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Ap Chem Unit 6 Quiz
Ap Chem Unit 6 Quiz
Ap Chem Unit 6 Quiz
1.Refertothediagrambelow.Whichofthefollowingbestdescribesthereaction?
A. Exothermic,itgivesoutheat
B. Endothermic,itgivesoutheat
C. Exothermic,itabsorbsheat
D. Endothermic,itabsorbsheat
2.Refertothediagrambelow(maynotbedrawnexactlytoscale)
Whatistheactivationenergyforthereversereaction?
A. 80kJ
B. 60kJ
C. 40kJ
D. 20kJ
3.A100gmetalblockwiththespecificheatcapacityof480Jkg-1 K-1
isheatedinabeakerof
wateruntilitisboilingatroomtemperature(20°C).Afterthat,themetalblockisimmediately
transferredintoacoolerbeakerofwater.Thetemperatureriseinthecoolerbeakerofwateris1°C.
Whatisthemassofcoldwater?Assumenoenergylosstosurroundings.
(Specificheatcapacityofwateris4200Jkg-1 K-1
)
A. 0.142kg
B. 0.914kg
C. 1.14kg
D. Thequestioncannotbesolvedasthefinaltemperatureisnotgiven.
4.Awoodenblockandametalblockareheatedupatthesametimeatthesamerate.Themetal
blockistwicethemassofthewoodenblock.Thewoodenblockhasaspecificheatcapacity3
timesofthemetalblock.Thetemperatureofthemetalblockisincreasedbyk°C whilethe
temperatureofthewoodenblockisincreasedbyn°C .Whatis nk ?
3
A. 2
2
B. 3
1
C. 2
1
D. 6
5.Whichofthefollowingprocessesreleasethemostamountofenergy?
A. 50goficemelting
B. 50gofmetalcoolingof500Jkg-1 K-1
downfrom70°C to20°C
C. 50gofsteamcondensingintowater
D. 50gofwaterfreezingintoice
6.Mayawantstowarmupaglassofmilk(250mL)whichis4°C .Abouthowmuchenergyhasto
besuppliedtowarmupherglassofmilkto40°C ?Thedensityofmilkis1.035kg/Lwhilethe
specificheatcapacityis3930Jkg-1 K-1
A. 9315J
B. 34200J
C. 36600J
D. 354000J
7.Theheatcapacityof0.5kgofcarrotsis940JK-1
,theheatcapacityof1.5kgofcabbageis2940
JK-1
whiletheheatcapacityof3kgofbeefis5010JK-1
.Thefoodareinroomtemperature,and
mustbeheatedupto100°C tobesafetoeat.Whichofthefollowingcombinationsrequirethe
leastamountofenergyforcooking?
A. 1.7kgofcarrots,2kgofbeefand3.1kgofcabbage
B. 2kgofcarrots,1.2kgofbeefand2.4kgofcabbage
C. 4.3kgofcarrots,0.4kgofbeef,1.9kgofcabbage
D. 1.9kgofcarrots,2.9kgofbeef,1.9kgofcabbage
8.Whatisthechangeinenthalpyofthebelowreaction?
AB 2 + 3C −−> D + 2EF
Substance ΔH °
AB 2 1.79kJ/mol
EF -0.57kJ/mol
A. 2930J
B. -2930J
C. -3660J
D. TheanswercannotbedeterminedaswedonotknowthestandardenthalpyofCandD
9.Thefollowingreactionoccurs:
C H 3 OH + 128.49 kJ → 2 H 2 + CO
If100.8gofH 2 isproduced,howmanykJofheatwillbeabsorbed?
A. 12951kJ
B. 6475.9kJ
C. 6424.5kJ
D. 7844.9kJ
10.Carbonandhydrogenarecombinedtoformmethaneinaclosedcontainer.
C (s) + H 2 (g) → CH 4 (g) ΔH = − 74.85 kJ
If30gofH 2 isused,howmuchheatwillbereleased?
A. 2246kJ
B. 2228kJ
C. 1123kJ
D. 1114kJ
11.Acopperblockisbeingheatedupinroomconditions.Theresultasfollows:
Massofcopperblock mkg
Finaltemperature 45°C
Initialjoulemeterreading R1 J
Finialjoulemeterreading R2 J
Whatisthespecificheatcapacityofthecopperblock?
