PHYSICS,CHEMISTRY & BIOLOGY VERSION-C

EEPER NEET DCT-2024

PART B :CHEMISTRY
SECTION- A

Q51. The Bronsted acids in the revertible reaction,

HCO+OH CO +H,O
(1) OH and CO (2) OH and H,O
(4) HCO and CO
HCO and H,O
Q52. In Lassaigne method, the treatment of sodium fusion extract with sodium nitroprusside produces
violet colour which indicates the presence of
Phosphorous (2) Sulphur
3) Iodine (4) Bromine

Q55. When ozonised oxygen is passed through propylene which on reduction with Zn dust and water it

gives
PPropylene (2) Acetaldehyde
3) Propionaldehyde Acetaldehyde and formaldehyde

will be
054. The solubility product of BasO. is 1.3 10
x the solubility
(2)
of the salt in pure water
1.69 x 10-18 mol litre-
1) 1.69 x 109 mol litre-1
(3) 3.6x 10-18 mollitre (4) 3.6 x 10 mol litre

Q55. The correct IUPAC name of following compound is

OMe

NC
OMe O
(1) Methyl - 4 cyano -3 - methoxy pentanoate

4-methoxy -carbonyl -methoxy butanenitrile

(3) Methyl- 4 cyano -3 -methoxy butanoate
(4) 4-carbomethoxy-2- methoxy butanenitrila

Q56. At 37 C osmotic pressure of blood is 8.21 atm then intravenous injection which is isotonic to blood
can contain, how many of glucose per liter in it.
(1) 58.06 gm (2) 180 gm
(3) 18.06 gm 82.1 gm
Q57. Rate constant oftwo reactions are given below Identify their order of reactions,
() K=5.3 x 10 L mol-'s (i) K 3.8x 104 s-1
( ) Second order (i) first order (2) () First order (i) second order
3) ) Zero order (ii) first order (4) (i) Second order (i) zero order
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 PHYSICS,CHEMISTRY &BIOLOGY VERSION-C DEEPERNEET DCT-2024
Q58. Match List- I with List -II and select the correct answer using the codes given below the ists.
List I-Compound List I1- Oxidation state of N
(A) NO (1) +5
(B) HNO
(11)-3
(C) NH (IID) +4
(D) NaOs (IV) +1
A-II; B-Ill ; C-IV; D-I (2) A-III ;B-I;C-II ; D-IV
(3) A-11I ; B-IV; C-II; D-I (4) A-II;B-III;C-I;D-IV
Q59. Equimolal solution in the same solvent have_
(Same elevation in boiling point and same depression in freezing point.
(2) Different evaluation in boiling point and different depression.
(3) Some elevation in boiling point but different depression in freezing point.
(4) Some depression in freezing point but diflerent elevation in boiling point.

Q60. Three element X, Y, Z has atomic numbers 18, 19 and 20 respectively. How many electrons are
present in the M shells of these element?
Q8,9, 10 (2) 8, 10, 13
(3) 8, 8, 8 (4) 8,9, 12

Q61. Which of the following compound give positive Iodoform and Tollen's test?
(1) CH:CH:OH (2) CH:CH CHCHO
CH:CHO (4) CHCOCH3

Q62. What will be the value of AH - AU for formation of carbon monoxide at 298 K temperate?
(1) -1238.78 J mol- (2) 1238.78 J mol-l
(3)-2477.54J mol- (4) 2477.57 J mol-l

Q63. Radioactive disintegration is an example

(1) Zero order reaction. First order reaction.
3) Second order reaction. (4) Third order reaction.

064. The density of 98% W/W aqueous solution of H:SO4 is 1.8 gmL-, then its molarity will be
(1) 20 M (2) 10 M
(3) 18 M (4) 24 M

Q65. Which of the following reaction not gives amine product?

Na
(1) R-X +NH (2) R-CH= N- OH + [HJ CH,OH
LiAIH
(3) R-CN+H0 R-CONH2
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 PHYSICS, CHEMISTRY &BIOLOGY VERSION-C EPER NEET DCT -2024
Q66. The Product A and B in the following reaction sequence are

(i)HBr (i)SOC >B

A
Ph i)Mg dry ether i)CH NH
(ii) CO, H,0
,CH3
OH
H

(1) A= B

,CH
N
OH H

(2) A B
OH

CH3
A B
OH

CH3
(4) A= B=

Q67. The mass of oxygen would require for complete combustion of 2.8 kilogram of ethene (CaHa) will
be
(1) 2.8 Kg (2) 6.4 Kg
9.69.6 Kg (4) 96 Kg

Q68. Which of the following complex is paramagnet ic?

