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06-Lecture-2023 With Answer
06-Lecture-2023 With Answer
Chapter 6
Electronic
Structure of Atoms
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
1 | The Wave Nature of Light
▪ Knowledge about the electronic structure of atoms comes from light
either emitted or absorbed by substances
▪ the light we see with our eyes = visible light = type of electromagnetic
radiation.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ Waves are periodic X
▪ Distance between two adjacent peaks: wavelength (λ)
▪ The number of waves passing a given point per unit of time is the
frequency ( ).
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ electromagnetic radiations are due to the
periodic oscillations in the intensities of the
o electric fields
o magnetic fields
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Frequency : cycles per second
▪ hertz (Hz).
▪ sˉ¹
▪ /s
Electronic
Structure
of Atoms
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▪ No
▪ Both visible light & X-rays are forms of electromagnetic radiation.
▪ They therefore both travel at the speed of light, c.
▪ Their differing ability to penetrate skin is due to their different energies
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Infrared light
The expanded visible-light portion of Figure 6.4 tells you that red light has
a longer wavelength than blue light.
© 2015 Pearson Education, Inc.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
2 | Quantized Energy and Photons
Wave model cannot express some aspects of light
(1)
the emission of light from hot objects (referred to as blackbody radiation
because the objects studied appear black before heating)
(2)
The emission of electrons from metal surfaces on which light shines (the
photoelectric effect)
(3)
the emission of light from electronically excited gas atoms (emission
spectra).
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
• When solids are heated
• They emit radiation
H : Planck constant
6.626 x 10-34 joule.second (J.s) Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Max Planck
▪ Matter can emit and absorb energy only in wholenumber multiples of
h, such as h, 2hn, 3h…
▪ Matter at the atomic level, the impact of quantized energies is far more
significant Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Albert Einstein
▪ Light shining on a clean metal surface
causes electrons to be emitted from the
surface.
▪ A minimum frequency of light, different
for different metals, is required for the
emission of electrons.
▪ Any excess energy of the photon is converted into kinetic energy of the
emitted electron.
Einstein won the Nobel Prize in Physics in 1921 primarily for his
explanation of the photoelectric effect. Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
(a) E = h
E = 6.626x10-34 J.s x 4.69x1014s -1
E = 31.1 x 10 -20 J this is the energy of one photon
(b) Total Energy = E x number of photons
= 31.1 x 10-20 x 5.0 x 1017
= 155.5 x 10-3 J this is the total energy of all photons
(c) Number of emitted photons = total energy / energy of a photon
= 1.3x10-2 / 31.1 x 10-20
= 4.18x1016 Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
3 | Line Spectra and the Bohr Model
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ H has 4 lines: Johann Balmer (1885) discovered a simple formula
relating the four lines to integers.
▪ Johannes Rydberg advanced this formula
Electronic
Structure
▪ Neils Bohr explained why this mathematical relationship works. of Atoms
© 2015 Pearson Education, Inc.
Electrons in an atom:
E = h
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Bohr calculated the energies corresponding to the allowed orbits for
the electron in the hydrogen atom.
Excited state
When the electron is in a higher-energy state
(n = 2 or higher)
zero - energy
Electronic
Structure
ofAtoms
© 2015 Pearson Education, Inc.
Electrons jump from one allowed orbit to another by either absorbing X
or emitting photons
o The electron must absorb energy in order to move to a higher-
energy state (higher value of n)
o Radiant energy is emitted when the electron jumps to a lower-
energy state (lower value of n)
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ Transition when an electron moves from ni = 3 to nf = 1 X
▪ A photon is emitted during this transition, and the energy of the photon
is equal to
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Bohr model explains
1. Electrons exist only in certain discrete energy levels, which are
described by quantum numbers.
.
2. Energy is involved in the transition of an electron from one level to
another.
h: Planck’s constant
mv: momentum of a particle
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Homework
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Dual Nature of Electrons
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Wave properties of matter (dual nature of
electron)
For big masses (ball)
❖ Position
❖ Direction of motion
❖ Speed at any instant
▪ the uncertainty in the position of the electron in the atom is greater than
the size of the atom.