A. 26 m (R2 − R1 )
R2 −R1
B. 15m
R1 −R2
C. 15m
D. Thespecificheatcapacitycannotbedeterminedbecausetheinitialtemperatureis
unknown
12.TwosolidsXandYofequalmassareseparatelyheatedbytwoidenticalheaters.Thegraph
belowshowsthevariationofthetemperaturesofthesubstanceswithtime.Whichofthefollowing
statementsis/arefalse?
I. ThemeltingpointofXishigherthanthatofY.
II. ThespecificheatcapacityofXislargerthanthatofY.
A. Ionly
B. IIonly
C. IandIIonly
D. Noneoftheabove
13. Giventhat
15.Giventhat
AB→A+B 156kJ
2A→A2 -130kJ
AC→A+C -277kJ
B+C→BC -55kJ
Bond Bondenthalpy
A-A 405kJ
B-B 365kJ
FindthebondenthalpyofA-BifthetotalΔ Hofthereactionis-174kJ
A. -472kJ
B. 298kJ
C. 385kJ
D. 472kJ
17.1kgofacertainliquidat60°Cand0.5kgofthesameliquidat30°Caremixed.Whatisthe
finaltemperature?
A. 42°C
B. 45°C
C. 50°C
D. Thefinaltemperaturecannotbedeterminedbecausethespecificheatcapacityisnotgiven
18.Anequalamountofenergyissuppliedtothefollowingsubstances.Whichofthefollowing
willhavethesmallestriseintemperature?
A 1 4200
B 2 2200
C 3 1400
D 5 830
19.ThegraphbelowshowsthechangeintheenergyabsorbedbytheliquidsX,YandZofequal
massandtheircorrespondingtemperature.
Letcx ,cy andcz bethespecificheatcapacitiesofX,YandZrespectively.Whichofthefollowing
iscorrect?
C. cy =
cz <
cz
D. cy =
cz >
cz
20.Equalmassesoffourdifferentliquidsareseparatelyheatedatthesamerate.Theinitial
temperatureofalltheliquidsareall20°C.Theboilingpointsandspecificheatcapacitiesofthe
liquidsareshownbelow.Whichoneofthemwillboilfirst?
Specificheatcapacity(Jkg–1 K–1
) Boilingpoint(°C)
A 1100 50
B 785 70
C 600 90
D 170 300
Explanations
1.A.Exothermicreactionsgiveoutheat.Thiscanbeobservedwhentheamountofpotential
energydecreases.Energycanneitherbecreatednordestroyed.Someoftheenergywillbe
convertedintoheatenergyandescape.BandCareconceptuallywrong.
2.D
Reverseactivationratereferstothedifferenceinenergybetweentheproduct(s)(right)andthe
transitionstate(hill)
80kJ-60kJ=20kJ
3.B
Q = mcΔT
Assumenoenergylosstosurroundings
Qlost by metal block = Qgained by water
mmetal cmetal ΔT = mwater cwater ΔT
100g=0.1kg
0.1 × 480 × (100 − 20)= mwater × 4200 × 1
mwater = 0.914 kg (3 sig figs)
4.B
Theyareheatedupatthesametimeatthesamerate,meaningthattheenergysuppliedisthesame.
BytheequationQ = mcΔT ,
mwood cwood ΔT wood = mmetal cmetal ΔT metal
Letmassofwoodenblockbem,massofmetalblockbe2m,specificheatcapacityofwooden
blockbe3c,specificheatcapacityofmetalblockofmetalbec
2m × c × n = m × 3c × k
2mc × n = 3mc × k
Crossoutmc ,
2n = 3k
k 2
n
= 3
5.B
Whensteamcondensesintowater,moreenergyisreleasedthanwhenwaterfreezesintoice.
Energyofparticlesinagas>energyofparticlesinaliquid>energyof particlesinasolid
Moreenergyisrequiredtoturngasintoliquidthanfromliquidtosolidbecausemoreenergyneeds
tobereleasedsothattheparticles.
ChoiceA(icemelting)takesupheat.
Ametalcoolingdownmayreleaseheat,butduetothesmallspecificheatcapacity,theenergy
releasedismuchlessthantheamountofenergyreleasedwhensteamcondensesintowater.
