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10-02-24 XPL 2.0 Module Exam 6 Solutions
10-02-24 XPL 2.0 Module Exam 6 Solutions
SOLUTIONS
PHYSICS
1. Ans : (2)
¯ ¯ ¯ ¯
¯ ¯ ¯ ¯ ¯ ¯
¯εavg ¯ = ¯ ∆ϕ ¯ = ¯ 0 − 2 ¯ = 1 V
¯ ∆t ¯ ¯ 6 ¯ 3
2. Ans : (1)
¯ ¯
¯ ∆ϕ ¯
εavg = ¯¯ ¯
∆t ¯
¯ ¯
¯0 − 20 × (0.1)2 ¯
⇒ 10 =
∆t
⇒ ∆ t = 20 ms The emf will be induced in each loop in such a
way that induced current will be anti-clockwise
3. Ans : (4)
bigger loop so that net induced flux , should op-
dϕ ¡ ¢
e=− = −3 3at2 − 2 bt pose the flux increasing in ⊗ direction : ε2 > ε1 ∵
dt
¡ ¢ {Induced emf will be greater in the bigger loop}
ε
i = = − 3at2 − 2 bt So, current in bigger loop will be anti-clockwise
R
di and in the smaller loop clockwise.
= −(6at − 2 b) = 0
dt
b 6. Ans : (3)
t= Current at t1 , t2 , t3 , will be in same direction as
3a
dt is of same sign (negative) at t 1 , t 2 and t 3 .
di
b
At t = , i = i max
3a
· µ ¶2 µ ¶¸ 7. Ans : (3)
b b b2
⇒ i max = − 3a − 2b = = 6A
3a 3a 3a
4. Ans : (3)
¯ ¯ ¡ ¢
¯ d ϕ ¯ d BπR 2 dR
|ε| = ¯¯ ¯= = B π2 R = 2π (R 0 + t) B
dt ¯ dt dt
As radius increases, magnetic flux through the
loop increases. To oppose that induced current 8. Ans : (1)
will be anti-clockwise. According to Lenz’s law, conductor Q will be at-
tracted to conductor P to oppose change of flux.
5. Ans : (1)
9. Ans : (1)
1
12. Ans : (1) 20. Ans : (4)
ε = Blv = 4 × 1 × 20
21. Ans : (1)
= 80 V Current in inductor branch will gradually in-
q = C ε = (10µF)(80 V) crease to its steady state value.
= 800µC
22. Ans : (2)
q A = + q = +800µC;
For current to be maximum; 100π t + 30◦ = 90◦
q B = − q = −800µC
π
⇒ 100π t =
13. Ans : (3) µ ¶2
3
N l 1
L = µ0 n 2 V = µ0 π r 2 l and N = ⇒ t= s
l 2π r 300
µ0 l
⇒L= ⇒L∝l 23. Ans : (2)
4π
AC ammeter measures rms current.
Since length is same, self-inductance will be p
same.
(300
p 2)
Vrms 2
i rms = =³ ´ = 30 mA
Xc 1
14. Ans : (2) 100×10−6
di 2
ε=M = M (10 × 100π cos(100π t)) π π π
dt Hence, ω ( t1 − t2 ) = − ⇒ t2 − t1 =
2 4 4ω
εmax = (1000π) M = 5π ⇒ M = 5mH = 2.5 × 10−3 s
dU 1
µ
di
¶
di
µ 2 ¶µ ¶
t 2t
28. Ans : (1)
= L 2i = Li =2 1
dt 2 dt dt 2 2 x L = x C ⇒ ω0 L =
ω0 C
dU ⇒ ω20 LC = 1
At t = 1 s; = 1 J/s
dt x0L 2ω 0 L
0 =³ ´ = 4ω20 LC = 4 : 1
xC
19. Ans : (1)
1
2ω0 C
At t = 0, inductor acts as open circuit. At t = ∞,
inductor acts as short-circuit. 29. Ans : (1)
2
Xc =
1
⇒ Xc ∝
1 35. Ans : (4)
ωc ω f secondary = f primary = 50 Hz
As frequency is increased, X C decreases. So,
impedance of circuit decreases and current in-
36. Ans : (3)
creases. Hence, brightness of bulb will increase.
