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Cambridge IGCSE® & O Level

Essential
Chemistry
Third Edition

d e n t m a t e r i a l
S a m p l e s t u

Roger Norris Mei Chew


Editor: Lawrie Ryan Bhavna Narayanan

Oxford excellence for Cambridge IGCSE® & O Level


Cambridge IGCSE® & O Level Cambridge IGCSE® & O Level
Essential Chemistry Student Book Essential Chemistry resources
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1.1 Solids, liquids
Unit 1: Particle theory

The kinetic particle theory

and gases In liquids and gases, the particles are constantly moving and
changing directions as they hit other particles. The idea that particles
are constantly in motion is called the kinetic particle theory.

Volume
The kinetic particle theory states that:
LEARNING OUTCOMES The three states of matter ●● particles in gases, liquids and solid behave as hard spheres
●● Describe the general Substances can be solids, liquids or gases. These are the three Pressure
●● particles in gases and liquids move randomly (in any direction)
properties of solids, liquids states of matter. Most substances can exist in all three states. For Fig.1.1.4 As the pressure of a gas increases, its
and gases example, water can exist as ice, liquid water or steam. ●● particles in gases do not attract each other volume decreases (at constant temperature).

●● Describe the structures of All matter is made up of particles. Three types of particles make up EXAM TIP
solids, liquids and gases in most matter – atoms, molecules and ions. Compressing gases
Note that increasing the
terms of particle separation, We can picture a gas as a collection of randomly moving particles temperature increases the
arrangement and motion An atom is the smallest particle that cannot be broken down by
chemical means. which collide with each other and with the walls of their container. average speed of the gas
●● State the effect of When we increase the pressure, the particles get closer to each particles, but increasing
temperature and pressure A molecule is an uncharged particle made of two or more atoms other. So the volume of the gas decreases. the pressure at constant
on the volume of gases using joined together. temperature has no effect on
the kinetic particle theory An ion is an atom or group of atoms that carries a positive or Heating gases the speed of the gas particles.
negative electrical charge. When the volume of gas is not fixed, for example in a gas syringe,
the volume of gas increases as the temperature increases. At higher
temperatures, the particles have more kinetic energy. So they move
faster and hit the walls of the syringe with greater force. So the plunger
in the syringe is pushed outwards, and the volume of the gas increases.

Volume
SUMMARY QUESTIONS
1 Which of these phrases refers to
a gases b liquids c solids? Temperature °C
Figure 1.1.5 As the temperature of a gas increases,
A solid has a definite shape and A liquid has a definite volume but takes the shape A gas has no definite volume. ●● The particles are close together its volume increases (at constant pressure).
volume, but cannot flow. of its container. It can flow. It can spread everywhere
throughout its container. ●● The particles are randomly arranged KEY POINTS
Figure 1.1.1 There are three states of matter: solid, liquid and gas.
●● The particles only vibrate. ●● Solids, liquids and gases can
2 Describe how a solid differs from a gas in its general be distinguished by their
We can explain the properties of solids, liquids and gases by properties. shapes and how easily they
looking at their particle arrangement, motion and separation (how flow or spread out.
close they are together). 3 State how the motion and average distance between the
gas particles changes in a closed container when a the
●● The properties of solids,
temperature increases and b the pressure increases. liquids and gases can be
explained in terms of the
Stronger Weaker
attractive closeness, arrangement and
forces
forces motion of their particles.
Figure 1.1.2 When solid iodine is heated it forms
a liquid at 114°C, then soon turns to gas at 184°C SOLID: arrangement: LIQUID: arrangement: GAS: arrangement: ●● The closer the particles in a
fixed pattern; random – no fixed pattern; random; gas, the higher the pressure
EXAM TIP motion: only vibrate; motion: slide past motion: move every
separation: close together each other; where rapidly;
and the lower the volume.
Remember that in liquids the separation: close together separation: far apart
particles slip and slide over each ●● Increasing the temperature
Figure 1.1.3 The general properties of solids, liquids and gases.
other. They are not completely of a gas increases the speed
free to move anywhere. at which its particles move.

