NEET Full Test – 4

Section – Chemistry

SECTION A – Compulsory Questions

Q51. The rate of reaction doubles when the
temperature changes from 300 to 310 K. The
activation energy of this reaction is
(Assume activation energy and pre-
exponential factor are independent of
temperature.) ℓn(2) = 0.693; R =
8.314 J mol−1 K −1 ) :-
(1) 53.6 kJ mol−1
(2) 214.4 kJ mol−1
(3) 107.2 kJ mol−1
(4) 26.8 kJ mol−1
Q52. The enthalpy of Hydrogenation of
cyclohexene and benzene are −119 kJ mol−1
and −208 kJ mol−1 respectively. Find the
resonance energy of benzene.
(1) −59 kJ mol−1
(2) −149 kJ mol−1
(3) −298 kJ mol−1
(4) −74.5 kJ mol−1
Q53. One mole of PCl5 were heated in a
closed vessel of 2 L. At equilibrium 20% of
PCl5 is dissociated into PCl3 and Cl2 . The
Q56. Factors which affect equilibrium
constant :-
(A) Concentration of reactant.
(B) Pressure at which reaction take place
(C) Presence of catalyst
(D) temperature at which reaction take place
(E) Method of writing balanced equation
(F) Time take by the reaction
(1) A, B, C
(2) D, E, F
(3) C, D, E
(4) D, E
Q57. Which of the following is incorrect?
(a) FeCl3 is used in detection of phenols.
(b) Fehling solution is used in detection of
glucose.
(c) Tollen's reagent is used in detection of
unsaturation.
(d) NaHSO3 is used in detection of carbonyl
compounds.
Q58. Consider the following E ∘ values
o 0
EZn/Zn 2+ = x Volt ; ECu2+ /Cu = y Volt The

value of equilibrium constant is :- standard potential for the reaction

(1) 0.267 Zn(s) + Cu2+ (aq) → Zn2+ (aq) + Cu(s) is :-
(2) 0.05 (1) 𝑥 − 𝑦 Volt
(3) 0.025 (2) 𝑦 − 𝑥 Volt
(4) 5.3 (3) 𝑥 + 𝑦 Volt
Q54. For given transitions order of wavelength (4) −(𝑥 + 𝑦) Volt
of photon emitted will be :- Q59. For combustion of one mole acetone into
(A) 6 → 4 CO2 and H2 O, moles of electron transferred
(B) 4 → 2 during redox reaction :-
(C) 3 → 1 (1) 4
(D) 2 → 1 (2) 16
(1) 𝜆C > 𝜆D > 𝜆B > 𝜆A (3) 8
(2) 𝜆C < 𝜆D < 𝜆B < 𝜆A (4) 4
(3) 𝜆A > 𝜆B > 𝜆D < 𝜆C
Q60. Which of the following are not a
(4) 𝜆D < 𝜆C < 𝜆A < 𝜆B
constant value between two given
Q55. For the reaction 2 N2 O5 ( g) → thermodynamic states of a given system?
4NO2 ( g) + O2 ( g) If the concentration of O2 (i) 𝑞
increases by 2 × 10−3 M in 100 seconds then (ii) q + w
the rate of disappearance of N2 O5 is :- (iii) 𝑈 + 𝑃𝑉
(1) 4 × 10−3 Ms−1 (iv) H − TS
(2) 1 × 10−5 Ms−1 (1) (i) and (iv)
(3) 4 × 10−5 Ms−1 (2) (iii) and (iv)
(4) 2 × 10−5 Ms−1
(3) (ii) only Q66.
(4) (i) only
Q61. The relative lowering of vapour pressure
of an aqueous solution containing non-volatile
solute is 0.025 . The molality of the solution
is:
(1) 0.7
(2) 1.42
(3) 0.5
(4) 0.8
Q62. The pH value of decinormal solution of
NH4 OH, which is 25% ionised, is :
(1) 12.4
(2) 13.3
(3) 11.4
(4) 12.95
Q63. How many hydrogen atoms are present
in 0.35 moles of C6 H12 O6
(Given : NA = 6.023 × 1023 )
(1) 2.53 × 102 H-atoms
(2) 2.53 × 1024 H-atoms
(3) 2.53 × 1044 H-atoms
(4) 2.53 × 1048 H-atoms
Q64. Which of the following type of
isomerism is shown by given complex
compound?

Q67. The spin only magnetic moment (in BM )

and geometry of [Cu(NH3 )4 ]+2 are
(1) 2.83, Tetrahedral
(2) 1.73 , Tetrahedral
(3) 2.83, Square planar
(4) 1.73, Square planar

