2 For common tangent we must have =  8m2 + 2  m = 
m 2
x x
Thus, common tangents are y = + 2 and y = − − 2
2 2
i.e. 2 y − x − 4 = 0 and 2 y + x + 4 = 0
19.(A) Parabola intersect y-axis at (0, 2), (0, 3)
20.(D) C  ( 7, − 1) r=5
Now y = mx touches the circle
7m + 1
 =5  ( 7m + 1)2 = 25 ( m2 + 1)
m2 + 1
 12m2 + 7m − 12 = 0  m1m 2 = − 1


 Angle between them =
2

Solutions | Page 14 JEE Main-6 (GEN 1&2) | JEE 2025


Vidyamandir Classes: Innovating For Your Success

SECTION-2
1.(1) C1C2 = | r1 − r2 |
 Circles touch internally
Hence, the number of common tangents is one.

a+b b
13
G13 + G23  a 2b + ab2 
A= , G1 = a 2 3b1 3 , G2 = a1 3b2 3 as r =    = 2 =2
 ab ( a + b ) 
2.(2)
2 a a Ab  
3.(6) 3sin 2  − 7sin  + 2 = 0
3sin 2  − 6sin  − sin  + 2 = 0
3sin  ( sin  − 2 ) − ( sin  − 2 ) = 0
1
 sin  = as sin   2
3
    2a b 
4.(17) P  a sec , b tan   P  , 
 6 6  3 3
x y
Therefore, the equation of tangent at P is − =1
3a 2 3b

1 3a
 Area of triangle =   3b = 3a 2
2 2
b b2
or =4 or e2 = 1 + = 17
a a2
5.(80) Let first term of G.P. be a and ratio be r.
 a + ar + ar 2 = 70 and 10ar = 4a + 4ar 2
 a = 40
1
r=
2
a 40
S= = = 80
1− r 1− 1
2
6.(6) a1 = h1 = 2, a10 = h10 = 3
3 = a10 = 2 + 9d
1
 d=
9
7
 a4 = 2 + 3d =
3
Also,
1 1 1 1
3 = h10 or = = + 9 D or D=−
3 h10 2 54
1 1 1 1 7 7 18
 = + 6D = − =  a4h7 =  = 6
h7 2 2 9 18 3 7

Solutions | Page 15 JEE Main-6 (GEN 1&2) | JEE 2025


Vidyamandir Classes: Innovating For Your Success

7.(4) |2 x − 1|2 −3 |2 x − 1| +2 =
Let |2 x − 1|= y

 y2 − 3y + 2 = 0  ( y − 2)( y − 1) = 0

( 3x − 4 y + 7 )
2
8.(4) ( x − 2) 2
+ ( y − 3)
2
=
25
( )SP2 ( PM 2 )
 Focus is ( 2, 3) & directrix is 3x − 4 y + 7 = 0
3 2 − 4  3 + 7
⊥ Distance from focus to directrix = 2a =
5
1 2
 2a =  4a =
5 5
9.(1) n + ( n + 1) = b = 2n + 1
n ( n + 1) = c

b 2 − 4c = ( 2n + 1) − 4n ( n + 1) = 4n2 + 1 + 4n − 4n2 − 4n = 1
2

10.(2) x, y and z are in G.P.


Hence, y = xr , z = xr
2

Also, x, 2y and 3z are in A.P.


Hence, 4y = x + 3z
 4xr = x + 3xr 2  3r 2 − 4r + 1 = 0  (3r − 1) (r − 1) = 0
1
 r= ( r  1 is not possible as x, y, z are distinct)
3

Solutions | Page 16 JEE Main-6 (GEN 1&2) | JEE 2025

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