2 3 3
1.2 Using the kinetic
Unit 1: Particle theory

Supplement
particle theory Gases and the kinetic particle theory
Pressure and volume

LEARNING OUTCOMES Changes of state The gas particles exert a force on the walls of their container,
causing pressure. When we decrease the volume of a fixed mass
●● Describe the changes of state
Melting of gas, the molecules get closer together and hit the walls of
in terms of melting, boiling,
When we heat a solid, energy is transferred to the solid. Its the container more frequently. This causes an increase in gas
evaporation, freezing and
particles gain energy and their vibrations are stronger. The forces pressure (see Figure 1.2.3). The higher the pressure, the closer
condensation.
of attraction between the particles are weakened and the the particles are to each other.
S ●● Explain the effects of EXAM TIP
solid melts. The solid turns to a liquid. The melting point is the gas molecules
pressure and temperature on When writing about the energy
temperature at which a solid turns to a liquid.
the volume of a gas using the increased in moving particles, make sure
kinetic particle theory. Boiling and evaporation pressure that you state kinetic energy
Heating a liquid to a higher temperature weakens the forces and not just energy.
LINK Figure 1.2.3 When the volume of the container is decreased,
of attraction between particles further. When a high enough the gas molecules are squashed closer together and hit the
Energy changes are looked at in temperature is reached, the attractive forces keeping the liquid’s walls of the container more frequently.
more detail in Topic 8.1 particles grouped together are broken. The particles can form
bubbles of gas that escape from the surface of the liquid. So as the Pressure and temperature KEY POINTS
bubbling liquid turns into a gas, we say that the liquid boils. The A closed container has a fixed volume. If we heat a gas in a closed ●● The terms melting, boiling,
EXAM TIP
boiling point is the temperature at which a liquid turns to a gas. container, as the temperature increases, the gas particles move condensing and freezing are
Remember that most of the faster and hit the walls of the container with increased force.
At temperatures below the boiling point of a liquid, some of its used for specific changes of
particles in liquids are touching We say that the molecules have greater kinetic energy (energy
particles have enough energy to escape from the surface. They state.
one another. It is a common associated with movement) at a higher temperature. Since the
error to think that all the form a vapour. This process is called evaporation. Energy needs to ●● In melting, boiling and
be taken in to melt, boil or evaporate a substance. volume of a closed container does not change, the pressure
particles are separated. evaporation energy is
increases when the temperature increases.
absorbed (put in).
Condensing and freezing
Temperature and volume ●● In condensing and freezing,
Cooling a gas makes it condense into a liquid. Further cooling
If the volume of the gas is not fixed, as for example in a gas energy is released.
results in the liquid freezing (solidifying). Energy is released
(given out or transferred) to the surroundings when a substance syringe, the volume of gas increases when the temperature ●● The volume of a gas
condenses or freezes. The surroundings include the air as well as increases. This is because at higher temperatures, gas molecules decreases when pressure
the container in which the solid, liquid or gas is placed. have more kinetic energy and move faster. The higher the increases because the
temperature, the greater is the force of the gas molecules on the particles are pushed closer
gas heating up syringe plunger. The plunger is pushed out until the pressure is together.
liquid boiling F balanced by the pressure of the atmosphere.
●● The volume of a gas in a S
Figure 1.2.1 Water changes to steam at its E
D syringe increases when
Temperature / °C

boiling point, 100°C SUMMARY QUESTIONS


temperature increases. This is
EXAM TIP 1 Give the names of these changes of state: because the particles hit the
solid liquid heating up a liquid to gas b solid to liquid
Remember the difference melting walls of the syringe with more
between boiling and B
c gas to liquid force at higher temperatures.
C
evaporation. Boiling takes solid heating up 2 Describe what happens to the energy and motion of the The volume increases as the
A
place at the boiling point of Time particles when ice changes to water. plunger moves outwards until
the liquid. Evaporation takes S 3 Explain, using the kinetic particle theory, how the volume of a the gas pressure in the syringe
Figure 1.2.2 The changes of state. Energy must be
place at temperatures below its absorbed to melt and boil a substance. Energy is released gas in a gas syringe changes when the temperature decreases. equals the atmospheric
boiling point. on condensing and freezing. The pressure is constant. pressure.
4 Explain, using the kinetic particle theory, how the volume of a
gas in a gas syringe changes when the pressure decreases.
4 5
1.3 Heating and
Unit 1: Particle theory

cooling curves
The flat part of the graph in Figure 1.3.2 shows where the solid is
gas cooling
changing to liquid. This is the melting point of stearic acid. There A
is no temperature rise here. So the energy supplied is not raising gas condensing