Electronic
▪ we have essentially no idea where the electron is located in the atom. Structure
of Atoms
© 2015 Pearson Education, Inc.
De Broglie’s hypothesis and Heisenberg’s
uncertainty principle
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
5 | Quantum Mechanics and Atomic Orbitals
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ Statistically : we can know the probably location of an electron at a
given instant
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ Electrons on guitar string:
▪ Standing waves:
▪ Waves do not travel in space
Electronic
Structure
ofAtoms
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Representation of atom: nucleus
surrounded by an electron cloud
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
▪ The solution to Schrödinger’s equation for the hydrogen atom yields a
set of wave functions called orbitals.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Shell : electrons in same n
X
All the orbitals n = 3, for example, are said to be in the third shell.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
1. The shell with principal quantum number n consists of exactly
X
subshells.
n = 1 : 1 subshell
# of subshells (l): 0 (n -1): 1s
n = 2 : 2 subshell
# of subshells (l): 0, 1: 2s, 2p
n = 3 : 3 subshell
# of subshells (l): 0, 1, 2: 3s, 3p, 3d
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
6 | Representation of Orbitals
spherically symmetric: electrons are same distance away from
nucleus regardless of direction
Electronic
Structure
ofAto ms
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Trends in radial probability distribution
1. # of peaks = n
outermost peak is larger than inner peaks
2. # of nodes: n-1
3. As n increases, the electron density becomes more spread out, there is a
greater probability of finding the electron further from the nucleus.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ l =1
▪ They have two lobes with a node between them.
▪ Beginning with the n = 2 shell, each shell has three p orbitals
▪ Each p subshell has three orbitals, corresponding to the
three allowed values of ml: -1, 0, and 1
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
d orbitals
▪ n = 3 or greater & l = 2
▪ five 3d and five 4d …for the ml quantum number : -2, -1, 0, 1, and 2
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
f orbitals
▪ n >= 4
▪ there are 7 equivalent f orbitals (for which l = 3). The shapes of the f
orbitals are complicated
▪ electronic structure of atoms in the lower part of the periodic table
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
7 | Many-Electron Atoms
quantum mechanics: hydrogen atom : only one electron
many-electron atom :
▪ nature of orbitals
▪ their relative energies
▪ how the electrons populate the available orbitals
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ for same value of n, the energy of an
orbital increases with increasing value
of l
▪ ms = +1/2 or -1/2
unpaired electron
paired electrons
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
new shell I A
group
p orbitals have
same energy
Hund’s Rule
electrons have paralel spins
a carbon atom in its ground state
has two unpaired electrons
Hund’s rule : for degenerate orbitals the lowest energy is attainedElectronic
when the number of electrons having the same spin is maximized Structure
of Atoms
© 2015 Pearson Education, Inc.
X
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ total number of orbitals in each shell equals n2: 1, 4, 9, or 16. X
▪ two electrons in each orbital: electron # in each shell: 2n2 electrons:
2, 8, 18, or 32.
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ d block X
▪ 10 columns
▪ containing the transition metals
▪ valence d orbitals are being filled d block
▪ f block metals
▪ 14 columns valence f orbitals are being filled
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
Write the electron configuration of Selenium (Se, element 34) X
▪ Locate Se in the table and then move backward until we come to the
noble gas that precedes Se.
▪ In this case, the noble gas is argon, Ar, element 18. Thus, the noble-
gas core for Se is [Ar]
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
➢ Write symbols for the outer electrons
➢ Because K is in the fourth period and the s block, we begin with the 4s
electrons, meaning our first two outer electrons are written 4s2
➢ We then move into the d block, which begins with the 3d electrons. (The
principal quantum number in the d block is always one less than that of
the preceding elements in the s block.)
s2 p2
2nd and 3rd row
4 A group elements
Electronic
Structure
of Atoms
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X
4th period
4s2
3d7
b) 5th period
[Kr] 4d¹º5s²5p¹
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
▪ for representative elements we do not consider the electrons in
X
completely filled d or f subshells to be valence electrons
Electronic
Structure
of Atoms
© 2015 Pearson Education, Inc.
X
▪ the electron configurations of certain elements appear to
violate the rules
Chromium (24)
Copper (29)