∆ϕ
∆Q =
30. Ans : (2) R
L
Time constant = = τ ⇒ L = τR 37. Ans : (2)
R
Let angular speed of electron be ω at any time
R 1
Power factor = cos ϕ = p =p eω µ0 i
R 2 + (ωL)2 1 + (ωτ)2 i= ;B =
2π 2R
³ µ ³ eω ´´
31. Ans : (4) ϕ=
0
πr2 ;
2R 2π
p
500 2 d ϕ µ0 er 2 d ω µ0 er 2
E rms = p = 500 V ε= = = α
2 dt 4R dt 4R
q
E = VR2 + (VL − VC )2 38. Ans : (4)
q
⇒ 500 = (400)2 + (700 − VC )2
⇒ VC = 400 V
or VC = 1000 V
p
Peak voltage across capacitor = 2VC
p p
= 400 2V or 1000 2V
V2 N2 i 1 1 i1
= = ⇒ =
V1 N1 i 2 5 12.5 · µ ¶¸
x+d
⇒ i 1 = 2.5 A εBC = B0 1 + v0 d
a
³ x ´
εD A = B 0 1 + v0 d
a
3
εnet = εBC − εD A
B 0 v0 d 2
=
a
εnet B 0 v0 d 2
i= =
R aR
4
Solving Eqs. (1) and (2), we get V 2 (100)2
Resistance of bulb, R = = = 100Ω
s P 100
XC 3
= P 100
R 5 i= = =1 A
V 100
CHEMISTRY
51. (3): 56. (1)
Biomolecule Metal atom/ion present Ligand Denticity
Chlorophyll Magnesium (a) en, ethane-1,2-diamine 2
Haemoglobin Iron (b) Cyanide, CN− 1
Vitamin B12 Cobalt (c) ox, Oxalate 2
(d) nitrito, NO−
2 1
52. (2):
Primary valences are ionizable; it is secondary 57. (3)
valence that are non-ionizable.
53. (4):
Here the complex is
H2 [PtCl6 ]
5
(2): (Correct):
61. (2):
Here Linkage, ionization, and coordination iso-
merism are correctly indicated.
65. (4)
63. (4)
(1):Correct:
£ ¤
Zn( gly )2 ,
Diglycinatozinc(II) is a tetrahedral complex with 66. (1):
no plane of symmetry; thus can exist as a pair of Both the statements are correct; further, state-
non-identical non superimposable object form ment II explains statement I, too.
and mirror image forms.
67. (4):
Valence EC of Co = 4 s2 (↑↓)3 d7 (↑↓↑↓↑↑↑) Valence
EC of Co3+ : 4 s0 (0)3 d6 (↑↓↑↑↑↑) NH3 is a fairly
strong ligand; it can pair up electrons to create
6
vacancy in inner d-subshell. together in the same order, gives the spectro-
Valence EC of Co3+ after pair up: chemical series , except (Cl− )missing between
4 s (0)3 d (↑↓↑↓↑↓) Making use of vacant 4 s, two
0 6 SCN− and S−2
vacant 3 d and three vacant 4 p, the ion under-
goes d 2 sp3 hybridization. 74. (3):
All the given statements are correct here.
68. (2)
Column I Column II 75. (2)
£
(A) [Ag (NH3 )2 ]+ (iii) sp, linear Co(CN)6 3−
(B) [Ni(CN)4 ]2− (ii)dsp 2 square planar based on chart 9.3
(C) [Ni(CO)4 ] (iv) sp3 , tetrahedral absorbs from uv light
(D) [Fe(CN)6 ]3− (i) d2 sp3 , octahedral
76. (1):
69. (1): Only when ligands approach the central atom or
Valence EC of Co = 4 s2 (↑↓)3 d7 (↑↓↑↓↑↑↑) Valence ion, crystal field splitting happen accordingly.