Temperature / °C
the temperature. The energy is being absorbed to overcome the X
B C liquid cooling
attractive forces holding the particles of solid in position. liquid freezing
E solid cooling
LEARNING OUTCOMES Using melting and boiling point data Y
D F
Cooling curves
●● Explain differences in We can determine the physical state of a substance at any given Time

physical state in terms of temperature by comparing the temperature with its melting point A cooling curve is a graph which shows temperature against time Figure 1.3.3 A cooling curve for the change
melting points and boiling and boiling point. Figure 1.3.1 shows the melting point and boiling when a substance is cooled at a constant rate. Figure 1.3.3 shows of state from gas to solid showing the boiling
points point of water. a cooling curve obtained when a gas at a temperature above its point, X, and the melting point, Y.
boiling point is cooled to form a solid below its melting point.
S ●● Explain changes of state ●● At 120°C water is a gas because 120°C is above its boiling point
using the kinetic particle (100°C) We can explain the cooling curve using ideas about the energy
theory and motion of the particles.
●● At 60°C water is a liquid because 60°C is above its melting point KEY POINTS
●● Interpret cooling curves and (0°C) but below its boiling point (100°C) ●● A–B: Decreasing the kinetic energy decreases the speed of
the gas particles. So the temperature of the gas falls.
●● The physical state of a
heating curves substance at a particular
●● At –15°C water is a solid because –15°C is below its melting
point (0°C) ●● B–C: The forces of attraction between the particles are temperature can be deduced
strengthened. The temperature is constant here because from its melting point and
heat energy is released when intermolecular attractive forces boiling point.
Supplement are formed. The heat given out during condensation stops
gas 120°C
the temperature from falling.
●● In melting, boiling and
Explaining changes of state evaporation energy is
100 boiling point
C–D: Decreasing the kinetic energy decreases the speed of the
Temperature / °C

Energy is absorbed or released when the particles in solids, ●● absorbed.


liquid liquids or gases rearrange themselves during a change of state. particles in the liquid. So the temperature of the liquid falls.
60°C ●● In condensing and freezing,
We can explain the shape of a heating or cooling curve of ●● D–E: The temperature is constant because heat energy is energy is released.
0 melting point temperature against time using ideas about the motion of the released when a liquid changes to a solid. The heat given out S
solid –15°C particles and energy changes. during freezing stops the temperature from falling.
●● The horizontal (flat) parts of
cooling and heating curves
Heating curves ●● E–F: Decreasing kinetic energy decreases the vibration of the show the melting point and
Figure 1.3.1 Water is a gas above 100°C and
particles in the solid. So the temperature decreases. boiling point.
PRACTICAL
a solid below 0°C.
A heating curve for stearic acid
EXAM TIP
A sample of solid stearic acid is heated at a constant rate SUMMARY QUESTIONS
When using melting and boiling using the apparatus shown. The temperature of the stearic
point data remember, for 1 Sodium chloride melts at 801°C and boils at 1413°C. Describe the physical state of sodium chloride
acid is recorded every 30 seconds.
example, that –200°C is a lower at a 970°C b 1500°C. Explain your answers.
Thermometer
Thermometer
temperature than –100°C. 2 Methane condenses at –164°C and freezes at –182°C. Describe the physical state of methane at
a –190°C b –150°C. Explain your answers.
3 Copy and complete using the words below: S
Temperature

Temperature

absorbed flat forces energy melting


(a) (a) (b) (b)

Water Water When we heat a solid, is absorbed and raises the temperature of the solid. At the
Stearic acid
Stearic acid point, the energy is to overcome the attractive between the particles rather than
Time Time
raising the temperature. That is why there is a part to the heating curve.
4 Sketch a graph to show how temperature changes when a solid is heated at a constant rate to form
a liquid and then a gas. Label the melting point of the liquid.
Heat Heat
5 Explain why there is no change in temperature when a solid melts.
Figure 1.3.2 a apparatus and b graph of results.