6.C
250 mL = 0.25 L
1.035 kg
0.25 L × 1L
=0.25875 kg
Q = mcΔT
Q = 0.25875 kg × 3930 J kg −1 K −1
× (40 − 4)K
Q = 36607.95 J
Q = 36600 J (3 sig figs)
7.D
Convertthespecificheatcapacityofthecarrots,cabbageandbeefintothespecificheatcapacity
(1kg)soitiseasierforcomparison
Carrots 1880
Beef 1960
Cabbage 1670
9.C
1 mol H 2 128.49 kJ
100.8gH 2 × 1.008 g H 2
× 2 mol H 2
=6424.5kJ
10.D
Balancetheequation
C + 2 H 2 → CH 4
1 mol H
30gH 2 × 1.008 g H2 × 274.85
mol H
kJ
=1114kJ
2 2
11.B
Q = mcΔT
R2 − R1 = mc(45 − 20)
R2 −R1
c = 15m
12.B
Iistrue.Theflatpartofthegraph(plateau)meansthattheobjectischangingstate.
ThemeltingpointofXishigherthanYbecausethecorrespondingyvalue(temperature)ishigher.
IIisfalse.Asteeperslopemeansthattemperaturechangesquicker.Lessenergyhastobesupplied
forachangeinstate.ThespecificheatcapacityofXissmallerthanthatofY.
13.C
2A+2B2 →2AB2 (Δ H°)=566kJ
2AB2 →2AB+B2 (Δ H°)=-111kJ
2A+2B2 →
2AB+B2 (Δ H°)=455kJ
2A+B2 →2AB (Δ H°)=455kJ
14.A
2AB→A2 +B2 Δ H°=108kJ
A2 +4C→2AC2 Δ H°=-366kJ
2AB+4C→2AC2+B2 Δ H°=-258kJ
15.C
Requiredreaction: A2 +BC→AB+AC
A2 → 2A Δ H=-130kJ
A+B→AB Δ H=-156kJ
A+C→AC Δ H=277kJ
BC→B+C Δ H=-55kJ
Simplify,
A2 +BC→AB+AC Δ H=-64kJ
16.D
Δ H°=∑Δ H°products-∑Δ H°reactants
Δ H°=∑Δ H°bondsbroken-∑Δ H°bondsformed
LetbondenthalpyofA-B=x,
-174= 405+365-2x
2x=944
x=472kJ
17.C
Letthefinaltemperaturebetandspecificheatcapacitybec,Q=mcΔT
mcΔT=mcΔT
1(c)(60-t)=0.5(c)(t-30)
Simplifybycrossingoutc
60-t=0.5t-15
75=1.5t
t=50
18.B
Q=mcΔT.Theenergysuppliedisthesame
SubstanceA:Q=(1)(4200)(ΔT)
Q
ΔT= 4200
SubstanceB:Q=(2)(2200)(ΔT)
Q
ΔT= 4400
SubstanceC:Q=(3)(1400)(ΔT)
Q
ΔT= 4200
SubstanceD:Q=(5)(830)(ΔT)
Q
ΔT= 4150
Thenumeratoristhesame(Q).Thelargerthedenominator,thesmallerthevalueofΔT.For
substanceB,thedenominatoristhelargest(4400>4200>4150).Hence,substanceBhasthe
smallestriseintemperature.
19.A
Q=mcΔT,Slope= change in y
change in x
Q
= ΔT =mc
Themassisthesame.Therefore,thesteepertheslope,thegreaterthespecificheatcapacity.
SlopeofX=slopeofZ.cx =
cz.SlopeofY issmallerthanX .mcx >
mcy ,misthesame,socx >
cy
Hence,cx =
cz >
cy
20.A
Q=mcΔT
LiquidA:Q=(m)(1100)(50-20)=33000m
LiquidB:Q=(m)(785)(70-20)=39250m
LiquidC:Q=(m)(600)(90-20)=42000m
LiquidD:Q=(m)(170)(300-20)=47600m
Theliquidshavethesamemass,somisthesame
Theenergyissuppliedatthesamerate.Thefirstliquidtoreachtherequiredamountofenergyto
boilwillboilfirst.33000<39250<42000<47600,soliquidArequirestheleastamountof
energytoreachtheboilingpoint.LiquidAwillboilfirst.