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AITS PRACTICE SHEET

12th NEET (2024)

AITS Test No.: 03 Date: dd/mm/yyyy

(CHEMISTRY)
Syllabus: AITS-2+ d and f - Block Elements The p-Block Elements Electrochemistry Aldehydes;
Ketones and Carboxylic acids Organic compounds containing nitrogen Biomolecules
(Chemistry) Chemical kinetics Principles Related to Practical Chemistry.

1. Which one of the following does not show (2) Bromobenzene


paramagnetic behavior? (3) Chloroethene
(1) [Fe(H2O)6]2+ (2) [Ni(CN)6]4– (4) Isopropyl chloride
2+
(3) [Mn(CO)6] (4) [CrCl6]2+
7. If 0.15 g of solute, dissolved in 15 g of solvent, is
2. Which of the following is the strongest acid? boiled at a temperature higher by 0.216°C, than that
of the pure solvent, the molecular weight of the
substance is (molal elevation constant for the
solvent is 2.16°C;
(1) (2) (1) 1.01 (2) 10
(3) 10.1 (4) 100

8. Which of the following orders regarding thermal


stability of hydrides MH3 of group 15 is correct?
(1) NH3 > PH3 > AsH3
(3) (4) (2) NH3 < PH3 < AsH3
(3) NH3 > PH3 < AsH3
(4) NH3 < PH3 > AsH3

3. Identify (B) in the following reaction, 9. When phenol is treated with CHCl3 and NaOH, the
Acetaldehyde ⎯⎯⎯ HCN
→ A ⎯⎯⎯H2 O
→B ; product formed is;
(1) CH3COOH (2) CH3CHOCOOH (1) Benzaldehyde (2) Salicylaldehyde
(3) CH3CH2NH2 (4) CH3CONH2 (3) Salicylic acid (4) Benzoic acid

4. 2-bromopentane is heated with potassium ethoxide 10. Reason of lanthanoid contraction is;
in ethanol. The major product obtained is; (1) Negligible screening effect of f-orbitals
(1) 2-ethoxypentane (2) Increasing nuclear charge
(2) pentene-1 (3) Decreasing nuclear charge
(3) trans-pentene-2 (4) Decreasing screening effect
(4) cis-pentane-2
11. Which of the following is correct statement?
5. Which one of the following has zero crystal field (1) F2 has higher dissociation energy than Cl2
stabilisation energy? (2) F has higher electron affinity than Cl
(1) [Mn(H2O)6]3+ (2) [Fe(H2O)6]3+ (3) HF is stronger acids that HCl
(3) [Co(H2O)6]2 (4) [Co(H2O)6]3+ (4) Boiling point increases down the group in
halogens
6. Which of the following can be used as the halide
component for Friedel-Crafts reaction? 12. XeF2 and XeF6 are separately hydrolysed then;
(1) Chlorobenzene (1) Both give out O2
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(2) XeF6 gives O2 and XeF2 does not
(3) XeF2 alone gives O2
(4) Neither of them gives HF
19. Match List I with List II;
13. The quantity of electricity required to completely List I List II
oxidise 0.1 mole of MnO24− to MnO−4 is; A I Hell-Volhard-
(1) 96500 C (2) 2×96500 C Zelinsky
(3) 9650 C (4) 96.50 C reaction
B II Gattermann-
14. Lassaigne’s test can detect; Koch reaction
(1) Nitrogen, Sulphur, Halogens C R–CH2–OH+RCOOH III Haloform
(2) Nitrogen, Cyanides, Sulphur ⎯⎯⎯⎯⎯
Conc.H2SO4
→ reaction
(3) Sodium, Sulphur, Halogens, Phosphorus D R–CH2–COOH IV Esterification
() 2
⎯⎯⎯⎯⎯ →
i X /Red P
(4) Sulphur, Halogens, Phosphorus
(ii ) H O
2

(1) A-IV, B-I, C-II, D-III


15. The correct order of reactivity of PhMgBr with,
(2) A-III, B-II, C-I, D-IV
(3) A-I, B-IV, C-III, D-II
(4) A-II, B-III, C-IV, D-I