6 7 7
1.4 Solvents, solutes
Unit 1: Particle theory

Solubility

and solutions You can only dissolve a certain amount of substance in a solvent.
When we can dissolve no more substance, we say that the solution is
saturated. A saturated solution contains the maximum concentration
of a solute dissolved in a solvent at a particular temperature. Different
LEARNING OUTCOMES Solutes, solvents and solutions substances have different solubilities in a solvent. The solubility in
g/dm3 is the maximum number of grams of solute that can be
●● Define the terms solvent, ●● A solvent is a substance which dissolves another substance. dissolved to make 1 dm3 of solution. For example, you can dissolve up
solute, solution and Water, ethanol and hexane are examples of solvents which are to 340 g of potassium chloride in water to make 1 dm3 of potassium
saturated solution often used in chemistry. chloride solution. We say that potassium chloride is soluble in water.
●● State that concentration can ●● A solute is a substance which dissolves in a solvent. Salt You can only dissolve about 0.3 g of iodine in water to make 1 dm3
be measured in g/dm3 or dissolves in water. So salt is a solute. Solutes can be solids, of iodine solution. We say that iodine is very slightly soluble in
mol/dm3 liquids or gases. water. Its solubility is so low that we can think of iodine as being
●● Describe the chemical tests ●● A solution is a mixture in which a solute is spread evenly insoluble. Sand is a substance that does not dissolve in water at
for water throughout a solvent. all. Sand is insoluble in water.
●● Explain why distilled water is An aqueous solution is formed when a solute dissolves in
●●
Water
used in practical chemistry water.
Testing for water
●● A saturated solution contains the maximum concentration of
a solute dissolved in a solvent at a specified temperature. There are two common chemical tests for water: Figure 1.4.2 Blue cobalt chloride paper turns
pink if water is present
When a solution is made, the solute particles are completely mixed 1 When we add water to white anhydrous copper(II) sulfate it
up with the solvent particles (Figure 1.4.1). Every part of the solution turns blue.
has the same concentration of particles. We know that the substance 2 When we add water to anhydrous cobalt(II) chloride the cobalt KEY POINTS
Solute, has dissolved completely when we cannot see the solute any more. chloride changes from blue to pink. ●● A solvent is a substance
e.g. salt
Anhydrous means ‘without water’. When water is added to which dissolves another
Solution concentration. anhydrous copper(II) sulfate or anhydrous cobalt(II) chloride, substance.
these compounds become hydrated. Hydrated means that the A solute is a substance which
If we dissolve a lot of salt in 100 cm3 of water, we say that the ●●
Solvent, crystals have water chemically combined in their structure. This dissolves in a solvent.
e.g. water solution is concentrated. If we dissolve only a little salt in the same
water is called water of crystallisation.
amount of water, we say that the solution is dilute. We measure ●● A solution is a mixture in
Solute dissolves
concentration in grams per decimetre cubed (written as g/dm3). Water as a solvent which a solute is spread
1 decimetre cubed (dm ) = 1000 cm
3 3 evenly throughout a solvent.
Water from the tap or from the ground contains soluble impurities.
Solution of We can also measure concentration in moles per decimetre cubed We use pure water in chemistry rather than tap water because ●● Concentration in g/dm3 =
salt in water (written as mol/dm3). Moles are the unit used by scientists to these impurities can interfere with chemical experiments. For mass in g / volume in dm3
measure ‘amount of substance’. example, magnesium compounds in tap water can react with ●● Anhydrous copper(II) sulfate
Figure 1.4.1 In a solution, the solute and solvent chemicals added during an experiment, such as sodium hydroxide. and anhydrous cobalt(II)
particles are completely mixed up. We can use this equation to calculate concentration in g/dm3: This can cause the solution to go cloudy. For most work in the
mass of substance (in g) chloride are used to test for
concentration (in g/dm3) = volume of solution (in dm3) chemical laboratory, distilled water is used because this contains water.
very few chemical impurities.
Example: SUMMARY QUESTIONS
EXAM TIP
When calculating the Calculate the concentration of a solution of magnesium chloride 1 Give the meaning of these terms: a solution 4 Describe the colour change of anhydrous
concentration of a solution, containing 5 g of magnesium chloride in 200 cm3 of water. b anhydrous c insoluble d aqueous solution cobalt(II) chloride when an aqueous solution
200 of sodium chloride is added.
remember to convert cm3 to Step 1: change cm3 into dm3. 200 cm3 = 1000 = 0.2 dm3 2 Explain why tap water is not used for making
dm3. You can do this by dividing 5 solutions for chemical experiments.
Step 2: use the equation for concentration: concentration = 0.2
the number of cm3 by 1000.
= 25 g /dm3 3 Calculate the concentration in g/dm3 of
a solution which contains 4 g of sodium
hydroxide in 125 cm3 of water.