EC of Co3+ : 4 s0 (0)3d 6 (↑↓↑↑↑↑) F is a fairly weak If splitting is not there all the five d - orbitals
ligand; it cannot pair up electrons to create va- are degenerate and so transfer of electron be-
cancy in inner d-subshell. tween them require no energy; so no absorption
Making use of vacant 4 s, two vacant 4 d and of light.
three vacant 4p, the ion undergoes sp3 d2 hy-
bridization. The presence of four unpaired elec- 77. (2):
trons makes the molecule, paramagnetic. Ruby and emerald are Natural gem stones which
are chemically alumina and beryl with some
70. (3): Cr3+ ion as impurity in them .
79. (3):
α-nitroso- β-naphthol is used to remove ions like
Cu2+ , Pb2+ , Cr3+ etc., from waste water or from
drinking water.Lead poisoning is removed using
CaH2 EDTA.
80. (2):
72. (1):
82. (4):
All the given statements about crystal field the- p
Here n(n + 2)µB = 3.87BM
ory are correct.
So, n(n + 2) = 3.872 = 14.98; so, approximately
n = 3.
73. (4):
All are correct; (a), (b), and (c) if presented So, here there are 3 unpaired electrons. (i) d7
7
configuration, weak ligand: High spin d7; E.C.:
For weak ligands, crystal field splitting is low t 2 g 5 ; e g0
and so ∆ < P; so the E.C. will be t52 g e g2 ; then
there will be one unpaired electrons in t2 g and CFSE = [−0.4 × 5 + 0.6 × 2]∆0 =
two unpaired electrons in eg level. The configu- (−2.0 + 1.2)∆0 = −0.8∆0
ration will be The highest octahedral crystal field splitting en-
ergy release is for case (3) here, which offers
maximum stability too.
86. (2)
Strong field complexes:
d4 : t2g 4 eg 0 ; so, two unpaired electrons.
Since there is only one unpaired electron this is d5 : t2g 5 eg 0 ; so, one unpaired electron.
not the case d6 : t2g 6 eg 0 ; so, no unpaired electrons.
(iii) d 3 in a strong field as well as weak field: d7 : t2g 6 eg 1 ; so, one unpaired electron.
t32 g Weak field complexes:
↑ ↑ ↑ d4 : t2g 3 eg 1 ; so, four unpaired electrons.
This also explains the observed magnetic mo- d5 : t2g 3 eg 2 ; so, five unpaired electrons.
ment. d6 : t2g 4 eg 2 ; so, four unpaired electrons.
So (i) & (iii) are valid cases. d7 : t2g 5 eg 2 ; so, three unpaired electron.
Thus, we see, for the total number electrons is 4,
83. (4): or 5 , or 6 , or 7 , if we compare number of un-
In both these complexes, synergic bonding can paired electrons in weak field complex Vs strong
happen; that is, the central metal atom, ion can field complex, they are never the same, but is as
donate back its lone pair of electrons in the va- d4 (2, 4); d5 (1; 5); d6 (0; 4); d7 (1; 3).
lence shell to antibonding π MO (or π∗ MO ) of
CO molecule; the term synergic means mutually 87. (4)
strengthening. (1): [Ti (H2 O)6 ]4+ :
Valence E.C. of Ti : 4 s2 3 d2
84. (3): Valence E.C. of Ti4+ : 4 s0 3 d0
So, no unpaired electrons at all; so, expected to
85. (3) be colourless.
CFSE (2): [Sc (H2 O)6 ]3+ :
h ¤ Valence E.C. of Sc : 4 s2 3 d1
= −0.4 × N e( t2 g ) + 0.6× N e( e g) ∆0
Valence E.C. of Ti4+ : 4 s0 3 d0
Case.(1): High spin d6 So, no unpaired electrons at all; so, expected to
be colourless.
; E.C.: t2 g 4 ; e g2
(3): [VF6 ]− :
CFSE = [−0.4 × 4 + 0.6 × 2]∆0 =
Valence E.C. of V : 4 s2 3d 3
(−1.6 + 1.2)∆0 = −0.4∆0
Valence E.C. of V5+ : 4 s0 3 d0
Case.(2): Low spin d 4
So, no unpaired electrons at all; so, expected to
; E.C.: t2 g 4 ; e g0 be colourless.