(1) Ni (NH:):Ch] K:[NiCu)
3) Ni (NH:)4]Ch (4) K2 [CoCl]

6 9 . Inter halogen compounds are more reactive then the individual halogen because
(1) They are prepared by direct combination and halogen.
X - X bond is weaker than X-X.
(3) They are thermally more stable than halogen.
(4) There is large difference in their electro negativity.

Q70. Which of the following is a correct set.

H20, Sp', angular (2) HO, Sp, linear
3) NHA', dsp, square planner (4) CH4, Sp?, tetrahedral
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 PHYSICS, CHEMISTRY &BIOLOGY VERSION-C DEEPERNEET DCT-2024
Q71. An oxide X in it's normal form is almost non-reactive due to very high X-O bond enthalpy. It resists
the attack by halogens, hydrogen and most of acid and metals even at elevated temperature, It only
attack by HF and NaOH. The oxide X
is
(1) SiO2 ) CO
(3) SnO2 (4) PbO2

Q72. Regarding Lanthanide.

(i) La (OH)3
is less basic then Lu(OH)3.
(i) As we move from Ce" to Lu their lonic radii decreases.
(ii) La is infact transition element.
(V) Atomic radius of Zn and Hfare similar due to lanthanide contraction.
The correct (T =True, F =False)
sequence of T and F is
(1) TFTE (2) FTFT
3) TFFF 4 FTTT

Q73. How much amount of reactant would be left after one hour in a first order reaction having half
period of 15 minute?

(1) 2) 4

(3)
16
Q74. From the following pairs of ions which one is not an iso-electronic pair?
(1) Fe2, Mn? (2) 0, F
4) Mn, Fe+
Na', Mg?
Q75. Identify incorrect pair.
1) Orthophosphorous acid dibasic oxidation number of P=+3
- -

(2) Dis phosphonic acid -tetra basic -oxidation number ofP =+5
3) Hypo phosphoric acid dibasic oxidation number ofP + 4
-
=

(4) Phosphonic acid dibasic oxidation number ofP + 1

- -
=

Q76. The 0.1 M aqueous solution of, acid HQ has PH =3, then it's lonisation constant will be
(1) 3x 10-1 (2) 1x 103
1x10- I x 107

Q77. Fe" compounds are more stable than Fe" compounds because
(1) Fes has smaller size than Fe2 F e s t has 3d configuration half filled
3) Fe3 has higher oxidation state (4) Fe" is paramagnetic in nature

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 PHYSICS, CHEMISTRY & BIOLOG VRRNION-
DERPER NETT DET 2024
Q78. Whieh
ofthe following order is correot for atomlo/ ionie radiu8
() AP <0Ne< Na () A<NeNa' 0
A'0
A Na' <Ne <O (4) Na' Ne

Q79 Whioh complex ion posNeSNeN geometrioal and optioalisomeriam?

Co(en):CL 2) [C%Cl(NH)3
3) (CoCb(NH)A (4) [Cr (Ox)
Q80. Aluminium Oxide is not reduced by chemioal reactiona due to
()it'shighly stable nature (2) i'a highly unatable nature
it's amphoterie nature (4) it's highly explo8ive nature

Q81 t combustion enthalpy of carbon and methane is-x kJ mol and- kJ mol and formation
C0 enthalpy ofwater is-y kJ mol" and then caloulate enthalpy of formation ofmethane,
- - x + 2y) k
CHG ()-x-y+2)
(3)--2y-2)klkJ (4) (-X-2y + z) Kj

Q82. If cIcH,coONa224 S en mol ANaCl -38.2 S on'mol' and AI 203 S om mol then

value of cCH,coOH Will be,

(1) 288.5 S em g eq () 289.5 S em g eq

388.8S em geq (4) 59.5 S cmg eq

Q83. Which one of following will have the highest bond order?
(1) NO CN
(3) CN (4) NO

Q84. Match List I with List-II.

