Alexandria University

Faculty of Engineering

Gas & Petrochemical Department

Submitted to DR : Hassan Farag

Name : Aya Allah Mahmoud

ID:5632
1. Introduction

2. MSDS “handling & storge”

2.1.CL2
2.2.HCL
2.3.H2O2
2.4.H2SO4
2.5.NH4NO3
2.6.HNO3

3. References
What is a Material Safety Data Sheet (MSDS)?

A Material Safety Data Sheet (MSDS) is a document that contains information on

the potential hazards (health, fire, reactivity and environmental) and how to work
safely with the chemical product. It is an essential starting point for the
development of a complete health and safety program. It also contains information
on the use, storage, handling and emergency procedures all related to the hazards
of the material. The MSDS contains much more information about the material
than the label. MSDSs are prepared by the supplier or manufacturer of the
material. It is intended to tell what the hazards of the product are, how to use the
product safely, what to expect if the recommendations are not followed, what to do
if accidents occur, how to recognize symptoms of overexposure, and what to do if
such incidents occur.

Handling and storage

Precautions for safe handling:

Protective measures: Put on appropriate personal protective equipment . Contains
gas under pressure. Do not get in eyes or on skin or clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Do not puncture or incinerate container. Use equipment rated for cylinder
pressure. Close valve after each use and when empty. Protect cylinders from
physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for
cylinder movement. Avoid release to the environment. Empty containers retain
product residue and can be hazardous. Keep away from clothing, incompatible
materials and combustible materials. Do not breathe gas. Keep reduction valves
free from grease and oil.

Advice on general occupational hygiene: Eating, drinking and smoking should be

prohibited in areas where this material is handled, stored and processed. Workers
should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. See
also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities: Store in accordance

with local regulations. Store in a segregated and approved area. Store away from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible
materials . Cylinders should be stored upright, with valve protection cap in place,
and firmly secured to prevent falling or being knocked over. Cylinder temperatures
should not exceed 52 °C (125 °F). Store locked up. Separate from reducing agents
and combustible materials. Store away from grease and oil. Keep container tightly
closed and sealed until ready for use. See Section 10 for incompatible materials
before handling or use.

Handling: Wear personal protective equipment. Use only in well-ventilated areas.

Provide sufficient air exchange and/or exhaust in work rooms. Avoid contact with
skin, eyes and clothing. Do not breathe vapors or spray mist. Do not ingest. When
using, do not eat, smoke, or drink. Keep away from incompatible materials. Handle
in accordance with good industrial hygiene and safety practice. Wash thoroughly
after handling. Containers of this material may be hazardous when empty since
they retain product residues (vapors, liquids). Observe all warnings and
precautions listed for the product Use caution when combining with water. DO
NOT add water to acid. ALWAYS add acid to water while stirring to prevent
release of heat, steam, and fumes.

Storage: Store in a cool, dry, ventilated area away from incompatible materials.
Store in original container. Keep containers tightly closed and upright. Keep away
from food, drink and animal feedingstuffs. Keep out of the reach of children .

Handling: Use only in well-ventilated areas. Keep/Store away from clothing/

combustible materials. Wear personal protective equipment. Never return unused
hydrogen peroxide to original container. Contamination may cause decomposition
and generation of oxygen gas whichcould result in high pressures and possible
container rupture. Empty drums should be triplerinsed with water before
discarding. Utensils used for handling hydrogen peroxide shouldonly be made of
glass, stainless steel, aluminum or plastic. Pipes and equipment should
bepassivated before first use. Hydrogen peroxide should be stored only in vented
containersand transferred only in a prescribed manner.

Storage: Keep containers in cool areas out of direct sunlight and away from
combustibles. Providemechanical general and/or local exhaust ventilation to
prevent release of vapor or mist intowork environment. Containers must be vented.
Keep/store only in original container. Storerooms or warehouses should be made
of non-combustible materials with impermeablefloors. In case of release, spillage
should flow to safe area. Containers should be visuallyinspected on a regular basis
to detect any abnormalities (swollen drums, increases intemperature, etc.).

