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  • s19 Ac Quim 10 Viellard Esteban 2

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    Esteban Mauricio Viellard Corrales
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    1. The document describes a series of chemical reactions involving chlorination and dechlorination of acetone and its derivatives. 2. Photochemical chlorination is used to add chlorine groups to acetone in several steps. 3. Basic hydrolysis or reaction with lithium and copper is then used to remove chlorine groups through dechlorination in other steps.

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    1. The document describes a series of chemical reactions involving chlorination and dechlorination of acetone and its derivatives. 2. Photochemical chlorination is used to add chlorine groups to acetone in several steps. 3. Basic hydrolysis or reaction with lithium and copper is then used to remove chlorine groups through dechlorination in other steps.

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    © All Rights Reserved
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    6 views1 page

    s19 Ac Quim 10 Viellard Esteban 2

    Uploaded by

    Esteban Mauricio Viellard Corrales
    1. The document describes a series of chemical reactions involving chlorination and dechlorination of acetone and its derivatives. 2. Photochemical chlorination is used to add chlorine groups to acetone in several steps. 3. Basic hydrolysis or reaction with lithium and copper is then used to remove chlorine groups through dechlorination in other steps.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 1

    H3C Cl Cl

    CH3 Zn
    CH3
    acetona
    H3C CH3

    CH3

    1 CH3 CH3

    2Cl2 Cl
    H3C
    H3 C CH3 hν
    Cl

    CH3
    2 CH3

    Cl NaOH OH
    H3C
    H3C
    acetona
    Cl Cl

    2Cl2
    3 CH4 Cl Cl
    hν
    Cl
    3Cl2
    4 CH4 Cl
    hν
    Cl

    Cl2 Cl
    5 H3C
    H3C CH3 hν

    CH3 OH
    6 Li/Cu Cl
    H3C
    OH
    + Cl Cl

    Cl H3C CH3

    7 OH Li/Cu Cl OH
    Cl + Cl Cl

    H3 C CH3
    H3C CH3

    8 Cl OH Li/Cu OH

    + Cl Cl Cl

    H3C CH3
    H3 C CH3

    Cl Cl
    Cl Li/Cu
    9 Cl +H C 3
    Cl

    Cl CH 3

    Cl Cl Cl OH
    10 OH
    Li/Cu
    + Cl

    H3C CH3
    H3C CH3
    CH 3
    CH3

    12
    11
    Cl OH
    Cl Cl H3C
    NaCl Zn CH3
    +
    H acetato
    CH3
    H3C CH3
    H3C CH3
    CH3
    CH3

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