(4): [Mn (H2 O)6 ]3+ :
CFSE = [−0.4 × 4 + 0.6 × 0]∆0
Valence E.C. of Mn : 4 s2 3 d5
= (−1.6 + 0)∆0 = −1.6∆0 Valence E.C. of Mn3+ : 4 s0 3d 4
So, four unpaired electrons; expected to be col-
Case.(3): Low spin d5 ; E.C.:
ored, and actually it is violet colored.
t 2 g 5 ; e g0
88. (1)
CFSE = [−0.4 × 5 + 0.6 × 0]∆0 = £ ¤
RhCl (PPh3 )3 :
(−2.0 + 0)∆0 = −2.0∆0 Chloridotris(triphenylphosphine)rhodium (I)
Case.(4):
8
ment:
↑↓ ↑↓ ↑↓ ↑↓
89. (3)
95. (3):
Stronger the ligand, higher the energy required
to excite electron, higher the light frequency,
lower the wavelength. Here strengths of ligands,
The di square pyramidal structure with Mn-Mn CN− > NH3 > H2 O; so order of wavelengths ab-
bond. sorbed:
£ ¤3+
90. (2): [Co (H2 O)6 ]3+ > Co (NH3 )6 > [Co(CN)6 ]3−
Both statements are independently correct here;
reason does not explain assertion. 96. (4)
∆o = 9/4∆t
91. (3): 9
= ×1600 = 3600
Vitamin B-12, contains the metal cobalt 4
97. (4):
92. (3):
£ ¤ triphenyl phosphene is a monodentate ligand,
Cr (NH3 )5 (NCS) [ZnCl4 ] where P is the ligating atom
is pentamminethiocyanato- N- chromium(III)
tetrachloridozincate(II).
93. (2):
Valence E.C. of Ni : 4 s2 3 d8
Valence E.C. of Ni2+ : 4 s0 3 d8
Valence E.C. of Ni2+ after strong field rearrange-
9
98. (1)
Beryl is aluminosilicate ore of beryllium,
Be3 Al2 Si6 O18 .
99. (2)
100. (2):
Ratio of observed osmotic pressure and calcu-
lated colligative property will be the same if the
substance is a non-electrolyte, that is, that which
neither dissociates, not associates in solution; in
£ ¤
the given set, Fe(CN)3 (NH3 )3 alone is a non-
electrolyte, whose Vant’ Hoff factor is 1.
BOTANY
101. (3) 111. (1) 121. (2) 131. (1) 141. (1)
102. (3) 112. (2) 122. (1) 132. (1) 142. (1)
103. (2) 113. (1) 123. (1) 133. (1) 143. (4)
104. (3) 114. (1) 124. (3) 134. (4) 144. (3)
105. (1) 115. (2) 125. (4) 135. (3) 145. (4)
106. (2) 116. (2) 126. (1) 136. (1) 146. (1)
107. (3) 117. (1) 127. (1) 137. (3) 147. (3)
108. (2) 118. (2) 128. (4) 138. (4) 148. (3)
109. (1) 119. (4) 129. (4) 139. (4) 149. (1)
110. (2) 120. (1) 130. (4) 140. (4) 150. (4)
10
ZOOLOGY
151. (1) 161. (2) 171. (1) 181. (3) 191. (2)
152. (3) 162. (1) 172. (3) 182. (1) 192. (4)
153. (2) 163. (4) 173. (4) 183. (4) 193. (1)
154. (1) 164. (3) 174. (4) 184. (3) 194. (4)
155. (1) 165. (1) 175. (1) 185. (3) 195. (2)
156. (2) 166. (4) 176. (1) 186. (4) 196. (2)
157. (1) 167. (1) 177. (1) 187. (3) 197. (4)
158. (1) 168. (4) 178. (2) 188. (2) 198. (2)
159. (4) 169. (2) 179. (3) 189. (3) 199. (3)
160. (2) 170. (2) 180. (2) 190. (3) 200. (3)
11