(a) Facial Q68. A compound of vanadium chloride has

(b) Meridional spin only magnetic moment of 1.73BM. The
(c) Cis formula of molecule is :-
(d) Both (b) and (c) (1) VCl2
(2) VCl5
Q65. The emf of the cell (3) VCl4
PtCl2 ( g)(P1 atm)/Cl− (aq) (1M) /Cl2 ( g)(P2 atm)Pt
(4) VCl3
will be positive when
Tricky Q69. Methanoic acid is heated with conc.
(a) P1 = P2 H2 SO4 to form
(c) P1 > P2 (1) CO2
(b) P 1 < P2 (2) CH4
(d) None of these (3) CO
(4) COOH
Q70. What is the final product (B) of this Q74. Which among the following allotrope's
sequence? of phosphorus is least reactive :-
(1) Red phosphorus
(2) White phosphorus
(3) Black phosphorus
(4) Pink Phosphorus
Q75. The most stable complex is :-
(1) [Fe(H2 O)6 ]3+
(2) [Fe(NH3 )6 ]3+
(3) [Fe(C2 O4 )3 ]3−
(4) [FeCl6 ]3−
Q76. Alcohol is less volatile than ether. This is
due to :-
(1) Dipole moment of ether
(2) Alcohol having dipole moment
(3) H-bond in ether
(4) H-bond in alcohol
Q77. The angle between the orbitals formed
by mixing of one s-orbital and two p-orbital is
(1) 180∘
(2) 120∘
Q71. Which of the following do not show (3) 109∘ 28′
geometrical isomerism :- (4) 150∘
(1) [Co(en)2 Cl2 ]Cl Q78. Which of the following compound is
(2) [Co(ox)3 ]−3 superoxide :-
(3) [Cr(NH3 )4 Cl2 ]Cl (1) KO2
(4) [Fe(NH3 )4 ClCO3 ] (2) BaO2
Q72. Amongst the following, the third (3) MnO2
ionization energy is highest for : (4) NO2
(1) Al Q79. At temperature 327∘ C and concentration
(2) Be C, osmotic pressure of a solution is P, the same
(3) B solution at concentration C/2 and at
(4) Mg temperature 427∘ C shows osmotic pressure of
Q73. Which of the following structure is more 2 atm, value of 𝑃 will be
12
stable? (a) 7
24
(b) 7
6
(c) 5
5
(d) 6
Q80. If sodium sulphate is considered to be
completely dissociated into cations and anions
in aqueous solution, the change in freezing
point of water (Δ𝑇𝑓 ), when 0.01 mol of
sodium sulphate is dissolved in 1 kg of water,
is (𝐾𝑓 = 1.86 K kg mol−1 )
(a) 0.372 K
(b) 0.0558 K
(c) 0.0744 K
(d) 0.0186 K
 Q81. In the given compounds, number of Q83.
secondary carbon atoms is respectively :
The incorrect statement is :
(1) A is formed through Kolbe's reaction
(2) B is salicylic acid
(3) C is methyl salicylate
(4) C is aspirin
Q84. Which of the following amines does not
react with Hinsberg's reagent?
(1) 6,4,10 (1) Benzyl amine
(2) 6,4,8 (2) N,N-Dimethyl aniline
(3) 5,6,8 (3) 2-Methyl aniline
(4) 7,4,8 (4) Para-toliudine
Q82. Which of the following statement is 1
Q85. In the Arrhenius plot of ln 𝑘Vs T, a
wrong ?
(1) More stable the carbocation, the faster it is linear plot is obtained with a slope of −2 ×
formed 104 K. The energy of activation of the reaction
(2) Propyl cation changes into more stable (in kJmole−1 ) is
isopropyl carbocation by 1,2-methyl shift ( R value is 8.3 J K −1 mol−1 )
(3) Isobutyl chloride reacts with sodium (a) 83
ethoxide to form mainly isobutene (b) 166
(4) Propyl halide reacts with sodium ethoxide (c) 249
to form1-ethoxy propane (d) 332

SECTION B – Questions with Choice

Q86. Which of the following reaction is incorrect: (2) 8
(3) 7
(4) 9
Q88.

Q87. Number of structural isomers formed by

C4 H6 is :
(1) 4
Q89. What is D ? (1) Absence of chirality centre
(2) Presence of more than 1 chiral center
(3) Dissymmetric structure
(4) Internal compensation
Q94. Which sodium salt will be heated with
sodalime to obtain propane?
(1) Primary amine
(2) An amide
(3) Phenyl isocyanate
(4) A chain lengthened hydrocarbon
Q90. Arrange in decreasing reactivity towards
Nucleophilic Substitution Reaction?

Q95.

(1) IV > II > I > III

(2) III > I > IV > II
(3) III > I > II > IV
(4) III > IV > I > II
Q91. Product formed in following reaction:

(1) C6 H5 OH and C2 H5 OH
(2) C6 H5 CH3 and CH3 OH
(3) C6 H5 CH2 OH and CH3 OH
(4) C6 H5 CH2 OH and C2 H5 OH
Q92. Arrange the following compounds in
decreasing order of acidity ?

Q96.

(1) III > II > IV > I

(2) III > IV > II > I
(3) IV > II > III > I
(4) IV > III > II > I
Q93. Which of the following is responsible for
inability of meso compound to show optical
inactivity?
Q97. Which of the following statements is
correct for the complex Ca2 [Fe(CN)5 O2 ]
having t 2 g 6 , eg 0 electronic configuration?
(a) 𝑑2 𝑠𝑝3 hybridised and diamagnetic
(b) 𝑠𝑝3 𝑑 2 hybridised and paramagnetic
(c) 𝑠𝑝3 𝑑2 hybridised and diamagnetic
(d) 𝑑2 𝑠𝑝3 hybridised and paramagnetic
Q98. A cyclic process 𝐴𝐵𝐶𝐷 is shown in P −
V diagram for an ideal gas. Which of the
following diagram represents the same
process?
Q100. Phenol on heating with CHCl3 and
NaOH gives salicylaldehyde. The reaction is
called:
(a) Reimer - Tiemann reaction
(b) Claisen reaction
(c) Cannizzaro's reaction
(d) Hell - Volhard - Zelinsky reaction

Q99. From given following equations and ΔH ∘

values, determine the enthalpy of reaction at
298 K for the reaction :
C2 H4 ( g) + 6 F2 ( g) ⟶ 2CF4 ( g) + 4HF(g)
H2 ( g) + F2 ( g) ⟶ 2HF(g); ΔH1∘ = −537 kJ
C(s) + 2 F2 ( g) ⟶ CF4 ( g); ΔH2∘ = −680 kJ
2C(s) + 2H2 ( g) ⟶ C2 H4 ( g); ΔH3∘ = 52 kJ

(a) -1165
(b) -2486
(c) +1165
(d) +2486