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Guided Plan-5 (E)
Guided Plan-5 (E)
3. + CH2Cl2 + AlCl3 X
(excess)
X + NBS Y
Hydrolysis
Y Z
Correct option regarding X, Y, Z.
(A) Z when reacts with lucas reagent, white turbidity is formed within 5-10 minutes.
(B) Maximum number of benzonoid structures X can have is two.
(C) Z when reacts with PCC, benzophenone is formed as product.
(D) Y when reacts with silver nitrate, white precipitate is formed instant.
O O
(i) NaOCH2CH3, Ethanol KOH.H2O H3O
4. CH3—C—CH2—C—OCH2CH3
Heat
(ii) CH2Cl
Which of the following is the final product of the series of reactions shwon above :
O O O
(A) CH2—C—CH2—C—CH3 (B) CH2—O—C—CH2—CH3
O O O
(C) CH2—CH2—C—CH3 (D) CH3—C—CH—C—OH
OH
NO2
Codes :
(P) (Q) (R) (S)
(A) 4 3 1 2
(B) 2 3 1 4
(C) 3 2 1 4
(D) 2 4 1 3
SECTION-III : (Integer Value Correct Type)
This section contains 05 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 4(–1)
1. All the compounds which gives positive test with Bredy's reagent (2,4–DNP) and are having
molecular mass 100 are treated separately with NaBH4. Product of how many of these can be
used effectively to separate racemic mixture of 2-methylbutanoic acid.
excess of
?
D3O in D2O
How many hydrogen atoms are replaced by deuterium atoms in the major product ?
3. Find the difference between the number of optically active and optically inactive isomers of
4. Find all possible Lactones with six membered ring having molecular formula (C6H10O2),
which when reacts with (1) LiAlH4 (2) H2O gives meso diol.
1) LiAlH4
Lacton Meso diol.
2) H2O
O
O
9 1 2 Br2 / FeBr3
5. 8 3 products.
7 6 5 4
major organic product will have Bromine at position.
1. Column-I Column-II
(A) CH3 Cl NaOH CH3OH NaCl (P) Rate of reaction increases in
polar protic solvent
(B) CH3 Cl NH3
CH3 NH2 HCl (Q)Rate of reaction increases in
polar aprotic solvent
Me
(C) S + NH3
Me NH2 Me2S (R) SN2 mechanism
Me Me
Cl OMe OMe
(D) + MeOH
+ (S) SN1 mechanism
(T) TS has positive charge