8 9
1.5 Diffusion
Unit 1: Particle theory

PRACTICAL
Diffusion along a glass tube
LEARNING OUTCOMES If we put a drop of ink into some water and leave it, the colour of A long glass tube is set up as shown.
●● Describe and explain the ink will spread throughout the water. Why is this?
Cotton wool soaked Cotton wool soaked in
diffusion using the kinetic The gradual spreading out and mixing up of different particles by in ammonia hydrochloric acid
particle theory random movement is called diffusion.
S ●● Describe and explain the Diffusion results in the particles spreading throughout the space
effect of molecular mass on available. The overall direction of the movement is from where White ring forms
the rate of diffusion in gases the particles are more concentrated to where the particles are less Figure 1.5.4 Apparatus to show the diffusion of gases.
concentrated.
EXAM TIP Concentrated hydrochloric acid gives off fumes of a colourless
gas called hydrogen chloride. Concentrated ammonia solution
You may be asked to explain
Water particles
gives off colourless ammonia gas. These gases diffuse along the
using the kinetic particle theory
Ink particles tube. After a few minutes a white ring is seen nearer one end
why the colour of a crystal
of the tube. When the molecules of ammonia and hydrogen
spreads through the water in
chloride collide with each other they react and form a white
which it is placed. Don’t forget Figure 1.5.1 The colour of the ink spreads because the moving particles of solid, ammonium chloride.
to write about the particles ink mix with the moving water particles.
going into solution as well as
writing about diffusion. Diffusion occurs only in liquids and gases because the particles Supplement
are able to move. Diffusion in gases is faster than in liquids. This
is because in gases the particles move rapidly but in liquids Speed of diffusion and molecular mass KEY POINTS
they move less rapidly. Diffusion does not occur readily in solids The speed at which a gas diffuses depends on the mass of its ●● Diffusion is the gradual
because the particles are packed tightly together and, although molecules. We compare the mass of molecules with each other by spreading out and mixing
they vibrate, they cannot move around. using their relative molecular masses, Mr. The greater the relative up of different particles by
molecular mass, the heavier the molecule. random movement.
Diffusion in gases
At the same temperature, molecules with a lower Mr move faster ●● Diffusion in liquids is slower
Diffusion provides evidence for the kinetic particle theory. Diffusion than molecules with a higher Mr. The white ring is nearer the than diffusion in gases.
occurs in gases because the molecules in gases are constantly hydrogen chloride end of the tube. This shows that hydrogen S
moving, colliding with each other and changing directions. This
●● A gas with a higher molecular
chloride has heavier molecules than ammonia. So hydrogen mass diffuses more slowly
results in the gases spreading out and mixing. If we put a gas chloride diffuses more slowly than ammonia.
jar containing (colourless) oxygen above a gas jar of bromine than a gas with a lower
vapour (brown), the molecules of the bromine vapour and oxygen molecular mass.
gradually mix because all the particles are moving and colliding SUMMARY QUESTIONS
randomly. 1 Copy and complete using the words below:
different diffusion gases mixed particles random
gas jar of The kinetic particle theory states that the in liquids and are in constant motion.
oxygen bromine When freely moving particles collide, they bounce off each other in directions. If the particles
molecules are different, they get up together. This process is called .
oxygen
molecules 2 Explain the following using the kinetic particle theory:
gas jar of
bromine a A red-coloured crystal is placed at the bottom of a beaker of water. At the start of the experiment
no colour is seen in the water. After two days, the red colour has spread throughout the water.
b A bottle of perfume is opened at the front of the classroom. After a little while, you can smell the
at start after 10 minutes after 30 minutes
Figure 1.5.3 The molecules in the gas jars collide and move randomly. This leads to the
perfume at the back of the classroom.
gases mixing by diffusion. S
Figure 1.5.2 Bromine gradually diffuses
3 The relative molecular masses of four gases are: carbon dioxide 44; methane 16; nitrogen 28; oxygen 32.
throughout the space available Put these gases in order of their rate of diffusion, with the fastest first.

