MPDA246 inorganic Name : ..............................

Reg No : ...........................
SIXTH SEMESTER UG EXAMINATION APRIL 2024
Core - CHEMISTRY
CHE6B09 - INORGANIC CHEMISTRY-IV
2019 to 2021 Admission

Time : 2 Hours Maximum : 60 Marks

SECTION A
Answer upto 20 marks. Each question carries 2 Marks
1. State Beer-Lambert law.

2. The metallic radii of (5d) series of transition metals are virtually the same as those of the corresponding group
members of the second (4d) series. Comment

3. What are nonstocheometric compounds? Give two examples.

4. What is the oxidation number of central atom in [Co(NH3)6][Co(CN)­6]?

5. Write the IUPAC name of the following compounds.

(a)Na3[Co(OX)3] (b)[Ag(NH3)2][Ag(CN)2].

6. Write the low-spin and high-spin configuration for d7 system in octahedral filed.

7. What do you mean by spectrochemical series?

8. Write any two applications of coordination compounds in quantitative analysis.

9. What is oxidative addition? Give an example.

10. What is Pi-acid ligands? Give any two complexes which contain different Pi-acid ligands.

11. What is cooperativity effect?

12. What is the reason for the toxicity of Pb?

[ Ceiling of marks : 20 ]

SECTION B

PTO
 Answer upto 30 marks. Each question carries 5 Marks
13. Briefly explain the instrumentation of STM.

14. Explain colorimetry.

15. Explain band theory of metallic bonding.

16. Explain the ion exchange chromatographic process for the separation of lanthanides.

17. Draw the σ-bond MO diagram for a [CoF6] 3-.

18. Discuss the following

(a)Linkage isomerism in coordination compounds. (b)Optical isomerism in octahedral complexes.

19. Explain the biochemistry of Ca

[ Ceiling of marks : 30 ]

SECTION C
Answer any one Question(s). It carries 10 Marks
20. Explain the principle, instrumentation and applications of TEM

21. Discuss the possible kinds of structural isomerism in coordination compounds.

[ 10 * 1 : 10 ]

PTO