List I (Oxoacid
ofsulphar) List 11 (Bonds)
(A) Peroxodisulphric acid Two S-OH, FourS 0, One S-O-S
(B) Sulphurie acid (i) Two S-OH, One S 0
(C) Pyro sulphuric acid (i) TwoS-OH, Four S O, One S-0-0-S
(D) Sulphurous acid (iv) Two S-OH, Two S=O
Choose the correet answer.
A-ii; B-iv;C-i; D-ii (2) A-iB-ili; C-iv ;D-i
(3) A-ii; B-iv;C-i ; D-i (4) A-i:B-ii ; C-i; D-iv

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PHYSICS, CHEMISTRY &BIOLOGY VERSIONC DEEPER NEET DCT -2024
Q85. Match list -I Match list -II.
List-I List- II
(a) PC Square pyramidal
()
(b) SF% i) Trigonal planar
(c)BrFs (i) Octahadral
(d) BF3 (iv) Trigonal bipyramidal
Choose the correct answer from the
option.
(1) a-iv ;b-ii ; c-ii ;d-i a-iv; b-ii ; c-i; d-ii
(3) a-ii; b-ii; c- iv; d-i (4) a-iii; b-i;c-iv;d-ii

SECTION -B
Q86. The major product formed in the following conversion is

CH-C CH3 (i)NaBHa

Maior product
(ii)H,SO

(2)

() (4)

Q87. Which one is the most acidic compound?

OH

OH

2) NO
(1)
OH OH
NO NO2
O
NO2 (4) CH3

Q88. RNA is different than DNA because in RNA is present.

ribose sugar and thymine
(1) deoxyribose sugar and Uracil (2)
(3) deoxyribose sugar and adenine ribose sugar and Uracil
work
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PHYSICS, CHEMISTRY & BIOLOGY VERSION-C DEEPER NEET DCT -2024
Q89. Anisole react with HI gives.
OH
+CH,OH +CH
(1) (2)
OH

(3)
OJ +CH,OH +CH

Q90. What are hormones and antibiotics?

(1) Carbohydrate 9Protein
(3) Lipid (4) Nucleic acid

Q91. Pair of acetone and prop--en-2-ol are example of which type of Isomerism?
(1) Position Tautomerism
(3) Functional group (4) Metamensm

Q92. The most convenient method to prepare an amine containing one carbon less than reactant is
(1) Gabriel phthalimide synthesis. (2) Reductive animation of aldehydes.
Hoffimann bromamide reaction. (4) Reduction of so nitriles.

Q93. A compound 'X with molecular formula C Hs is treated with Ch in presence of catalyst FeCh
Which of the following compounds are formed during the reaction?
CH CH CH, CH,
CI CI CI

O
CI (2) CI

CH CH, CH, CH,

CI

(3) Cl (4) CI C

Q94. Br H C =CH, x is
(1) Alcoholic KOH (2) Alcoholic KOH + NaNH2
(3) Aqueous KOH + NaNH2 (4) Zn/CH OH

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oHYSICS, CHEMISTRY &BIOLOGGY DEEPER NEET DCT -2024
95. Maximum how many electron can be filled inVERSION-C
Ma;
itals together from K to N shell.
all orbital
(1) 60
(3) 32 (2) 30
(4) 16

096. Which of the

following indicateth reaction time for first order reaction?
K 4
(1)
2.303 log (2 ) 230
K
1083
3) 2305
K
10g 4
K 3
4)2303
2.303 oE

097, Products of Aldol condensation

is/are
Unsaturated aldehyde or unsaturated ketone (2) Unsaturated acid
(3) Saturated acid
(4) Saturated aldehyde or saturated ketone
Q98. Make the incorrect match.
(1) Insulin - Zinc Hemoglobin - Iron
2
(3) Vitamins B12-Cobalt Chlorophyll - Chromium

Q99. In aqueous solution which of the following is correct order of basicity.

(1) NH< CsHsNH2 < (C.Hs)pNH < CaHsNH; < (CaHs)3N
(2) CsHsNH2 <NH < (CHs)3N < CaHsNH2 < (CHs)2NH
(3) CoHsNH2< NH < CHsNH2 < (CaHs)3N <(CoHs)2NH
4) (CoHs)NH < (C2H)3N < CaH$NH2 < NHJ < CcH;NH2

Q100. Identify the major product P, Q and R in following.

+CH,CH,CHCIAnhydrous (1)0,
P Q+R
AICl i) H,O+A
CH(CH)2 OH

(1) P= Q= R CH3CH(OH)CH3
CHCHCH2 OH COOH

(2) P= Q= R=
CH,CHCH CHO

(3) P= Q= R= CH3-CH-OH
CH(CH)2 OH

P= Q= R CH-Co-CH3

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