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IR

spectroswpymolecule.IR
i Too
r

ans
I Es
O

→ Bond S vis rate randomIs


DP이다 Might Change

/'
dontl.IR Made) do
(IR Act)

Over에 non Polar because


Polar
-

non -

He di pole are balanced


Molecular

O= C =
0

shiftswhenvibratedjpolaritychanged-theve.is

wrkdone-enersyabsorbe.cl from IR
to
less IR Leaves he moleale

Different bond absovbdifterentwavelengthsof.IR


11
% transmiHana Wavenumber Count )
1% IR ) ^

t!insevpvintregionheiit.li
100% in va cum M not anamed →

...

Thin Peak
Mass Spectrumetvy

IN NMR → sample received

Traditional its → sample is Change의 ; use a lot of sample

뺾毖.
M0
i
Close e)
IonisatI On

/ \ . m옮빲맶앖쏈읆 .
Molecular ion
iragme.ms

is ion
⇒ Only I

ion is delete d (signal )


The
positive
Results :
is Lost
The nomal ion

Relative abalance
^ Relative a bun da ne

abundantfragmentshli i.com
→ no Meaning in analysis
→ More stable = More

1t

I Mr
(Mass
charge ) =

element

① indtheheavies.tt agent (메리 +1

=
Molecular ion

② Find Me difference
t
(M 17 )
g)
-

M1t =
NMR (Nuclear Magnetic Resonance)

magnetic Moment
'
H nucleus has a

not Go I
o _ external B
Radio

frequency 1
/

www.cule-wideefted/f
High Electro negative element
-
→ have a
-

1
O
(0 , X ,
N)

Very an site technique and will


/
→ ,

4 diinguishbetween-C.tk and -
CH3

H
response
After entry H based distance

dependsonhowshielde.cl Me , on

H nucleus tre E
is by OH

浚必
c-c-c.ir

(5) 빲읂 I I I 1
HS 10W in ft
1t-7
C -
H unshielde.de
$0
-
H

Hydrogen Environment

geometry symme.tvy

I I I I I I I 1

-
c -

c -

c -

c - -
G C -

G0 -

c -

1 ( I I I I
1 I

(fl .it H
not The same

environme.int
same

∴ 2 H Environment
Distance mapping Distance from
oxygen

이에 대3 TH B
o
C00H01th
/
H C -

0-대3 '
te
9T대3
-

CH -

1
H
2
1 CHART
OH OH 심崧
∴ 5 H envivomont
NMR -
Low reSolution results

Integral Trace
Integral
f. = # of H in The en .

7
are

11111in f
5 O
4 3 2 1

Chemical shift 1ppm )


→ (en = 1 Peak
N MR High result

s_rt _split ingscausedbyneighbourH.eu


-
reSolution

ion mont

( OH
binding split)
-

.no

H
# of NightsOur H split by Peak S pattern

# i
2 H 3 .li# 1 : 2 : 1

3 H 4 IIIin 1 : 3 : 3 : I

causes

-
H nucleus is magnetic ,
nene

→ Head by external magnetic find


Ch -
Has 2H : Can ber 7 T ( www.rsy)

They aHey each other andng s ping
(
,

f d
magnetic held
y
-
When played in a ,
Honda an same was

→ Ali ga to The find ( www.rgy) CH3 d f


→ Anti alias to The held ( mesh entry )

ffmighenersstsumoftwirewgiesaffeet.me
_

neighbovins.tt ew
Tetramethyls.ie (TMD

CH3
Very Iowa
n

/
Gr
Si
_
→ H is almostfcunus.ua )

⇒ Standard
1 CH3
CH3 ⇒ TMS H response 0ppm 8
=

CH3

-
12 H in a Single Environment

vevytanpeak.no

spit ng-volatilekasiyevaporatedhremoveoD-TMSwnta.in
s C

l
and Si

'
si -
NMR

C -
N MR

→ Can ber Used for Multiple Cliffevent N MRS

* Ray Crystal tograph y


Crystal ( Lance)

of I mole ale

o Response i
X-ray
moni > te is as bond

g) DNA
length h
,
Believe
angle

Index of Hydrogen Define ng ( IH미 :

The number of H2 Molecular required to said rate an organic compound

Ring
4C10 have
1-1 IND =
,
6th -
) Saturn di GH , 4
\ -
/

ho.ofdoublebonds.EC IHD의

X = # of C+ N ( 2742) -

Y
IH D
Te

Y = # of H txt N
2

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