XCu 1 0.8 0.6 0.4 0.2 0.

1 0
YCu 1 1.1 1.4 2 3.5 7.5 10

Regla del trapecio:

Fe XA YB X=inYB F(x)=Fe/XA trapecio I=integral YA=exp(-I)

0 1 10 2.30258509 0 0 0 1

0.2 0.8 7.5 2.01490302 0.25 -0.035960259 -0.035960259 1.03661465

0.4 0.6 3.5 1.25276297 0.66666667 -0.349314191 -0.38527445 1.47001771

0.6 0.4 2 0.69314718 1.5 -0.606250437 -0.991524887 2.69534143

0.8 0.2 1.4 0.33647224 4 -0.980856096 -1.972380982 7.18777008

0.9 0.1 1.1 0.09531018 9 -1.567553369 -3.539934352 34.4646566

1 0 1 0

R= 8.3144
Energia de exceso en el
sistema
∆𝐺 𝑋𝑆 = 𝑅𝑇 ෍ 𝑋𝑖 𝐼𝑛𝑌𝑖
∆GA
Energia parcial del Energia integral del
sistema sistema
∆𝐺𝐴𝑋𝑆 = 𝑅𝑇𝐼𝑛𝑌𝐴 = 𝛼𝑋𝐵2
T ∆G^XS
𝑋𝐵
300 0 2𝛼 𝑋𝐵2 𝛼𝑋𝐵2
400 119.595191 𝐼𝑛𝑌𝐴 = =
𝑅𝑇 2 0
𝑅𝑇
500 1921.99553
600 4946.36071
700 11479.4151
800 23545.9441

∆G^XS
25000

20000
20000

15000

10000

5000

0
0 100 200 300 400 500 600 700 800 900
-5000
 actividad vs fraccion mol
1.2

0.8

0.6

0.4

0.2

0
0 5 10 15 20 25 30 35 40

d∆𝐺
𝛥𝐺𝐴 = 𝛥𝐺 + 𝑥𝐵
A 𝑑𝑋𝐴 B

∆GB
XB
∆GA