(1) I > II > III (2) III > II > I


20. Match List I with List II;
(3) II > III > I (4) I > III > II
List I List II
A AlCl3 if  = 0.8 I i = 3.4
16. Which of the following is the weakest acid?
B BaCl2 if  = 0.9 II i = 2.8
C Na3PO4 if  = 0.9 III i = 3.8
D K4[Fe(CN)6]if  = 0.7 IV i = 3.7
(1) (2) CH3COOH (1) A-III, B-IV, C-II, D-I
(2) A-I, B-IV, C-II, D-III
(3) A-I, B-II, C-IV, D-III
(3) HCOOH (4) (4) A-II, B-I, C-IV, D-III

21. Assertion(A): Molar conductivity increases with


17. Gabriel phthalimide synthesis is used in the decrease in concentration for weak electrolytes.
preparation of; Reason(R): No. of ions increases and No. of ions
(1) 1° amine per unit volume decreases due to dilution.
(2) 2° amine (1) Both Assertion (A) and Reason (R) are true,
(3) 3° amine and Reason (R) is a correct explanation of
(4) 4° amine Assertion (A).
(2) Both Assertion (A) and Reason (R) are true, but
18. The correct order of basicities of the following Reason (R) is not a correct explanation of
compounds is; Assertion (A).
(3) Assertion (A) is true, but Reason (R) is false.
(4) Assertion (A) is false, but Reason (R) is true.

22. Assertion(A): Carbylamine reaction involves


chemical reaction between 1° amine and chloroform
in basic medium.
Reason(R): In carbylamine reaction, –NH2 group
changes into –NC group.
(1) II >I >III > IV (1) Both Assertion (A) and Reason (R) are true,
(2) I > III > II > IV and Reason (R) is a correct explanation of
(3) III > I > II > IV Assertion (A).
(4) I> II> III > IV

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(2) Both Assertion (A) and Reason (R) are true, but (1) Statement I and Statement II both are correct.
Reason (R) is not a correct explanation of (2) Statement I and Statement II both are incorrect.
Assertion (A). (3) Statement I is correct, but Statement II is
(3) Assertion (A) is true, but Reason (R) is false. incorrect.
(4) Assertion (A) is false, but Reason (R) is true. (4) Statement I is incorrect, but Statement II is
23. Assertion(A): Lower aldehydes and ketones are correct.
soluble in water but the solubility decreases as the
molecular mass increase. 25. Statement-I: For exothermic reaction equilibrium
Reason(R): Distinction between aldehydes and constant decreases with increase in temperature.
ketones can be made by Tollens’ reagent. Statement-II: For exothermic reaction rate
(1) Both Assertion (A) and Reason (R) are true, constant decreases with decrease in temperature.
and Reason (R) is a correct explanation of (1) Statement I and Statement II both are correct.
Assertion (A). (2) Statement I and Statement II both are incorrect.
(2) Both Assertion (A) and Reason (R) are true, but (3) Statement I is correct, but Statement II is
Reason (R) is not a correct explanation of incorrect.
Assertion (A). (4) Statement I is incorrect, but Statement II is
(3) Assertion (A) is true, but Reason (R) is false. correct.
(4) Assertion (A) is false, but Reason (R) is true.

24. Statement-I: Purine base present in DNA are


adenine and guanine.
Statement-II: The base thymine is present in RNA
whereas base uracil is present in DNA.
■■■

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AITS PRACTICE SHEET
12th NEET (2024)

AITS Test No.: 03 Date: dd/mm/yyyy

Answer Key

1. (2) 14. (1)


2. (1) 15. (3)
3. (2) 16. (2)
4. (3) 17. (1)
5. (2) 18. (2)
6. (4) 19. (4)
7. (4) 20. (3)
8. (1) 21. (1)
9. (2) 22. (1)
10. (1) 23. (2)
11. (4) 24. (3)
12. (3) 25. (1)
13. (3)

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