Incompatible products: Combustible materials. Copper alloys, galvanized iron.

Strong reducing agents. Heavymetals. Iron. Copper alloys. Contact with metals,
metallic ions, alkalis, reducing agents andorganic matter (such as alcohols or
terpenes) may produce self-accelerated thermal decomposition.

Precautions for safe handling: Avoid contact with skin, eyes, and clothing.Follow
good hygiene procedures when handling chemical materials.Follow proper
disposal methods.Do not eat, drink, smoke, or use personal products when
handling chemical substances.

Conditions for safe storage, including any incompatibilities: Store in a cool

location. Keep away from food and beverages.Protect from freezing and physical
damage.Provide ventilation for containers. Keep container tightly sealed.Store
away from incompatible materials.
Handling: Wear personal protective equipment/face protection. Ensure adequate
ventilation. Avoiddust formation. Avoid contact with skin, eyes or clothing. Avoid
ingestion and inhalation. Keep away from clothing and other combustible
materials.

Storage: Keep containers tightly closed in a dry, cool and well-ventilated place.
Do not storenearcombustible materials. Incompatible Materials. Strong oxidizing
agents. Strongreducingagents. Strong acids. Finely powdered metals. Combustible
material.

Precautions for safe handling: Avoid dust formation.

Advice on general occupational hygiene:Wash hands before breaks and after

work. Keep away from food, drink and animal feedingstuffs.

Conditions for safe storage, including any incompatibilities:Store in a dry place.

Keep container tightly closed. Hygroscopic solid.

Incompatible substances or mixtures:Observe hints for combined storage.

Keep/store away from clothing/combustible materials. Take any precaution to
avoid mixing with combustibles.

Control of effects,Protect against external exposure, such as humidity, UV-

radiation/sunlight, direct light irradiation

Consideration of other advice: Specific designs for storage rooms or vessels

Recommended storage temperature: 15 – 25 °C

Precautions for safe handling

Provide adequate ventilation as well as local exhaustion at critical locations.

Handle and open container with care. Clear contaminated areas thoroughly.

Advice on general occupational hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal
feedingstuffs.

Conditions for safe storage, including any incompatibilities

Store in a well-ventilated place. Keep container tightly closed. Keep only in

original container. May causedecomposition by long-term light influence.

• Incompatible substances or mixtures

Observe hints for combined storage.
• Protect against external exposure, such as:
UV-radiation/sunlight, contact with air/oxygen

Consideration of other advice:

Specific designs for storage rooms or vessels

Recommended storage temperature: 15 – 25 °C

• https://www.ccohs.ca/oshanswers/legisl/msdss.html
• https://www.airgas.com/msds/001015.pdf
• https://sds.chemtel.net/webclients/safariland/finished_goods/Pioneer%20Forensics%20-
%20PF021%20-%20PF022%20-%20Hydrochloric%20Acid.pdf
• https://www.h2o2.com/files/PeroxyChem%20SDS%20OxyPure%2050.pdf
• https://beta-
static.fishersci.com/content/dam/fishersci/en_US/documents/programs/education/regulatory-
documents/sds/chemicals/chemicals-s/S25899.pdf
• https://www.carlroth.com/medias/SDB-X988-GB-
EN.pdf?context=bWFzdGVyfHNlY3VyaXR5RGF0YXNoZWV0c3wyNjIxNTF8YXBwbGljYX
Rpb24vcGRmfHNlY3VyaXR5RGF0YXNoZWV0cy9oNjUvaDFiLzkwMTUzMDQyMjQ3OTg
ucGRmfDZjZGU1NDNjNTUyOGRlMDE3OGQzMGIzODE2ZWUwMTM1YTRlZTkxMzIzM
DYxMDk5MjIzZjYyYzM3YWI3YjJiMjY