10 11
SUMMARY QUESTIONS
1 Give definitions of:
(a) diffusion
Practice questions
(b) The experiment is repeated at 40 °C. The gas in a gas syringe. The temperature
(b) evaporation pressure is constant. Describe and explain stays the same. [3]
1 Sodium chloride is a solid which dissolves the difference in the volume of gas in the
(c) condensation. (b) Describe and explain the change in state
in water but not in hexane. Iodine is a solid syringe. [2] when water changes into steam. Use the
2 Match each of the words on the left with two which dissolves in hexane but not in water.
(c) Chlorine dissolves in hexane to form a kinetic particle theory and ideas about
of the statements on the right. Choose the mixture of substances which
solution. energy changes. [3]
forms a solution.
solid particles close together (i) Choose from the list, the word that best (c) The diagram shows the cooling curve when
A a mixture of iodine and sodium chloride describes the chlorine in this solution. sodium gas is cooled to form solid sodium.
particles move everywhere
B a mixture of sodium chloride and hexane gas saturated solute solvent [1]
liquid particles far apart C a mixture of iodine and hexane
can flow but has a definite (ii) State the units of concentration
D a mixture of sodium chloride and hexane [1] A
in a solution. [1]

Temperature / °C
surface B
(Paper 1) (d) Chlorine is a liquid at –120 °C. Describe
gas has a definite shape C
the arrangement and motion of the
particles only vibrate 2 A solution contains 2.0 g of copper(II) sulfate D
particles in liquid chlorine. [2]
dissolved in 50 cm3 of water. Choose the E
3 State whether energy is absorbed or released (Paper 3)
correct concentration of copper(II) sulfate
in these changes of state.
solution. 6 A student set up the apparatus shown. Time
(a) A solid changes to a liquid. A 0.4 g/cm3 C 40 mol/dm3
Cotton wool soaked Cotton wool soaked with (i) State which letter on the curve shows:
(b) A gas changes to a liquid. B 25 g/cm3 D 40 g/dm3 [1] with methylamine hydrochloric acid
Glass tube ● a liquid cooling
4 Match the words A to D with the definitions (Paper 2) ● a gas changing to liquid at the
1 to 4. 3 A crystal of a water-soluble red dye was boiling point. [2]
A anhydrous: 1 a substance which dissolves placed in a beaker of water. Methylamine and hydrochloric acid give off (ii) Explain what happens to the motion
in a solvent (a) Describe what you would see: vapours which react with each other to form a and separation of the particles when
B hydrated: 2 a substance which (i) after 10 minutes white ring at point S in the tube. a gas changes to a liquid. [2]
does not contain water of (ii) after several days. [2] (a) Use ideas about moving particles and (iii) Explain, in terms of energy changes,
crystallisation (b) Describe the arrangement and motion of energy to explain: the shape of the curve between
the particles in: (i) the process of evaporation C, D and E. [3]
C solute: 3 a substance which dissolves
(i) the crystal [2] (ii) the water. [2] from the cotton wool [2] (Paper 4)
a solid, liquid or gas
4 (a) Name the change of state from: (ii) how the particles of methylamine
D solvent: 4 a substance which contains 8 The diagram shows a porous pot, which
and hydrogen chloride move allows the passage of gases through tiny
water of crystallisation (i) solid to liquid (ii) liquid to gas
along the tube. [2]
holes in the walls of the pot.
(iii) gas to liquid. [3]
5 Describe and explain using the kinetic (b) Describe and explain the position Hydrogen
particle theory how the volume of a gas (b) Which two of these changes of state occur of the white ring, S, in the tube. [2]
changes when the temperature is gradually when energy is absorbed? Explain your answer
(c) An ammonia molecule has about half Porous pot
increased. Pressure is constant. using ideas about forces between particles. [2] CO2
the mass of a methylamine molecule. If
(c) Describe the arrangement and motion ammonia is used in this experiment in
6 Use ideas about particles to explain why: of the particles in a gas. [2] place of methylamine:
(a) a balloon gets bigger when you blow (Paper 3) (i) predict the position of the white ring [1]
into it Coloured
5 Chlorine is a green gas. A sample of chlorine (ii) suggest why the white ring would water
(b) solids have a fixed shape is placed in a gas syringe. be in this position by referring to
(c) you can’t squash a sealed syringe full of Blocked end Chlorine Syringe molecular mass. [2]
plunger
water. (Paper 4)
7 Sodium reacts with water to produce (a) Describe how this apparatus can be
hydrogen gas. used to show that hydrogen has a lower
molecular mass than carbon dioxide. [3]
(a) Describe and explain using the kinetic
particle theory, the effect of decreasing (b) Explain your answer to part (a) using the
(a) Describe and explain what happens when the volume on the pressure of hydrogen kinetic particle theory. [5]
pressure is applied to the syringe plunger. (Paper 4)
12 The temperature was kept at 20 °C. [2] 13
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